Graphene-like Boron–Carbon–Nitrogen Monolayers
Abstract
A strategy to synthesize a 2D graphenic but ternary monolayer containing atoms of carbon, nitrogen, and boron, h-BCN, is presented. The synthesis utilizes bis- BN cyclohexane, B2N2C2H12, as a precursor molecule and relies on thermally induced dehydrogenation of the precursor molecules and the formation of an epitaxial monolayer on Ir(111) through covalent bond formation. The lattice mismatch between the film and substrate causes a strain-driven periodic buckling of the film. The structure of the film and its corrugated morphology is discussed based on comprehensive data from molecular-resolved scanning tunneling microscopy imaging, X-ray photoelectron spectroscopy, low-energy electron diffraction, and density functional theory. First-principles calculations further predict a direct electronic band gap that is intermediate between gapless graphene and insulating h-BN.
- Authors:
-
- Department of Physics &, Astronomy, University of Nebraska, Lincoln, Nebraska 68588-0299, United States
- Department of Theoretical Chemistry, Faculty of Chemistry, Jagiellonian University, Krakow, Poland 30-060
- Department of Chemistry, State University of New York at Buffalo, Buffalo, New York 14260-3000, United States
- Department of Chemistry, Boston College, Chestnut Hill, Massachusetts 02467-3860, United States
- Department of Chemistry, Tufts University, Medford, Massachusetts 02155, United States
- Department of Physics &, Astronomy, University of Nebraska, Lincoln, Nebraska 68588-0299, United States, Physikalisches Institut, Universität Bayreuth, 95440 Bayreuth, Germany
- Publication Date:
- Research Org.:
- Univ. of Nebraska, Lincoln, NE (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE)
- OSTI Identifier:
- 1409881
- Alternate Identifier(s):
- OSTI ID: 1529560
- Grant/Contract Number:
- EE0005658
- Resource Type:
- Published Article
- Journal Name:
- ACS Nano
- Additional Journal Information:
- Journal Name: ACS Nano Journal Volume: 11 Journal Issue: 3; Journal ID: ISSN 1936-0851
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 77 NANOSCIENCE AND NANOTECHNOLOGY; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE; 2D material; 2D; BCN; graphene; boron nitride; STM; bis-BN cyclohexane
Citation Formats
Beniwal, Sumit, Hooper, James, Miller, Daniel P., Costa, Paulo S., Chen, Gang, Liu, Shih-Yuan, Dowben, Peter A., Sykes, E. Charles H., Zurek, Eva, and Enders, Axel. Graphene-like Boron–Carbon–Nitrogen Monolayers. United States: N. p., 2017.
Web. doi:10.1021/acsnano.6b08136.
Beniwal, Sumit, Hooper, James, Miller, Daniel P., Costa, Paulo S., Chen, Gang, Liu, Shih-Yuan, Dowben, Peter A., Sykes, E. Charles H., Zurek, Eva, & Enders, Axel. Graphene-like Boron–Carbon–Nitrogen Monolayers. United States. https://doi.org/10.1021/acsnano.6b08136
Beniwal, Sumit, Hooper, James, Miller, Daniel P., Costa, Paulo S., Chen, Gang, Liu, Shih-Yuan, Dowben, Peter A., Sykes, E. Charles H., Zurek, Eva, and Enders, Axel. Mon .
"Graphene-like Boron–Carbon–Nitrogen Monolayers". United States. https://doi.org/10.1021/acsnano.6b08136.
@article{osti_1409881,
title = {Graphene-like Boron–Carbon–Nitrogen Monolayers},
author = {Beniwal, Sumit and Hooper, James and Miller, Daniel P. and Costa, Paulo S. and Chen, Gang and Liu, Shih-Yuan and Dowben, Peter A. and Sykes, E. Charles H. and Zurek, Eva and Enders, Axel},
abstractNote = {A strategy to synthesize a 2D graphenic but ternary monolayer containing atoms of carbon, nitrogen, and boron, h-BCN, is presented. The synthesis utilizes bis- BN cyclohexane, B2N2C2H12, as a precursor molecule and relies on thermally induced dehydrogenation of the precursor molecules and the formation of an epitaxial monolayer on Ir(111) through covalent bond formation. The lattice mismatch between the film and substrate causes a strain-driven periodic buckling of the film. The structure of the film and its corrugated morphology is discussed based on comprehensive data from molecular-resolved scanning tunneling microscopy imaging, X-ray photoelectron spectroscopy, low-energy electron diffraction, and density functional theory. First-principles calculations further predict a direct electronic band gap that is intermediate between gapless graphene and insulating h-BN.},
doi = {10.1021/acsnano.6b08136},
journal = {ACS Nano},
number = 3,
volume = 11,
place = {United States},
year = {Mon Feb 13 00:00:00 EST 2017},
month = {Mon Feb 13 00:00:00 EST 2017}
}
https://doi.org/10.1021/acsnano.6b08136
Web of Science
Figures / Tables:
Works referenced in this record:
Photodetectors based on graphene, other two-dimensional materials and hybrid systems
journal, October 2014
- Koppens, F. H. L.; Mueller, T.; Avouris, Ph.
- Nature Nanotechnology, Vol. 9, Issue 10
X-ray Photoelectron Spectroscopy Studies of Metallic Diborides
journal, October 1992
- Zdaniewski, Wieslaw A.; Brungard, Nancy L.
- Journal of the American Ceramic Society, Vol. 75, Issue 10
Carbon-doped BN nanosheets for metal-free photoredox catalysis
journal, July 2015
- Huang, Caijin; Chen, Cheng; Zhang, Mingwen
- Nature Communications, Vol. 6, Issue 1
Binary and Ternary Atomic Layers Built from Carbon, Boron, and Nitrogen
journal, July 2012
- Song, Li; Liu, Zheng; Reddy, Arava Leela Mohana
- Advanced Materials, Vol. 24, Issue 36
Computational Screening of 2D Materials for Photocatalysis
journal, March 2015
- Singh, Arunima K.; Mathew, Kiran; Zhuang, Houlong L.
- The Journal of Physical Chemistry Letters, Vol. 6, Issue 6
Electron cyclotron resonance plasma-assisted pulsed laser deposition of boron carbon nitride films
journal, September 2002
- Ling, H.; Wu, J. D.; Sun, J.
- Diamond and Related Materials, Vol. 11, Issue 9
Atomic layers of hybridized boron nitride and graphene domains
journal, February 2010
- Ci, Lijie; Song, Li; Jin, Chuanhong
- Nature Materials, Vol. 9, Issue 5, p. 430-435
Periodically Rippled Graphene: Growth and Spatially Resolved Electronic Structure
journal, February 2008
- Vázquez de Parga, A. L.; Calleja, F.; Borca, B.
- Physical Review Letters, Vol. 100, Issue 5
Graphene-Like Two-Dimensional Materials
journal, January 2013
- Xu, Mingsheng; Liang, Tao; Shi, Minmin
- Chemical Reviews, Vol. 113, Issue 5, p. 3766-3798
Structural stability and electronic properties of carbon-boron nitride compounds
journal, July 2006
- Azevedo, S.; Paiva, R. de
- Europhysics Letters (EPL), Vol. 75, Issue 1
Characterization of BCN films synthesized by radiofrequency plasma enhanced chemical vapor deposition
journal, January 2009
- Abdul Mannan, Md.; Nagano, Masamitsu; Kida, Tetsuya
- Journal of Physics and Chemistry of Solids, Vol. 70, Issue 1
Epitaxial hexagonal boron nitride on Ir(111): A work function template
journal, June 2014
- Schulz, Fabian; Drost, Robert; Hämäläinen, Sampsa K.
- Physical Review B, Vol. 89, Issue 23
Structure of epitaxial graphene on Ir(111)
journal, April 2008
- N'Diaye, Alpha T.; Coraux, Johann; Plasa, Tim N.
- New Journal of Physics, Vol. 10, Issue 4
Tunable band gaps of mono-layer hexagonal BNC heterostructures
journal, April 2012
- Peng, Qing; De, Suvranu
- Physica E: Low-dimensional Systems and Nanostructures, Vol. 44, Issue 7-8
Experimental and computational insight into the properties of the lattice-mismatched structures: Monolayers of -BN and graphene on Ir(111)
journal, October 2012
- Usachov, D.; Fedorov, A.; Vilkov, O.
- Physical Review B, Vol. 86, Issue 15
Bis-BN Cyclohexane: A Remarkably Kinetically Stable Chemical Hydrogen Storage Material
journal, December 2014
- Chen, Gang; Zakharov, Lev N.; Bowden, Mark E.
- Journal of the American Chemical Society, Vol. 137, Issue 1
B and N doping in graphene ruled by grain boundary defects
journal, January 2012
- Brito, W. H.; Kagimura, R.; Miwa, R. H.
- Physical Review B, Vol. 85, Issue 3
Aqueous Noncovalent Functionalization and Controlled Near-Surface Carbon Doping of Multiwalled Boron Nitride Nanotubes
journal, July 2008
- Wang, Wenlong; Bando, Yoshio; Zhi, Chunyi
- Journal of the American Chemical Society, Vol. 130, Issue 26
A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu
journal, April 2010
- Grimme, Stefan; Antony, Jens; Ehrlich, Stephan
- The Journal of Chemical Physics, Vol. 132, Issue 15
Chemical vapour deposition of BC2N films and their laser-induced etching with SF6
journal, January 1998
- Popov, Cyril; Saito, Kimitsugu; Ivanov, Borislav
- Thin Solid Films, Vol. 312, Issue 1-2
Controlling graphene corrugation on lattice-mismatched substrates
journal, August 2008
- Preobrajenski, A. B.; Ng, May Ling; Vinogradov, A. S.
- Physical Review B, Vol. 78, Issue 7
Boron carbonitride films deposited by pulsed laser ablation
journal, August 1998
- Perrone, A.; Caricato, A. P.; Luches, A.
- Applied Surface Science, Vol. 133, Issue 4
Direct chemical conversion of graphene to boron- and nitrogen- and carbon-containing atomic layers
journal, January 2014
- Gong, Yongji; Shi, Gang; Zhang, Zhuhua
- Nature Communications, Vol. 5, Issue 1
Electron Counting and a Large Family of Two-Dimensional Semiconductors
journal, March 2016
- Miao, Mao-sheng; Botana, Jorge; Zurek, Eva
- Chemistry of Materials, Vol. 28, Issue 7
Growth and characterization of stoichiometric BCN films on highly oriented pyrolytic graphite by radiofrequency plasma enhanced chemical vapor deposition
journal, May 2010
- Mannan, Md. Abdul; Noguchi, Hideyuki; Kida, Tetsuya
- Thin Solid Films, Vol. 518, Issue 15
Quasi-Freestanding Monolayer Heterostructure of Graphene and Hexagonal Boron Nitride on Ir(111) with a Zigzag Boundary
journal, October 2014
- Liu, Mengxi; Li, Yuanchang; Chen, Pengcheng
- Nano Letters, Vol. 14, Issue 11
Interpolation of Atomically Thin Hexagonal Boron Nitride and Graphene: Electronic Structure and Thermodynamic Stability in Terms of All-Carbon Conjugated Paths and Aromatic Hexagons
journal, April 2011
- Zhu, Jun; Bhandary, Sumanta; Sanyal, Biplab
- The Journal of Physical Chemistry C, Vol. 115, Issue 20
Atomic arrangement and electronic structure of N
journal, January 1989
- Liu, Amy Y.; Wentzcovitch, Renata M.; Cohen, Marvin L.
- Physical Review B, Vol. 39, Issue 3
C2H4B2N2: a prediction of ring and chain [boron-nitrogen-carbon] compounds
journal, December 1992
- Cernusak, Ivan; Urban, Miroslav; Ertl, Peter
- Journal of the American Chemical Society, Vol. 114, Issue 27
Direct Synthesis of B−C−N Single-Walled Nanotubes by Bias-Assisted Hot Filament Chemical Vapor Deposition
journal, May 2006
- Wang, W. L.; Bai, X. D.; Liu, K. H.
- Journal of the American Chemical Society, Vol. 128, Issue 20
Electronics and optoelectronics of two-dimensional transition metal dichalcogenides
journal, November 2012
- Wang, Qing Hua; Kalantar-Zadeh, Kourosh; Kis, Andras
- Nature Nanotechnology, Vol. 7, Issue 11, p. 699-712
Spectroscopic studies of BN films deposited by dynamic ion mixing
journal, May 1993
- Rivière, J. P.; Pacaud, Y.; Cahoreau, M.
- Thin Solid Films, Vol. 227, Issue 1
Optoelectronic devices based on electrically tunable p–n diodes in a monolayer dichalcogenide
journal, March 2014
- Baugher, Britton W. H.; Churchill, Hugh O. H.; Yang, Yafang
- Nature Nanotechnology, Vol. 9, Issue 4
Disorder and Segregation in B−C−N Graphene-Type Layers and Nanotubes: Tuning the Band Gap
journal, December 2010
- da Rocha Martins, Jonathan; Chacham, Hélio
- ACS Nano, Vol. 5, Issue 1
Synthesis of N-Doped Graphene by Chemical Vapor Deposition and Its Electrical Properties
journal, May 2009
- Wei, Dacheng; Liu, Yunqi; Wang, Yu
- Nano Letters, Vol. 9, Issue 5
High-Resolution X-Ray Photoemission Spectrum of the Valence Bands of Gold
journal, June 1972
- Shirley, D. A.
- Physical Review B, Vol. 5, Issue 12
Heteroepitaxial Growth of Two-Dimensional Hexagonal Boron Nitride Templated by Graphene Edges
journal, January 2014
- Liu, L.; Park, J.; Siegel, D. A.
- Science, Vol. 343, Issue 6167
Two-dimensional atomic crystals
journal, July 2005
- Novoselov, K. S.; Jiang, D.; Schedin, F.
- Proceedings of the National Academy of Sciences, Vol. 102, Issue 30, p. 10451-10453
Local Electronic Properties of Graphene on a BN Substrate via Scanning Tunneling Microscopy
journal, June 2011
- Decker, Régis; Wang, Yang; Brar, Victor W.
- Nano Letters, Vol. 11, Issue 6
Aluminum, Titanium Boride, and Nitride Films Sputter-Deposited from Multicomponent Alloy Targets Studied by XPS
journal, January 1993
- Onyiriuka, Emmanuel C.
- Applied Spectroscopy, Vol. 47, Issue 1
Orientation of B–C–N hybrid films deposited on Ni (111) and polycrystalline Ti substrates explored by X-ray absorption spectroscopy
journal, January 2011
- Mannan, Md. Abdul; Baba, Yuji; Kida, Tetsuya
- Thin Solid Films, Vol. 519, Issue 6
Electronic decoupling and templating of Co nanocluster arrays on the boron nitride nanomesh
journal, July 2008
- Brihuega, Iván; Michaelis, Christian Heinrich; Zhang, Jian
- Surface Science, Vol. 602, Issue 14
X-ray photoelectron spectroscopic observation on B–C–N hybrids synthesized by ion beam deposition of borazine
journal, May 2005
- Uddin, Md. Nizam; Shimoyama, Iwao; Baba, Yuji
- Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 23, Issue 3
ESCA surface study of metal borides
journal, March 1973
- Mavel, G.; Escard, J.; Costa, P.
- Surface Science, Vol. 35
Electronics based on two-dimensional materials
journal, October 2014
- Fiori, Gianluca; Bonaccorso, Francesco; Iannaccone, Giuseppe
- Nature Nanotechnology, Vol. 9, Issue 10
Bonding characterization of BC 2 N thin films
journal, May 1996
- Watanabe, M. O.; Itoh, S.; Mizushima, K.
- Applied Physics Letters, Vol. 68, Issue 21
Synthesis, conductivity and high-pressure phase transition of amorphous boron carbon nitride
journal, June 2007
- Bai, Suo Zhu; Yao, Bin; Xing, Guo Zhong
- Physica B: Condensed Matter, Vol. 396, Issue 1-2
Self-Assembly of a Hexagonal Boron Nitride Nanomesh on Ru(0001)
journal, March 2007
- Goriachko, Andrii; Knapp, Marcus
- Langmuir, Vol. 23, Issue 6
Chemical bonding states and local structures of the oriented hexagonal BCN films synthesized by microwave plasma CVD
journal, June 2008
- Mannan, Md. Abdul; Noguchi, Hideyuki; Kida, Tetsuya
- Materials Science in Semiconductor Processing, Vol. 11, Issue 3
Epitaxial Growth of Hexagonal Boron Nitride on Ir(111)
journal, December 2011
- Orlando, Fabrizio; Larciprete, Rosanna; Lacovig, Paolo
- The Journal of Physical Chemistry C, Vol. 116, Issue 1
Comparison of background removal methods for XPS
journal, July 1992
- Repoux, M.
- Surface and Interface Analysis, Vol. 18, Issue 7
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