Multi-layered chalcogenides with potential for magnetism and superconductivity

Li, Li; Parker, David S.; dela Cruz, Clarina R.; Sefat, Athena Safa

doi:10.1016/j.physc.2016.10.005

Title: Multi-layered chalcogenides with potential for magnetism and superconductivity

Abstract

Layered thallium copper chalcogenides can form single, double, or triple layers of Cu–Ch separated by Tl sheets. Here we report on the preparation and properties of Tl-based materials of TlCu₂Se₂, TlCu₄S₃, TlCu₄Se₃ and TlCu₆S₄. Having no long-range magnetism for these materials is quite surprising considering the possibilities of inter- and intra-layer exchange interactions through Cu 3d, and we measure by magnetic susceptibility and confirm by neutron diffraction. First principles density-functional theory calculations for both the single-layer TlCu₂Se₂ (isostructural to the ‘122’ iron-based superconductors) and the double-layer TlCu₄Se₃ suggest a lack of Fermi-level spectral weight that is needed to drive a magnetic or superconducting instability. Furthermore, for multiple structural layers with Fe, there is much greater likelihood for magnetism and superconductivity.

Authors:

^[1]; Parker, David S. ^[1]; dela Cruz, Clarina R. ^[1]; Sefat, Athena Safa ^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Publication Date:: Mon Oct 24 00:00:00 EDT 2016

Research Org.:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). High Flux Isotope Reactor (HFIR)

Sponsoring Org.:: USDOE Office of Science (SC)

OSTI Identifier:: 1339407

Alternate Identifier(s):: OSTI ID: 1397009

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Accepted Manuscript

Journal Name:: Physica. C, Superconductivity

Additional Journal Information:: Journal Volume: 531; Journal Issue: C; Journal ID: ISSN 0921-4534

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; thallium copper chalcogenides; superconductivity and magnetism; 2D crystal structures

Citation Formats


                    Li, Li, Parker, David S., dela Cruz, Clarina R., and Sefat, Athena Safa. Multi-layered chalcogenides with potential for magnetism and superconductivity.  United States: N. p., 2016. 
Web.  doi:10.1016/j.physc.2016.10.005.

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                    Li, Li, Parker, David S., dela Cruz, Clarina R., & Sefat, Athena Safa. Multi-layered chalcogenides with potential for magnetism and superconductivity.  United States.  https://doi.org/10.1016/j.physc.2016.10.005

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                    Li, Li, Parker, David S., dela Cruz, Clarina R., and Sefat, Athena Safa. Mon .  
"Multi-layered chalcogenides with potential for magnetism and superconductivity".  United States.  https://doi.org/10.1016/j.physc.2016.10.005.  https://www.osti.gov/servlets/purl/1339407.

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@article{osti_1339407,

  title        = {Multi-layered chalcogenides with potential for magnetism and superconductivity},

  author       = {Li, Li and Parker, David S. and dela Cruz, Clarina R. and Sefat, Athena Safa},

  abstractNote = {Layered thallium copper chalcogenides can form single, double, or triple layers of Cu–Ch separated by Tl sheets. Here we report on the preparation and properties of Tl-based materials of TlCu2Se2, TlCu4S3, TlCu4Se3 and TlCu6S4. Having no long-range magnetism for these materials is quite surprising considering the possibilities of inter- and intra-layer exchange interactions through Cu 3d, and we measure by magnetic susceptibility and confirm by neutron diffraction. First principles density-functional theory calculations for both the single-layer TlCu2Se2 (isostructural to the ‘122’ iron-based superconductors) and the double-layer TlCu4Se3 suggest a lack of Fermi-level spectral weight that is needed to drive a magnetic or superconducting instability. Furthermore, for multiple structural layers with Fe, there is much greater likelihood for magnetism and superconductivity.},

  doi          = {10.1016/j.physc.2016.10.005},

  journal      = {Physica. C, Superconductivity},

  number       = C,

  volume       = 531,

  place        = {United States},

  year         = {Mon Oct 24 00:00:00 EDT 2016},

  month        = {Mon Oct 24 00:00:00 EDT 2016}

}

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https://doi.org/10.1016/j.physc.2016.10.005

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Works referenced in this record:

Chemistry and electronic structure of iron-based superconductors
journal, August 2011

Sefat, Athena S.; Singh, David J.
MRS Bulletin, Vol. 36, Issue 8
DOI: 10.1557/mrs.2011.175

Charge and spin in low-dimensional cuprates
journal, February 2001

Maekawa, Sadamichi; Tohyama, Takami
Reports on Progress in Physics, Vol. 64, Issue 3
DOI: 10.1088/0034-4885/64/3/202

Superconductivity gets an iron boost
journal, March 2010

Mazin, Igor I.
Nature, Vol. 464, Issue 7286
DOI: 10.1038/nature08914

Bulk synthesis of iron-based superconductors
journal, April 2013

Sefat, Athena S.
Current Opinion in Solid State and Materials Science, Vol. 17, Issue 2
DOI: 10.1016/j.cossms.2013.04.001

Synthesis of cuprate superconductors
journal, January 1993

Rao, C. N. R.; Nagarajan, R.; Vijayaraghaven, R.
Superconductor Science and Technology, Vol. 6, Issue 1
DOI: 10.1088/0953-2048/6/1/001

Crystal structure of Tl0.5Pb0.5Sr2Ca2Cu3O9 at 300 K and around Tc (118 K)
journal, October 1996

Marcos, M. D.; Attfield, J. P.
Physica C: Superconductivity, Vol. 270, Issue 3-4
DOI: 10.1016/S0921-4534(96)00518-7

Chemistry and structure of Hg-based superconducting Cu mixed oxides
journal, May 2002

Antipov, E. V.; Abakumov, A. M.; Putilin, S. N.
Superconductor Science and Technology, Vol. 15, Issue 7
DOI: 10.1088/0953-2048/15/7/201

Superconductivity at 22 K in Co-Doped ${BaFe}_{2} {As}_{2}$ Crystals
journal, September 2008

Sefat, Athena S.; Jin, Rongying; McGuire, Michael A.
Physical Review Letters, Vol. 101, Issue 11
DOI: 10.1103/PhysRevLett.101.117004

Variation of physical properties in the nominal Sr4V2O6Fe2As2
journal, March 2011

Sefat, Athena S.; Singh, David J.; Ovidiu Garlea, V.
Physica C: Superconductivity, Vol. 471, Issue 5-6
DOI: 10.1016/j.physc.2011.01.004

Structure and property correlations in FeS
journal, March 2017

Kuhn, S. J.; Kidder, M. K.; Parker, D. S.
Physica C: Superconductivity and its Applications, Vol. 534
DOI: 10.1016/j.physc.2016.12.006

Physical and chemical tuning of two-dimensional transition metal dichalcogenides
journal, January 2015

Wang, Haotian; Yuan, Hongtao; Sae Hong, Seung
Chemical Society Reviews, Vol. 44, Issue 9
DOI: 10.1039/C4CS00287C

Charge Density Wave, Superconductivity, and Anomalous Metallic Behavior in 2D Transition Metal Dichalcogenides
journal, May 2001

Castro Neto, A. H.
Physical Review Letters, Vol. 86, Issue 19
DOI: 10.1103/PhysRevLett.86.4382

Superconductivity in CuxTiSe2
journal, July 2006

Morosan, E.; Zandbergen, H. W.; Dennis, B. S.
Nature Physics, Vol. 2, Issue 8
DOI: 10.1038/nphys360

Charge-Orbital Density Wave and Superconductivity in the Strong Spin-Orbit Coupled ${IrTe}_{2} ∶ Pd$
journal, March 2012

Yang, J. J.; Choi, Y. J.; Oh, Y. S.
Physical Review Letters, Vol. 108, Issue 11
DOI: 10.1103/PhysRevLett.108.116402

Superconductivity in ${Cu}_{x} {Bi}_{2} {Se}_{3}$ and its Implications for Pairing in the Undoped Topological Insulator
journal, February 2010

Hor, Y. S.; Williams, A. J.; Checkelsky, J. G.
Physical Review Letters, Vol. 104, Issue 5
DOI: 10.1103/PhysRevLett.104.057001

Superconductivity with Topological Surface State in Sr _x Bi ₂ Se ₃
journal, August 2015

Liu, Zhongheng; Yao, Xiong; Shao, Jifeng
Journal of the American Chemical Society, Vol. 137, Issue 33
DOI: 10.1021/jacs.5b06815

BiS $_{2}$ -based layered superconductor Bi $_{4}$ O $_{4}$ S $_{3}$
journal, December 2012

Mizuguchi, Yoshikazu; Fujihisa, Hiroshi; Gotoh, Yoshito
Physical Review B, Vol. 86, Issue 22
DOI: 10.1103/PhysRevB.86.220510

Review of Fe Chalcogenides as the Simplest Fe-Based Superconductor
journal, October 2010

Mizuguchi, Yoshikazu; Takano, Yoshihiko
Journal of the Physical Society of Japan, Vol. 79, Issue 10
DOI: 10.1143/JPSJ.79.102001

Observation of Superconductivity in Tetragonal FeS
journal, August 2015

Lai, Xiaofang; Zhang, Hui; Wang, Yingqi
Journal of the American Chemical Society, Vol. 137, Issue 32
DOI: 10.1021/jacs.5b06687

Superconductivity in the iron selenide $K_{x} {Fe}_{2} {Se}_{2}$ $(0 \leq x \leq 1.0)$
journal, November 2010

Guo, Jiangang; Jin, Shifeng; Wang, Gang
Physical Review B, Vol. 82, Issue 18
DOI: 10.1103/PhysRevB.82.180520

Enhancement of the superconducting transition temperature of FeSe by intercalation of a molecular spacer layer
journal, October 2012

Burrard-Lucas, Matthew; Free, David G.; Sedlmaier, Stefan J.
Nature Materials, Vol. 12, Issue 1
DOI: 10.1038/nmat3464

Phase transitions in copper chalcogenides: I. The copper-selenium system
journal, January 1971

Stevels, A. L. N.; Jellinek, F.
Recueil des Travaux Chimiques des Pays-Bas, Vol. 90, Issue 3
DOI: 10.1002/recl.19710900307

Magnetoelectric and multiferroic properties of ternary copper chalcogenides Cu ₂ M ^II M ^IV S ₄
journal, March 2009

Nénert, G.; Palstra, T. T. M.
Journal of Physics: Condensed Matter, Vol. 21, Issue 17
DOI: 10.1088/0953-8984/21/17/176002

Electrical, Magnetic, and Superconducting Properties of Copper Disulfide
journal, September 1967

Munson, Ronald A.; DeSorbo, Warren; Kouvel, J. S.
The Journal of Chemical Physics, Vol. 47, Issue 5
DOI: 10.1063/1.1712162

Superconductivity in the spinels CuRh2S4 and CuRh2Se4
journal, December 1967

Robbins, M.; Willens, R. H.; Miller, R. C.
Solid State Communications, Vol. 5, Issue 12
DOI: 10.1016/0038-1098(67)90469-3

Synthesis and characterization of the layered metal TlCu2S2
journal, February 1989

Berger, R.
Journal of the Less Common Metals, Vol. 147, Issue 1
DOI: 10.1016/0022-5088(89)90157-4

TlCu2Se2: A p-type metal with a layer structure
journal, May 1984

Berger, R.; Van Bruggen, C. F.
Journal of the Less Common Metals, Vol. 99, Issue 1
DOI: 10.1016/0022-5088(84)90340-0

Neue Verbindungen mit KCu4S3-Struktur
journal, January 1980

Klepp, Kurt; Boller, Herbert; V�llenkle, Horst
Monatshefte f�r Chemie, Vol. 111, Issue 3
DOI: 10.1007/BF00903326

The crystal structure of room-temperature synthesised orthorhombic TlCu4Se3 from direct methods on X-ray powder data
journal, July 1995

Berger, R.; Tergenius, L. -E.; Norén, L.
Journal of Alloys and Compounds, Vol. 224, Issue 2
DOI: 10.1016/0925-8388(95)01655-4

Crookesite and sabatierite in a new light – A crystallographer's comment
journal, January 1987

Berger, Rolf A.
Zeitschrift für Kristallographie, Vol. 181, Issue 1-4
DOI: 10.1524/zkri.1987.181.1-4.241

Quantitative phase analysis from neutron powder diffraction data using the Rietveld method
journal, December 1987

Hill, R. J.; Howard, C. J.
Journal of Applied Crystallography, Vol. 20, Issue 6
DOI: 10.1107/S0021889887086199

Generalized Gradient Approximation Made Simple
journal, October 1996

Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
DOI: 10.1103/PhysRevLett.77.3865

BaT2As2 single crystals (T=Fe, Co, Ni) and superconductivity upon Co-doping
journal, May 2009

Sefat, Athena S.; Singh, David J.; Jin, Rongying
Physica C: Superconductivity, Vol. 469, Issue 9-12
DOI: 10.1016/j.physc.2009.03.025

Structure and anisotropic properties of ${BaFe}_{2 - x} {Ni}_{x} {As}_{2}$ ( $x = 0$ , 1, and 2) single crystals
journal, March 2009

Sefat, Athena S.; McGuire, Michael A.; Jin, Rongying
Physical Review B, Vol. 79, Issue 9
DOI: 10.1103/PhysRevB.79.094508

Metallicity of Ca2Cu6P5 with single and double copper-pnictide layers
journal, June 2016

Li, Li; Parker, David; Chi, Miaofang
Journal of Alloys and Compounds, Vol. 671
DOI: 10.1016/j.jallcom.2016.02.084

Empirical electron-phonon $λ$ values from resistivity of cubic metallic elements
journal, August 1987

Allen, Philip B.
Physical Review B, Vol. 36, Issue 5
DOI: 10.1103/PhysRevB.36.2920

Uniform susceptibilities of metallic elements
journal, July 1977

Janak, J. F.
Physical Review B, Vol. 16, Issue 1
DOI: 10.1103/PhysRevB.16.255

Transport and Magnetic Properties of K0.8Fe2−x Cu x Se2(0 ⩽ x ⩽ 2) System
journal, October 2014

He, Junbao; Fu, Yu; Leng, Yumin
Journal of Superconductivity and Novel Magnetism, Vol. 28, Issue 1
DOI: 10.1007/s10948-014-2843-2

Anion p-band hole generation and annihilation in layered potassium trithiotetracuprate, KCu ₄ S ₃
journal, January 1992

Viola, Frank; Schöllhorn, Robert
J. Chem. Soc., Chem. Commun., Issue 12
DOI: 10.1039/C39920000907

Electron transport and magnetic properties of some mixed-valent alkalithiocuprates
journal, May 1983

Ghosh, Bijoy Prosad; Chaudhury, Muktimoy; Nag, K.
Journal of Solid State Chemistry, Vol. 47, Issue 3
DOI: 10.1016/0022-4596(83)90023-3

Bulk Synthesis of Iron-based Superconductors
text, January 2013

Sefat, Athena S.
arXiv
DOI: 10.48550/arxiv.1304.7708

Works referencing / citing this record:

K ₂ ZnSn ₃ Se ₈ : A Non-Centrosymmetric Zinc Selenidostannate(IV) Featuring Interesting Covalently Bonded [ZnSn ₃ Se ₈ ] ²⁻ Layer and Exhibiting Intriguing Second Harmonic Generation Activity
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Chemistry - An Asian Journal, Vol. 12, Issue 12
DOI: 10.1002/asia.201700426

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Title: Multi-layered chalcogenides with potential for magnetism and superconductivity

Abstract

Citation Formats

Chemistry and electronic structure of iron-based superconductors journal, August 2011

Charge and spin in low-dimensional cuprates journal, February 2001

Superconductivity gets an iron boost journal, March 2010

Bulk synthesis of iron-based superconductors journal, April 2013

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Crystal structure of Tl0.5Pb0.5Sr2Ca2Cu3O9 at 300 K and around Tc (118 K) journal, October 1996

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Superconductivity at 22 K in Co-Doped BaFe 2 As 2 Crystals journal, September 2008

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Physical and chemical tuning of two-dimensional transition metal dichalcogenides journal, January 2015

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Superconductivity in CuxTiSe2 journal, July 2006

Charge-Orbital Density Wave and Superconductivity in the Strong Spin-Orbit Coupled IrTe 2 ∶ Pd journal, March 2012

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Crookesite and sabatierite in a new light – A crystallographer's comment journal, January 1987

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Generalized Gradient Approximation Made Simple journal, October 1996

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Structure and anisotropic properties of ${BaFe}_{2 - x} {Ni}_{x} {As}_{2}$ ( $x = 0$ , 1, and 2) single crystals
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Metallicity of Ca2Cu6P5 with single and double copper-pnictide layers
journal, June 2016

Empirical electron-phonon $λ$ values from resistivity of cubic metallic elements
journal, August 1987

Uniform susceptibilities of metallic elements
journal, July 1977

Transport and Magnetic Properties of K0.8Fe2−x Cu x Se2(0 ⩽ x ⩽ 2) System
journal, October 2014

Anion p-band hole generation and annihilation in layered potassium trithiotetracuprate, KCu ₄ S ₃
journal, January 1992

Electron transport and magnetic properties of some mixed-valent alkalithiocuprates
journal, May 1983

Bulk Synthesis of Iron-based Superconductors
text, January 2013

K ₂ ZnSn ₃ Se ₈ : A Non-Centrosymmetric Zinc Selenidostannate(IV) Featuring Interesting Covalently Bonded [ZnSn ₃ Se ₈ ] ²⁻ Layer and Exhibiting Intriguing Second Harmonic Generation Activity
journal, May 2017