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Title: [2](1,3)Adamantano[2](2,7)pyrenophane: A Hydrocarbon with a Large Dipole Moment

Journal Article · · Angewandte Chemie (International Edition)
 [1];  [1];  [2];  [3];  [1];  [4]; ORCiD logo [1]
  1. Institute of Organic Chemistry Justus-Liebig-University Heinrich-Buff-Ring 17 35392 Giessen Germany
  2. Department of Chemical Sciences University of Padova, Via Marzolo 1-35131 Padova Italy
  3. Institute of Inorganic Chemistry Justus-Liebig-University Heinrich-Buff-Ring 17 35392 Giessen Germany
  4. Department of Chemistry Memorial University of Newfoundland St. John's NL A1B 3X7 Canada
+ Show Author Affiliations

Abstract The fusion of the sp 3 ‐hybridized parent diamondoid adamantane with the sp 2 ‐hybridized pyrene results in a hybrid structure with a very large dipole moment which arises from bending the pyrene moiety. Presented herein is the synthesis, study of the electronic and optical properties, as well as the dynamic behavior of this new hydrocarbon.

Sponsoring Organization:
USDOE
Grant/Contract Number:
AC02-76SF00515
OSTI ID:
1401695
Journal Information:
Angewandte Chemie (International Edition), Journal Name: Angewandte Chemie (International Edition) Journal Issue: 32 Vol. 55; ISSN 1433-7851
Publisher:
Wiley Blackwell (John Wiley & Sons)Copyright Statement
Country of Publication:
Germany
Language:
English

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