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Title: Preparation and Characterization of Antimony and Arsenic Tricyanide and Their 2,2′‐Bipyridine Adducts

Journal Article · · Chemistry - A European Journal
 [1];  [1];  [2];  [2];  [2];  [1]; ORCiD logo [1]
  1. Loker Hydrocarbon Research Institute and Department of Chemistry University of Southern California Los Angeles CA 90089 USA
  2. Department of Chemistry The University of Alabama Tuscaloosa AL 35487 USA
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Abstract The arsenic(III) and antimony(III) cyanides M(CN) 3 (M=As, Sb) have been prepared in quantitative yields from the corresponding trifluorides through fluoride–cyanide exchange with Me 3 SiCN in acetonitrile. When the reaction was carried out in the presence of one equivalent of 2,2′‐bipyridine, the adducts [M(CN) 3 ⋅ (2,2′‐bipy)] were obtained. The crystal structures of As(CN) 3 , [As(CN) 3 ⋅ (2,2′‐bipy)] and [Sb(CN) 3 ⋅ (2,2′‐bipy)] were determined and are surprisingly different. As(CN) 3 possesses a polymeric three‐dimensional structure, [As(CN) 3 ⋅ (2,2′‐bipy)] exhibits a two‐dimensional sheet structure, and [Sb(CN) 3 ⋅ (2,2′‐bipy)] has a chain structure, and none of the structures resembles those found for the corresponding arsenic and antimony triazides.

Sponsoring Organization:
USDOE
OSTI ID:
1401459
Journal Information:
Chemistry - A European Journal, Journal Name: Chemistry - A European Journal Journal Issue: 37 Vol. 22; ISSN 0947-6539
Publisher:
Wiley Blackwell (John Wiley & Sons)Copyright Statement
Country of Publication:
Germany
Language:
English

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