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Title: Synthesis of Monodisperse Palladium Nanoclusters Using Metal–Organic Frameworks as Sacrificial Templates

Abstract

Abstract An interfacial etching approach was developed for the synthesis of monodisperse and ultrasmall thiolated palladium nanoclusters (Pd NCs) using Zr‐UiO‐66‐NH 2 metal–organic frameworks (MOFs) as sacrificial templates. The Pd NCs were originally synthesized inside the cavities of the MOFs (Pd@UiO‐66‐NH 2 ). The Pd NCs released from the MOFs have a strikingly small size with narrow distribution (1.1±0.1 nm), amounting to a cluster size of ca. 40 Pd atoms. The 1 H NMR spectrum indicates that thiol is the only capping agent for these Pd NCs. We derived the composition of the thiolated Pd NCs using thermogravimetric analysis (TGA) and inductively coupled plasma mass spectrometry (ICP‐MS) analysis. Moreover, the Pd NCs size can be tuned by using MOF templates with different cavity sizes. The thiolated Pd NCs are catalytically active in a model Suzuki–Miyaura coupling reaction.

Authors:
 [1];  [1];  [1];  [2];  [1]; ORCiD logo [2]; ORCiD logo [1]
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  1. Department of Chemistry Iowa State University Ames Laboratory U.S. Department of Energy Ames Iowa 50011 United States
  2. Department of Chemistry University of Illinois at Urbana-Champaign Urbana Illinois 61801 United States
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1400977
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
ChemNanoMat
Additional Journal Information:
Journal Name: ChemNanoMat Journal Volume: 2 Journal Issue: 8; Journal ID: ISSN 2199-692X
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Li, Xinle, Goh, Tian Wei, Xiao, Chaoxian, Stanton, Alexandria L. D., Pei, Yuchen, Jain, Prashant K., and Huang, Wenyu. Synthesis of Monodisperse Palladium Nanoclusters Using Metal–Organic Frameworks as Sacrificial Templates. Germany: N. p., 2016. Web. doi:10.1002/cnma.201600121.
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Li, Xinle, Goh, Tian Wei, Xiao, Chaoxian, Stanton, Alexandria L. D., Pei, Yuchen, Jain, Prashant K., & Huang, Wenyu. Synthesis of Monodisperse Palladium Nanoclusters Using Metal–Organic Frameworks as Sacrificial Templates. Germany. https://doi.org/10.1002/cnma.201600121
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Li, Xinle, Goh, Tian Wei, Xiao, Chaoxian, Stanton, Alexandria L. D., Pei, Yuchen, Jain, Prashant K., and Huang, Wenyu. Mon . "Synthesis of Monodisperse Palladium Nanoclusters Using Metal–Organic Frameworks as Sacrificial Templates". Germany. https://doi.org/10.1002/cnma.201600121.
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@article{osti_1400977,
title = {Synthesis of Monodisperse Palladium Nanoclusters Using Metal–Organic Frameworks as Sacrificial Templates},
author = {Li, Xinle and Goh, Tian Wei and Xiao, Chaoxian and Stanton, Alexandria L. D. and Pei, Yuchen and Jain, Prashant K. and Huang, Wenyu},
abstractNote = {Abstract An interfacial etching approach was developed for the synthesis of monodisperse and ultrasmall thiolated palladium nanoclusters (Pd NCs) using Zr‐UiO‐66‐NH 2 metal–organic frameworks (MOFs) as sacrificial templates. The Pd NCs were originally synthesized inside the cavities of the MOFs (Pd@UiO‐66‐NH 2 ). The Pd NCs released from the MOFs have a strikingly small size with narrow distribution (1.1±0.1 nm), amounting to a cluster size of ca. 40 Pd atoms. The 1 H NMR spectrum indicates that thiol is the only capping agent for these Pd NCs. We derived the composition of the thiolated Pd NCs using thermogravimetric analysis (TGA) and inductively coupled plasma mass spectrometry (ICP‐MS) analysis. Moreover, the Pd NCs size can be tuned by using MOF templates with different cavity sizes. The thiolated Pd NCs are catalytically active in a model Suzuki–Miyaura coupling reaction.},
doi = {10.1002/cnma.201600121},
journal = {ChemNanoMat},
number = 8,
volume = 2,
place = {Germany},
year = {Mon Jun 20 00:00:00 EDT 2016},
month = {Mon Jun 20 00:00:00 EDT 2016}
}
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https://doi.org/10.1002/cnma.201600121
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