Hydride-Based Solid Oxide Fuel Cell–Battery Hybrid Electrochemical System
Abstract
Abstract The deployment of renewable energy technologies, such as solar photovoltaics and wind turbines, poses challenges in terms of electricity grid stability due to the intermittent nature of such energy sources, which creates a need for innovative storage solutions. We demonstrate a metal hydride‐based hybrid electrochemical system that enables a solid‐oxide fuel cell to operate in both fuel cell mode and battery mode, allowing for un‐interrupted electricity generation. In the fuel cell mode, the device acts as a conventional fuel cell and converts the chemical energy stored in fuels into electrical energy. In the battery mode, the metal hydride near the anode releases hydrogen and quickly responds to fuel supply interruption or power demand surges. The concept demonstrated here is a promising way to provide a robust and economical solution for balancing power supply and demand for the electrical grid of the future.
- Authors:
-
- Harvard Univ., Cambridge, MA (United States)
- SiEnergy Systems LLC Cambridge MA 02138 USA
- Purdue Univ., West Lafayette, IN (United States)
- Publication Date:
- Research Org.:
- SiEnergy Systems LLC, Quincy, MA (United States)
- Sponsoring Org.:
- USDOE Advanced Research Projects Agency - Energy (ARPA-E)
- OSTI Identifier:
- 1533168
- Alternate Identifier(s):
- OSTI ID: 1401465
- Grant/Contract Number:
- AR0000491
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Energy Technology
- Additional Journal Information:
- Journal Volume: 5; Journal Issue: 4; Journal ID: ISSN 2194-4288
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; Energy & Fuels
Citation Formats
Guan, Xiaofei, Jiang, Jun, Lattimer, Judith, Tsuchiya, Masaru, Friend, Cynthia M., and Ramanathan, Shriram. Hydride-Based Solid Oxide Fuel Cell–Battery Hybrid Electrochemical System. United States: N. p., 2016.
Web. doi:10.1002/ente.201600406.
Guan, Xiaofei, Jiang, Jun, Lattimer, Judith, Tsuchiya, Masaru, Friend, Cynthia M., & Ramanathan, Shriram. Hydride-Based Solid Oxide Fuel Cell–Battery Hybrid Electrochemical System. United States. https://doi.org/10.1002/ente.201600406
Guan, Xiaofei, Jiang, Jun, Lattimer, Judith, Tsuchiya, Masaru, Friend, Cynthia M., and Ramanathan, Shriram. Tue .
"Hydride-Based Solid Oxide Fuel Cell–Battery Hybrid Electrochemical System". United States. https://doi.org/10.1002/ente.201600406. https://www.osti.gov/servlets/purl/1533168.
@article{osti_1533168,
title = {Hydride-Based Solid Oxide Fuel Cell–Battery Hybrid Electrochemical System},
author = {Guan, Xiaofei and Jiang, Jun and Lattimer, Judith and Tsuchiya, Masaru and Friend, Cynthia M. and Ramanathan, Shriram},
abstractNote = {Abstract The deployment of renewable energy technologies, such as solar photovoltaics and wind turbines, poses challenges in terms of electricity grid stability due to the intermittent nature of such energy sources, which creates a need for innovative storage solutions. We demonstrate a metal hydride‐based hybrid electrochemical system that enables a solid‐oxide fuel cell to operate in both fuel cell mode and battery mode, allowing for un‐interrupted electricity generation. In the fuel cell mode, the device acts as a conventional fuel cell and converts the chemical energy stored in fuels into electrical energy. In the battery mode, the metal hydride near the anode releases hydrogen and quickly responds to fuel supply interruption or power demand surges. The concept demonstrated here is a promising way to provide a robust and economical solution for balancing power supply and demand for the electrical grid of the future.},
doi = {10.1002/ente.201600406},
journal = {Energy Technology},
number = 4,
volume = 5,
place = {United States},
year = {Tue Aug 16 00:00:00 EDT 2016},
month = {Tue Aug 16 00:00:00 EDT 2016}
}
Web of Science
Works referenced in this record:
Metal hydride materials for solid hydrogen storage: A review☆
journal, June 2007
- Sakintuna, B.; Lamaridarkrim, F.; Hirscher, M.
- International Journal of Hydrogen Energy, Vol. 32, Issue 9
High capacity of an Fe–air rechargeable battery using LaGaO3-based oxide ion conductor as an electrolyte
journal, January 2012
- Inoishi, Atsushi; Ida, Shintaro; Uratani, Shouichi
- Physical Chemistry Chemical Physics, Vol. 14, Issue 37
Metal hydrides for lithium-ion batteries
journal, October 2008
- Oumellal, Y.; Rougier, A.; Nazri, G. A.
- Nature Materials, Vol. 7, Issue 11, p. 916-921
Modeling and experimental performance of an intermediate temperature reversible solid oxide cell for high-efficiency, distributed-scale electrical energy storage
journal, June 2015
- Wendel, Christopher H.; Gao, Zhan; Barnett, Scott A.
- Journal of Power Sources, Vol. 283
The decomposition behavior of as-received and oxidized TiH2 foaming-agent powder
journal, September 2003
- Kennedy, A. R.; Lopez, V. H.
- Materials Science and Engineering: A, Vol. 357, Issue 1-2
Materials for fuel-cell technologies
journal, November 2001
- Steele, Brian C. H.; Heinzel, Angelika
- Nature, Vol. 414, Issue 6861, p. 345-352
Electronic Transport in 8 Mole Percent Y[sub 2]O[sub 3]-ZrO[sub 2]
journal, January 1989
- Park, Jong-Hee
- Journal of The Electrochemical Society, Vol. 136, Issue 10
Electrochemical Energy Storage for Green Grid
journal, May 2011
- Yang, Zhenguo; Zhang, Jianlu; Kintner-Meyer, Michael C. W.
- Chemical Reviews, Vol. 111, Issue 5, p. 3577-3613
A Nickel Metal Hydride Battery for Electric Vehicles
journal, April 1993
- Ovshinsky, S. R.; Fetcenko, M. A.; Ross, J.
- Science, Vol. 260, Issue 5105
Solid-State Ionics: Roots, Status, and Future Prospects
journal, July 2002
- Knauth, Philippe; Tuller, Harry L.
- Journal of the American Ceramic Society, Vol. 85, Issue 7
Some metallographie and lattice parameter observations on titanium hydride
journal, February 1971
- Irving, P. E.; Beevers, C. J.
- Metallurgical Transactions, Vol. 2, Issue 2
Air–metal hydride secondary battery with long cycle life
journal, January 2002
- Chartouni, D.; Kuriyama, N.; Kiyobayashi, T.
- Journal of Alloys and Compounds, Vol. 330-332
Towards a ‘proton flow battery’: Investigation of a reversible PEM fuel cell with integrated metal-hydride hydrogen storage
journal, January 2014
- Andrews, John; Seif Mohammadi, Saeed
- International Journal of Hydrogen Energy, Vol. 39, Issue 4
A comprehensive review of direct borohydride fuel cells
journal, January 2010
- Ma, Jia; Choudhury, Nurul A.; Sahai, Yogeshwar
- Renewable and Sustainable Energy Reviews, Vol. 14, Issue 1
Overview of current development in electrical energy storage technologies and the application potential in power system operation
journal, January 2015
- Luo, Xing; Wang, Jihong; Dooner, Mark
- Applied Energy, Vol. 137
Electrical Energy Storage for the Grid: A Battery of Choices
journal, November 2011
- Dunn, B.; Kamath, H.; Tarascon, J. -M.
- Science, Vol. 334, Issue 6058
A novel solid oxide redox flow battery for grid energy storage
journal, January 2011
- Xu, Nansheng; Li, Xue; Zhao, Xuan
- Energy & Environmental Science, Vol. 4, Issue 12, 4942
Electrochemical properties of Ml(NiCoMnCu)5 used as an alkaline fuel cell anode
journal, December 1999
- Wang, X. H.; Chen, Y.; Pan, H. G.
- Journal of Alloys and Compounds, Vol. 293-295
Discharge Performance of Solid-State Oxygen Shuttle Metal-Air Battery Using Ca-Stabilized ZrO 2 Electrolyte
journal, February 2015
- Inoishi, Atsushi; Kim, Hack-Ho; Sakai, Takaaki
- ChemSusChem, Vol. 8, Issue 7
Integrating Renewable Electricity on the Grid
journal, January 2011
- Crabtree, George; Misewich, Jim; Ambrosio, Ron
- AIP Conference Proceedings, Vol. 1401, Issue 1, Article No. 387
Energy Storage in Ultrathin Solid Oxide Fuel Cells
journal, June 2012
- Van Overmeere, Quentin; Kerman, Kian; Ramanathan, Shriram
- Nano Letters, Vol. 12, Issue 7
Alkaline Fuel Cell with Intrinsic Energy Storage
journal, January 2004
- Wang, Chunsheng; Appleby, A. John; Cocke, David L.
- Journal of The Electrochemical Society, Vol. 151, Issue 2
The Characterization of an Alkaline Fuel Cell That Uses Hydrogen Storage Alloys
journal, January 2002
- Lee, Sang-Min; Kim, Jin-Ho; Lee, Han-Ho
- Journal of The Electrochemical Society, Vol. 149, Issue 5
Eliminating degradation in solid oxide electrochemical cells by reversible operation
journal, December 2014
- Graves, Christopher; Ebbesen, Sune Dalgaard; Jensen, Søren Højgaard
- Nature Materials, Vol. 14, Issue 2
Thermal Decomposition of the Non-Interstitial Hydrides for the Storage and Production of Hydrogen
journal, March 2004
- Grochala, Wojciech; Edwards, Peter P.
- Chemical Reviews, Vol. 104, Issue 3
Kinetic study on nonisothermal dehydrogenation of TiH2 powders
journal, April 2009
- Liu, H.; He, P.; Feng, J. C.
- International Journal of Hydrogen Energy, Vol. 34, Issue 7
The investigation of titanium hydride oxidation process
journal, September 1997
- Gromov, A. R.; Kouznetsova, N. N.; Yudina, S. L.
- Journal of Alloys and Compounds, Vol. 261, Issue 1-2
Periodic Shorting of SOM Cell to Remove Soluble Magnesium in Molten Flux and Improve Faradaic Efficiency
journal, August 2014
- Guan, Xiaofei; Su, Shizhao; Pal, Uday B.
- Metallurgical and Materials Transactions B, Vol. 45, Issue 6
Simulation of a thermally coupled metal-hydride hydrogen storage and fuel cell system
journal, March 2005
- Jiang, Z.; Dougal, R. A.; Liu, S.
- Journal of Power Sources, Vol. 142, Issue 1-2
Materials for hydrogen storage
journal, September 2003
- Züttel, Andreas
- Materials Today, Vol. 6, Issue 9
Mg–air oxygen shuttle batteries using a ZrO2-based oxide ion-conducting electrolyte
journal, January 2013
- Inoishi, Atsushi; Ju, Young-Wan; Ida, Shintaro
- Chemical Communications, Vol. 49, Issue 41