Operando Spectromicroscopy of Sulfur Species in Lithium-Sulfur Batteries
Abstract
Abstract not provided.
- Authors:
-
- SLAC National Accelerator Lab., Menlo Park, CA (United States). Stanford Synchrotron Radiation Lightsource
- SLAC National Accelerator Lab., Menlo Park, CA (United States). Stanford Synchrotron Radiation Lightsource; Stanford Univ., CA (United States). Dept. of Materials Science and Engineering
- Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Joint Center for Energy Storage Research
- Publication Date:
- Research Org.:
- SLAC National Accelerator Lab., Menlo Park, CA (United States); Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1407716
- Alternate Identifier(s):
- OSTI ID: 1472266
- Report Number(s):
- SAND2018-9772J
Journal ID: ISSN 0013-4651
- Grant/Contract Number:
- AC02-76SF00515
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of the Electrochemical Society
- Additional Journal Information:
- Journal Volume: 165; Journal Issue: 1; Journal ID: ISSN 0013-4651
- Publisher:
- The Electrochemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; lithium-sulfur batteries; x-ray absorption spectroscopy; x-ray spectromicroscopy
Citation Formats
Miller, Elizabeth C., Kasse, Robert M., Heath, Khloe N., Perdue, Brian R., and Toney, Michael F. Operando Spectromicroscopy of Sulfur Species in Lithium-Sulfur Batteries. United States: N. p., 2017.
Web. doi:10.1149/2.0091801jes.
Miller, Elizabeth C., Kasse, Robert M., Heath, Khloe N., Perdue, Brian R., & Toney, Michael F. Operando Spectromicroscopy of Sulfur Species in Lithium-Sulfur Batteries. United States. https://doi.org/10.1149/2.0091801jes
Miller, Elizabeth C., Kasse, Robert M., Heath, Khloe N., Perdue, Brian R., and Toney, Michael F. Fri .
"Operando Spectromicroscopy of Sulfur Species in Lithium-Sulfur Batteries". United States. https://doi.org/10.1149/2.0091801jes. https://www.osti.gov/servlets/purl/1407716.
@article{osti_1407716,
title = {Operando Spectromicroscopy of Sulfur Species in Lithium-Sulfur Batteries},
author = {Miller, Elizabeth C. and Kasse, Robert M. and Heath, Khloe N. and Perdue, Brian R. and Toney, Michael F.},
abstractNote = {Abstract not provided.},
doi = {10.1149/2.0091801jes},
journal = {Journal of the Electrochemical Society},
number = 1,
volume = 165,
place = {United States},
year = {Fri Nov 03 00:00:00 EDT 2017},
month = {Fri Nov 03 00:00:00 EDT 2017}
}
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Works referenced in this record:
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT
journal, June 2005
- Ravel, B.; Newville, M.
- Journal of Synchrotron Radiation, Vol. 12, Issue 4
In Situ Raman Spectroscopy of Sulfur Speciation in Lithium–Sulfur Batteries
journal, January 2015
- Wu, Heng-Liang; Huff, Laura A.; Gewirth, Andrew A.
- ACS Applied Materials & Interfaces, Vol. 7, Issue 3
In Situ, Time-Resolved Raman Spectromicrotopography of an Operating Lithium-Ion Battery
journal, January 2004
- Luo, Yu; Cai, Wen-Bin; Xing, Xue-kun
- Electrochemical and Solid-State Letters, Vol. 7, Issue 1
Equilibrium Distribution of Polysulfide Ions in Aqueous Solutions at 25 °C: A New Approach for the Study of Polysulfides' Equilibria
journal, December 2004
- Kamyshny, Alexey; Goifman, Anatoly; Gun, Jenny
- Environmental Science & Technology, Vol. 38, Issue 24
A Sulfur Cathode with Pomegranate-Like Cluster Structure
journal, May 2015
- Li, Weiyang; Liang, Zheng; Lu, Zhenda
- Advanced Energy Materials, Vol. 5, Issue 16
Recent progress and remaining challenges in sulfur-based lithium secondary batteries – a review
journal, January 2013
- Bresser, Dominic; Passerini, Stefano; Scrosati, Bruno
- Chemical Communications, Vol. 49, Issue 90
Li-S Battery Analyzed by UV/Vis in Operando Mode
journal, June 2013
- Patel, Manu U. M.; Demir-Cakan, Rezan; Morcrette, Mathieu
- ChemSusChem, Vol. 6, Issue 7
Shuttle phenomenon – The irreversible oxidation mechanism of sulfur active material in Li–S battery
journal, August 2013
- Diao, Yan; Xie, Kai; Xiong, Shizhao
- Journal of Power Sources, Vol. 235
New insight into liquid electrolyte of rechargeable lithium/sulfur battery
journal, May 2013
- Zhang, Sheng S.
- Electrochimica Acta, Vol. 97
Review on Li-Sulfur Battery Systems: an Integral Perspective
journal, May 2015
- Rosenman, Ariel; Markevich, Elena; Salitra, Gregory
- Advanced Energy Materials, Vol. 5, Issue 16
Stabilizing lithium–sulphur cathodes using polysulphide reservoirs
journal, May 2011
- Ji, Xiulei; Evers, Scott; Black, Robert
- Nature Communications, Vol. 2, Article No. 325
Ab Initio Structure Search and in Situ 7 Li NMR Studies of Discharge Products in the Li–S Battery System
journal, November 2014
- See, Kimberly A.; Leskes, Michal; Griffin, John M.
- Journal of the American Chemical Society, Vol. 136, Issue 46
Best Practices for Operando Battery Experiments: Influences of X-ray Experiment Design on Observed Electrochemical Reactivity
journal, May 2015
- Borkiewicz, Olaf J.; Wiaderek, Kamila M.; Chupas, Peter J.
- The Journal of Physical Chemistry Letters, Vol. 6, Issue 11
Understanding the degradation mechanism of rechargeable lithium/sulfur cells: a comprehensive study of the sulfur–graphene oxide cathode after discharge–charge cycling
journal, January 2014
- Feng, Xuefei; Song, Min-Kyu; Stolte, Wayne C.
- Phys. Chem. Chem. Phys., Vol. 16, Issue 32
Operando Characterization of Intermediates Produced in a Lithium-Sulfur Battery
journal, January 2015
- Gorlin, Yelena; Siebel, Armin; Piana, Michele
- Journal of The Electrochemical Society, Vol. 162, Issue 7
Analytical Detection of Polysulfides in the Presence of Adsorption Additives by Operando X-ray Absorption Spectroscopy
journal, August 2015
- Dominko, Robert; Patel, Manu U. M.; Lapornik, Vida
- The Journal of Physical Chemistry C, Vol. 119, Issue 33
Towards Stable Lithium-Sulfur Batteries with a Low Self-Discharge Rate: Ion Diffusion Modulation and Anode Protection
journal, June 2015
- Xu, Wen-Tao; Peng, Hong-Jie; Huang, Jia-Qi
- ChemSusChem, Vol. 8, Issue 17
Rechargeable Lithium–Sulfur Batteries
journal, July 2014
- Manthiram, Arumugam; Fu, Yongzhu; Chung, Sheng-Heng
- Chemical Reviews, Vol. 114, Issue 23
Understanding the Charging Mechanism of Lithium-Sulfur Batteries Using Spatially Resolved Operando X-Ray Absorption Spectroscopy
journal, January 2016
- Gorlin, Yelena; Patel, Manu U. M.; Freiberg, Anna
- Journal of The Electrochemical Society, Vol. 163, Issue 6
Solvate Ionic Liquid Electrolyte for Li–S Batteries
journal, January 2013
- Dokko, Kaoru; Tachikawa, Naoki; Yamauchi, Kento
- Journal of The Electrochemical Society, Vol. 160, Issue 8
Polysulfide dissolution control: the common ion effect
journal, January 2013
- Shin, Eon Sung; Kim, Keon; Oh, Si Hyoung
- Chem. Commun., Vol. 49, Issue 20
Suppression of degradation for lithium iron phosphate cylindrical batteries by nano silicon surface modification
journal, January 2017
- Yang, Wenyu; Wang, Zhisheng; Chen, Lei
- RSC Advances, Vol. 7, Issue 53
X-ray Absorption Spectroscopy Characterization of a Li/S Cell
journal, January 2016
- Ye, Yifan; Kawase, Ayako; Song, Min-Kyu
- Nanomaterials, Vol. 6, Issue 1
Emerging In Situ and Operando Nanoscale X-Ray Imaging Techniques for Energy Storage Materials
journal, February 2015
- Nelson Weker, Johanna; Toney, Michael F.
- Advanced Functional Materials, Vol. 25, Issue 11
Polysulfide Shuttle Study in the Li/S Battery System
journal, January 2004
- Mikhaylik, Yuriy V.; Akridge, James R.
- Journal of The Electrochemical Society, Vol. 151, Issue 11, p. A1969-A1976
A Lithium/Dissolved Sulfur Battery with an Organic Electrolyte
journal, January 1979
- Rauh, R. D.
- Journal of The Electrochemical Society, Vol. 126, Issue 4
In Operando X-ray Diffraction and Transmission X-ray Microscopy of Lithium Sulfur Batteries
journal, March 2012
- Nelson, Johanna; Misra, Sumohan; Yang, Yuan
- Journal of the American Chemical Society, Vol. 134, Issue 14
Status and prospects in sulfur–carbon composites as cathode materials for rechargeable lithium–sulfur batteries
journal, October 2015
- Li, Zhen; Huang, Yimeng; Yuan, Lixia
- Carbon, Vol. 92
New Approaches for High Energy Density Lithium–Sulfur Battery Cathodes
journal, June 2012
- Evers, Scott; Nazar, Linda F.
- Accounts of Chemical Research, Vol. 46, Issue 5
Three-Dimensional Growth of Li 2 S in Lithium–Sulfur Batteries Promoted by a Redox Mediator
journal, December 2015
- Gerber, Laura C. H.; Frischmann, Peter D.; Fan, Frank Y.
- Nano Letters, Vol. 16, Issue 1
Balancing surface adsorption and diffusion of lithium-polysulfides on nonconductive oxides for lithium–sulfur battery design
journal, April 2016
- Tao, Xinyong; Wang, Jianguo; Liu, Chong
- Nature Communications, Vol. 7, Issue 1
Recent Advances in Electrolytes for Lithium-Sulfur Batteries
journal, April 2015
- Zhang, Shiguo; Ueno, Kazuhide; Dokko, Kaoru
- Advanced Energy Materials, Vol. 5, Issue 16
Sulfur Speciation in Li–S Batteries Determined by Operando X-ray Absorption Spectroscopy
journal, September 2013
- Cuisinier, Marine; Cabelguen, Pierre-Etienne; Evers, Scott
- The Journal of Physical Chemistry Letters, Vol. 4, Issue 19
The MicroAnalysis Toolkit: X-ray Fluorescence Image Processing Software
conference, January 2011
- Webb, S. M.; McNulty, Ian; Eyberger, Catherine
- THE 10TH INTERNATIONAL CONFERENCE ON X-RAY MICROSCOPY, AIP Conference Proceedings
Identification of lithium–sulfur battery discharge products through 6Li and 33S solid-state MAS and 7Li solution NMR spectroscopy
journal, January 2015
- Huff, Laura A.; Rapp, Jennifer L.; Baughman, Jessi A.
- Surface Science, Vol. 631
Lithium Sulfur Battery: Oxidation/Reduction Mechanisms of Polysulfides in THF Solutions
journal, January 1988
- Yamin, H.; Gorenshtein, A.; Penciner, J.
- Journal of The Electrochemical Society, Vol. 135, Issue 5, p. 1045-1048
Exploring 3D microstructural evolution in Li-Sulfur battery electrodes using in-situ X-ray tomography
journal, October 2016
- Yermukhambetova, Assiya; Tan, Chun; Daemi, Sohrab R.
- Scientific Reports, Vol. 6, Issue 1
X-ray Absorption Spectra of Dissolved Polysulfides in Lithium–Sulfur Batteries from First-Principles
journal, April 2014
- Pascal, Tod A.; Wujcik, Kevin H.; Velasco-Velez, Juan
- The Journal of Physical Chemistry Letters, Vol. 5, Issue 9
Direct observation of lithium polysulfides in lithium–sulfur batteries using operando X-ray diffraction
journal, May 2017
- Conder, Joanna; Bouchet, Renaud; Trabesinger, Sigita
- Nature Energy, Vol. 2, Issue 6
In operando scanning electron microscopy and ultraviolet–visible spectroscopy studies of lithium/sulfur cells using all solid-state polymer electrolyte
journal, July 2016
- Marceau, Hugues; Kim, Chi-Su; Paolella, Andrea
- Journal of Power Sources, Vol. 319
Lithium-sulfur batteries
journal, May 2014
- Nazar, Linda F.; Cuisinier, Marine; Pang, Quan
- MRS Bulletin, Vol. 39, Issue 5
Characterization of Polysulfide Radicals Present in an Ether-Based Electrolyte of a Lithium-Sulfur Battery During Initial Discharge Using In Situ X-Ray Absorption Spectroscopy Experiments and First-Principles Calculations
journal, June 2015
- Wujcik, Kevin H.; Pascal, Tod A.; Pemmaraju, C. D.
- Advanced Energy Materials, Vol. 5, Issue 16
Li–O2 and Li–S batteries with high energy storage
journal, January 2012
- Bruce, Peter G.; Freunberger, Stefan A.; Hardwick, Laurence J.
- Nature Materials, Vol. 11, Issue 1, p. 19-29
Ionic Conduction in Lithium Ion Battery Composite Electrode Governs Cross-sectional Reaction Distribution
journal, May 2016
- Orikasa, Yuki; Gogyo, Yuma; Yamashige, Hisao
- Scientific Reports, Vol. 6, Issue 1
Caste-specific RNA editomes in the leaf-cutting ant Acromyrmex echinatior
journal, September 2014
- Li, Qiye; Wang, Zongji; Lian, Jinmin
- Nature Communications, Vol. 5, Issue 1
New insight into the working mechanism of lithium–sulfur batteries: in situ and operando X-ray diffraction characterization
journal, January 2013
- Waluś, Sylwia; Barchasz, Céline; Colin, Jean-François
- Chemical Communications, Vol. 49, Issue 72
In situ monitoring the viscosity change of an electrolyte in a Li–S battery
journal, January 2017
- Ding, Ning; Li, Xiaodong; Chien, Sheau Wei
- Chemical Communications, Vol. 53, Issue 73
The Li–S battery: an investigation of redox shuttle and self-discharge behaviour with LiNO 3 -containing electrolytes
journal, January 2016
- Lacey, Matthew J.; Yalamanchili, Anurag; Maibach, Julia
- RSC Advances, Vol. 6, Issue 5
High Energy Density Lithium-Sulfur Batteries: Challenges of Thick Sulfur Cathodes
journal, March 2015
- Lv, Dongping; Zheng, Jianming; Li, Qiuyan
- Advanced Energy Materials, Vol. 5, Issue 16, Article No. 1402290
Works referencing / citing this record:
The Absence and Importance of Operando Techniques for Metal‐Free Catalysts
journal, November 2018
- Yuan, Yifei; Li, Matthew; Bai, Zhengyu
- Advanced Materials, Vol. 31, Issue 13
A Lithium-Sulfur Cell Based on Reversible Lithium Deposition from a Li 2 S Cathode Host onto a Hostless-Anode Substrate
journal, July 2018
- Nanda, Sanjay; Gupta, Abhay; Manthiram, Arumugam
- Advanced Energy Materials, Vol. 8, Issue 25
Deciphering the Reaction Mechanism of Lithium–Sulfur Batteries by In Situ/Operando Synchrotron‐Based Characterization Techniques
journal, March 2019
- Yan, Yingying; Cheng, Chen; Zhang, Liang
- Advanced Energy Materials, Vol. 9, Issue 18
Polysulfide Speciation in the Bulk Electrolyte of a Lithium Sulfur Battery
journal, January 2018
- McBrayer, Josefine D.; Beechem, Thomas E.; Perdue, Brian R.
- Journal of The Electrochemical Society, Vol. 165, Issue 5
Rate Constants of Electrochemical Reactions in a Lithium-Sulfur Cell Determined by Operando X-ray Absorption Spectroscopy
journal, January 2018
- Wang, Dunyang Rita; Shah, Deep B.; Maslyn, Jacqueline A.
- Journal of The Electrochemical Society, Vol. 165, Issue 14