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Title: Impact of Stoichiometry on Structural and Optical Properties of Sputter Deposited Multicomponent Tellurite Glass Films

Abstract

Multicomponent TeO 2 –Bi 2 O 3 –ZnO ( TBZ ) glass thin films were prepared using RF magnetron sputtering under different oxygen flow rates. The influences of oxygen flow rate on the structural and optical properties of the resulting thin films were investigated. We observed that thin films sputtered in an oxygen‐rich environment are optically transparent while those sputtered in an oxygen‐deficient environment exhibit broadband absorption. The structural origin of the optical property variation was studied using X‐ray diffraction, X‐ray photoelectron spectroscopy, Raman Spectroscopy, and transmission electron microscopy which revealed that the presence of under‐coordinated Te leads to the observed optical absorption in oxygen‐deficient films.

Authors:
 [1];  [1];  [1];  [1];  [1];  [2];  [2];  [2];  [2];  [1];
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  1. Department of Materials Science &, Engineering University of Delaware Newark Delaware 19716
  2. College of Optics and Photonics CREOL Department of Materials Science and Engineering University of Central Florida Orlando Florida 32816
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1400906
Grant/Contract Number:  
DE‐EE0005327
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of the American Ceramic Society
Additional Journal Information:
Journal Name: Journal of the American Ceramic Society Journal Volume: 98 Journal Issue: 6; Journal ID: ISSN 0002-7820
Publisher:
Wiley-Blackwell
Country of Publication:
United States
Language:
English

Citation Formats

Ogbuu, Okechukwu, Du, Qingyang, Lin, Hongtao, Li, Lan, Zou, Yi, Koontz, Erick, Smith, Charmayne, Danto, Sylvain, Richardson, Kathleen, Hu, Juejun, and Lucas, ed., P. Impact of Stoichiometry on Structural and Optical Properties of Sputter Deposited Multicomponent Tellurite Glass Films. United States: N. p., 2015. Web. doi:10.1111/jace.13534.
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Ogbuu, Okechukwu, Du, Qingyang, Lin, Hongtao, Li, Lan, Zou, Yi, Koontz, Erick, Smith, Charmayne, Danto, Sylvain, Richardson, Kathleen, Hu, Juejun, & Lucas, ed., P. Impact of Stoichiometry on Structural and Optical Properties of Sputter Deposited Multicomponent Tellurite Glass Films. United States. https://doi.org/10.1111/jace.13534
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Ogbuu, Okechukwu, Du, Qingyang, Lin, Hongtao, Li, Lan, Zou, Yi, Koontz, Erick, Smith, Charmayne, Danto, Sylvain, Richardson, Kathleen, Hu, Juejun, and Lucas, ed., P. Wed . "Impact of Stoichiometry on Structural and Optical Properties of Sputter Deposited Multicomponent Tellurite Glass Films". United States. https://doi.org/10.1111/jace.13534.
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@article{osti_1400906,
title = {Impact of Stoichiometry on Structural and Optical Properties of Sputter Deposited Multicomponent Tellurite Glass Films},
author = {Ogbuu, Okechukwu and Du, Qingyang and Lin, Hongtao and Li, Lan and Zou, Yi and Koontz, Erick and Smith, Charmayne and Danto, Sylvain and Richardson, Kathleen and Hu, Juejun and Lucas, ed., P.},
abstractNote = {Multicomponent TeO 2 –Bi 2 O 3 –ZnO ( TBZ ) glass thin films were prepared using RF magnetron sputtering under different oxygen flow rates. The influences of oxygen flow rate on the structural and optical properties of the resulting thin films were investigated. We observed that thin films sputtered in an oxygen‐rich environment are optically transparent while those sputtered in an oxygen‐deficient environment exhibit broadband absorption. The structural origin of the optical property variation was studied using X‐ray diffraction, X‐ray photoelectron spectroscopy, Raman Spectroscopy, and transmission electron microscopy which revealed that the presence of under‐coordinated Te leads to the observed optical absorption in oxygen‐deficient films.},
doi = {10.1111/jace.13534},
journal = {Journal of the American Ceramic Society},
number = 6,
volume = 98,
place = {United States},
year = {Wed Mar 04 00:00:00 EST 2015},
month = {Wed Mar 04 00:00:00 EST 2015}
}
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Journal Article:
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https://doi.org/10.1111/jace.13534
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