High‐Pressure‐Induced Pseudo‐oxidation of Copper Surfaces by Carbon Monoxide
Abstract
Abstract Instantaneous electronic and structural modifications of Cu surfaces by high‐pressure CO were explored. At pressures over a millibar range the coverage of CO on the Cu(1 1 1) surface reached approximately one monolayer, and we observed several shake‐up peaks in the Cu 2p photoemission spectra for the first time by using ambient pressure X‐ray photoelectron spectroscopy. These shake‐up peaks resembled those obtained for oxidized surface Cu atoms. We propose that these changes are related to the generation of a copper–carbonyl complex and subsequent Cu surface restructuring owing to lateral CO–CO repulsions. The generality of this finding was investigated in two model reactions, the water‐gas shift and CO oxidation, on a Cu(1 1 1) surface, and we clearly identified the pseudo‐oxidation of Cu. These reversible changes were found to be independent of the orientation of the Cu surface and are of general importance for Cu‐based heterogeneous catalysis.
- Authors:
-
[1];
- Radiation Laboratory and Department of Chemistry and Biochemistry University of Notre Dame Notre Dame IN 46556 USA
- Radiation Laboratory and Department of Physics University of Notre Dame Notre Dame IN 46556 USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1400553
- Grant/Contract Number:
- FC02-04ER15533
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- ChemCatChem
- Additional Journal Information:
- Journal Name: ChemCatChem Journal Volume: 8 Journal Issue: 9; Journal ID: ISSN 1867-3880
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Zhang, Xueqiang, and Ptasinska, Sylwia. High‐Pressure‐Induced Pseudo‐oxidation of Copper Surfaces by Carbon Monoxide. Germany: N. p., 2016.
Web. doi:10.1002/cctc.201600046.
Zhang, Xueqiang, & Ptasinska, Sylwia. High‐Pressure‐Induced Pseudo‐oxidation of Copper Surfaces by Carbon Monoxide. Germany. https://doi.org/10.1002/cctc.201600046
Zhang, Xueqiang, and Ptasinska, Sylwia. Sat .
"High‐Pressure‐Induced Pseudo‐oxidation of Copper Surfaces by Carbon Monoxide". Germany. https://doi.org/10.1002/cctc.201600046.
@article{osti_1400553,
title = {High‐Pressure‐Induced Pseudo‐oxidation of Copper Surfaces by Carbon Monoxide},
author = {Zhang, Xueqiang and Ptasinska, Sylwia},
abstractNote = {Abstract Instantaneous electronic and structural modifications of Cu surfaces by high‐pressure CO were explored. At pressures over a millibar range the coverage of CO on the Cu(1 1 1) surface reached approximately one monolayer, and we observed several shake‐up peaks in the Cu 2p photoemission spectra for the first time by using ambient pressure X‐ray photoelectron spectroscopy. These shake‐up peaks resembled those obtained for oxidized surface Cu atoms. We propose that these changes are related to the generation of a copper–carbonyl complex and subsequent Cu surface restructuring owing to lateral CO–CO repulsions. The generality of this finding was investigated in two model reactions, the water‐gas shift and CO oxidation, on a Cu(1 1 1) surface, and we clearly identified the pseudo‐oxidation of Cu. These reversible changes were found to be independent of the orientation of the Cu surface and are of general importance for Cu‐based heterogeneous catalysis.},
doi = {10.1002/cctc.201600046},
journal = {ChemCatChem},
number = 9,
volume = 8,
place = {Germany},
year = {Sat Apr 09 00:00:00 EDT 2016},
month = {Sat Apr 09 00:00:00 EDT 2016}
}
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Works referenced in this record:
A high-pressure-induced dense CO overlayer on a Pt(111) surface: a chemical analysis using in situ near ambient pressure XPS
journal, January 2014
- Toyoshima, Ryo; Yoshida, Masaaki; Monya, Yuji
- Phys. Chem. Chem. Phys., Vol. 16, Issue 43
Tailored Mesostructured Copper/Ceria Catalysts with Enhanced Performance for Preferential Oxidation of CO at Low Temperature
journal, October 2012
- Yen, Hoang; Seo, Yongbeom; Kaliaguine, Serge
- Angewandte Chemie, Vol. 124, Issue 48
CO adsorption on close-packed transition and noble metal surfaces: trends from ab initio calculations
journal, February 2004
- Gajdo, Marek; Eichler, Andreas; Hafner, Jürgen
- Journal of Physics: Condensed Matter, Vol. 16, Issue 8
Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Sc, Ti, V, Cu and Zn
journal, November 2010
- Biesinger, Mark C.; Lau, Leo W. M.; Gerson, Andrea R.
- Applied Surface Science, Vol. 257, Issue 3
X-ray photoemission analysis of clean and carbon monoxide-chemisorbed platinum(111) stepped surfaces using a curved crystal
journal, November 2015
- Walter, Andrew L.; Schiller, Frederik; Corso, Martina
- Nature Communications, Vol. 6, Issue 1
CO Oxidation as a Prototypical Reaction for Heterogeneous Processes
journal, September 2011
- Freund, Hans-Joachim; Meijer, Gerard; Scheffler, Matthias
- Angewandte Chemie International Edition, Vol. 50, Issue 43
Water Gas Shift Reaction on Cu and Au Nanoparticles Supported on CeO2(111) and ZnO(000): Intrinsic Activity and Importance of Support Interactions
journal, February 2007
- Rodriguez, José A.; Liu, Ping; Hrbek, Jan
- Angewandte Chemie, Vol. 119, Issue 8
Water-Gas Shift Reaction on a Highly Active Inverse CeO x /Cu(111) Catalyst: Unique Role of Ceria Nanoparticles
journal, October 2009
- Rodriguez, José A.; Graciani, Jesús; Evans, Jaime
- Angewandte Chemie International Edition, Vol. 48, Issue 43
Low‐Temperature CO Oxidation over a Ternary Oxide Catalyst with High Resistance to Hydrocarbon Inhibition
journal, September 2015
- Binder, Andrew J.; Toops, Todd J.; Unocic, Raymond R.
- Angewandte Chemie, Vol. 127, Issue 45
Heterogene Katalysatoren - fundamental betrachtet
journal, February 2015
- Schlögl, Robert
- Angewandte Chemie, Vol. 127, Issue 11
Solution-Based Evolution and Enhanced Methanol Oxidation Activity of Monodisperse Platinum-Copper Nanocubes
journal, May 2009
- Xu, Dan; Liu, Zhaoping; Yang, Hongzhou
- Angewandte Chemie International Edition, Vol. 48, Issue 23
Tailored Mesostructured Copper/Ceria Catalysts with Enhanced Performance for Preferential Oxidation of CO at Low Temperature
journal, October 2012
- Yen, Hoang; Seo, Yongbeom; Kaliaguine, Serge
- Angewandte Chemie International Edition, Vol. 51, Issue 48
Break-Up of Stepped Platinum Catalyst Surfaces by High CO Coverage
journal, February 2010
- Tao, F.; Dag, S.; Wang, L. -W.
- Science, Vol. 327, Issue 5967
Die CO-Oxidation als Modellreaktion für heterogene Prozesse
journal, September 2011
- Freund, Hans-Joachim; Meijer, Gerard; Scheffler, Matthias
- Angewandte Chemie, Vol. 123, Issue 43
Ambient pressure photoelectron spectroscopy: A new tool for surface science and nanotechnology
journal, April 2008
- Salmeron, M.; Schlogl, R.
- Surface Science Reports, Vol. 63, Issue 4
Water-Gas Shift Reaction on a Highly Active Inverse CeO x /Cu(111) Catalyst: Unique Role of Ceria Nanoparticles
journal, October 2009
- Rodriguez, José A.; Graciani, Jesús; Evans, Jaime
- Angewandte Chemie, Vol. 121, Issue 43
Water-gas shift reaction: finding the mechanistic boundary
journal, January 1995
- Rhodes, C.; Hutchings, G. J.; Ward, A. M.
- Catalysis Today, Vol. 23, Issue 1
Kinetics of the CO oxidation reaction on Pt(111) studied by in situ high-resolution x-ray photoelectron spectroscopy
journal, April 2004
- Kinne, M.; Fuhrmann, T.; Zhu, J. F.
- The Journal of Chemical Physics, Vol. 120, Issue 15
Water Gas Shift Catalysis
journal, September 2009
- Ratnasamy, Chandra; Wagner, Jon P.
- Catalysis Reviews, Vol. 51, Issue 3
Carbon Monoxide-Assisted Size Confinement of Bimetallic Alloy Nanoparticles
journal, March 2014
- Cui, Chunhua; Gan, Lin; Neumann, Maximilian
- Journal of the American Chemical Society, Vol. 136, Issue 13
Solution-Based Evolution and Enhanced Methanol Oxidation Activity of Monodisperse Platinum-Copper Nanocubes
journal, May 2009
- Xu, Dan; Liu, Zhaoping; Yang, Hongzhou
- Angewandte Chemie, Vol. 121, Issue 23
Shape and Composition-Controlled Platinum Alloy Nanocrystals Using Carbon Monoxide as Reducing Agent
journal, February 2011
- Wu, Jianbo; Gross, Adam; Yang, Hong
- Nano Letters, Vol. 11, Issue 2
Determination of Site Specific Adsorption Energies of CO on Copper
journal, January 2001
- Vollmer, Stefan; Witte, Gregor; Wöll, Christof
- Catalysis Letters, Vol. 77, Issue 1/3, p. 97-101
Study of Supported PtCu and PdAu Bimetallic Nanoparticles Using In-Situ X-ray Tools
journal, June 2010
- Oxford, Sean M.; Lee, Peter L.; Chupas, Peter J.
- The Journal of Physical Chemistry C, Vol. 114, Issue 40
On the Mechanism of Low-Temperature Water Gas Shift Reaction on Copper
journal, January 2008
- Gokhale, Amit A.; Dumesic, James A.; Mavrikakis, Manos
- Journal of the American Chemical Society, Vol. 130, Issue 4
Investigation of solid/vapor interfaces using ambient pressure X-ray photoelectron spectroscopy
journal, January 2013
- Starr, D. E.; Liu, Z.; Hävecker, M.
- Chemical Society Reviews, Vol. 42, Issue 13
Enhanced CO Oxidation on the Oxide/Metal Interface: From Ultra-High Vacuum to Near-Atmospheric Pressures
journal, August 2015
- Pan, Qiushi; Weng, Xuefei; Chen, Mingshu
- ChemCatChem, Vol. 7, Issue 17
CO Oxidation on Metal-Supported Ultrathin Oxide Films: What Makes Them Active?
journal, May 2013
- Martynova, Yulia; Shaikhutdinov, Shamil; Freund, Hans-Joachim
- ChemCatChem, Vol. 5, Issue 8
Carbon Monoxide-Induced Dynamic Metal-Surface Nanostructuring
journal, July 2014
- Carenco, Sophie
- Chemistry - A European Journal, Vol. 20, Issue 34
Activation of Cu(111) surface by decomposition into nanoclusters driven by CO adsorption
journal, January 2016
- Eren, B.; Zherebetskyy, D.; Patera, L. L.
- Science, Vol. 351, Issue 6272
Stearate-Based Cu Colloids in Methanol Synthesis: Structural Changes Driven by Strong Metal-Support Interactions
journal, February 2010
- Schimpf, Sabine; Rittermeier, André; Zhang, Xiaoning
- ChemCatChem, Vol. 2, Issue 2
The mechanism of CO oxidation over Cu(110): Effect of CO gas energy
journal, January 1991
- Domagala, Melanie E.; Campbell, Charles T.
- Catalysis Letters, Vol. 9, Issue 1-2
Recent advances in heterogeneous selective oxidation catalysis for sustainable chemistry
journal, January 2014
- Guo, Zhen; Liu, Bin; Zhang, Qinghong
- Chemical Society Reviews, Vol. 43, Issue 10
Temperature and pressure effects in CO titration of ensembles in PdAu(111) alloys using first principles
journal, August 2010
- García-Mota, Mónica; López, Núria
- Physical Review B, Vol. 82, Issue 7
Carbon monoxide-induced adatom sintering in a Pd–Fe3O4 model catalyst
journal, June 2013
- Parkinson, Gareth S.; Novotny, Zbynek; Argentero, Giacomo
- Nature Materials, Vol. 12, Issue 8
Catalyst Chemical State during CO Oxidation Reaction on Cu(111) Studied with Ambient-Pressure X-ray Photoelectron Spectroscopy and Near Edge X-ray Adsorption Fine Structure Spectroscopy
journal, August 2015
- Eren, Baran; Heine, Christian; Bluhm, Hendrik
- Journal of the American Chemical Society, Vol. 137, Issue 34
Carbon Monoxide Oxidation over Three Different Oxidation States of Copper: Metallic Copper, Copper (I) Oxide, and Copper (II) Oxide - A Surface Science and Kinetic Study
journal, June 1994
- Jernigan, G. G.; Somorjai, G. A.
- Journal of Catalysis, Vol. 147, Issue 2
Surface Segregation of Pd from TiO 2 -Supported AuPd Nanoalloys under CO Oxidation Conditions Observed In situ by ETEM and DRIFTS
journal, February 2013
- Delannoy, Laurent; Giorgio, Suzanne; Mattei, Jean Gabriel
- ChemCatChem, Vol. 5, Issue 9
Redox-Mediated Reconstruction of Copper during Carbon Monoxide Oxidation
journal, July 2014
- Xu, Fang; Mudiyanselage, Kumudu; Baber, Ashleigh E.
- The Journal of Physical Chemistry C, Vol. 118, Issue 29
Low-Temperature CO Oxidation over a Ternary Oxide Catalyst with High Resistance to Hydrocarbon Inhibition
journal, September 2015
- Binder, Andrew J.; Toops, Todd J.; Unocic, Raymond R.
- Angewandte Chemie International Edition, Vol. 54, Issue 45
Reaction of CO with Preadsorbed Oxygen on Low-Index Copper Surfaces: An Ambient Pressure X-ray Photoelectron Spectroscopy and Scanning Tunneling Microscopy Study
journal, March 2015
- Eren, Baran; Lichtenstein, Leonid; Wu, Cheng Hao
- The Journal of Physical Chemistry C, Vol. 119, Issue 26
Importance of the Metal-Oxide Interface in Catalysis: In Situ Studies of the Water-Gas Shift Reaction by Ambient-Pressure X-ray Photoelectron Spectroscopy
journal, April 2013
- Mudiyanselage, Kumudu; Senanayake, Sanjaya D.; Feria, Leticia
- Angewandte Chemie International Edition, Vol. 52, Issue 19
Importance of the Metal-Oxide Interface in Catalysis: In Situ Studies of the Water-Gas Shift Reaction by Ambient-Pressure X-ray Photoelectron Spectroscopy
journal, April 2013
- Mudiyanselage, Kumudu; Senanayake, Sanjaya D.; Feria, Leticia
- Angewandte Chemie, Vol. 125, Issue 19
Water Gas Shift Reaction on Cu and Au Nanoparticles Supported on CeO2(111) and ZnO(000): Intrinsic Activity and Importance of Support Interactions
journal, February 2007
- Rodriguez, José A.; Liu, Ping; Hrbek, Jan
- Angewandte Chemie International Edition, Vol. 46, Issue 8
Distinct and dramatic water dissociation on GaP(111) tracked by near-ambient pressure X-ray photoelectron spectroscopy
journal, January 2015
- Zhang, Xueqiang; Ptasinska, Sylwia
- Physical Chemistry Chemical Physics, Vol. 17, Issue 5
Heterogeneous Catalysis
journal, February 2015
- Schlögl, Robert
- Angewandte Chemie International Edition, Vol. 54, Issue 11
Selective Hydrogenation of 1,3-Butadiene in the Presence of an Excess of Alkenes over Supported Bimetallic Gold−Palladium Catalysts
journal, May 2010
- Hugon, Antoine; Delannoy, Laurent; Krafft, Jean-Marc
- The Journal of Physical Chemistry C, Vol. 114, Issue 24
Catalysts for methanol steam reforming—A review
journal, August 2010
- Sá, Sandra; Silva, Hugo; Brandão, Lúcia
- Applied Catalysis B: Environmental, Vol. 99, Issue 1-2
Dealloying of Cobalt from CuCo Nanoparticles under Syngas Exposure
journal, March 2013
- Carenco, Sophie; Tuxen, Anders; Chintapalli, Mahati
- The Journal of Physical Chemistry C, Vol. 117, Issue 12
Kinetic parameters of CO adsorbed on Pt(111) studied by in situ high resolution x-ray photoelectron spectroscopy
journal, December 2002
- Kinne, M.; Fuhrmann, T.; Whelan, C. M.
- The Journal of Chemical Physics, Vol. 117, Issue 23
Dissociative Adsorption of Water on an H 2 O/GaAs(100) Interface: In Situ Near-Ambient Pressure XPS Studies
journal, February 2014
- Zhang, Xueqiang; Ptasinska, Sylwia
- The Journal of Physical Chemistry C, Vol. 118, Issue 8