Fast kinetics of magnesium monochloride cations in interlayer-expanded titanium disulfide for magnesium rechargeable batteries

Yoo, Hyun Deog; Liang, Yanliang; Dong, Hui; Lin, Junhao; Wang, Hua; Liu, Yisheng; Ma, Lu; Wu, Tianpin; Li, Yifei; Ru, Qiang; Jing, Yan; An, Qinyou; Zhou, Wu; Guo, Jinghua; Lu, Jun; Pantelides, Sokrates T.; Qian, Xiaofeng; Yao, Yan

doi:10.1038/s41467-017-00431-9

Title: Fast kinetics of magnesium monochloride cations in interlayer-expanded titanium disulfide for magnesium rechargeable batteries

Journal Article · Thu Aug 24 00:00:00 EDT 2017 · Nature Communications

DOI: https://doi.org/10.1038/s41467-017-00431-9 · OSTI ID:1398523

Yoo, Hyun Deog ^[1]; Liang, Yanliang ^[1]; Dong, Hui ^[1]; Lin, Junhao ^[2]; Wang, Hua ^[3]; Liu, Yisheng ^[4]; Ma, Lu ^[5]; Wu, Tianpin ^[5]; Li, Yifei ^[1]; Ru, Qiang ^[1];

^[1]; An, Qinyou ^[1];

^[6];

^[4];

^[7];

^[2]; Qian, Xiaofeng ^[3];

^[8]

Univ. of Houston, Houston, TX (United States). Dept. of Electrical and Computer Engineering & Materials Science and Engineering Program
Vanderbilt Univ., Nashville, TN (United States). Dept. of Physics and Astronomy; Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science & Technology Division
Texas A&M Univ., College Station, TX (United States). Dept. of Materials Science and Engineering
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
Argonne National Lab. (ANL), Argonne, IL (United States). X-Ray Science Division
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science & Technology Division
Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Sciences and Engineering Division
Univ. of Houston, Houston, TX (United States). Dept. of Electrical and Computer Engineering & Materials Science and Engineering Program; Univ. of Houston, Houston, TX (United States). Texas Center for Superconductivity

Magnesium rechargeable batteries potentially offer high-energy density, safety, and low cost due to the ability to employ divalent, dendrite-free, and earth-abundant magnesium metal anode. Despite recent progress, further development remains stagnated mainly due to the sluggish scission of magnesium-chloride bond and slow diffusion of divalent magnesium cations in cathodes. Here in this paper we report a battery chemistry that utilizes magnesium monochloride cations in expanded titanium disulfide. Combined theoretical modeling, spectroscopic analysis, and electrochemical study reveal fast diffusion kinetics of magnesium monochloride cations without scission of magnesium-chloride bond. The battery demonstrates the reversible intercalation of 1 and 1.7 magnesium monochloride cations per titanium at 25 and 60 °C, respectively, corresponding to up to 400 mAh g^-1 capacity based on the mass of titanium disulfide. The large capacity accompanies with excellent rate and cycling performances even at room temperature, opening up possibilities for a variety of effective intercalation hosts for multivalent-ion batteries.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); US Department of the Navy, Office of Naval Research (ONR)

Grant/Contract Number:: AC02-05CH11231; AC02-06CH11357; FG02-09ER46554

OSTI ID:: 1398523

Journal Information:: Nature Communications, Journal Name: Nature Communications Journal Issue: 1 Vol. 8; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Flexible n-type thermoelectric materials by organic intercalation of layered transition metal dichalcogenide TiS2 Wan, Chunlei; Gu, Xiaokun; Dang, Feng Nature Materials, Vol. 14, Issue 6 https://doi.org/10.1038/nmat4251	journal	April 2015
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