skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: A new Pu(iii) coordination geometry in (C5H5NBr)2[PuCl3(H2O)5 ]·2Cl·2H2O as obtained via supramolecular assembly in aqueous, high chloride media

Abstract

Here, a novel hydrated Pu(iii) chloride, (C5H5NBr)2[PuCl3(H2O)5]·Cl·2H2O, is prepared from aqueous media and the non-covalent interaction pairings are rationalized using electrostatic potentials.

Authors:
ORCiD logo [1]; ORCiD logo [2];  [3];  [3]; ORCiD logo [4];  [2]; ORCiD logo [1]
  1. George Washington Univ., Washington, DC (United States)
  2. Univ. of São Paulo (Brazil)
  3. Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
  4. Univ. at Buffalo, State Univ. of New York, Buffalo, NY (United States)
Publication Date:
Research Org.:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1406758
Report Number(s):
PNNL-SA-128010
Journal ID: ISSN 1359-7345; CHCOFS; 45304036L
Grant/Contract Number:  
AC05-76RL01830
Resource Type:
Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Volume: 53; Journal Issue: 78; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Surbella, III, Robert G., Ducati, Lucas C., Pellegrini, Kristi L., McNamara, Bruce K., Autschbach, Jochen, Schwantes, Jon M., and Cahill, Christopher L. A new Pu(iii) coordination geometry in (C5H5NBr)2[PuCl3(H2O)5 ]·2Cl·2H2O as obtained via supramolecular assembly in aqueous, high chloride media. United States: N. p., 2017. Web. doi:10.1039/c7cc05988d.
Surbella, III, Robert G., Ducati, Lucas C., Pellegrini, Kristi L., McNamara, Bruce K., Autschbach, Jochen, Schwantes, Jon M., & Cahill, Christopher L. A new Pu(iii) coordination geometry in (C5H5NBr)2[PuCl3(H2O)5 ]·2Cl·2H2O as obtained via supramolecular assembly in aqueous, high chloride media. United States. doi:10.1039/c7cc05988d.
Surbella, III, Robert G., Ducati, Lucas C., Pellegrini, Kristi L., McNamara, Bruce K., Autschbach, Jochen, Schwantes, Jon M., and Cahill, Christopher L. Tue . "A new Pu(iii) coordination geometry in (C5H5NBr)2[PuCl3(H2O)5 ]·2Cl·2H2O as obtained via supramolecular assembly in aqueous, high chloride media". United States. doi:10.1039/c7cc05988d. https://www.osti.gov/servlets/purl/1406758.
@article{osti_1406758,
title = {A new Pu(iii) coordination geometry in (C5H5NBr)2[PuCl3(H2O)5 ]·2Cl·2H2O as obtained via supramolecular assembly in aqueous, high chloride media},
author = {Surbella, III, Robert G. and Ducati, Lucas C. and Pellegrini, Kristi L. and McNamara, Bruce K. and Autschbach, Jochen and Schwantes, Jon M. and Cahill, Christopher L.},
abstractNote = {Here, a novel hydrated Pu(iii) chloride, (C5H5NBr)2[PuCl3(H2O)5]·Cl·2H2O, is prepared from aqueous media and the non-covalent interaction pairings are rationalized using electrostatic potentials.},
doi = {10.1039/c7cc05988d},
journal = {ChemComm},
number = 78,
volume = 53,
place = {United States},
year = {2017},
month = {9}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Citation Metrics:
Cited by: 2 works
Citation information provided by
Web of Science

Figures / Tables:

Fig. 2 Fig. 2: Top: Double chains of [PuCl3(H2O)5] tectons (circled) form a layer in (0–10). Bottom: Hydrogen bonds link the [PuCl3(H2O)5] tectons into chains along [100]. The chloride anions and 4-BrPyH cations are omitted for clarity.

Save / Share:

Works referenced in this record:

Self-assembly of [UO2X4]2− (X=Cl, Br) dianions with γ substituted pyridinium cations: Structural systematics and fluorescence properties
journal, April 2016

  • Surbella, Robert G.; Andrews, Michael B.; Cahill, Christopher L.
  • Journal of Solid State Chemistry, Vol. 236
  • DOI: 10.1016/j.jssc.2015.09.011

The Halogen Bond
journal, January 2016


Fundamental Investigations of Separations Science for Radioactive Materials
journal, July 2000

  • Nash, Kenneth L.; Barrans, Richard E.; Chiarizia, Renato
  • Solvent Extraction and Ion Exchange, Vol. 18, Issue 4
  • DOI: 10.1080/07366290008934700

The Cambridge Structural Database
journal, April 2016

  • Groom, Colin R.; Bruno, Ian J.; Lightfoot, Matthew P.
  • Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials, Vol. 72, Issue 2, p. 171-179
  • DOI: 10.1107/S2052520616003954

Transuranic Hybrid Materials: Crystallographic and Computational Metrics of Supramolecular Assembly
journal, July 2017

  • Surbella, Robert G.; Ducati, Lucas C.; Pellegrini, Kristi L.
  • Journal of the American Chemical Society, Vol. 139, Issue 31
  • DOI: 10.1021/jacs.7b05689

The Structure and Synthesis of Plutonium(III) Chlorides from Aqueous Solution
journal, October 2006

  • Wilson, Richard E.; Almond, Philip M.; Burns, Peter C.
  • Inorganic Chemistry, Vol. 45, Issue 21
  • DOI: 10.1021/ic060979a

The exploration of supramolecular interactions stemming from the [UO 2 (NCS) 4 (H 2 O)] 2− tecton and substituted pyridinium cations
journal, January 2014

  • Surbella III, Robert G.; Cahill, Christopher L.
  • CrystEngComm, Vol. 16, Issue 12
  • DOI: 10.1039/C3CE42106F

Exploring the solution behavior of f-element coordination compounds: a case study on some trivalent rare earth and plutonium complexes
journal, January 2013

  • Löble, Matthias W.; Oña-Burgos, Pascual; Fernández, Ignacio
  • Chemical Science, Vol. 4, Issue 9
  • DOI: 10.1039/c3sc50708d

Uncovering f-element bonding differences and electronic structure in a series of 1 : 3 and 1 : 4 complexes with a diselenophosphinate ligand
journal, January 2013

  • Jones, Matthew B.; Gaunt, Andrew J.; Gordon, John C.
  • Chemical Science, Vol. 4, Issue 3
  • DOI: 10.1039/c2sc21806b

Redox speciation of plutonium
journal, May 1997

  • Choppin, G. R.; Bond, A. H.; Hromadka, P. M.
  • Journal of Radioanalytical and Nuclear Chemistry, Vol. 219, Issue 2
  • DOI: 10.1007/BF02038501

Differentiating between Trivalent Lanthanides and Actinides
journal, June 2012

  • Polinski, Matthew J.; Grant, Daniel J.; Wang, Shuao
  • Journal of the American Chemical Society, Vol. 134, Issue 25
  • DOI: 10.1021/ja303804r

Covalency in f-element complexes
journal, January 2013

  • Neidig, Michael L.; Clark, David L.; Martin, Richard L.
  • Coordination Chemistry Reviews, Vol. 257, Issue 2
  • DOI: 10.1016/j.ccr.2012.04.029

New developments in the Inorganic Crystal Structure Database (ICSD): accessibility in support of materials research and design
journal, May 2002

  • Belsky, Alec; Hellenbrandt, Mariette; Karen, Vicky Lynn
  • Acta Crystallographica Section B Structural Science, Vol. 58, Issue 3
  • DOI: 10.1107/S0108768102006948

Incipient class II mixed valency in a plutonium solid-state compound
journal, May 2017

  • Cary, Samantha K.; Galley, Shane S.; Marsh, Matthew L.
  • Nature Chemistry, Vol. 9, Issue 9
  • DOI: 10.1038/nchem.2777

Recent developments in nonaqueous plutonium coordination chemistry
journal, June 2010


An overview and historical look back at the solvent extraction using nitrogen donor ligands to extract and separate An(III) from Ln(III)
journal, January 2008

  • Ekberg, Christian; Fermvik, Anna; Retegan, Teodora
  • Radiochimica Acta, Vol. 96, Issue 4-5
  • DOI: 10.1524/ract.2008.1483

Investigation of Aquo and Chloro Complexes of UO 2 2+ , NpO 2 + , Np 4+ , and Pu 3+ by X-ray Absorption Fine Structure Spectroscopy
journal, October 1997

  • Allen, P. G.; Bucher, J. J.; Shuh, D. K.
  • Inorganic Chemistry, Vol. 36, Issue 21
  • DOI: 10.1021/ic970502m

The uranyl tetrachloride anion as a tecton in the assembly of U(VI) hybrid materials
journal, January 2009

  • Deifel, Nicholas P.; Cahill, Christopher L.
  • CrystEngComm, Vol. 11, Issue 12
  • DOI: 10.1039/b911470j

Environmental Speciation of Actinides
journal, June 2012

  • Maher, Kate; Bargar, John R.; Brown, Gordon E.
  • Inorganic Chemistry, Vol. 52, Issue 7
  • DOI: 10.1021/ic301686d

Coordination Chemistry of Trivalent Lanthanide and Actinide Ions in Dilute and Concentrated Chloride Solutions
journal, February 2000

  • Allen, P. G.; Bucher, J. J.; Shuh, D. K.
  • Inorganic Chemistry, Vol. 39, Issue 3
  • DOI: 10.1021/ic9905953

Preparation and crystal structures of plutonium(III) pentachloro complexes, K2PuCl5 and Rb2PuCl5
journal, February 1988


Avoiding “Synthon Crossover” in Crystal Engineering with Halogen Bonds and Hydrogen Bonds
journal, December 2011

  • Aakeröy, Christer B.; Chopade, Prashant D.; Desper, John
  • Crystal Growth & Design, Vol. 11, Issue 12
  • DOI: 10.1021/cg2009013

The Hydrogen Bond in the Solid State
journal, January 2002


Synthesis and structural characterization of a molecular plutonium(iv) compound constructed from dimeric building blocks
journal, January 2007

  • Runde, Wolfgang; Brodnax, Lia F.; Goff, George S.
  • Chemical Communications, Issue 17
  • DOI: 10.1039/b617878b

Engaging the Terminal: Promoting Halogen Bonding Interactions with Uranyl Oxo Atoms
journal, August 2017

  • Carter, Korey P.; Kalaj, Mark; Surbella, Robert G.
  • Chemistry - A European Journal, Vol. 23, Issue 61
  • DOI: 10.1002/chem.201702744

Ammoniates of plutonium(III) and (IV) halides
journal, January 1972


Structural Periodicity in Plutonium(IV) Sulfates
journal, June 2011


Crystallographic studies of some transuranic trihalides: 239PuCl3, 244CmBr3, 249BkBr3 and 249CfBr3
journal, March 1975

  • Burns, John H.; Peterson, J. R.; Stevenson, J. N.
  • Journal of Inorganic and Nuclear Chemistry, Vol. 37, Issue 3
  • DOI: 10.1016/0022-1902(75)80532-X

Flexible coordination environments of lanthanide complexes grown from chloride-based ionic liquids
journal, January 2008

  • Hines, C. Corey; Cordes, David B.; Griffin, Scott T.
  • New Journal of Chemistry, Vol. 32, Issue 5
  • DOI: 10.1039/b800045j

Low-Valent Molecular Plutonium Halide Complexes
journal, September 2008

  • Gaunt, Andrew J.; Reilly, Sean D.; Enriquez, Alejandro E.
  • Inorganic Chemistry, Vol. 47, Issue 18
  • DOI: 10.1021/ic8009139

Actinide speciation in the environment
journal, June 2007


Harnessing uranyl oxo atoms via halogen bonding interactions in molecular uranyl materials featuring 2,5-diiodobenzoic acid and N-donor capping ligands
journal, January 2017

  • Carter, Korey P.; Kalaj, Mark; Cahill, Christopher L.
  • Inorganic Chemistry Frontiers, Vol. 4, Issue 1
  • DOI: 10.1039/C6QI00352D

High-Yield Synthesis and Single-Crystal X-ray Structure of a Plutonium(III) Aquo Complex:  [Pu(H 2 O) 9 ][CF 3 SO 3 ] 3
journal, June 2001

  • Matonic, John H.; Scott, Brian L.; Neu, Mary P.
  • Inorganic Chemistry, Vol. 40, Issue 12
  • DOI: 10.1021/ic015509p

Encoding and decoding hydrogen-bond patterns of organic compounds
journal, April 1990


Structural Characterization of Pu[N(SiMe 3 ) 2 ] 3 , a Synthetically Useful Nonaqueous Plutonium(III) Precursor
journal, January 2008

  • Gaunt, Andrew J.; Enriquez, Alejandro E.; Reilly, Sean D.
  • Inorganic Chemistry, Vol. 47, Issue 1
  • DOI: 10.1021/ic701673e

Utilizing hydrogen bonds and halogen–halogen interactions in the design of uranyl hybrid materials
journal, January 2012

  • Andrews, Michael B.; Cahill, Christopher L.
  • Dalton Trans., Vol. 41, Issue 14
  • DOI: 10.1039/C2DT11985D

Heterogeneous Reduction of PuO 2 with Fe(II): Importance of the Fe(III) Reaction Product
journal, May 2011

  • Felmy, Andrew R.; Moore, Dean A.; Rosso, Kevin M.
  • Environmental Science & Technology, Vol. 45, Issue 9
  • DOI: 10.1021/es104212g

Probing the Influence of N-Donor Capping Ligands on Supramolecular Assembly in Molecular Uranyl Materials
journal, December 2015

  • Carter, Korey P.; Kalaj, Mark; Cahill, Christopher L.
  • European Journal of Inorganic Chemistry, Vol. 2016, Issue 1
  • DOI: 10.1002/ejic.201501118

Structural Systematics of Rare Earth Complexes. XXII 4-Methylpyridinium Salts of Diverse Complex Aqua/Chloro/Lanthanoid(III) Species
journal, November 2006

  • Semenova, Lioubov I.; Skelton, Brian W.; White, Allan H.
  • Zeitschrift für anorganische und allgemeine Chemie, Vol. 632, Issue 15
  • DOI: 10.1002/zaac.200600206

Actinide speciation in the environment
journal, January 2003


    Works referencing / citing this record:

    Engaging the Terminal: Promoting Halogen Bonding Interactions with Uranyl Oxo Atoms
    journal, August 2017

    • Carter, Korey P.; Kalaj, Mark; Surbella, Robert G.
    • Chemistry - A European Journal, Vol. 23, Issue 61
    • DOI: 10.1002/chem.201702744

    Structural Periodicity in Plutonium(IV) Sulfates
    journal, June 2011


    Ammoniates of plutonium(III) and (IV) halides
    journal, January 1972


    Actinide speciation in the environment
    journal, June 2007


    Probing the Influence of N-Donor Capping Ligands on Supramolecular Assembly in Molecular Uranyl Materials
    journal, December 2015

    • Carter, Korey P.; Kalaj, Mark; Cahill, Christopher L.
    • European Journal of Inorganic Chemistry, Vol. 2016, Issue 1
    • DOI: 10.1002/ejic.201501118

    Encoding and decoding hydrogen-bond patterns of organic compounds
    journal, April 1990


    Structural Characterization of Pu[N(SiMe 3 ) 2 ] 3 , a Synthetically Useful Nonaqueous Plutonium(III) Precursor
    journal, January 2008

    • Gaunt, Andrew J.; Enriquez, Alejandro E.; Reilly, Sean D.
    • Inorganic Chemistry, Vol. 47, Issue 1
    • DOI: 10.1021/ic701673e

    Crystallographic studies of some transuranic trihalides: 239PuCl3, 244CmBr3, 249BkBr3 and 249CfBr3
    journal, March 1975

    • Burns, John H.; Peterson, J. R.; Stevenson, J. N.
    • Journal of Inorganic and Nuclear Chemistry, Vol. 37, Issue 3
    • DOI: 10.1016/0022-1902(75)80532-x

    Environmental Speciation of Actinides
    journal, June 2012

    • Maher, Kate; Bargar, John R.; Brown, Gordon E.
    • Inorganic Chemistry, Vol. 52, Issue 7
    • DOI: 10.1021/ic301686d

    New developments in the Inorganic Crystal Structure Database (ICSD): accessibility in support of materials research and design
    journal, May 2002

    • Belsky, Alec; Hellenbrandt, Mariette; Karen, Vicky Lynn
    • Acta Crystallographica Section B Structural Science, Vol. 58, Issue 3
    • DOI: 10.1107/s0108768102006948

    Synthesis and structural characterization of a molecular plutonium(iv) compound constructed from dimeric building blocks
    journal, January 2007

    • Runde, Wolfgang; Brodnax, Lia F.; Goff, George S.
    • Chemical Communications, Issue 17
    • DOI: 10.1039/b617878b

    Harnessing uranyl oxo atoms via halogen bonding interactions in molecular uranyl materials featuring 2,5-diiodobenzoic acid and N-donor capping ligands
    journal, January 2017

    • Carter, Korey P.; Kalaj, Mark; Cahill, Christopher L.
    • Inorganic Chemistry Frontiers, Vol. 4, Issue 1
    • DOI: 10.1039/c6qi00352d

    Structural Systematics of Rare Earth Complexes. XXII 4-Methylpyridinium Salts of Diverse Complex Aqua/Chloro/Lanthanoid(III) Species
    journal, November 2006

    • Semenova, Lioubov I.; Skelton, Brian W.; White, Allan H.
    • Zeitschrift für anorganische und allgemeine Chemie, Vol. 632, Issue 15
    • DOI: 10.1002/zaac.200600206

    Self-assembly of [UO2X4]2− (X=Cl, Br) dianions with γ substituted pyridinium cations: Structural systematics and fluorescence properties
    journal, April 2016

    • Surbella, Robert G.; Andrews, Michael B.; Cahill, Christopher L.
    • Journal of Solid State Chemistry, Vol. 236
    • DOI: 10.1016/j.jssc.2015.09.011

    Utilizing hydrogen bonds and halogen–halogen interactions in the design of uranyl hybrid materials
    journal, January 2012

    • Andrews, Michael B.; Cahill, Christopher L.
    • Dalton Trans., Vol. 41, Issue 14
    • DOI: 10.1039/c2dt11985d

    The Halogen Bond
    journal, January 2016


    The exploration of supramolecular interactions stemming from the [UO 2 (NCS) 4 (H 2 O)] 2− tecton and substituted pyridinium cations
    journal, January 2014

    • Surbella III, Robert G.; Cahill, Christopher L.
    • CrystEngComm, Vol. 16, Issue 12
    • DOI: 10.1039/c3ce42106f

    Fundamental Investigations of Separations Science for Radioactive Materials
    journal, July 2000

    • Nash, Kenneth L.; Barrans, Richard E.; Chiarizia, Renato
    • Solvent Extraction and Ion Exchange, Vol. 18, Issue 4
    • DOI: 10.1080/07366290008934700

    Heterogeneous Reduction of PuO 2 with Fe(II): Importance of the Fe(III) Reaction Product
    journal, May 2011

    • Felmy, Andrew R.; Moore, Dean A.; Rosso, Kevin M.
    • Environmental Science & Technology, Vol. 45, Issue 9
    • DOI: 10.1021/es104212g

    Flexible coordination environments of lanthanide complexes grown from chloride-based ionic liquids
    journal, January 2008

    • Hines, C. Corey; Cordes, David B.; Griffin, Scott T.
    • New Journal of Chemistry, Vol. 32, Issue 5
    • DOI: 10.1039/b800045j

    Preparation and crystal structures of plutonium(III) pentachloro complexes, K2PuCl5 and Rb2PuCl5
    journal, February 1988


    High-Yield Synthesis and Single-Crystal X-ray Structure of a Plutonium(III) Aquo Complex:  [Pu(H 2 O) 9 ][CF 3 SO 3 ] 3
    journal, June 2001

    • Matonic, John H.; Scott, Brian L.; Neu, Mary P.
    • Inorganic Chemistry, Vol. 40, Issue 12
    • DOI: 10.1021/ic015509p

    The Structure and Synthesis of Plutonium(III) Chlorides from Aqueous Solution
    journal, October 2006

    • Wilson, Richard E.; Almond, Philip M.; Burns, Peter C.
    • Inorganic Chemistry, Vol. 45, Issue 21
    • DOI: 10.1021/ic060979a

    The Cambridge Structural Database
    journal, April 2016

    • Groom, Colin R.; Bruno, Ian J.; Lightfoot, Matthew P.
    • Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials, Vol. 72, Issue 2, p. 171-179
    • DOI: 10.1107/s2052520616003954

    Differentiating between Trivalent Lanthanides and Actinides
    journal, June 2012

    • Polinski, Matthew J.; Grant, Daniel J.; Wang, Shuao
    • Journal of the American Chemical Society, Vol. 134, Issue 25
    • DOI: 10.1021/ja303804r

    Transuranic Hybrid Materials: Crystallographic and Computational Metrics of Supramolecular Assembly
    journal, July 2017

    • Surbella, Robert G.; Ducati, Lucas C.; Pellegrini, Kristi L.
    • Journal of the American Chemical Society, Vol. 139, Issue 31
    • DOI: 10.1021/jacs.7b05689

    Recent developments in nonaqueous plutonium coordination chemistry
    journal, June 2010


    Exploring the solution behavior of f-element coordination compounds: a case study on some trivalent rare earth and plutonium complexes
    journal, January 2013

    • Löble, Matthias W.; Oña-Burgos, Pascual; Fernández, Ignacio
    • Chemical Science, Vol. 4, Issue 9
    • DOI: 10.1039/c3sc50708d

    Low-Valent Molecular Plutonium Halide Complexes
    journal, September 2008

    • Gaunt, Andrew J.; Reilly, Sean D.; Enriquez, Alejandro E.
    • Inorganic Chemistry, Vol. 47, Issue 18
    • DOI: 10.1021/ic8009139

    Avoiding “Synthon Crossover” in Crystal Engineering with Halogen Bonds and Hydrogen Bonds
    journal, December 2011

    • Aakeröy, Christer B.; Chopade, Prashant D.; Desper, John
    • Crystal Growth & Design, Vol. 11, Issue 12
    • DOI: 10.1021/cg2009013

    Redox speciation of plutonium
    journal, May 1997

    • Choppin, G. R.; Bond, A. H.; Hromadka, P. M.
    • Journal of Radioanalytical and Nuclear Chemistry, Vol. 219, Issue 2
    • DOI: 10.1007/bf02038501

    Uncovering f-element bonding differences and electronic structure in a series of 1 : 3 and 1 : 4 complexes with a diselenophosphinate ligand
    journal, January 2013

    • Jones, Matthew B.; Gaunt, Andrew J.; Gordon, John C.
    • Chemical Science, Vol. 4, Issue 3
    • DOI: 10.1039/c2sc21806b

    Incipient class II mixed valency in a plutonium solid-state compound
    journal, May 2017

    • Cary, Samantha K.; Galley, Shane S.; Marsh, Matthew L.
    • Nature Chemistry, Vol. 9, Issue 9
    • DOI: 10.1038/nchem.2777

    The uranyl tetrachloride anion as a tecton in the assembly of U(VI) hybrid materials
    journal, January 2009

    • Deifel, Nicholas P.; Cahill, Christopher L.
    • CrystEngComm, Vol. 11, Issue 12
    • DOI: 10.1039/b911470j

    Investigation of Aquo and Chloro Complexes of UO 2 2+ , NpO 2 + , Np 4+ , and Pu 3+ by X-ray Absorption Fine Structure Spectroscopy
    journal, October 1997

    • Allen, P. G.; Bucher, J. J.; Shuh, D. K.
    • Inorganic Chemistry, Vol. 36, Issue 21
    • DOI: 10.1021/ic970502m

    An overview and historical look back at the solvent extraction using nitrogen donor ligands to extract and separate An(III) from Ln(III)
    journal, January 2008

    • Ekberg, Christian; Fermvik, Anna; Retegan, Teodora
    • Radiochimica Acta, Vol. 96, Issue 4-5
    • DOI: 10.1524/ract.2008.1483

    The Hydrogen Bond in the Solid State
    journal, January 2002


    Covalency in f-element complexes
    journal, January 2013

    • Neidig, Michael L.; Clark, David L.; Martin, Richard L.
    • Coordination Chemistry Reviews, Vol. 257, Issue 2
    • DOI: 10.1016/j.ccr.2012.04.029

    Coordination Chemistry of Trivalent Lanthanide and Actinide Ions in Dilute and Concentrated Chloride Solutions
    journal, February 2000

    • Allen, P. G.; Bucher, J. J.; Shuh, D. K.
    • Inorganic Chemistry, Vol. 39, Issue 3
    • DOI: 10.1021/ic9905953

      Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.