Enabling room temperature sodium metal batteries

Cao, Ruiguo; Mishra, Kuber; Li, Xiaolin; Qian, Jiangfeng; Engelhard, Mark H.; Bowden, Mark E.; Han, Kee Sung; Mueller, Karl T.; Henderson, Wesley A.; Zhang, Ji-Guang

doi:10.1016/j.nanoen.2016.09.013

Title: Enabling room temperature sodium metal batteries

Full Record
Other Related Research

Authors:: Cao, Ruiguo; Mishra, Kuber; Li, Xiaolin; Qian, Jiangfeng; Engelhard, Mark H.; Bowden, Mark E.; Han, Kee Sung; Mueller, Karl T.; Henderson, Wesley A.; Zhang, Ji-Guang

Publication Date:: Thu Dec 01 00:00:00 EST 2016

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Biological and Environmental Research (BER)

OSTI Identifier:: 1397459

Grant/Contract Number:: 57558; AC05-76RLO1830

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Nano Energy

Additional Journal Information:: Journal Name: Nano Energy Journal Volume: 30 Journal Issue: C; Journal ID: ISSN 2211-2855

Publisher:: Elsevier

Country of Publication:: Netherlands

Language:: English

Citation Formats


                    Cao, Ruiguo, Mishra, Kuber, Li, Xiaolin, Qian, Jiangfeng, Engelhard, Mark H., Bowden, Mark E., Han, Kee Sung, Mueller, Karl T., Henderson, Wesley A., and Zhang, Ji-Guang. Enabling room temperature sodium metal batteries.  Netherlands: N. p., 2016. 
Web.  doi:10.1016/j.nanoen.2016.09.013.

Copy to clipboard


                    Cao, Ruiguo, Mishra, Kuber, Li, Xiaolin, Qian, Jiangfeng, Engelhard, Mark H., Bowden, Mark E., Han, Kee Sung, Mueller, Karl T., Henderson, Wesley A., & Zhang, Ji-Guang. Enabling room temperature sodium metal batteries.  Netherlands.  https://doi.org/10.1016/j.nanoen.2016.09.013

Copy to clipboard


                    Cao, Ruiguo, Mishra, Kuber, Li, Xiaolin, Qian, Jiangfeng, Engelhard, Mark H., Bowden, Mark E., Han, Kee Sung, Mueller, Karl T., Henderson, Wesley A., and Zhang, Ji-Guang. Thu .  
"Enabling room temperature sodium metal batteries".  Netherlands.  https://doi.org/10.1016/j.nanoen.2016.09.013.

Copy to clipboard


                    
@article{osti_1397459,

  title        = {Enabling room temperature sodium metal batteries},

  author       = {Cao, Ruiguo and Mishra, Kuber and Li, Xiaolin and Qian, Jiangfeng and Engelhard, Mark H. and Bowden, Mark E. and Han, Kee Sung and Mueller, Karl T. and Henderson, Wesley A. and Zhang, Ji-Guang},

  abstractNote = {},

  doi          = {10.1016/j.nanoen.2016.09.013},

  journal      = {Nano Energy},

  number       = C,

  volume       = 30,

  place        = {Netherlands},

  year         = {Thu Dec 01 00:00:00 EST 2016},

  month        = {Thu Dec 01 00:00:00 EST 2016}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Publisher's Version of Record
https://doi.org/10.1016/j.nanoen.2016.09.013

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 198 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Similar Records in DOE PAGES and OSTI.GOV collections:

Enabling room temperature sodium metal batteries

Journal Article Cao, Ruiguo ; Mishra, Kuber ; Li, Xiaolin ; ... - Nano Energy

Rechargeable batteries based upon sodium (Na+) cations are at the core of many new battery chemistries beyond Li-ion batteries. Rather than using carbon or alloy-based anodes, the direct utilization of solid sodium metal as an anode would be highly advantageous, but its use has been highly problematic due to its high reactivity. In this work, however, it is demonstrated that, by tailoring the electrolyte formulation, solid Na metal can be electrochemically plated/stripped at ambient temperature with high efficiency (> 99%) on both copper and inexpensive aluminum current collectors thereby enabling a shift in focus to new battery chemical couples basedmore »« less
https://doi.org/10.1016/j.nanoen.2016.09.013
High-performance room-temperature sodium–sulfur battery enabled by electrocatalytic sodium polysulfides full conversion

Journal Article Wang, Nana ; Wang, Yunxiao ; Bai, Zhongchao ; ... - Energy & Environmental Science

Room-temperature sodium–sulfur (RT-Na–S) batteries are highly desirable for grid-scale stationary energy storage due to their low cost; however, short cycling stability caused by the incomplete conversion of sodium polysulfides is a major issue for their application. Herein, we introduce an effective sulfiphilic host, gold nanodots decorated on hierarchical N-doped carbon microspheres (CN/Au/S), to achieve completely reversible conversion reactions in the S cathode by electrocatalyzing the low-kinetics conversion of Na₂S₄ into NaS₂ (discharge process) or S (charge process). Besides, gold nanodots and N-doped carbon can increase the conductivity of the S cathode and provide strong polar–polar adsorption of sodium polysulfides tomore »« less
Cited by 107
https://doi.org/10.1039/c9ee03251g

Full Text Available
Liquid-Metal Electrode to Enable Ultra-Low Temperature Sodium-Beta Alumina Batteries for Renewable Energy Storage

Journal Article Lu, Xiaochuan ; Li, Guosheng ; Kim, Jin Yong ; ... - Nature Communications, 5:Article No. 4578

Metal electrodes have a high capacity for energy storage but have found limited applications in batteries because of dendrite formation and other problems. In this paper, we report a new alloying strategy that can significantly reduce the melting temperature and improve wetting with the electrolyte to allow the use of liquid metal as anode in sodium-beta alumina batteries (NBBs) at much lower temperatures (e.g., 95 to 175°C). Commercial NBBs such as sodium-sulfur (Na-S) battery and sodium-metal halide (ZEBRA) batteries typically operate at relatively high temperatures (e.g., 300-350°C) due to poor wettability of sodium on the surface of β"-Al2O3. Our combinedmore »« less
https://doi.org/10.1038/ncomms5578
Room Temperature to 150 °C Lithium Metal Batteries Enabled by a Rigid Molecular Ionic Composite Electrolyte

Journal Article Yu, Deyang ; Pan, Xiaona ; Bostwick, Joshua E. ; ... - Advanced Energy Materials

Abstract Molecular ionic composites (MICs), made from ionic liquids and a rigid‐rod polymer poly(2,2′‐disulfonyl‐4,4′‐benzidine terephthalamide) (PBDT), are a new type of rigid gel electrolyte that combine fast ion transport with high thermal stability and mechanical strength. In this work, a MIC electrolyte membrane is prepared that is composed of PBDT, lithium bis(trifluoromethylsulfonyl)imide (LiTFSI), and 1‐butyl‐1‐methylpyrrolidinium bis(trifluoromethylsulfonyl)imide (Pyr ₁₄ TFSI) in a mass ratio of 10:10:80. The ionic conductivity at 25 ° C is 0.56 mS cm ⁻¹ with no added flammable/volatile components. Although the polymer content is only 10 wt%, this MIC membrane is rigid with a tensile modulus of 410 MPa atmore »« less
https://doi.org/10.1002/aenm.202003559

Full Text Available
Room Temperature to 150 ° C Lithium Metal Batteries Enabled by a Rigid Molecular Ionic Composite Electrolyte

Journal Article Yu, Deyang ; Pan, Xiaona ; Bostwick, Joshua E. ; ... - Advanced Energy Materials

Not provided.
https://doi.org/10.1002/aenm.202003559

Similar Records