Olefin‐Supported Rhenium(III) Terminal Oxo Complexes Generated by Nucleophilic Addition to a Cyclopentadienyl Ligand
Abstract
Abstract The reactivity of the oxo Re V β‐diketiminate, OReCl 2 (BDI), with various cyclopentadienide (Cp) sources has been investigated. As a result, we have developed a route to a new class of terminal oxo complexes of Re III supported by olefin moieties of substituted cyclopentadienes. The success of this pathway is due to the electrophilic nature of the Cp ligand in the cation, [ORe(η 5 ‐Cp)(BDI)] + ( 3 + ), which allows for nucleophilic attack by a variety of reagents under mild conditions. In contrast, t BuNC was found to attack at the oxo moiety to produce isocyanate by oxygen atom transfer.
- Authors:
-
[1];
[1]
- Department of Chemistry University of California, Berkeley 420 Latimer Hall Berkeley CA 94720 USA, Chemical Sciences Division Lawrence Berkeley National Laboratory 1 Cyclotron Road Berkeley CA 94720 USA
- Department of Chemistry University of California, Berkeley 420 Latimer Hall Berkeley CA 94720 USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1398286
- Grant/Contract Number:
- AC02-05CH11231
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Angewandte Chemie (International Edition)
- Additional Journal Information:
- Journal Name: Angewandte Chemie (International Edition) Journal Volume: 56 Journal Issue: 45; Journal ID: ISSN 1433-7851
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Lohrey, Trevor D., Bergman, Robert G., and Arnold, John. Olefin‐Supported Rhenium(III) Terminal Oxo Complexes Generated by Nucleophilic Addition to a Cyclopentadienyl Ligand. Germany: N. p., 2017.
Web. doi:10.1002/anie.201707957.
Lohrey, Trevor D., Bergman, Robert G., & Arnold, John. Olefin‐Supported Rhenium(III) Terminal Oxo Complexes Generated by Nucleophilic Addition to a Cyclopentadienyl Ligand. Germany. https://doi.org/10.1002/anie.201707957
Lohrey, Trevor D., Bergman, Robert G., and Arnold, John. Fri .
"Olefin‐Supported Rhenium(III) Terminal Oxo Complexes Generated by Nucleophilic Addition to a Cyclopentadienyl Ligand". Germany. https://doi.org/10.1002/anie.201707957.
@article{osti_1398286,
title = {Olefin‐Supported Rhenium(III) Terminal Oxo Complexes Generated by Nucleophilic Addition to a Cyclopentadienyl Ligand},
author = {Lohrey, Trevor D. and Bergman, Robert G. and Arnold, John},
abstractNote = {Abstract The reactivity of the oxo Re V β‐diketiminate, OReCl 2 (BDI), with various cyclopentadienide (Cp) sources has been investigated. As a result, we have developed a route to a new class of terminal oxo complexes of Re III supported by olefin moieties of substituted cyclopentadienes. The success of this pathway is due to the electrophilic nature of the Cp ligand in the cation, [ORe(η 5 ‐Cp)(BDI)] + ( 3 + ), which allows for nucleophilic attack by a variety of reagents under mild conditions. In contrast, t BuNC was found to attack at the oxo moiety to produce isocyanate by oxygen atom transfer.},
doi = {10.1002/anie.201707957},
journal = {Angewandte Chemie (International Edition)},
number = 45,
volume = 56,
place = {Germany},
year = {Fri Oct 06 00:00:00 EDT 2017},
month = {Fri Oct 06 00:00:00 EDT 2017}
}
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