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Title: Hydrothermal Atomic Force Microscopy Investigation of Barite Growth: Role of Spectator Ions in Elementary Step Edge Growth Kinetics and Hillock Morphology [Plus Supporting Information]

Abstract

In this paper to better understand the role of spectator ions in barite growth, the kinetics of step edge growth on barite (001) surfaces were studied under various salt solutions. Hydrothermal atomic force microscopy (HAFM) was used to investigate the effect of background electrolytes (NaCl, NaBr, and NaNO3) as a function of saturation index and ionic strength (I) on barite growth sourced at dislocations at 108 °C. Results demonstrate that hillock morphology is affected by I, as well as type of anion, where the prevalence of steps aligned on the [010] direction is highest under Cl–. There is a modest increase in kinetic coefficient of 55–130% with a 10-fold increase in I for each salt. In comparing the kinetic coefficients of the salts at low ionic strength (0.01 M), there is a moderate difference, suggesting that the anion may play a role in barium attachment.

Authors:
 [1];  [1]; ORCiD logo [2]; ORCiD logo [1]
+ Show Author Affiliations
  1. Wright State Univ., Dayton, OH (United States)
  2. Wright State Univ., Dayton, OH (United States); Argonne National Lab. (ANL), Argonne, IL (United States)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1399228
Alternate Identifier(s):
OSTI ID: 1461407
Grant/Contract Number:  
AC05-00OR22725; AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
Crystal Growth and Design
Additional Journal Information:
Journal Volume: 17; Journal Issue: 11; Journal ID: ISSN 1528-7483
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Jindra, Sarah A., Bertagni, Angela L., Bracco, Jacquelyn N., and Higgins, Steven R. Hydrothermal Atomic Force Microscopy Investigation of Barite Growth: Role of Spectator Ions in Elementary Step Edge Growth Kinetics and Hillock Morphology [Plus Supporting Information]. United States: N. p., 2017. Web. doi:10.1021/acs.cgd.7b01198.
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Jindra, Sarah A., Bertagni, Angela L., Bracco, Jacquelyn N., & Higgins, Steven R. Hydrothermal Atomic Force Microscopy Investigation of Barite Growth: Role of Spectator Ions in Elementary Step Edge Growth Kinetics and Hillock Morphology [Plus Supporting Information]. United States. https://doi.org/10.1021/acs.cgd.7b01198
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Jindra, Sarah A., Bertagni, Angela L., Bracco, Jacquelyn N., and Higgins, Steven R. Mon . "Hydrothermal Atomic Force Microscopy Investigation of Barite Growth: Role of Spectator Ions in Elementary Step Edge Growth Kinetics and Hillock Morphology [Plus Supporting Information]". United States. https://doi.org/10.1021/acs.cgd.7b01198. https://www.osti.gov/servlets/purl/1399228.
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@article{osti_1399228,
title = {Hydrothermal Atomic Force Microscopy Investigation of Barite Growth: Role of Spectator Ions in Elementary Step Edge Growth Kinetics and Hillock Morphology [Plus Supporting Information]},
author = {Jindra, Sarah A. and Bertagni, Angela L. and Bracco, Jacquelyn N. and Higgins, Steven R.},
abstractNote = {In this paper to better understand the role of spectator ions in barite growth, the kinetics of step edge growth on barite (001) surfaces were studied under various salt solutions. Hydrothermal atomic force microscopy (HAFM) was used to investigate the effect of background electrolytes (NaCl, NaBr, and NaNO3) as a function of saturation index and ionic strength (I) on barite growth sourced at dislocations at 108 °C. Results demonstrate that hillock morphology is affected by I, as well as type of anion, where the prevalence of steps aligned on the [010] direction is highest under Cl–. There is a modest increase in kinetic coefficient of 55–130% with a 10-fold increase in I for each salt. In comparing the kinetic coefficients of the salts at low ionic strength (0.01 M), there is a moderate difference, suggesting that the anion may play a role in barium attachment.},
doi = {10.1021/acs.cgd.7b01198},
journal = {Crystal Growth and Design},
number = 11,
volume = 17,
place = {United States},
year = {2017},
month = {9}
}
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https://doi.org/10.1021/acs.cgd.7b01198
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Works referenced in this record:

Barite accumulation, ocean productivity, and Sr/Ba in barite across the Paleocene–Eocene Thermal Maximum
journal, January 2007

Structural recovery behavior of barite-loaded bentonite drilling muds
journal, August 2011

Barium and Strontium Sulfate Solid Solution Formation in Relation to North Sea Scaling Problems
journal, August 1990

  • Todd, Adrian C.; Yuan, Mingdong
  • SPE Production Engineering, Vol. 5, Issue 03
  • DOI: 10.2118/18200-PA

The influence of pH on barite nucleation and growth
journal, January 2015

Dissolution of barite by a chelating ligand: An atomic force microscopy study
journal, November 1995

  • Putnis, Andrew; Junta-Rosso, Jodi L.; Hochella, Michael F.
  • Geochimica et Cosmochimica Acta, Vol. 59, Issue 22
  • DOI: 10.1016/0016-7037(95)00324-X

The mechanism and kinetics of DTPA-promoted dissolution of barite
journal, September 2008

The effect of specific background electrolytes on water structure and solute hydration: Consequences for crystal dissolution and growth
journal, September 2008

The Growth of Crystals and the Equilibrium Structure of their Surfaces
journal, June 1951

  • Burton, W. K.; Cabrera, N.; Frank, F. C.
  • Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 243, Issue 866
  • DOI: 10.1098/rsta.1951.0006

Kink kinetics, exchange fluxes, 1D `nucleation' and adsorption on the (010) face of orthorhombic lysozyme crystals
journal, November 1999

  • Chernov, A. A.; Rashkovich, L. N.; Yaminski, I. V.
  • Journal of Physics: Condensed Matter, Vol. 11, Issue 49
  • DOI: 10.1088/0953-8984/11/49/314

Nucleation-controlled growth on a one-dimensional growth of finite length
journal, May 1974

Reversed calcite morphologies induced by microscopic growth kinetics: insight into biomineralization
journal, October 1999

Hydrothermal atomic force microscopy observations of barite step growth rates as a function of the aqueous barium-to-sulfate ratio
journal, June 2016

  • Bracco, Jacquelyn N.; Gooijer, Yiscka; Higgins, Steven R.
  • Geochimica et Cosmochimica Acta, Vol. 183
  • DOI: 10.1016/j.gca.2016.03.009

Molecular-scale mechanisms of crystal growth in barite
journal, October 1998

  • Pina, Carlos M.; Becker, Udo; Risthaus, Peter
  • Nature, Vol. 395, Issue 6701
  • DOI: 10.1038/26718

Lattice Kinetic Modeling of the Anisotropic Growth of Two-Dimensional Islands on Barite (001) Surface
journal, May 2013

  • de Antonio Gómez, Santiago; Pina, Carlos M.; Martin-Bragado, Ignacio
  • Crystal Growth & Design, Vol. 13, Issue 7
  • DOI: 10.1021/cg4002237

In Situ AFM Study of Crystal Growth on a Barite (001) Surface in BaSO4 Solutions at 30 °C
journal, November 2016

  • Kuwahara, Yoshihiro; Liu, Wen; Makio, Masato
  • Minerals, Vol. 6, Issue 4
  • DOI: 10.3390/min6040117

Growth Kinetics and Morphology of Barite Crystals Derived from Face-Specific Growth Rates
journal, March 2015

  • Godinho, Jose R. A.; Stack, Andrew G.
  • Crystal Growth & Design, Vol. 15, Issue 5
  • DOI: 10.1021/cg501507p

Barite scale formation and dissolution at high ionic strength studied with atomic force microscopy
journal, November 2001

  • Risthaus, Peter; Bosbach, Dirk; Becker, Udo
  • Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 191, Issue 3
  • DOI: 10.1016/S0927-7757(00)00843-8

The Nucleation Kinetics of Barium Sulfate in NaCl Solutions up to 6 m and 90°C
journal, September 1995

  • He, Shiliang; Oddo, John E.; Tomson, Mason B.
  • Journal of Colloid and Interface Science, Vol. 174, Issue 2
  • DOI: 10.1006/jcis.1995.1397

Experimental determination of barite dissolution and precipitation rates as a function of temperature and aqueous fluid composition
journal, December 2016

Calculation of mass transfer in geochemical processes involving aqueous solutions
journal, May 1970

  • Helgeson, Harold C.; Brown, Thomas H.; Nigrini, Andrew
  • Geochimica et Cosmochimica Acta, Vol. 34, Issue 5
  • DOI: 10.1016/0016-7037(70)90017-7

A hydrothermal atomic force microscope for imaging in aqueous solution up to 150 °C
journal, August 1998

  • Higgins, Steven R.; Eggleston, Carrick M.; Knauss, Kevin G.
  • Review of Scientific Instruments, Vol. 69, Issue 8
  • DOI: 10.1063/1.1149226

An in-situ AFM investigation of canavalin crystallization kinetics
journal, July 1997

Charge density-dependent strength of hydration and biological structure
journal, January 1997

Viscosity of aqueous Na2SO4 solutions at temperatures from 298 to 573K and at pressures up to 40MPa
journal, January 2005

Thermochemical Radii of Complex Ions
journal, November 1999

  • Roobottom, Helen K.; Jenkins, H. Donald B.; Passmore, Jack
  • Journal of Chemical Education, Vol. 76, Issue 11
  • DOI: 10.1021/ed076p1570

Accurate Rates of the Complex Mechanisms for Growth and Dissolution of Minerals Using a Combination of Rare-Event Theories
journal, July 2011

  • Stack, Andrew G.; Raiteri, Paolo; Gale, Julian D.
  • Journal of the American Chemical Society, Vol. 134, Issue 1
  • DOI: 10.1021/ja204714k
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    Works referencing / citing this record:

    The Effect of Ionic Strength and Sraq upon the Uptake of Ra during the Recrystallization of Barite
    journal, November 2018

    • Brandt, Felix; Klinkenberg, Martina; Poonoosamy, Jenna
    • Minerals, Vol. 8, Issue 11
    • DOI: 10.3390/min8110502
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