Search Menu
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information
Search Scholarly Publications

Title: Hexaazatrinaphthylene Derivatives: Efficient Electron‐Transporting Materials with Tunable Energy Levels for Inverted Perovskite Solar Cells

Abstract

Abstract Hexaazatrinaphthylene (HATNA) derivatives have been successfully shown to function as efficient electron‐transporting materials (ETMs) for perovskite solar cells (PVSCs). The cells demonstrate a superior power conversion efficiency (PCE) of 17.6 % with negligible hysteresis. This study provides one of the first nonfullerene small‐molecule‐based ETMs for high‐performance p–i–n PVSCs.

Authors:
 [1];  [1];  [1];  [1];  [1]
+ Show Author Affiliations
  1. Department of Materials Science and Engineering University of Washington Seattle WA 98195 USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1401211
Grant/Contract Number:  
DEEE0006710
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Angewandte Chemie
Additional Journal Information:
Journal Name: Angewandte Chemie Journal Volume: 128 Journal Issue: 31; Journal ID: ISSN 0044-8249
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Zhao, Dongbing, Zhu, Zonglong, Kuo, Ming‐Yu, Chueh, Chu‐Chen, and Jen, Alex K. ‐Y. Hexaazatrinaphthylene Derivatives: Efficient Electron‐Transporting Materials with Tunable Energy Levels for Inverted Perovskite Solar Cells. Germany: N. p., 2016. Web. doi:10.1002/ange.201604399.
Copy to clipboard
Zhao, Dongbing, Zhu, Zonglong, Kuo, Ming‐Yu, Chueh, Chu‐Chen, & Jen, Alex K. ‐Y. Hexaazatrinaphthylene Derivatives: Efficient Electron‐Transporting Materials with Tunable Energy Levels for Inverted Perovskite Solar Cells. Germany. https://doi.org/10.1002/ange.201604399
Copy to clipboard
Zhao, Dongbing, Zhu, Zonglong, Kuo, Ming‐Yu, Chueh, Chu‐Chen, and Jen, Alex K. ‐Y. Wed . "Hexaazatrinaphthylene Derivatives: Efficient Electron‐Transporting Materials with Tunable Energy Levels for Inverted Perovskite Solar Cells". Germany. https://doi.org/10.1002/ange.201604399.
Copy to clipboard
@article{osti_1401211,
title = {Hexaazatrinaphthylene Derivatives: Efficient Electron‐Transporting Materials with Tunable Energy Levels for Inverted Perovskite Solar Cells},
author = {Zhao, Dongbing and Zhu, Zonglong and Kuo, Ming‐Yu and Chueh, Chu‐Chen and Jen, Alex K. ‐Y.},
abstractNote = {Abstract Hexaazatrinaphthylene (HATNA) derivatives have been successfully shown to function as efficient electron‐transporting materials (ETMs) for perovskite solar cells (PVSCs). The cells demonstrate a superior power conversion efficiency (PCE) of 17.6 % with negligible hysteresis. This study provides one of the first nonfullerene small‐molecule‐based ETMs for high‐performance p–i–n PVSCs.},
doi = {10.1002/ange.201604399},
journal = {Angewandte Chemie},
number = 31,
volume = 128,
place = {Germany},
year = {Wed Jun 08 00:00:00 EDT 2016},
month = {Wed Jun 08 00:00:00 EDT 2016}
}
Copy to clipboard
Journal Article:
Free Publicly Available Full Text
Accepted Manuscript (Publisher)
Publisher's Version of Record
https://doi.org/10.1002/ange.201604399
Copyright Statement
Other availability
Search WorldCat Search WorldCat to find libraries that may hold this journal
Save / Share:
Export Metadata
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.

Works referenced in this record:

Multifunctional Fullerene Derivative for Interface Engineering in Perovskite Solar Cells
journal, December 2015

  • Li, Yaowen; Zhao, Yue; Chen, Qi
  • Journal of the American Chemical Society, Vol. 137, Issue 49
  • DOI: 10.1021/jacs.5b10614

Inverted Planar Heterojunction Perovskite Solar Cells Employing Polymer as the Electron Conductor
journal, February 2015

  • Wang, Weiwei; Yuan, Jianyu; Shi, Guozheng
  • ACS Applied Materials & Interfaces, Vol. 7, Issue 7
  • DOI: 10.1021/am506785k

High Charge-Carrier Mobility in an Amorphous Hexaazatrinaphthylene Derivative
journal, November 2005

  • Kaafarani, Bilal R.; Kondo, Takeshi; Yu, Junsheng
  • Journal of the American Chemical Society, Vol. 127, Issue 47
  • DOI: 10.1021/ja0553147

The emergence of perovskite solar cells
journal, July 2014

  • Green, Martin A.; Ho-Baillie, Anita; Snaith, Henry J.
  • Nature Photonics, Vol. 8, Issue 7, p. 506-514
  • DOI: 10.1038/nphoton.2014.134

Multiphase Growth and Electronic Structure of Ultrathin Hexaazatrinaphthylene on Au(111)
journal, July 2007

  • Ha, Sieu D.; Kaafarani, Bilal R.; Barlow, Stephen
  • The Journal of Physical Chemistry C, Vol. 111, Issue 28
  • DOI: 10.1021/jp0718404

CH 3 NH 3 PbI 3 Perovskite/Fullerene Planar-Heterojunction Hybrid Solar Cells
journal, June 2013

  • Jeng, Jun-Yuan; Chiang, Yi-Fang; Lee, Mu-Huan
  • Advanced Materials, Vol. 25, Issue 27
  • DOI: 10.1002/adma.201301327

Self-Assembling of n-Type Semiconductor Tri(phenanthrolino)hexaazatriphenylenes with a Large Aromatic Core
journal, February 2006

  • Ishi-i, Tsutomu; Yaguma, Kentaro; Kuwahara, Rempei
  • Organic Letters, Vol. 8, Issue 4
  • DOI: 10.1021/ol052779t

Highly Reproducible Perovskite Solar Cells with Average Efficiency of 18.3% and Best Efficiency of 19.7% Fabricated via Lewis Base Adduct of Lead(II) Iodide
journal, July 2015

  • Ahn, Namyoung; Son, Dae-Yong; Jang, In-Hyuk
  • Journal of the American Chemical Society, Vol. 137, Issue 27
  • DOI: 10.1021/jacs.5b04930

Effect of the Metal-Assisted Assembling Mode on the Redox States of Hexaazatriphenylene Hexacarbonitrile
journal, April 2005

  • Furukawa, Shuhei; Okubo, Takashi; Masaoka, Shigeyuki
  • Angewandte Chemie, Vol. 117, Issue 18
  • DOI: 10.1002/ange.200462962

Relationships between Lead Halide Perovskite Thin-Film Fabrication, Morphology, and Performance in Solar Cells
journal, November 2015

  • Sharenko, Alexander; Toney, Michael F.
  • Journal of the American Chemical Society, Vol. 138, Issue 2
  • DOI: 10.1021/jacs.5b10723

Organic Charge Carriers for Perovskite Solar Cells
journal, August 2015

  • Völker, Sebastian F.; Collavini, Silvia; Delgado, Juan Luis
  • ChemSusChem, Vol. 8, Issue 18
  • DOI: 10.1002/cssc.201500742

High-Performance Hole-Extraction Layer of Sol-Gel-Processed NiO Nanocrystals for Inverted Planar Perovskite Solar Cells
journal, July 2014

Material and Energy Intensity of Fullerene Production
journal, March 2011

  • Anctil, Annick; Babbitt, Callie W.; Raffaelle, Ryne P.
  • Environmental Science & Technology, Vol. 45, Issue 6
  • DOI: 10.1021/es103860a

Anomalous Hysteresis in Perovskite Solar Cells
journal, April 2014

  • Snaith, Henry J.; Abate, Antonio; Ball, James M.
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 9
  • DOI: 10.1021/jz500113x

Improved air stability of perovskite solar cells via solution-processed metal oxide transport layers
journal, October 2015

High Charge-Carrier Mobility in π-Deficient Discotic Mesogens: Design and Structure-Property Relationship
journal, May 2005

  • Lehmann, Matthias; Kestemont, Gaël; Gómez Aspe, Rafael
  • Chemistry - A European Journal, Vol. 11, Issue 11
  • DOI: 10.1002/chem.200400586

The light and shade of perovskite solar cells
journal, August 2014

Effect of the Metal-Assisted Assembling Mode on the Redox States of Hexaazatriphenylene Hexacarbonitrile
journal, April 2005

  • Furukawa, Shuhei; Okubo, Takashi; Masaoka, Shigeyuki
  • Angewandte Chemie International Edition, Vol. 44, Issue 18
  • DOI: 10.1002/anie.200462962

Thiols as interfacial modifiers to enhance the performance and stability of perovskite solar cells
journal, January 2015

Electron-Deficient Columnar Plastic Crystals
journal, June 2002

Roles of Fullerene-Based Interlayers in Enhancing the Performance of Organometal Perovskite Thin-Film Solar Cells
journal, February 2015

  • Liang, Po-Wei; Chueh, Chu-Chen; Williams, Spencer T.
  • Advanced Energy Materials, Vol. 5, Issue 10
  • DOI: 10.1002/aenm.201402321

Well-Defined Thiolated Nanographene as Hole-Transporting Material for Efficient and Stable Perovskite Solar Cells
journal, August 2015

  • Cao, Jing; Liu, Yu-Min; Jing, Xiaojing
  • Journal of the American Chemical Society, Vol. 137, Issue 34
  • DOI: 10.1021/jacs.5b06493

Metal-Oxide-Free Methylammonium Lead Iodide Perovskite-Based Solar Cells: the Influence of Organic Charge Transport Layers
journal, June 2014

  • Malinkiewicz, Olga; Roldán-Carmona, Cristina; Soriano, Alejandra
  • Advanced Energy Materials, Vol. 4, Issue 15
  • DOI: 10.1002/aenm.201400345

Enhanced Photovoltaic Performance of CH 3 NH 3 PbI 3 Perovskite Solar Cells through Interfacial Engineering Using Self-Assembling Monolayer
journal, February 2015

  • Zuo, Lijian; Gu, Zhuowei; Ye, Tao
  • Journal of the American Chemical Society, Vol. 137, Issue 7
  • DOI: 10.1021/ja512518r

Perovskite Solar Cells: Influence of Hole Transporting Materials on Power Conversion Efficiency
journal, December 2015

Indene−C60 Bisadduct: A New Acceptor for High-Performance Polymer Solar Cells
journal, February 2010

  • He, Youjun; Chen, Hsiang-Yu; Hou, Jianhui
  • Journal of the American Chemical Society, Vol. 132, Issue 4, p. 1377-1382
  • DOI: 10.1021/ja908602j

Recent progress and perspective in solution-processed Interfacial materials for efficient and stable polymer and organometal perovskite solar cells
journal, January 2015

  • Chueh, Chu-Chen; Li, Chang-Zhi; Jen, Alex K. -Y.
  • Energy & Environmental Science, Vol. 8, Issue 4
  • DOI: 10.1039/C4EE03824J

Organometal Perovskite Light Absorbers Toward a 20% Efficiency Low-Cost Solid-State Mesoscopic Solar Cell
journal, July 2013

  • Park, Nam-Gyu
  • The Journal of Physical Chemistry Letters, Vol. 4, Issue 15, p. 2423-2429
  • DOI: 10.1021/jz400892a

Hexaazatrinaphthylenes with Different Twists
journal, December 2013

  • Choudhary, Sunil; Gozalvez, Cristian; Higelin, Alexander
  • Chemistry - A European Journal, Vol. 20, Issue 6
  • DOI: 10.1002/chem.201304071

High-Performance Hole-Extraction Layer of Sol-Gel-Processed NiO Nanocrystals for Inverted Planar Perovskite Solar Cells
journal, July 2014

N-type polymers as electron extraction layers in hybrid perovskite solar cells with improved ambient stability
journal, January 2016

  • Shao, S.; Chen, Z.; Fang, H. -H.
  • Journal of Materials Chemistry A, Vol. 4, Issue 7
  • DOI: 10.1039/C5TA10696F

Improved organic p-i-n type solar cells with n-doped fluorinated hexaazatrinaphthylene derivatives HATNA-F 6 and HATNA-F 12 as transparent electron transport material
journal, February 2014

  • Selzer, Franz; Falkenberg, Christiane; Hamburger, Manuel
  • Journal of Applied Physics, Vol. 115, Issue 5
  • DOI: 10.1063/1.4864260

Highly Efficient Electron Transport Obtained by Doping PCBM with Graphdiyne in Planar-Heterojunction Perovskite Solar Cells
journal, March 2015

Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber
journal, October 2013

  • Stranks, S. D.; Eperon, G. E.; Grancini, G.
  • Science, Vol. 342, Issue 6156, p. 341-344
  • DOI: 10.1126/science.1243982

Fully Printable Mesoscopic Perovskite Solar Cells with Organic Silane Self-Assembled Monolayer
journal, January 2015

  • Liu, Linfeng; Mei, Anyi; Liu, Tongfa
  • Journal of the American Chemical Society, Vol. 137, Issue 5
  • DOI: 10.1021/ja5125594

Current Challenges and Prospective Research for Upscaling Hybrid Perovskite Photovoltaics
journal, February 2016

  • Williams, Spencer T.; Rajagopal, Adharsh; Chueh, Chu-Chen
  • The Journal of Physical Chemistry Letters, Vol. 7, Issue 5
  • DOI: 10.1021/acs.jpclett.5b02651

Organohalide Lead Perovskites for Photovoltaic Applications
journal, February 2016

  • Yusoff, Abd. Rashid bin Mohd; Nazeeruddin, Mohammad Khaja
  • The Journal of Physical Chemistry Letters, Vol. 7, Issue 5
  • DOI: 10.1021/acs.jpclett.5b02893

Enhanced Photoluminescence and Solar Cell Performance via Lewis Base Passivation of Organic–Inorganic Lead Halide Perovskites
journal, September 2014

  • Noel, Nakita K.; Abate, Antonio; Stranks, Samuel D.
  • ACS Nano, Vol. 8, Issue 10
  • DOI: 10.1021/nn5036476

Efficient Regular Perovskite Solar Cells Based on Pristine [70]Fullerene as Electron-Selective Contact
journal, March 2016

  • Collavini, Silvia; Kosta, Ivet; Völker, Sebastian F.
  • ChemSusChem, Vol. 9, Issue 11
  • DOI: 10.1002/cssc.201600051

Origin of the Open Circuit Voltage of Plastic Solar Cells
journal, October 2001

In Situ Synthesis of Hexakis(alkoxy)diquinoxalino[2,3- a :2‘,3‘- c ]phenazines:  Mesogenic Phase Transition of the Electron-Deficient Discotic Compounds
journal, April 2004

  • Ong, Chi Wi; Liao, Su-Chih; Chang, Tsu Hsing
  • The Journal of Organic Chemistry, Vol. 69, Issue 9
  • DOI: 10.1021/jo035840l

Synthesis, Ionisation Potentials and Electron Affinities of Hexaazatrinaphthylene Derivatives
journal, April 2007

  • Barlow, Stephen; Zhang, Qing; Kaafarani, Bilal R.
  • Chemistry - A European Journal, Vol. 13, Issue 12
  • DOI: 10.1002/chem.200601298

Patterning of Robust Self-Assembled n-type Hexaazatrinaphthylene-Based Nanorods and Nanowires by Microcontact Printing
journal, October 2006

  • Yip, Hin-Lap; Zou, Jingyu; Ma, Hong
  • Journal of the American Chemical Society, Vol. 128, Issue 40
  • DOI: 10.1021/ja064934k

Interfaces in Perovskite Solar Cells
journal, February 2015

Room-temperature, solution-processable organic electron extraction layer for high-performance planar heterojunction perovskite solar cells
journal, January 2015

  • Kim, Jong H.; Chueh, Chu-Chen; Williams, Spencer T.
  • Nanoscale, Vol. 7, Issue 41
  • DOI: 10.1039/C5NR04250J

Self-Directed Orientation of Molecular Columns Based on n-Type Hexaazatrinaphthylenes (HATNAs) for Electron Transport
journal, September 2014

  • Liu, Xu-Ying; Usui, Takayuki; Hanna, Junichi
  • Chemistry - A European Journal, Vol. 20, Issue 44
  • DOI: 10.1002/chem.201403472

Recent advancements in perovskite solar cells: flexibility, stability and large scale
journal, January 2016

  • Ye, Meidan; Hong, Xiaodan; Zhang, Fayin
  • Journal of Materials Chemistry A, Vol. 4, Issue 18
  • DOI: 10.1039/C5TA09661H

Perovskite solar cells employing organic charge-transport layers
journal, December 2013

Perovskites: The Emergence of a New Era for Low-Cost, High-Efficiency Solar Cells
journal, October 2013

  • Snaith, Henry J.
  • The Journal of Physical Chemistry Letters, Vol. 4, Issue 21, p. 3623-3630
  • DOI: 10.1021/jz4020162

Stability of Metal Halide Perovskite Solar Cells
journal, September 2015

  • Leijtens, Tomas; Eperon, Giles E.; Noel, Nakita K.
  • Advanced Energy Materials, Vol. 5, Issue 20
  • DOI: 10.1002/aenm.201500963
    Sort by:
    [ × clear filter / sort ]

    Similar Records in DOE PAGES and OSTI.GOV collections: