Atomic-layered Au clusters on α-MoC as catalysts for the low-temperature water-gas shift reaction
Abstract
Here, the water-gas shift (WGS) reaction (where carbon monoxide plus water yields dihydrogen and carbon dioxide) is an essential process for hydrogen generation and carbon monoxide removal in various energy-related chemical operations. This equilibrium-limited reaction is favored at a low working temperature. Potential application in fuel cells also requires a WGS catalyst to be highly active, stable, and energy-efficient and to match the working temperature of on-site hydrogen generation and consumption units. We synthesized layered gold (Au) clusters on a molybdenum carbide (α-MoC) substrate to create an interfacial catalyst system for the ultralow-temperature WGS reaction. Water was activated over α-MoC at 303 kelvin, whereas carbon monoxide adsorbed on adjacent Au sites was apt to react with surface hydroxyl groups formed from water splitting, leading to a high WGS activity at low temperatures.
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- Peking Univ., Beijing (China)
- Dalian Univ. of Technology, Dalian (China)
- Univ. of Chinese Academy of Sciences, Beijing (China); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Chinese Academy of Sciences, Shanxi (China); Synfuels China, Beijing (China)
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Taiyuan Univ. of Technology, Shanxi (China)
- Lehigh Univ., Bethlehem, PA (United States)
- Chinese Academy of Sciences (CAS), Beijing (China)
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States); Brookhaven National Laboratory (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1418304
- Alternate Identifier(s):
- OSTI ID: 1411142
- Report Number(s):
- BNL-114190-2017-JA
Journal ID: ISSN 0036-8075; ark:/13030/qt92s96063; TRN: US1801262
- Grant/Contract Number:
- AC02-05CH11231; SC0012704
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Science
- Additional Journal Information:
- Journal Volume: 357; Journal Issue: 6349; Journal ID: ISSN 0036-8075
- Publisher:
- AAAS
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Yao, Siyu, Zhang, Xiao, Zhou, Wu, Gao, Rui, Xu, Wenqian, Ye, Yifan, Lin, Lili, Wen, Xiaodong, Liu, Ping, Chen, Bingbing, Crumlin, Ethan, Guo, Jinghua, Zuo, Zhijun, Li, Weizhen, Xie, Jinglin, Lu, Li, Kiely, Christopher J., Gu, Lin, Shi, Chuan, Rodriguez, José A., and Ma, Ding. Atomic-layered Au clusters on α-MoC as catalysts for the low-temperature water-gas shift reaction. United States: N. p., 2017.
Web. doi:10.1126/science.aah4321.
Yao, Siyu, Zhang, Xiao, Zhou, Wu, Gao, Rui, Xu, Wenqian, Ye, Yifan, Lin, Lili, Wen, Xiaodong, Liu, Ping, Chen, Bingbing, Crumlin, Ethan, Guo, Jinghua, Zuo, Zhijun, Li, Weizhen, Xie, Jinglin, Lu, Li, Kiely, Christopher J., Gu, Lin, Shi, Chuan, Rodriguez, José A., & Ma, Ding. Atomic-layered Au clusters on α-MoC as catalysts for the low-temperature water-gas shift reaction. United States. https://doi.org/10.1126/science.aah4321
Yao, Siyu, Zhang, Xiao, Zhou, Wu, Gao, Rui, Xu, Wenqian, Ye, Yifan, Lin, Lili, Wen, Xiaodong, Liu, Ping, Chen, Bingbing, Crumlin, Ethan, Guo, Jinghua, Zuo, Zhijun, Li, Weizhen, Xie, Jinglin, Lu, Li, Kiely, Christopher J., Gu, Lin, Shi, Chuan, Rodriguez, José A., and Ma, Ding. Fri .
"Atomic-layered Au clusters on α-MoC as catalysts for the low-temperature water-gas shift reaction". United States. https://doi.org/10.1126/science.aah4321. https://www.osti.gov/servlets/purl/1418304.
@article{osti_1418304,
title = {Atomic-layered Au clusters on α-MoC as catalysts for the low-temperature water-gas shift reaction},
author = {Yao, Siyu and Zhang, Xiao and Zhou, Wu and Gao, Rui and Xu, Wenqian and Ye, Yifan and Lin, Lili and Wen, Xiaodong and Liu, Ping and Chen, Bingbing and Crumlin, Ethan and Guo, Jinghua and Zuo, Zhijun and Li, Weizhen and Xie, Jinglin and Lu, Li and Kiely, Christopher J. and Gu, Lin and Shi, Chuan and Rodriguez, José A. and Ma, Ding},
abstractNote = {Here, the water-gas shift (WGS) reaction (where carbon monoxide plus water yields dihydrogen and carbon dioxide) is an essential process for hydrogen generation and carbon monoxide removal in various energy-related chemical operations. This equilibrium-limited reaction is favored at a low working temperature. Potential application in fuel cells also requires a WGS catalyst to be highly active, stable, and energy-efficient and to match the working temperature of on-site hydrogen generation and consumption units. We synthesized layered gold (Au) clusters on a molybdenum carbide (α-MoC) substrate to create an interfacial catalyst system for the ultralow-temperature WGS reaction. Water was activated over α-MoC at 303 kelvin, whereas carbon monoxide adsorbed on adjacent Au sites was apt to react with surface hydroxyl groups formed from water splitting, leading to a high WGS activity at low temperatures.},
doi = {10.1126/science.aah4321},
journal = {Science},
number = 6349,
volume = 357,
place = {United States},
year = {Fri Jul 28 00:00:00 EDT 2017},
month = {Fri Jul 28 00:00:00 EDT 2017}
}
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- Energy & Environmental Science, Vol. 12, Issue 12
Carbon vacancy defect-activated Pt cluster for hydrogen generation
journal, January 2019
- Bao, Xiaobing; Gong, Yutong; Chen, Yuzhuo
- Journal of Materials Chemistry A, Vol. 7, Issue 25
Controlled synthesis of 2D Mo 2 C/graphene heterostructure on liquid Au substrates as enhanced electrocatalytic electrodes
journal, July 2019
- Sun, Wenyu; Wang, Xinqi; Feng, Jingqi
- Nanotechnology, Vol. 30, Issue 38
Recent advances in the precise control of isolated single-site catalysts by chemical methods
journal, June 2018
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Effect of Nickel Oxide Doping to Ceria-Supported Gold Catalyst for CO Oxidation and Water-Gas Shift Reactions
journal, November 2018
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- Catalysts, Vol. 8, Issue 12
Recent Advances in the Gold-Catalysed Low-Temperature Water–Gas Shift Reaction
journal, December 2018
- Carter, James H.; Hutchings, Graham J.
- Catalysts, Vol. 8, Issue 12
Hierarchical AuNPs-Loaded Fe3O4/Polymers Nanocomposites Constructed by Electrospinning with Enhanced and Magnetically Recyclable Catalytic Capacities
journal, October 2017
- Guo, Rong; Jiao, Tifeng; Xing, Ruirui
- Nanomaterials, Vol. 7, Issue 10
The Multifaceted Reactivity of Single-Atom Heterogeneous Catalysts
text, January 2018
- Mitchell, Sharon; Vorobyeva, Evgeniya; Pérez-Ramírez, Javier
- ETH Zurich
Atomic cobalt as an efficient electrocatalyst in sulfur cathodes for superior room-temperature sodium-sulfur batteries
journal, October 2018
- Zhang, Bin-Wei; Sheng, Tian; Liu, Yun-Dan
- Nature Communications, Vol. 9, Issue 1
Construction of stabilized bulk-nano interfaces for highly promoted inverse CeO2/Cu catalyst
journal, August 2019
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- Nature Communications, Vol. 10, Issue 1
Single Ru atoms with precise coordination on a monolayer layered double hydroxide for efficient electrooxidation catalysis
journal, January 2019
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- Chemical Science, Vol. 10, Issue 2
The Success Story of Gold-Based Catalysts for Gas- and Liquid-Phase Reactions: A Brief Perspective and Beyond
journal, October 2019
- Price, Cameron A. H.; Pastor-Pérez, Laura; Ivanova, Svetlana
- Frontiers in Chemistry, Vol. 7
Activation of Gold on Metal Carbides: Novel Catalysts for C1 Chemistry
journal, January 2020
- Rodriguez, José A.
- Frontiers in Chemistry, Vol. 7
Hierarchical AuNPs-Loaded Fe3O4/Polymers Nanocomposites Constructed by Electrospinning with Enhanced and Magnetically Recyclable Catalytic Capacities
journal, October 2017
- Guo, Rong; Jiao, Tifeng; Xing, Ruirui
- Nanomaterials, Vol. 7, Issue 10