An Organic Semiconductor Organized into 3D DNA Arrays by “Bottom‐up” Rational Design
Abstract
Abstract A 3D array of organic semiconductors was assembled using a DNA scaffold. An octameric aniline molecule (“octaniline”) was incorporated into a DNA building block based on a dimeric tensegrity triangle. The construct self‐assembled to form a 3D crystal. Reversible redox conversion between the pernigraniline and leucoemeraldine states of the octaniline is retained in the crystal. Protonic doping gave emeraldine salt at pH 5, corresponding to the conductive form of polyaniline. Redox cycling within the crystal was visualized by color changes and Raman microscopy. The ease of conversion between the octaniline states suggests that it is a viable electronic switch within a unique 3D structure.
- Authors:
-
- Department of Chemistry New York University New York NY 10003 USA
- Department of Chemistry Purdue University West Lafayette IN 47907 USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1399624
- Grant/Contract Number:
- SC0007991
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Angewandte Chemie
- Additional Journal Information:
- Journal Name: Angewandte Chemie Journal Volume: 129 Journal Issue: 23; Journal ID: ISSN 0044-8249
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Wang, Xiao, Sha, Ruojie, Kristiansen, Martin, Hernandez, Carina, Hao, Yudong, Mao, Chengde, Canary, James W., and Seeman, Nadrian C. An Organic Semiconductor Organized into 3D DNA Arrays by “Bottom‐up” Rational Design. Germany: N. p., 2017.
Web. doi:10.1002/ange.201700462.
Wang, Xiao, Sha, Ruojie, Kristiansen, Martin, Hernandez, Carina, Hao, Yudong, Mao, Chengde, Canary, James W., & Seeman, Nadrian C. An Organic Semiconductor Organized into 3D DNA Arrays by “Bottom‐up” Rational Design. Germany. https://doi.org/10.1002/ange.201700462
Wang, Xiao, Sha, Ruojie, Kristiansen, Martin, Hernandez, Carina, Hao, Yudong, Mao, Chengde, Canary, James W., and Seeman, Nadrian C. Wed .
"An Organic Semiconductor Organized into 3D DNA Arrays by “Bottom‐up” Rational Design". Germany. https://doi.org/10.1002/ange.201700462.
@article{osti_1399624,
title = {An Organic Semiconductor Organized into 3D DNA Arrays by “Bottom‐up” Rational Design},
author = {Wang, Xiao and Sha, Ruojie and Kristiansen, Martin and Hernandez, Carina and Hao, Yudong and Mao, Chengde and Canary, James W. and Seeman, Nadrian C.},
abstractNote = {Abstract A 3D array of organic semiconductors was assembled using a DNA scaffold. An octameric aniline molecule (“octaniline”) was incorporated into a DNA building block based on a dimeric tensegrity triangle. The construct self‐assembled to form a 3D crystal. Reversible redox conversion between the pernigraniline and leucoemeraldine states of the octaniline is retained in the crystal. Protonic doping gave emeraldine salt at pH 5, corresponding to the conductive form of polyaniline. Redox cycling within the crystal was visualized by color changes and Raman microscopy. The ease of conversion between the octaniline states suggests that it is a viable electronic switch within a unique 3D structure.},
doi = {10.1002/ange.201700462},
journal = {Angewandte Chemie},
number = 23,
volume = 129,
place = {Germany},
year = {Wed May 03 00:00:00 EDT 2017},
month = {Wed May 03 00:00:00 EDT 2017}
}
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