Extended Ladder-Type Benzo[k]tetraphene-Derived Oligomers
Abstract
Abstract Well‐defined, fused‐ring aromatic oligomers represent promising candidates for the fundamental understanding and application of advanced carbon‐rich materials, though bottom‐up synthesis and structure–property correlation of these compounds remain challenging. In this work, an efficient synthetic route was employed to construct extended benzo[ k ]tetraphene‐derived oligomers with up to 13 fused rings. The molecular and electronic structures of these compounds were clearly elucidated. Precise correlation of molecular sizes and crystallization dynamics was established, thus demonstrating the pivotal balance between intermolecular interaction and molecular mobility for optimized processing of highly ordered solids of these extended conjugated molecules.
- Authors:
-
- Texas A & M Univ., College Station, TX (United States)
- Zhejiang Univ., Hangzhou (China)
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division
- OSTI Identifier:
- 1408109
- Alternate Identifier(s):
- OSTI ID: 1395909
- Grant/Contract Number:
- AC02-06CH11357; CHE-1359175; CHE-0541587
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Angewandte Chemie (International Edition)
- Additional Journal Information:
- Journal Name: Angewandte Chemie (International Edition); Journal Volume: 56; Journal Issue: 44; Journal ID: ISSN 1433-7851
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- ENGLISH
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Lee, Jongbok, Li, Huanbin, Kalin, Alexander J., Yuan, Tianyu, Wang, Chenxu, Olson, Troy, Li, Hanying, and Fang, Lei. Extended Ladder-Type Benzo[k]tetraphene-Derived Oligomers. United States: N. p., 2017.
Web. doi:10.1002/anie.201707595.
Lee, Jongbok, Li, Huanbin, Kalin, Alexander J., Yuan, Tianyu, Wang, Chenxu, Olson, Troy, Li, Hanying, & Fang, Lei. Extended Ladder-Type Benzo[k]tetraphene-Derived Oligomers. United States. https://doi.org/10.1002/anie.201707595
Lee, Jongbok, Li, Huanbin, Kalin, Alexander J., Yuan, Tianyu, Wang, Chenxu, Olson, Troy, Li, Hanying, and Fang, Lei. Fri .
"Extended Ladder-Type Benzo[k]tetraphene-Derived Oligomers". United States. https://doi.org/10.1002/anie.201707595. https://www.osti.gov/servlets/purl/1408109.
@article{osti_1408109,
title = {Extended Ladder-Type Benzo[k]tetraphene-Derived Oligomers},
author = {Lee, Jongbok and Li, Huanbin and Kalin, Alexander J. and Yuan, Tianyu and Wang, Chenxu and Olson, Troy and Li, Hanying and Fang, Lei},
abstractNote = {Abstract Well‐defined, fused‐ring aromatic oligomers represent promising candidates for the fundamental understanding and application of advanced carbon‐rich materials, though bottom‐up synthesis and structure–property correlation of these compounds remain challenging. In this work, an efficient synthetic route was employed to construct extended benzo[ k ]tetraphene‐derived oligomers with up to 13 fused rings. The molecular and electronic structures of these compounds were clearly elucidated. Precise correlation of molecular sizes and crystallization dynamics was established, thus demonstrating the pivotal balance between intermolecular interaction and molecular mobility for optimized processing of highly ordered solids of these extended conjugated molecules.},
doi = {10.1002/anie.201707595},
journal = {Angewandte Chemie (International Edition)},
number = 44,
volume = 56,
place = {United States},
year = {Fri Sep 08 00:00:00 EDT 2017},
month = {Fri Sep 08 00:00:00 EDT 2017}
}
Web of Science
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