Preparation and Characterization of Antimony and Arsenic Tricyanide and Their 2,2′‐Bipyridine Adducts
Abstract
Abstract The arsenic(III) and antimony(III) cyanides M(CN) 3 (M=As, Sb) have been prepared in quantitative yields from the corresponding trifluorides through fluoride–cyanide exchange with Me 3 SiCN in acetonitrile. When the reaction was carried out in the presence of one equivalent of 2,2′‐bipyridine, the adducts [M(CN) 3 ⋅ (2,2′‐bipy)] were obtained. The crystal structures of As(CN) 3 , [As(CN) 3 ⋅ (2,2′‐bipy)] and [Sb(CN) 3 ⋅ (2,2′‐bipy)] were determined and are surprisingly different. As(CN) 3 possesses a polymeric three‐dimensional structure, [As(CN) 3 ⋅ (2,2′‐bipy)] exhibits a two‐dimensional sheet structure, and [Sb(CN) 3 ⋅ (2,2′‐bipy)] has a chain structure, and none of the structures resembles those found for the corresponding arsenic and antimony triazides.
- Authors:
-
[1]
- Loker Hydrocarbon Research Institute and Department of Chemistry University of Southern California Los Angeles CA 90089 USA
- Department of Chemistry The University of Alabama Tuscaloosa AL 35487 USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1401459
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Chemistry - A European Journal
- Additional Journal Information:
- Journal Name: Chemistry - A European Journal Journal Volume: 22 Journal Issue: 37; Journal ID: ISSN 0947-6539
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Deokar, Piyush, Leitz, Dominik, Stein, Trent H., Vasiliu, Monica, Dixon, David A., Christe, Karl O., and Haiges, Ralf. Preparation and Characterization of Antimony and Arsenic Tricyanide and Their 2,2′‐Bipyridine Adducts. Germany: N. p., 2016.
Web. doi:10.1002/chem.201602436.
Deokar, Piyush, Leitz, Dominik, Stein, Trent H., Vasiliu, Monica, Dixon, David A., Christe, Karl O., & Haiges, Ralf. Preparation and Characterization of Antimony and Arsenic Tricyanide and Their 2,2′‐Bipyridine Adducts. Germany. https://doi.org/10.1002/chem.201602436
Deokar, Piyush, Leitz, Dominik, Stein, Trent H., Vasiliu, Monica, Dixon, David A., Christe, Karl O., and Haiges, Ralf. Fri .
"Preparation and Characterization of Antimony and Arsenic Tricyanide and Their 2,2′‐Bipyridine Adducts". Germany. https://doi.org/10.1002/chem.201602436.
@article{osti_1401459,
title = {Preparation and Characterization of Antimony and Arsenic Tricyanide and Their 2,2′‐Bipyridine Adducts},
author = {Deokar, Piyush and Leitz, Dominik and Stein, Trent H. and Vasiliu, Monica and Dixon, David A. and Christe, Karl O. and Haiges, Ralf},
abstractNote = {Abstract The arsenic(III) and antimony(III) cyanides M(CN) 3 (M=As, Sb) have been prepared in quantitative yields from the corresponding trifluorides through fluoride–cyanide exchange with Me 3 SiCN in acetonitrile. When the reaction was carried out in the presence of one equivalent of 2,2′‐bipyridine, the adducts [M(CN) 3 ⋅ (2,2′‐bipy)] were obtained. The crystal structures of As(CN) 3 , [As(CN) 3 ⋅ (2,2′‐bipy)] and [Sb(CN) 3 ⋅ (2,2′‐bipy)] were determined and are surprisingly different. As(CN) 3 possesses a polymeric three‐dimensional structure, [As(CN) 3 ⋅ (2,2′‐bipy)] exhibits a two‐dimensional sheet structure, and [Sb(CN) 3 ⋅ (2,2′‐bipy)] has a chain structure, and none of the structures resembles those found for the corresponding arsenic and antimony triazides.},
doi = {10.1002/chem.201602436},
journal = {Chemistry - A European Journal},
number = 37,
volume = 22,
place = {Germany},
year = {Fri Aug 05 00:00:00 EDT 2016},
month = {Fri Aug 05 00:00:00 EDT 2016}
}
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