Electrostatic‐Assisted Liquefaction of Porous Carbons
Abstract
Abstract Porous liquids are a newly developed porous material that combine unique fluidity with permanent porosity, which exhibit promising functionalities for a variety of applications. However, the apparent incompatibility between fluidity and permanent porosity makes the stabilization of porous nanoparticle with still empty pores in the dense liquid phase a significant challenging. Herein, by exploiting the electrostatic interaction between carbon networks and polymerized ionic liquids, we demonstrate that carbon‐based porous nanoarchitectures can be well stabilized in liquids to afford permanent porosity, and thus opens up a new approach to prepare porous carbon liquids. Furthermore, we hope this facile synthesis strategy can be widely applicated to fabricate other types of porous liquids, such as those (e.g., carbon nitride, boron nitride, metal–organic frameworks, covalent organic frameworks etc.) also having the electrostatic interaction with polymerized ionic liquids, evidently advancing the development and understanding of porous liquids.
- Authors:
-
[3];
[4];
[4];
[4];
[2]
- Chemical Science Division Oak Ridge National Laboratory Oak Ridge TN 37831 USA, Key Laboratory of Space Applied Physics and Chemistry, Ministry of Education, School of Natural and Applied Sciences Northwestern Polytechnical University Xi'an Shaanxi 710129 P.R. China
- Chemical Science Division Oak Ridge National Laboratory Oak Ridge TN 37831 USA, Department of Chemistry University of Tennessee Knoxville TN 37996 USA
- Chemical Science Division Oak Ridge National Laboratory Oak Ridge TN 37831 USA, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry Fuzhou University Fouzhou 350116 P.R. China
- Chemical Science Division Oak Ridge National Laboratory Oak Ridge TN 37831 USA
- State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, International Joint Research Laboratory of Nano-Micro Architecture Chemistry, College of Chemistry Jilin University Changchun Jilin 130012 P.R. China
- Materials Science and Technology Division Oak Ridge National Laboratory Oak Ridge TN 37831 USA
- Key Laboratory of Space Applied Physics and Chemistry, Ministry of Education, School of Natural and Applied Sciences Northwestern Polytechnical University Xi'an Shaanxi 710129 P.R. China
- Department of Chemistry University of Tennessee Knoxville TN 37996 USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1402090
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Angewandte Chemie
- Additional Journal Information:
- Journal Name: Angewandte Chemie Journal Volume: 129 Journal Issue: 47; Journal ID: ISSN 0044-8249
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Li, Peipei, Schott, Jennifer A., Zhang, Jinshui, Mahurin, Shannon M., Sheng, Yujie, Qiao, Zhen‐An, Hu, Xunxiang, Cui, Guokai, Yao, Dongdong, Brown, Suree, Zheng, Yaping, and Dai, Sheng. Electrostatic‐Assisted Liquefaction of Porous Carbons. Germany: N. p., 2017.
Web. doi:10.1002/ange.201708843.
Li, Peipei, Schott, Jennifer A., Zhang, Jinshui, Mahurin, Shannon M., Sheng, Yujie, Qiao, Zhen‐An, Hu, Xunxiang, Cui, Guokai, Yao, Dongdong, Brown, Suree, Zheng, Yaping, & Dai, Sheng. Electrostatic‐Assisted Liquefaction of Porous Carbons. Germany. https://doi.org/10.1002/ange.201708843
Li, Peipei, Schott, Jennifer A., Zhang, Jinshui, Mahurin, Shannon M., Sheng, Yujie, Qiao, Zhen‐An, Hu, Xunxiang, Cui, Guokai, Yao, Dongdong, Brown, Suree, Zheng, Yaping, and Dai, Sheng. Mon .
"Electrostatic‐Assisted Liquefaction of Porous Carbons". Germany. https://doi.org/10.1002/ange.201708843.
@article{osti_1402090,
title = {Electrostatic‐Assisted Liquefaction of Porous Carbons},
author = {Li, Peipei and Schott, Jennifer A. and Zhang, Jinshui and Mahurin, Shannon M. and Sheng, Yujie and Qiao, Zhen‐An and Hu, Xunxiang and Cui, Guokai and Yao, Dongdong and Brown, Suree and Zheng, Yaping and Dai, Sheng},
abstractNote = {Abstract Porous liquids are a newly developed porous material that combine unique fluidity with permanent porosity, which exhibit promising functionalities for a variety of applications. However, the apparent incompatibility between fluidity and permanent porosity makes the stabilization of porous nanoparticle with still empty pores in the dense liquid phase a significant challenging. Herein, by exploiting the electrostatic interaction between carbon networks and polymerized ionic liquids, we demonstrate that carbon‐based porous nanoarchitectures can be well stabilized in liquids to afford permanent porosity, and thus opens up a new approach to prepare porous carbon liquids. Furthermore, we hope this facile synthesis strategy can be widely applicated to fabricate other types of porous liquids, such as those (e.g., carbon nitride, boron nitride, metal–organic frameworks, covalent organic frameworks etc.) also having the electrostatic interaction with polymerized ionic liquids, evidently advancing the development and understanding of porous liquids.},
doi = {10.1002/ange.201708843},
journal = {Angewandte Chemie},
number = 47,
volume = 129,
place = {Germany},
year = {Mon Oct 23 00:00:00 EDT 2017},
month = {Mon Oct 23 00:00:00 EDT 2017}
}
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1002/ange.201708843
https://doi.org/10.1002/ange.201708843
Other availability
Search WorldCat to find libraries that may hold this journal
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Functionalized graphene sheets with poly(ionic liquid)s and high adsorption capacity of anionic dyes
journal, January 2015
- Zhao, Weifeng; Tang, Yusheng; Xi, Jia
- Applied Surface Science, Vol. 326
Dopamine as a Carbon Source: The Controlled Synthesis of Hollow Carbon Spheres and Yolk-Structured Carbon Nanocomposites
journal, June 2011
- Liu, Rui; Mahurin, Shannon M.; Li, Chen
- Angewandte Chemie International Edition, Vol. 50, Issue 30
25th Anniversary Article: Chemically Modified/Doped Carbon Nanotubes & Graphene for Optimized Nanostructures & Nanodevices
journal, October 2013
- Maiti, Uday Narayan; Lee, Won Jun; Lee, Ju Min
- Advanced Materials, Vol. 26, Issue 1
Designing and understanding permanent microporosity in liquids
journal, January 2014
- Melaugh, Gavin; Giri, Nicola; Davidson, Christine E.
- Phys. Chem. Chem. Phys., Vol. 16, Issue 20
Functionalized ZnO Nanoparticles with Liquidlike Behavior and their Photoluminescence Properties
journal, April 2006
- Bourlinos, Athanasios B.; Stassinopoulos, Andreas; Anglos, Demetrios
- Small, Vol. 2, Issue 4
Thermodynamics and Kinetics of Gas Storage in Porous Liquids
journal, July 2016
- Zhang, Fei; Yang, Fengchang; Huang, Jingsong
- The Journal of Physical Chemistry B, Vol. 120, Issue 29
The new age of MOFs and of their porous-related solids
journal, January 2017
- Maurin, Guillaume; Serre, Christian; Cooper, Andrew
- Chemical Society Reviews, Vol. 46, Issue 11
Solid-state synthesis of ordered mesoporous carbon catalysts via a mechanochemical assembly through coordination cross-linking
journal, April 2017
- Zhang, Pengfei; Wang, Li; Yang, Shize
- Nature Communications, Vol. 8, Issue 1
Inserting CO 2 into Aryl C−H Bonds of Metal-Organic Frameworks: CO 2 Utilization for Direct Heterogeneous C−H Activation
journal, April 2016
- Gao, Wen-Yang; Wu, Haifan; Leng, Kunyue
- Angewandte Chemie, Vol. 128, Issue 18
Porous Molecular Solids and Liquids
journal, May 2017
- Cooper, Andrew I.
- ACS Central Science, Vol. 3, Issue 6
Exploiting non-covalent π interactions for catalyst design
journal, March 2017
- Neel, Andrew J.; Hilton, Margaret J.; Sigman, Matthew S.
- Nature, Vol. 543, Issue 7647
Covalent nanocrystals-decorated solvent-free graphene oxide liquids
journal, December 2016
- Li, Peipei; Shi, Ting; Yao, Dongdong
- Carbon, Vol. 110
Alkylated organic cages: from porous crystals to neat liquids
journal, January 2012
- Giri, Nicola; Davidson, Christine E.; Melaugh, Gavin
- Chemical Science, Vol. 3, Issue 6
Intricate Hollow Structures: Controlled Synthesis and Applications in Energy Storage and Conversion
journal, February 2017
- Zhou, Liang; Zhuang, Zechao; Zhao, Huihui
- Advanced Materials, Vol. 29, Issue 20
Enhanced toughness and glass transition temperature of epoxy nanocomposites filled with solvent-free liquid-like nanocrystal-functionalized graphene oxide
journal, January 2016
- Li, Peipei; Zheng, Yaping; Li, Mengzhi
- Materials & Design, Vol. 89
Entrapping an Ionic Liquid with Nanocarbon: The Formation of a Tailorable and Functional Surface
journal, November 2014
- Ding, Yuxiao; Sun, Xiaoyan; Zhang, Liyun
- Angewandte Chemie International Edition, Vol. 54, Issue 1
Probing the interaction of ionic liquids with graphene using surface-enhanced Raman spectroscopy: Interaction of ionic liquids with graphene
journal, December 2015
- Mahurin, Shannon M.; Surwade, Sumedh P.; Crespo, Marcos
- Journal of Raman Spectroscopy, Vol. 47, Issue 5
Solvent-free Fluids Based on Rhombohedral Nanoparticles of Calcium Carbonate
journal, July 2009
- Li, Qi; Dong, Lijie; Deng, Wei
- Journal of the American Chemical Society, Vol. 131, Issue 26
Hypercrosslinked porous polymer materials: design, synthesis, and applications
journal, January 2017
- Tan, Liangxiao; Tan, Bien
- Chemical Society Reviews, Vol. 46, Issue 11
Dopamine as a Carbon Source: The Controlled Synthesis of Hollow Carbon Spheres and Yolk-Structured Carbon Nanocomposites
journal, June 2011
- Liu, Rui; Mahurin, Shannon M.; Li, Chen
- Angewandte Chemie, Vol. 123, Issue 30
Synthesis of nitrogen-doped hollow carbon nanospheres for CO 2 capture
journal, January 2014
- Feng, Shanshan; Li, Wei; Shi, Quan
- Chem. Commun., Vol. 50, Issue 3
Internal Morphology-Controllable Self-Assembly in Poly(Ionic Liquid) Nanoparticles
journal, July 2016
- Zhang, Weiyi; Kochovski, Zdravko; Lu, Yan
- ACS Nano, Vol. 10, Issue 8
Porous Liquids: A Promising Class of Media for Gas Separation
journal, November 2014
- Zhang, Jinshui; Chai, Song-Hai; Qiao, Zhen-An
- Angewandte Chemie, Vol. 127, Issue 3
Cation−π Interactions and Rattling Motion through Two-Dimensional Carbon Networks: Graphene vs Graphynes
journal, April 2015
- Shekar, S. Chandra; Swathi, R. S.
- The Journal of Physical Chemistry C, Vol. 119, Issue 16
Function-led design of new porous materials
journal, May 2015
- Slater, A. G.; Cooper, A. I.
- Science, Vol. 348, Issue 6238
Perspective of microporous metal–organic frameworks for CO 2 capture and separation
journal, January 2014
- Zhang, Zhangjing; Yao, Zi-Zhu; Xiang, Shengchang
- Energy & Environmental Science, Vol. 7, Issue 9
Nanoscale Perturbations of Room Temperature Ionic Liquid Structure at Charged and Uncharged Interfaces
journal, October 2012
- Zhou, Hua; Rouha, Michael; Feng, Guang
- ACS Nano, Vol. 6, Issue 11
Fluxible Monodisperse Quantum Dots with Efficient Luminescence
journal, November 2010
- Feng, Qisong; Dong, Lijie; Huang, Jing
- Angewandte Chemie International Edition, Vol. 49, Issue 51
Porous Liquids: A Promising Class of Media for Gas Separation
journal, November 2014
- Zhang, Jinshui; Chai, Song-Hai; Qiao, Zhen-An
- Angewandte Chemie International Edition, Vol. 54, Issue 3
Hollow Carbon Nanospheres with Tunable Hierarchical Pores for Drug, Gene, and Photothermal Synergistic Treatment
journal, November 2016
- Du, Xin; Zhao, Caixia; Zhou, Mengyun
- Small, Vol. 13, Issue 6
Superior Conductive Solid-like Electrolytes: Nanoconfining Liquids within the Hollow Structures
journal, April 2015
- Zhang, Jinshui; Bai, Ying; Sun, Xiao-Guang
- Nano Letters, Vol. 15, Issue 5
Porous ionic liquids: synthesis and application
journal, January 2015
- Zhang, Shiguo; Dokko, Kaoru; Watanabe, Masayoshi
- Chemical Science, Vol. 6, Issue 7
Synthesis and properties of polymerized ionic liquids
journal, May 2017
- Eftekhari, Ali; Saito, Tomonori
- European Polymer Journal, Vol. 90
Polystyrene Sulfonate Threaded through a Metal-Organic Framework Membrane for Fast and Selective Lithium-Ion Separation
journal, October 2016
- Guo, Yi; Ying, Yulong; Mao, Yiyin
- Angewandte Chemie, Vol. 128, Issue 48
Extension of The Stöber Method to the Preparation of Monodisperse Resorcinol-Formaldehyde Resin Polymer and Carbon Spheres
journal, May 2011
- Liu, Jian; Qiao, Shi Zhang; Liu, Hao
- Angewandte Chemie International Edition, Vol. 50, Issue 26
A sulfur host based on titanium monoxide@carbon hollow spheres for advanced lithium–sulfur batteries
journal, October 2016
- Li, Zhen; Zhang, Jintao; Guan, Buyuan
- Nature Communications, Vol. 7, Issue 1
Role of electrostatic repulsion on colloidal stability of Bacillus halmapalus alpha-amylase
journal, July 2009
- Olsen, Søren N.; Andersen, Kim B.; Randolph, Ted W.
- Biochimica et Biophysica Acta (BBA) - Proteins and Proteomics, Vol. 1794, Issue 7
Entrapping an Ionic Liquid with Nanocarbon: The Formation of a Tailorable and Functional Surface
journal, November 2014
- Ding, Yuxiao; Sun, Xiaoyan; Zhang, Liyun
- Angewandte Chemie, Vol. 127, Issue 1
Frontiers in poly(ionic liquid)s: syntheses and applications
journal, January 2017
- Qian, Wenjing; Texter, John; Yan, Feng
- Chemical Society Reviews, Vol. 46, Issue 4
Understanding gas capacity, guest selectivity, and diffusion in porous liquids
journal, January 2017
- Greenaway, Rebecca L.; Holden, Daniel; Eden, Edward G. B.
- Chemical Science, Vol. 8, Issue 4
Surfactant-Assisted Stabilization of Au Colloids on Solids for Heterogeneous Catalysis
journal, March 2017
- Zhan, Wangcheng; Shu, Yuan; Sheng, Yujie
- Angewandte Chemie, Vol. 129, Issue 16
Direct exfoliation of natural graphite into micrometre size few layers graphene sheets using ionic liquids
journal, January 2010
- Wang, Xiqing; Fulvio, Pasquale F.; Baker, Gary A.
- Chemical Communications, Vol. 46, Issue 25
Porous Structure Design of Polymeric Membranes for Gas Separation
journal, April 2017
- Zhang, Jinshui; Schott, Jennifer Ann; Mahurin, Shannon M.
- Small Methods, Vol. 1, Issue 5
Synthesis, characterization and application of 1-butyl-3-methylimidazolium tetrafluoroborate for extractive desulfurization of liquid fuel
journal, July 2016
- Dharaskar, Swapnil A.; Wasewar, Kailas L.; Varma, Mahesh N.
- Arabian Journal of Chemistry, Vol. 9, Issue 4
Fluxible Monodisperse Quantum Dots with Efficient Luminescence
journal, November 2010
- Feng, Qisong; Dong, Lijie; Huang, Jing
- Angewandte Chemie, Vol. 122, Issue 51
Membrane-Based Gas Separation Accelerated by Hollow Nanosphere Architectures
journal, November 2016
- Zhang, Jinshui; Schott, Jennifer Ann; Li, Yunchao
- Advanced Materials, Vol. 29, Issue 4
Liquids with permanent porosity
journal, November 2015
- Giri, Nicola; Del Pópolo, Mario G.; Melaugh, Gavin
- Nature, Vol. 527, Issue 7577
Polystyrene Sulfonate Threaded through a Metal-Organic Framework Membrane for Fast and Selective Lithium-Ion Separation
journal, November 2016
- Guo, Yi; Ying, Yulong; Mao, Yiyin
- Angewandte Chemie International Edition, Vol. 55, Issue 48
Property−Structure Relationship of Nanoscale Ionic Materials Based on Multiwalled Carbon Nanotubes
journal, September 2010
- Li, Qi; Dong, Lijie; Fang, Jingfei
- ACS Nano, Vol. 4, Issue 10
From Filter Paper to Functional Actuator by Poly(Ionic Liquid)-Modified Graphene Oxide
journal, March 2016
- Song, Haojie; Lin, Huijuan; Antonietti, Markus
- Advanced Materials Interfaces, Vol. 3, Issue 12
Inserting CO 2 into Aryl C−H Bonds of Metal-Organic Frameworks: CO 2 Utilization for Direct Heterogeneous C−H Activation
journal, April 2016
- Gao, Wen-Yang; Wu, Haifan; Leng, Kunyue
- Angewandte Chemie International Edition, Vol. 55, Issue 18
The Dam Bursts for Porous Liquids
journal, March 2016
- James, Stuart L.
- Advanced Materials, Vol. 28, Issue 27
General Synthetic Route toward Highly Dispersed Metal Clusters Enabled by Poly(ionic liquid)s
journal, June 2017
- Sun, Jian-Ke; Kochovski, Zdravko; Zhang, Wei-Yi
- Journal of the American Chemical Society, Vol. 139, Issue 26
General route to graphene with liquid-like behavior by non-covalent modification
journal, January 2012
- Tang, Zhenghai; Zhang, Liqun; Zeng, Chunfang
- Soft Matter, Vol. 8, Issue 35
A comprehensive review on graphene nanofluids: Recent research, development and applications
journal, March 2016
- Sadeghinezhad, Emad; Mehrali, Mohammad; Saidur, R.
- Energy Conversion and Management, Vol. 111
Hydrogels with a Memory: Dual-Responsive, Organometallic Poly(ionic liquid)s with Hysteretic Volume-Phase Transition
journal, July 2017
- Zhang, Kaihuan; Feng, Xueling; Ye, Chongnan
- Journal of the American Chemical Society, Vol. 139, Issue 29
Host-Guest Nanocomposites of Multiwalled Carbon Nanotubes and Ionic Liquids with Controllable Composition
journal, March 2014
- Ding, Yuxiao; Su, Dang Sheng
- ChemSusChem, Vol. 7, Issue 6
Extension of The Stöber Method to the Preparation of Monodisperse Resorcinol-Formaldehyde Resin Polymer and Carbon Spheres
journal, May 2011
- Liu, Jian; Qiao, Shi Zhang; Liu, Hao
- Angewandte Chemie, Vol. 123, Issue 26
Fluorescent whitening agent stabilized graphene and its composites with chitosan
journal, January 2011
- Tang, Zhenghai; Zeng, Chunfang; Lei, Yanda
- Journal of Materials Chemistry, Vol. 21, Issue 43
Porous Liquids
journal, April 2007
- O'Reilly, Niamh; Giri, Nicola; James, Stuart L.
- Chemistry - A European Journal, Vol. 13, Issue 11
Surfactant-Assisted Stabilization of Au Colloids on Solids for Heterogeneous Catalysis
journal, March 2017
- Zhan, Wangcheng; Shu, Yuan; Sheng, Yujie
- Angewandte Chemie International Edition, Vol. 56, Issue 16