A new Pu(iii) coordination geometry in (C5H5NBr)2[PuCl3(H2O)5 ]·2Cl·2H2O as obtained via supramolecular assembly in aqueous, high chloride media
Abstract
Here, a novel hydrated Pu(iii) chloride, (C5H5NBr)2[PuCl3(H2O)5]·Cl·2H2O, is prepared from aqueous media and the non-covalent interaction pairings are rationalized using electrostatic potentials.
- Authors:
-
- George Washington Univ., Washington, DC (United States)
- Univ. of São Paulo (Brazil)
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- Univ. at Buffalo, State Univ. of New York, Buffalo, NY (United States)
- Publication Date:
- Research Org.:
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1406758
- Report Number(s):
- PNNL-SA-128010
Journal ID: ISSN 1359-7345; CHCOFS; 45304036L
- Grant/Contract Number:
- AC05-76RL01830
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ChemComm
- Additional Journal Information:
- Journal Volume: 53; Journal Issue: 78; Journal ID: ISSN 1359-7345
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Surbella, III, Robert G., Ducati, Lucas C., Pellegrini, Kristi L., McNamara, Bruce K., Autschbach, Jochen, Schwantes, Jon M., and Cahill, Christopher L. A new Pu(iii) coordination geometry in (C5H5NBr)2[PuCl3(H2O)5 ]·2Cl·2H2O as obtained via supramolecular assembly in aqueous, high chloride media. United States: N. p., 2017.
Web. doi:10.1039/c7cc05988d.
Surbella, III, Robert G., Ducati, Lucas C., Pellegrini, Kristi L., McNamara, Bruce K., Autschbach, Jochen, Schwantes, Jon M., & Cahill, Christopher L. A new Pu(iii) coordination geometry in (C5H5NBr)2[PuCl3(H2O)5 ]·2Cl·2H2O as obtained via supramolecular assembly in aqueous, high chloride media. United States. https://doi.org/10.1039/c7cc05988d
Surbella, III, Robert G., Ducati, Lucas C., Pellegrini, Kristi L., McNamara, Bruce K., Autschbach, Jochen, Schwantes, Jon M., and Cahill, Christopher L. Tue .
"A new Pu(iii) coordination geometry in (C5H5NBr)2[PuCl3(H2O)5 ]·2Cl·2H2O as obtained via supramolecular assembly in aqueous, high chloride media". United States. https://doi.org/10.1039/c7cc05988d. https://www.osti.gov/servlets/purl/1406758.
@article{osti_1406758,
title = {A new Pu(iii) coordination geometry in (C5H5NBr)2[PuCl3(H2O)5 ]·2Cl·2H2O as obtained via supramolecular assembly in aqueous, high chloride media},
author = {Surbella, III, Robert G. and Ducati, Lucas C. and Pellegrini, Kristi L. and McNamara, Bruce K. and Autschbach, Jochen and Schwantes, Jon M. and Cahill, Christopher L.},
abstractNote = {Here, a novel hydrated Pu(iii) chloride, (C5H5NBr)2[PuCl3(H2O)5]·Cl·2H2O, is prepared from aqueous media and the non-covalent interaction pairings are rationalized using electrostatic potentials.},
doi = {10.1039/c7cc05988d},
journal = {ChemComm},
number = 78,
volume = 53,
place = {United States},
year = {Tue Sep 12 00:00:00 EDT 2017},
month = {Tue Sep 12 00:00:00 EDT 2017}
}
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Cited by: 6 works
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Figures / Tables:
Fig. 2: Top: Double chains of [PuCl3(H2O)5] tectons (circled) form a layer in (0–10). Bottom: Hydrogen bonds link the [PuCl3(H2O)5] tectons into chains along [100]. The chloride anions and 4-BrPyH cations are omitted for clarity.
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