Amorphous boron nanorod as an anode material for lithium-ion batteries at room temperature

Deng, Changjian; Lau, Miu Lun; Barkholtz, Heather M.; Xu, Haiping; Parrish, Riley; Xu, Meiyue (Olivia); Xu, Tao; Liu, Yuzi; Wang, Hao; Connell, Justin G.; Smith, Kassiopeia A.; Xiong, Hui

doi:10.1039/c7nr03017g

Title: Amorphous boron nanorod as an anode material for lithium-ion batteries at room temperature

Journal Article · Thu Jun 22 00:00:00 UTC 2017 · Nanoscale

DOI: https://doi.org/10.1039/c7nr03017g · OSTI ID:1395544

Deng, Changjian ^[1]; Lau, Miu Lun ^[1]; Barkholtz, Heather M. ^[2]; Xu, Haiping ^[2]; Parrish, Riley ^[1]; Xu, Meiyue (Olivia) ^[2]; Xu, Tao ^[2]; Liu, Yuzi ^[3]; Wang, Hao ^[4]; Connell, Justin G. ^[5]; Smith, Kassiopeia A. ^[1];

^[1]

Boise State Univ., ID (United States). Micron School of Materials Science and Engineering
Northern Illinois Univ., DeKalb, IL (United States). Dept. of Chemistry and Biochemistry
Argonne National Lab. (ANL), Argonne, IL (United States). Center for Nanoscale Materials
Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Science and Engineering
Argonne National Lab. (ANL), Argonne, IL (United States). Joint Center for Energy Storage Research

We report an amorphous boron nanorod anode material for lithium-ion batteries prepared through smelting non-toxic boron oxide in liquid lithium.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1395544

Journal Information:: Nanoscale, Journal Name: Nanoscale Journal Issue: 30 Vol. 9; ISSN NANOHL; ISSN 2040-3364

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

References (30)

Dilithium Hexaboride, Li2B6 Mair, Gunther; von Schnering, Hans Georg; Wörle, Michael Zeitschrift für anorganische und allgemeine Chemie, Vol. 625, Issue 7 https://doi.org/10.1002/(SICI)1521-3749(199907)625:7<1207::AID-ZAAC1207>3.0.CO;2-9	journal	July 1999
The Structure Chemistry of Boron-Rich Solids of the Alkali Metals Albert, Barbara European Journal of Inorganic Chemistry, Vol. 2000, Issue 8 https://doi.org/10.1002/1099-0682(200008)2000:8<1679::AID-EJIC1679>3.0.CO;2-K	journal	August 2000
Infinite, Linear, Unbranched Borynide Chains in LiBx—Isoelectronic to Polyyne and Polycumulene Wörle, Michael; Nesper, Reinhard Angewandte Chemie International Edition, Vol. 39, Issue 13 https://doi.org/10.1002/1521-3773(20000703)39:13<2349::AID-ANIE2349>3.0.CO;2-U	journal	July 2000
Structure and Bulk Modulus of High-Strength Boron Compounds Lundström, Torsten Journal of Solid State Chemistry, Vol. 133, Issue 1 https://doi.org/10.1006/jssc.1997.7320	journal	October 1997
Comparison of anodic dischargability of Li-B alloy with pure lithium in LiClO4-propylene carbonate James, S. D. Journal of Applied Electrochemistry, Vol. 12, Issue 3 https://doi.org/10.1007/BF00615097	journal	May 1982
Electrochemical studies of lithium-boron alloys in non-aqueous media — comparison with pure lithium Sanchez, P.; Belin, C.; Crepy, C. Journal of Applied Electrochemistry, Vol. 19, Issue 3 https://doi.org/10.1007/BF01015246	journal	May 1989
Investigations of a number of alternative negative electrode materials for use in lithium cells Netz, A.; Huggins, R. A.; Weppner, W. Ionics, Vol. 7, Issue 4-6 https://doi.org/10.1007/BF02373580	journal	July 2001
Preparation and characterization of lithium-boron alloys: electrochemical studies as anodes in molten salt media, and comparison with pure lithium-involving systems Sanchez, P.; Belin, C.; Crepy, G. Journal of Materials Science, Vol. 27, Issue 1 https://doi.org/10.1007/BF02403669	journal	January 1992
An unusual phenomenon in the formation of Li5B4 compound-alloy Wang, Frederick E. Metallurgical Transactions A, Vol. 10, Issue 3 https://doi.org/10.1007/BF02658343	journal	March 1979
A neutron diffraction study of amorphous boron using a pulsed source Delaplane, R. G.; Dahlborg, U.; Howells, W. S. Journal of Non-Crystalline Solids, Vol. 106, Issue 1-3 https://doi.org/10.1016/0022-3093(88)90229-3	journal	December 1988
A neutron diffraction study of amorphous boron Delaplane, R. G.; Dahlborg, U.; Granéli, B. Journal of Non-Crystalline Solids, Vol. 104, Issue 2-3 https://doi.org/10.1016/0022-3093(88)90395-X	journal	September 1988
The molecular and electronic structure of Li5B4 Letelier, Jorge R.; Ying-Nan, Chiu; Wang, Frederick E. Journal of the Less Common Metals, Vol. 67, Issue 1 https://doi.org/10.1016/0022-5088(79)90090-0	journal	September 1979
The role and utilization of pseudocapacitance for energy storage by supercapacitors Conway, B. E.; Birss, V.; Wojtowicz, J. Journal of Power Sources, Vol. 66, Issue 1-2 https://doi.org/10.1016/S0378-7753(96)02474-3	journal	May 1997
The dimensionality of Sn anodes in Li-ion batteries Wang, Bin; Luo, Bin; Li, Xianglong Materials Today, Vol. 15, Issue 12 https://doi.org/10.1016/S1369-7021(13)70012-9	journal	December 2012
Electrochemical studies of LiB compound as anode material for lithium-ion battery Zhou, Debi; Liu, Zhijian; Lv, Xinkun Electrochimica Acta, Vol. 51, Issue 26 https://doi.org/10.1016/j.electacta.2006.03.023	journal	August 2006
Temperature-dependent lithium storage behavior in tetragonal boron (B50) thin film anode for Li-ion batteries Ding, Xingle; Lu, Xia; Fu, Zhengwen Electrochimica Acta, Vol. 87 https://doi.org/10.1016/j.electacta.2012.09.017	journal	January 2013
One-pot synthesis of heterogeneous Co3O4-nanocube/Co(OH)2-nanosheet hybrids for high-performance flexible asymmetric all-solid-state supercapacitors Pang, Huan; Li, Xinran; Zhao, Qunxing Nano Energy, Vol. 35 https://doi.org/10.1016/j.nanoen.2017.02.044	journal	May 2017
Alloy Negative Electrodes for Li-Ion Batteries Obrovac, M. N.; Chevrier, V. L. Chemical Reviews, Vol. 114, Issue 23 https://doi.org/10.1021/cr500207g	journal	October 2014
Pseudocapacitive Contributions to Electrochemical Energy Storage in TiO₂ (Anatase) Nanoparticles Wang, John; Polleux, Julien; Lim, James The Journal of Physical Chemistry C, Vol. 111, Issue 40, p. 14925-14931 https://doi.org/10.1021/jp074464w	journal	October 2007
Li ⁺ Ion Insertion in TiO ₂ (Anatase). 2. Voltammetry on Nanoporous Films Lindström, Henrik; Södergren, Sven; Solbrand, Anita The Journal of Physical Chemistry B, Vol. 101, Issue 39 https://doi.org/10.1021/jp970490q	journal	September 1997
Controlled vesicle deformation and lysis by single oscillating bubbles Marmottant, Philippe; Hilgenfeldt, Sascha Nature, Vol. 423, Issue 6936 https://doi.org/10.1038/nature01613	journal	May 2003
Ionic high-pressure form of elemental boron Oganov, Artem R.; Chen, Jiuhua; Gatti, Carlo Nature, Vol. 457, Issue 7231 https://doi.org/10.1038/nature07736	journal	January 2009
Neutron- and x-ray-diffraction measurements of the bulk modulus of boron Nelmes, R. J.; Loveday, J. S.; Allan, D. R. Physical Review B, Vol. 47, Issue 13 https://doi.org/10.1103/PhysRevB.47.7668	journal	April 1993
Superhard Semiconducting Optically Transparent High Pressure Phase of Boron Zarechnaya, E. Yu.; Dubrovinsky, L.; Dubrovinskaia, N. Physical Review Letters, Vol. 102, Issue 18 https://doi.org/10.1103/PhysRevLett.102.185501	journal	May 2009
Chemical Composition and Morphology of the Elevated Temperature SEI on Graphite Andersson, A. M.; Edström, K. Journal of The Electrochemical Society, Vol. 148, Issue 10 https://doi.org/10.1149/1.1397771	journal	January 2001
The Electrochemical Reaction of Li with Amorphous Si-Sn Alloys Beaulieu, L. Y.; Hewitt, K. C.; Turner, R. L. Journal of The Electrochemical Society, Vol. 150, Issue 2 https://doi.org/10.1149/1.1530151	journal	January 2003
An Advanced Tool for the Selection of Electrolyte Components for Rechargeable Lithium Batteries Peled, E. Journal of The Electrochemical Society, Vol. 145, Issue 10 https://doi.org/10.1149/1.1838831	journal	January 1998
Thermal Analysis of Lithium-Boron Alloys Dallek, S. Journal of The Electrochemical Society, Vol. 126, Issue 5 https://doi.org/10.1149/1.2129157	journal	January 1979
A Comparison of the Reactions of the SiSn, SiAg, and SiZn Binary Systems with L3i Hatchard, T. D.; Obrovac, M. N.; Dahn, J. R. Journal of The Electrochemical Society, Vol. 153, Issue 2 https://doi.org/10.1149/1.2140607	journal	January 2006
The B-Li (Boron-Lithium) system Borgstedt, H. B.; Guminski, C. Journal of Phase Equilibria, Vol. 24, Issue 6 https://doi.org/10.1361/105497103772084723	journal	December 2003

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MoS _0.5 Se _1.5 Embedded in 2D Porous Carbon Sheets Boost Lithium Storage Performance as an Anode Material Li, Tongfei; Wang, Ao; Li, Xin Advanced Materials Interfaces, Vol. 5, Issue 7 https://doi.org/10.1002/admi.201701604	journal	January 2018
In Situ Synthesis of Mn ₃ O ₄ Nanoparticles on Hollow Carbon Nanofiber as High-Performance Lithium-Ion Battery Anode Zhang, Dan; Li, Guangshe; Fan, Jianming Chemistry - A European Journal, Vol. 24, Issue 38 https://doi.org/10.1002/chem.201801196	journal	June 2018

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