Cu‐Decorated ZnO Nanorod Array Integrated Structured Catalysts for Low‐Pressure CO 2 Hydrogenation to Methanol
Abstract
Abstract CO 2 conversion into valuable chemicals and fuels, such as methanol, is one of the most practical routes for utilizing emitted CO 2 and mitigating global warming. Herein, a 3D Cu‐decorated ZnO nanorod array based structured catalysts for efficient thermochemical CO 2 hydrogenation to methanol at relatively low pressures (<10 atm) is successfully fabricated and demonstrated. This new type of nanorod array integrated structured catalysts has yielded a methanol formation rate of 1.9 mol h −1 kg −1 with a methanol selectivity of 56%, rivaling the state‐of‐the‐art powder‐form catalysts. The well‐dispersed copper species on the array structure as well as the array‐structure‐enhanced interfacial effect are key factors that improve the activity of the nanorod array catalysts in CO 2 hydrogenation. The Cu‐ZnO nanorod array interface also suppresses reverse water‐gas shift reaction, reducing the selectivity to CO. Further improvement of the performance of the nanorod array based catalysts is demonstrated by tuning the ZnO nanorod array length. The developed nanorod array integrated monolithic catalysts also exhibit good stability during a long‐time continuous operation, demonstrating the potential and the feasibility of their practical implementation in industrial situation.
- Authors:
-
- Department of Materials Science and Engineering and Institute of Materials Science University of Connecticut Storrs CT 06269‐3136 USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1410830
- Grant/Contract Number:
- DE‐EE0006854
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Advanced Materials Interfaces
- Additional Journal Information:
- Journal Name: Advanced Materials Interfaces Journal Volume: 5 Journal Issue: 3; Journal ID: ISSN 2196-7350
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Du, Shoucheng, Tang, Wenxiang, Lu, Xingxu, Wang, Sibo, Guo, Yanbing, and Gao, Pu‐Xian. Cu‐Decorated ZnO Nanorod Array Integrated Structured Catalysts for Low‐Pressure CO 2 Hydrogenation to Methanol. Germany: N. p., 2017.
Web. doi:10.1002/admi.201700730.
Du, Shoucheng, Tang, Wenxiang, Lu, Xingxu, Wang, Sibo, Guo, Yanbing, & Gao, Pu‐Xian. Cu‐Decorated ZnO Nanorod Array Integrated Structured Catalysts for Low‐Pressure CO 2 Hydrogenation to Methanol. Germany. https://doi.org/10.1002/admi.201700730
Du, Shoucheng, Tang, Wenxiang, Lu, Xingxu, Wang, Sibo, Guo, Yanbing, and Gao, Pu‐Xian. Fri .
"Cu‐Decorated ZnO Nanorod Array Integrated Structured Catalysts for Low‐Pressure CO 2 Hydrogenation to Methanol". Germany. https://doi.org/10.1002/admi.201700730.
@article{osti_1410830,
title = {Cu‐Decorated ZnO Nanorod Array Integrated Structured Catalysts for Low‐Pressure CO 2 Hydrogenation to Methanol},
author = {Du, Shoucheng and Tang, Wenxiang and Lu, Xingxu and Wang, Sibo and Guo, Yanbing and Gao, Pu‐Xian},
abstractNote = {Abstract CO 2 conversion into valuable chemicals and fuels, such as methanol, is one of the most practical routes for utilizing emitted CO 2 and mitigating global warming. Herein, a 3D Cu‐decorated ZnO nanorod array based structured catalysts for efficient thermochemical CO 2 hydrogenation to methanol at relatively low pressures (<10 atm) is successfully fabricated and demonstrated. This new type of nanorod array integrated structured catalysts has yielded a methanol formation rate of 1.9 mol h −1 kg −1 with a methanol selectivity of 56%, rivaling the state‐of‐the‐art powder‐form catalysts. The well‐dispersed copper species on the array structure as well as the array‐structure‐enhanced interfacial effect are key factors that improve the activity of the nanorod array catalysts in CO 2 hydrogenation. The Cu‐ZnO nanorod array interface also suppresses reverse water‐gas shift reaction, reducing the selectivity to CO. Further improvement of the performance of the nanorod array based catalysts is demonstrated by tuning the ZnO nanorod array length. The developed nanorod array integrated monolithic catalysts also exhibit good stability during a long‐time continuous operation, demonstrating the potential and the feasibility of their practical implementation in industrial situation.},
doi = {10.1002/admi.201700730},
journal = {Advanced Materials Interfaces},
number = 3,
volume = 5,
place = {Germany},
year = {Fri Dec 01 00:00:00 EST 2017},
month = {Fri Dec 01 00:00:00 EST 2017}
}
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Works referenced in this record:
The role of metal oxides in promoting a copper catalyst for methanol synthesis
journal, January 1994
- Fujitani, T.; Saito, M.; Kanai, Y.
- Catalysis Letters, Vol. 25, Issue 3-4
In Situ Electron Energy Loss Spectroscopy Studies of Gas-Dependent Metal−Support Interactions in Cu/ZnO Catalysts
journal, August 2003
- Wagner, Jakob B.; Hansen, Poul L.; Molenbroek, Alfons M.
- The Journal of Physical Chemistry B, Vol. 107, Issue 31
Controlled assembly of Cu nanoparticles on pyridinic-N rich graphene for electrochemical reduction of CO2 to ethylene
journal, June 2016
- Li, Qing; Zhu, Wenlei; Fu, Jiaju
- Nano Energy, Vol. 24
Selective Electroreduction of CO 2 toward Ethylene on Nano Dendritic Copper Catalysts at High Current Density
journal, January 2017
- Reller, Christian; Krause, Ralf; Volkova, Elena
- Advanced Energy Materials, Vol. 7, Issue 12
Discovery of a Ni-Ga catalyst for carbon dioxide reduction to methanol
journal, March 2014
- Studt, Felix; Sharafutdinov, Irek; Abild-Pedersen, Frank
- Nature Chemistry, Vol. 6, Issue 4
Catalytic performance for CO2 conversion to methanol of gallium-promoted copper-based catalysts: influence of metallic precursors
journal, November 2001
- Toyir, Jamil; Ramı́rez de la Piscina, Pilar; Fierro, José Luis G.
- Applied Catalysis B: Environmental, Vol. 34, Issue 4
Atom-Resolved Imaging of Dynamic Shape Changes in Supported Copper Nanocrystals
journal, March 2002
- Hansen, P. L.
- Science, Vol. 295, Issue 5562
Nanostructured Zinc Oxide Nanorods with Copper Nanoparticles as a Microreformation Catalyst
journal, September 2009
- Lin, Yan-Gu; Hsu, Yu-Kuei; Chen, San-Yuan
- Angewandte Chemie International Edition, Vol. 48, Issue 41
In situ XRD and HRTEM studies on the evolution of the Cu/ZnO methanol synthesis catalyst during its reduction and re-oxidation
journal, January 2004
- Yurieva, Tamara M.; Plyasova, Lyudmila M.; Zaikovskii, Vladimir I.
- Physical Chemistry Chemical Physics, Vol. 6, Issue 18
An improved N2O-method for measuring Cu-dispersion
journal, July 2004
- Jensen, J. R.; Johannessen, T.; Livbjerg, H.
- Applied Catalysis A: General, Vol. 266, Issue 1
Quantifying the promotion of Cu catalysts by ZnO for methanol synthesis
journal, May 2016
- Kuld, S.; Thorhauge, M.; Falsig, H.
- Science, Vol. 352, Issue 6288
Methanol synthesis from CO2 and H2 over gallium promoted copper-based supported catalysts. Effect of hydrocarbon impurities in the CO2/H2 source
journal, October 2001
- Toyir, Jamil; de la Piscina, Pilar RamÃrez; Llorca, Jordi
- Physical Chemistry Chemical Physics, Vol. 3, Issue 21
Active sites for CO 2 hydrogenation to methanol on Cu/ZnO catalysts
journal, March 2017
- Kattel, Shyam; Ramírez, Pedro J.; Chen, Jingguang G.
- Science, Vol. 355, Issue 6331
Understanding low temperature oxidation activity of nanoarray-based monolithic catalysts: from performance observation to structural and chemical insights
journal, December 2016
- Du, Shoucheng; Tang, Wenxiang; Guo, Yanbing
- Emission Control Science and Technology, Vol. 3, Issue 1
Formation of a ZnO Overlayer in Industrial Cu/ZnO/Al 2 O 3 Catalysts Induced by Strong Metal-Support Interactions
journal, February 2015
- Lunkenbein, Thomas; Schumann, Julia; Behrens, Malte
- Angewandte Chemie, Vol. 127, Issue 15
The chemical modification seen in the Cu/ZnO methanol synthesis catalysts
journal, January 2000
- Fujitani, T.; Nakamura, J.
- Applied Catalysis A: General, Vol. 191, Issue 1-2
Yttria-Stabilized Zirconia Supported Copper Oxide Catalyst
journal, May 1996
- Dow, Wei-Ping; Wang, Yu-Piao; Huang, Ta-Jen
- Journal of Catalysis, Vol. 160, Issue 2
Fe-Doped CoP Nanoarray: A Monolithic Multifunctional Catalyst for Highly Efficient Hydrogen Generation
journal, October 2016
- Tang, Chun; Zhang, Rong; Lu, Wenbo
- Advanced Materials, Vol. 29, Issue 2
Preparation of a coprecipitated Cu/ZnO catalyst for the methanol synthesis from CO2 — effects of the calcination and reduction conditions on the catalytic performance
journal, February 2001
- Fujita, Shin-ichiro; Moribe, Shuhei; Kanamori, Yoshinori
- Applied Catalysis A: General, Vol. 207, Issue 1-2
CO2 hydrogenation to methanol over Cu/ZnO/ZrO2 catalysts prepared by precipitation-reduction method
journal, August 2016
- Dong, Xiaosu; Li, Feng; Zhao, Ning
- Applied Catalysis B: Environmental, Vol. 191
Gas Conversion to Liquid Fuels and Chemicals: The Methanol Route‐Catalysis and Processes Development
journal, January 2009
- Mokrani, Touhami; Scurrell, Mike
- Catalysis Reviews, Vol. 51, Issue 1, p. 1-145
Influence of ZrO 2 Structure and Copper Electronic State on Activity of Cu/ZrO 2 Catalysts in Methanol Synthesis from CO 2
journal, September 2014
- Samson, K.; Śliwa, M.; Socha, R. P.
- ACS Catalysis, Vol. 4, Issue 10
Nanowire Array Structures for Photocatalytic Energy Conversion and Utilization: A Review of Design Concepts, Assembly and Integration, and Function Enabling
journal, August 2016
- Hoang, Son; Gao, Pu-Xian
- Advanced Energy Materials, Vol. 6, Issue 23
Development of highly stable catalyst for methanol synthesis from carbon dioxide
journal, January 2014
- Li, Congming; Yuan, Xingdong; Fujimoto, Kaoru
- Applied Catalysis A: General, Vol. 469
Hydrogenation of CO2 to methanol over CuCeTiO catalysts
journal, June 2017
- Chang, Kuan; Wang, Tiefeng; Chen, Jingguang G.
- Applied Catalysis B: Environmental, Vol. 206
Photocatalytic CO2 conversion to methanol by Cu2O/graphene/TNA heterostructure catalyst in a visible-light-driven dual-chamber reactor
journal, September 2016
- Li, Fei; Zhang, Li; Tong, Jincheng
- Nano Energy, Vol. 27
An overview of current status of carbon dioxide capture and storage technologies
journal, November 2014
- Leung, Dennis Y. C.; Caramanna, Giorgio; Maroto-Valer, M. Mercedes
- Renewable and Sustainable Energy Reviews, Vol. 39
Mechanism of the hydrogenation of CO2 to methanol on a Cu(100) surface: dipped adcluster model study
journal, November 1999
- Hu, Zhen-Ming; Takahashi, Kunio; Nakatsuji, Hiroshi
- Surface Science, Vol. 442, Issue 1
Fabrication and photoresponse of ZnO nanowires/CuO coaxial heterojunction
journal, January 2013
- Wu, Jen-Kai; Chen, Wei-Jen; Chang, Yuan
- Nanoscale Research Letters, Vol. 8, Issue 1
Synthesis, characterization and activity pattern of Cu–ZnO/ZrO2 catalysts in the hydrogenation of carbon dioxide to methanol
journal, July 2007
- Arena, F.; Barbera, K.; Italiano, G.
- Journal of Catalysis, Vol. 249, Issue 2
The role of copper particle size in low pressure methanol synthesis via CO 2 hydrogenation over Cu/ZnO catalysts
journal, January 2015
- Karelovic, Alejandro; Ruiz, Patricio
- Catalysis Science & Technology, Vol. 5, Issue 2
ZnO/perovskite core–shell nanorod array based monolithic catalysts with enhanced propane oxidation and material utilization efficiency at low temperature
journal, December 2015
- Wang, Sibo; Ren, Zheng; Song, Wenqiao
- Catalysis Today, Vol. 258
Facile synthesis of ZnO nanopencil arrays for photoelectrochemical water splitting
journal, July 2014
- Lv, Rui; Wang, Tuo; Su, Fengli
- Nano Energy, Vol. 7
Nano-array based monolithic catalysts: Concept, rational materials design and tunable catalytic performance
journal, December 2015
- Ren, Zheng; Guo, Yanbing; Gao, Pu-Xian
- Catalysis Today, Vol. 258
Worldwide innovations in the development of carbon capture technologies and the utilization of CO2
journal, January 2012
- Markewitz, Peter; Kuckshinrichs, Wilhelm; Leitner, Walter
- Energy & Environmental Science, Vol. 5, Issue 6
Robust 3-D configurated metal oxide nano-array based monolithic catalysts with ultrahigh materials usage efficiency and catalytic performance tunability
journal, September 2013
- Guo, Yanbing; Ren, Zheng; Xiao, Wen
- Nano Energy, Vol. 2, Issue 5
Methanol synthesis reactions over a CuZr based catalyst investigated using periodic variations of reactant concentrations
journal, August 2001
- Ortelli, E. E.; Wambach, J.; Wokaun, A.
- Applied Catalysis A: General, Vol. 216, Issue 1-2
High-Performance Electrolytic Oxygen Evolution in Neutral Media Catalyzed by a Cobalt Phosphate Nanoarray
journal, December 2016
- Xie, Lisi; Zhang, Rong; Cui, Liang
- Angewandte Chemie, Vol. 129, Issue 4
Beyond Oil and Gas: The Methanol Economy
journal, April 2005
- Olah, George A.
- Angewandte Chemie International Edition, Vol. 44, Issue 18
Effects of oxide carriers on surface functionality and process performance of the Cu–ZnO system in the synthesis of methanol via CO2 hydrogenation
journal, April 2013
- Arena, Francesco; Mezzatesta, Giovanni; Zafarana, Giovanni
- Journal of Catalysis, Vol. 300
In Situ Investigations of Structural Changes in Cu/ZnO Catalysts
journal, September 2000
- Grunwaldt, J. -D; Molenbroek, A. M.; Topsøe, N. -Y
- Journal of Catalysis, Vol. 194, Issue 2
The role of copper and zinc oxide in methanol synthesis catalysts
journal, January 1990
- Burch, Robert; Golunski, Stanislaw E.; Spencer, Michael S.
- Journal of the Chemical Society, Faraday Transactions, Vol. 86, Issue 15
In situ DRIFT study of low-temperature methanol synthesis mechanism on Cu/ZnO catalysts from CO-containing syngas using ethanol promoter
journal, November 2004
- Yang, R.; Fu, Y.; Zhang, Y.
- Journal of Catalysis, Vol. 228, Issue 1
Perovskite-based nanocubes with simultaneously improved visible-light absorption and charge separation enabling efficient photocatalytic CO2 reduction
journal, December 2016
- Hou, Jungang; Cao, Shuyan; Wu, Yunzhen
- Nano Energy, Vol. 30
Catalytic valorization of CO2 via methanol synthesis with Ga-promoted Cu–ZnO–ZrO2 catalysts
journal, October 2013
- Ladera, Rosa; Pérez-Alonso, Francisco J.; González-Carballo, Juan M.
- Applied Catalysis B: Environmental, Vol. 142-143
Hydrogenation of CO2 to methanol and CO on Cu/ZnO/Al2O3: Is there a common intermediate or not?
journal, August 2015
- Kunkes, Edward L.; Studt, Felix; Abild-Pedersen, Frank
- Journal of Catalysis, Vol. 328
Catalytic synthesis of methanol from CO/H2I. Phase composition, electronic properties, and activities of the Cu/ZnO/M2O3 catalysts
journal, March 1979
- Herman, R.
- Journal of Catalysis, Vol. 56, Issue 3
Methanol Synthesis and Reverse Water–Gas Shift Kinetics over Cu(110) Model Catalysts: Structural Sensitivity
journal, July 1996
- Yoshihara, Jun; Campbell, Charles T.
- Journal of Catalysis, Vol. 161, Issue 2
Highly active copper-ceria and copper-ceria-titania catalysts for methanol synthesis from CO2
journal, July 2014
- Graciani, J.; Mudiyanselage, K.; Xu, F.
- Science, Vol. 345, Issue 6196
Surface active structure of ultra-fine Cu/ZrO2 catalysts used for the CO2+H2 to methanol reaction
journal, September 2001
- Liu, Jinyao; Shi, Jiangliu; He, Dehua
- Applied Catalysis A: General, Vol. 218, Issue 1-2
Thermodynamic investigation of methanol and dimethyl ether synthesis from CO2 Hydrogenation
journal, March 2000
- Shen, Wen-Jie; Jun, Ki-Won; Choi, Ho-Suk
- Korean Journal of Chemical Engineering, Vol. 17, Issue 2
Enhanced photoresponse of ZnO nanorods-based self-powered photodetector by piezotronic interface engineering
journal, October 2014
- Zhang, Zheng; Liao, Qingliang; Yu, Yanhao
- Nano Energy, Vol. 9
Intermetallic GaPd 2 Nanoparticles on SiO 2 for Low-Pressure CO 2 Hydrogenation to Methanol: Catalytic Performance and In Situ Characterization
journal, September 2015
- Fiordaliso, Elisabetta M.; Sharafutdinov, Irek; Carvalho, Hudson W. P.
- ACS Catalysis, Vol. 5, Issue 10
Effect of pressure on the mechanisms of the CO2/H2 reaction on a CO-precipitated CuO/ZnO/Al2O3 catalyst
journal, April 2011
- Sahki, Rachid; Benlounes, Ouarda; Chérifi, Ouiza
- Reaction Kinetics, Mechanisms and Catalysis, Vol. 103, Issue 2
Construction of Cu/ZrO2/Al2O3 composites for ethanol synthesis: Synergies of ternary sites for cascade reaction
journal, May 2015
- Zhu, Yifeng; Kong, Xiao; Zhu, Shanhui
- Applied Catalysis B: Environmental, Vol. 166-167
Correlations between synthesis, precursor, and catalyst structure and activity of a large set of CuO/ZnO/Al2O3 catalysts for methanol synthesis
journal, September 2008
- Baltes, C.; Vukojevic, S.; Schuth, F.
- Journal of Catalysis, Vol. 258, Issue 2
Role of Lattice Strain and Defects in Copper Particles on the Activity of Cu/ZnO/Al2O3 Catalysts for Methanol Synthesis
journal, September 2007
- Kasatkin, Igor; Kurr, Patrick; Kniep, Benjamin
- Angewandte Chemie International Edition, Vol. 46, Issue 38
Scalable Integration of Highly Uniform Mn x Co 3− x O 4 Nanosheet Array onto Ceramic Monolithic Substrates for Low-Temperature Propane Oxidation
journal, October 2017
- Tang, Wenxiang; Ren, Zheng; Lu, Xingxu
- ChemCatChem, Vol. 9, Issue 21
Transient behavior of Cu/ZnO-based methanol synthesis catalysts
journal, February 2009
- Vesborg, Peter C. K.; Chorkendorff, Ib; Knudsen, Ida
- Journal of Catalysis, Vol. 262, Issue 1
Development of an active Ga2O3 supported palladium catalyst for the synthesis of methanol from carbon dioxide and hydrogen
journal, May 1995
- Fujitani, T.; Saito, M.; Kanai, Y.
- Applied Catalysis A: General, Vol. 125, Issue 2
Hydrogenation of CO2 to methanol over In2O3 catalyst
journal, December 2015
- Sun, Kaihang; Fan, Zhigang; Ye, Jingyun
- Journal of CO2 Utilization, Vol. 12
The Active Site of Methanol Synthesis over Cu/ZnO/Al2O3 Industrial Catalysts
journal, April 2012
- Behrens, M.; Studt, F.; Kasatkin, I.
- Science, Vol. 336, Issue 6083, p. 893-897
Nano-array integrated monolithic devices: toward rational materials design and multi-functional performance by scalable nanostructures assembly
journal, January 2016
- Wang, Sibo; Ren, Zheng; Guo, Yanbing
- CrystEngComm, Vol. 18, Issue 17
Methanol technology developments for the new millennium
journal, November 2001
- Tijm, P. J. A.; Waller, F. J.; Brown, D. M.
- Applied Catalysis A: General, Vol. 221, Issue 1-2
The Potential Applications of Nanoporous Materials for the Adsorption, Separation, and Catalytic Conversion of Carbon Dioxide
journal, March 2014
- Sneddon, Gregor; Greenaway, Alex; Yiu, Humphrey H. P.
- Advanced Energy Materials, Vol. 4, Issue 10
Dispersion and surface states of copper catalysts by temperature-programmed-reduction of oxidized surfaces (s-TPR)
journal, March 2005
- Gervasini, Antonella; Bennici, Simona
- Applied Catalysis A: General, Vol. 281, Issue 1-2
Impact of K and Ba promoters on CO 2 hydrogenation over Cu/Al 2 O 3 catalysts at high pressure
journal, January 2013
- Bansode, Atul; Tidona, Bruno; von Rohr, Philipp Rudolf
- Catal. Sci. Technol., Vol. 3, Issue 3
Bimetallic Pd–Cu catalysts for selective CO2 hydrogenation to methanol
journal, July 2015
- Jiang, Xiao; Koizumi, Naoto; Guo, Xinwen
- Applied Catalysis B: Environmental, Vol. 170-171
The Role of the Oxide Component in the Development of Copper Composite Catalysts for Methanol Synthesis
journal, May 2013
- Zander, Stefan; Kunkes, Edward L.; Schuster, Manfred E.
- Angewandte Chemie International Edition, Vol. 52, Issue 25
Atomic-scale studies of metallic nanocluster catalysts by in situ high-resolution transmission electron microscopy
journal, January 2006
- Helveg, Stig; Hansen, Poul L.
- Catalysis Today, Vol. 111, Issue 1-2
The changing nature of the active site of Cu-Zn-Zr catalysts for the CO2 hydrogenation reaction to methanol
journal, June 2014
- Bonura, G.; Cordaro, M.; Cannilla, C.
- Applied Catalysis B: Environmental, Vol. 152-153
Highly effective conversion of CO2 to methanol over supported and promoted copper-based catalysts: influence of support and promoter
journal, February 2001
- Toyir, Jamil; de la Piscina, Pilar Ramı́rez; Fierro, José Luis G.
- Applied Catalysis B: Environmental, Vol. 29, Issue 3
Scalable continuous flow synthesis of ZnO nanorod arrays in 3-D ceramic honeycomb substrates for low-temperature desulfurization
journal, January 2017
- Wang, Sibo; Wu, Yunchao; Miao, Ran
- CrystEngComm, Vol. 19, Issue 34
Hydrogenation of CO2 to value-added products—A review and potential future developments
journal, March 2014
- Saeidi, Samrand; Amin, Nor Aishah Saidina; Rahimpour, Mohammad Reza
- Journal of CO2 Utilization, Vol. 5
Nanocrystalline zirconia as catalyst support in methanol synthesis
journal, January 2005
- Liu, Xin-Mei; Lu, G. Q.; Yan, Zi-Feng
- Applied Catalysis A: General, Vol. 279, Issue 1-2
Comparative study of hydrotalcite-derived supported Pd2Ga and PdZn intermetallic nanoparticles as methanol synthesis and methanol steam reforming catalysts
journal, September 2012
- Ota, Antje; Kunkes, Edward L.; Kasatkin, Igor
- Journal of Catalysis, Vol. 293
Zinc oxide nanorods based catalysts for hydrogen production by steam reforming of methanol
journal, April 2012
- Danwittayakul, Supamas; Dutta, Joydeep
- International Journal of Hydrogen Energy, Vol. 37, Issue 7
Fundamental studies of methanol synthesis from CO2 hydrogenation on Cu(111), Cu clusters, and Cu/ZnO(0001̄)
journal, January 2010
- Yang, Yixiong; Evans, Jaime; Rodriguez, Jose A.
- Physical Chemistry Chemical Physics, Vol. 12, Issue 33
Mechanism of Methanol Synthesis on Cu through CO 2 and CO Hydrogenation
journal, February 2011
- Grabow, L. C.; Mavrikakis, M.
- ACS Catalysis, Vol. 1, Issue 4
High Efficiency Cu-ZnO Hydrogenation Catalyst: The Tailoring of Cu-ZnO Interface Sites by Molecular Layer Deposition
journal, August 2015
- Zhang, Bin; Chen, Yao; Li, Jianwei
- ACS Catalysis, Vol. 5, Issue 9