Chlorite dissolution kinetics at pH 3–10 and temperature to 275°C

Smith, Megan M.; Carroll, Susan A.

doi:10.1016/j.chemgeo.2015.11.022

Title: Chlorite dissolution kinetics at pH 3–10 and temperature to 275°C

Abstract

Sheet silicates and clays are ubiquitous in geothermal environments. Their dissolution is of interest because this process contributes to scaling reactions along fluid pathways and alteration of fracture surfaces which could affect reservoir permeability. Here, in order to better predict the geochemical impacts on long-term performance of engineered geothermal systems, we have measured chlorite dissolution and developed a generalized kinetic rate law applicable over an expanded range of solution pH and temperature. Chlorite, (Mg,Al,Fe)₁₂(Si,Al)₈O₂₀(OH)₁₆, commonly occurs in many geothermal host rocks as either a primary mineral or alteration product.

Authors:

Smith, Megan M. ^[1]; Carroll, Susan A. ^[1]

Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

Publication Date:: Wed Dec 02 00:00:00 EST 2015

Research Org.:: Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1345334

Alternate Identifier(s):: OSTI ID: 1397575

Report Number(s):: LLNL-JRNL-680118
Journal ID: ISSN 0009-2541

Grant/Contract Number:: AC52-07NA27344; LLNL-JOUR-680118

Resource Type:: Accepted Manuscript

Journal Name:: Chemical Geology

Additional Journal Information:: Journal Volume: 421; Journal Issue: C; Journal ID: ISSN 0009-2541

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: 58 GEOSCIENCES; 15 GEOTHERMAL ENERGY; 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; chlorite; clinochlore; sheet silicate; phyllosilicate; dissolution; kinetics; reaction affinity; geothermal

Citation Formats


                    Smith, Megan M., and Carroll, Susan A. Chlorite dissolution kinetics at pH 3–10 and temperature to 275°C.  United States: N. p., 2015. 
Web.  doi:10.1016/j.chemgeo.2015.11.022.

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                    Smith, Megan M., & Carroll, Susan A. Chlorite dissolution kinetics at pH 3–10 and temperature to 275°C.  United States.  https://doi.org/10.1016/j.chemgeo.2015.11.022

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                    Smith, Megan M., and Carroll, Susan A. Wed .  
"Chlorite dissolution kinetics at pH 3–10 and temperature to 275°C".  United States.  https://doi.org/10.1016/j.chemgeo.2015.11.022.  https://www.osti.gov/servlets/purl/1345334.

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@article{osti_1345334,

  title        = {Chlorite dissolution kinetics at pH 3–10 and temperature to 275°C},

  author       = {Smith, Megan M. and Carroll, Susan A.},

  abstractNote = {Sheet silicates and clays are ubiquitous in geothermal environments. Their dissolution is of interest because this process contributes to scaling reactions along fluid pathways and alteration of fracture surfaces which could affect reservoir permeability. Here, in order to better predict the geochemical impacts on long-term performance of engineered geothermal systems, we have measured chlorite dissolution and developed a generalized kinetic rate law applicable over an expanded range of solution pH and temperature. Chlorite, (Mg,Al,Fe)12(Si,Al)8O20(OH)16, commonly occurs in many geothermal host rocks as either a primary mineral or alteration product.},

  doi          = {10.1016/j.chemgeo.2015.11.022},

  journal      = {Chemical Geology},

  number       = C,

  volume       = 421,

  place        = {United States},

  year         = {Wed Dec 02 00:00:00 EST 2015},

  month        = {Wed Dec 02 00:00:00 EST 2015}

}

Copy to clipboard

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https://doi.org/10.1016/j.chemgeo.2015.11.022

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Works referenced in this record:

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Chemical affinity and pH effects on chlorite dissolution kinetics under geological CO2 sequestration related conditions
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Zhang, Shuo; Yang, Li; DePaolo, Donald J.
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Works referencing / citing this record:

Using Reservoir Geology and Petrographic Observations to Improve CO2 Mineralization Estimates: Examples from the Johansen Formation, North Sea, Norway
journal, October 2019

Sundal, Anja; Hellevang, Helge
Minerals, Vol. 9, Issue 11
DOI: 10.3390/min9110671

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Summary Sheet silicates and clays are ubiquitous in geothermal environments. Their dissolution is of interest because this process contributes to scaling reactions along fluid pathways and alteration of fracture surfaces, which could affect reservoir permeability. In order to better predict the geochemical impacts on long-term performance of engineered geothermal systems, we have measured chlorite, biotite, illite, and muscovite dissolution and developed generalized kinetic rate laws that are applicable over an expanded range of solution pH and temperature for each mineral. This report summarizes the rate equations for layered silicates where data were lacking for geothermal systems.
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Similar Records

Title: Chlorite dissolution kinetics at pH 3–10 and temperature to 275°C

Abstract

Citation Formats

The diffusion of dissolved silica in dilute aqueous solution journal, August 1987

Chlorite dissolution rates under CO2 saturated conditions from 50 to 120°C and 120 to 200bar CO2 journal, January 2014

Chlorite dissolution in the acid ph-range: a combined microscopic and macroscopic approach journal, April 2003

Smectite dissolution kinetics at 80°C and pH 8.8 journal, August 2000

Heterogeneous kinetics and diffusion boundary layers: The example of reaction in a fracture journal, January 1987

Diopside and anthophyllite dissolution at 25° and 90°C and acid pH journal, May 1998

Dissolution rates of actinolite and chlorite from a whole-rock experimental study of metabasalt dissolution from 2 ≤ pH ≤ 12 at 25 °C journal, December 2014

Dissolution kinetics of diopside as a function of solution saturation state: Macroscopic measurements and implications for modeling of geological storage of CO2 journal, May 2010

Lizardite serpentine dissolution kinetics as a function of pH and temperature, including effects of elevated pCO2 journal, August 2013

Chlorite Geothermometry: A Review journal, January 1993

Kinetics of quartz dissolution in electrolyte solutions using a hydrothermal mixed flow reactor journal, April 1990

Theoretical consideration on the application of the Aagaard–Helgeson rate law to the dissolution of silicate minerals and glasses journal, September 2008

Dissolution of Ripidolite (Mg, Fe-Chlorite) in Organic and Inorganic Acid Solutions journal, March 2003

Thermodynamic and kinetic constraints on reaction rates among minerals and aqueous solutions. II. Rate constants, effective surface area, and the hydrolysis of feldspar journal, December 1984

Biotite Dissolution in Brine at Varied Temperatures and CO 2 Pressures: Its Activation Energy and Potential CO 2 Intercalation journal, October 2012

Modification to the crystal structure of chlorite during early stages of its dissolution journal, April 2009

Solubility of Two High-Mg and Two High-Fe Chlorites Using Multiple Equilibria1 journal, January 1982

Diopside dissolution kinetics as a function of pH, CO2, temperature, and time journal, January 1993

Dissolution of Chlorite Minerals by Fulvic acid journal, May 1973

An experimental study of illite dissolution kinetics as a function of ph from 1.4 to 12.4 and temperature from 5 to 50°C journal, October 2003

The kinetics of the dissolution of chlorite as a function of pH and at 25°C journal, April 2005

The kinetics of chlorite dissolution journal, March 2007

The dissolution of biotite and chlorite at 25°C in the near-neutral pH region journal, February 1996

Permeability of granite in a temperature gradient journal, April 1981

Permeability reduction in granite under hydrothermal conditions journal, December 2001

Surface reaction versus diffusion control of mineral dissolution and growth rates in geochemical processes journal, December 1989

Dissolution and precipitation kinetics of gibbsite at 80°C and pH 3: The dependence on solution saturation state journal, August 1992

Calculation of the thermodynamic and transport properties of aqueous species at high pressures and temperatures: Aqueous tracer diffusion coefficients of ions to 1000°C and 5 kb journal, January 1988

A compilation of rate parameters of water-mineral interaction kinetics for application to geochemical modeling report, January 2004

Permeability reduction of a natural fracture under net dissolution by hydrothermal fluids: PERMEABILITY REDUCTION OF A NATURAL FRACTURE journal, October 2003

Spontaneous switching of permeability changes in a limestone fracture with net dissolution: SPONTANEOUS SWITCHING OF PERMEABILITY CHANGES journal, March 2004

The Chlorite Series of Flagstaff Hill Area, California: A Preliminary Investigation journal, January 1972

Experimental Determination of Chlorite Dissolution Rates journal, January 1994

Kinetics of acid dissolution of an orthochlorite mineral journal, December 1967

Dissolution rates of talc as a function of solution composition, pH and temperature journal, July 2007

The role of fractures on coupled dissolution and precipitation patterns in carbonate rocks journal, May 2005

Kinetics of chlorite dissolution at elevated temperatures and CO2 conditions journal, June 2013

Diffusion Coefficient of Silica in Seawater journal, January 1971

Evolution of fracture permeability through fluid–rock reaction under hydrothermal conditions journal, April 2006

Temporal alteration of fracture permeability in granite under hydrothermal conditions and its interpretation by coupled chemo-mechanical model journal, December 2011

Compaction of a Rock Fracture Moderated by Competing Roles of Stress Corrosion and Pressure Solution journal, July 2008

Chemical affinity and pH effects on chlorite dissolution kinetics under geological CO2 sequestration related conditions journal, March 2015

Using Reservoir Geology and Petrographic Observations to Improve CO2 Mineralization Estimates: Examples from the Johansen Formation, North Sea, Norway journal, October 2019

The diffusion of dissolved silica in dilute aqueous solution
journal, August 1987

Chlorite dissolution rates under CO2 saturated conditions from 50 to 120°C and 120 to 200bar CO2
journal, January 2014

Chlorite dissolution in the acid ph-range: a combined microscopic and macroscopic approach
journal, April 2003

Smectite dissolution kinetics at 80°C and pH 8.8
journal, August 2000

Heterogeneous kinetics and diffusion boundary layers: The example of reaction in a fracture
journal, January 1987

Diopside and anthophyllite dissolution at 25° and 90°C and acid pH
journal, May 1998

Dissolution rates of actinolite and chlorite from a whole-rock experimental study of metabasalt dissolution from 2 ≤ pH ≤ 12 at 25 °C
journal, December 2014

Dissolution kinetics of diopside as a function of solution saturation state: Macroscopic measurements and implications for modeling of geological storage of CO2
journal, May 2010

Lizardite serpentine dissolution kinetics as a function of pH and temperature, including effects of elevated pCO2
journal, August 2013

Chlorite Geothermometry: A Review
journal, January 1993

Kinetics of quartz dissolution in electrolyte solutions using a hydrothermal mixed flow reactor
journal, April 1990

Theoretical consideration on the application of the Aagaard–Helgeson rate law to the dissolution of silicate minerals and glasses
journal, September 2008

Dissolution of Ripidolite (Mg, Fe-Chlorite) in Organic and Inorganic Acid Solutions
journal, March 2003

Thermodynamic and kinetic constraints on reaction rates among minerals and aqueous solutions. II. Rate constants, effective surface area, and the hydrolysis of feldspar
journal, December 1984

Biotite Dissolution in Brine at Varied Temperatures and CO ₂ Pressures: Its Activation Energy and Potential CO ₂ Intercalation
journal, October 2012

Modification to the crystal structure of chlorite during early stages of its dissolution
journal, April 2009

Solubility of Two High-Mg and Two High-Fe Chlorites Using Multiple Equilibria1
journal, January 1982

Diopside dissolution kinetics as a function of pH, CO2, temperature, and time
journal, January 1993

Dissolution of Chlorite Minerals by Fulvic acid
journal, May 1973

An experimental study of illite dissolution kinetics as a function of ph from 1.4 to 12.4 and temperature from 5 to 50°C
journal, October 2003

The kinetics of the dissolution of chlorite as a function of pH and at 25°C
journal, April 2005

The kinetics of chlorite dissolution
journal, March 2007

The dissolution of biotite and chlorite at 25°C in the near-neutral pH region
journal, February 1996

Permeability of granite in a temperature gradient
journal, April 1981

Permeability reduction in granite under hydrothermal conditions
journal, December 2001

Surface reaction versus diffusion control of mineral dissolution and growth rates in geochemical processes
journal, December 1989

Dissolution and precipitation kinetics of gibbsite at 80°C and pH 3: The dependence on solution saturation state
journal, August 1992

Calculation of the thermodynamic and transport properties of aqueous species at high pressures and temperatures: Aqueous tracer diffusion coefficients of ions to 1000°C and 5 kb
journal, January 1988

A compilation of rate parameters of water-mineral interaction kinetics for application to geochemical modeling
report, January 2004

Permeability reduction of a natural fracture under net dissolution by hydrothermal fluids: PERMEABILITY REDUCTION OF A NATURAL FRACTURE
journal, October 2003

Spontaneous switching of permeability changes in a limestone fracture with net dissolution: SPONTANEOUS SWITCHING OF PERMEABILITY CHANGES
journal, March 2004

The Chlorite Series of Flagstaff Hill Area, California: A Preliminary Investigation
journal, January 1972

Experimental Determination of Chlorite Dissolution Rates
journal, January 1994

Kinetics of acid dissolution of an orthochlorite mineral
journal, December 1967

Dissolution rates of talc as a function of solution composition, pH and temperature
journal, July 2007

The role of fractures on coupled dissolution and precipitation patterns in carbonate rocks
journal, May 2005

Kinetics of chlorite dissolution at elevated temperatures and CO2 conditions
journal, June 2013

Diffusion Coefficient of Silica in Seawater
journal, January 1971

Evolution of fracture permeability through fluid–rock reaction under hydrothermal conditions
journal, April 2006

Temporal alteration of fracture permeability in granite under hydrothermal conditions and its interpretation by coupled chemo-mechanical model
journal, December 2011

Compaction of a Rock Fracture Moderated by Competing Roles of Stress Corrosion and Pressure Solution
journal, July 2008

Chemical affinity and pH effects on chlorite dissolution kinetics under geological CO2 sequestration related conditions
journal, March 2015

Using Reservoir Geology and Petrographic Observations to Improve CO2 Mineralization Estimates: Examples from the Johansen Formation, North Sea, Norway
journal, October 2019