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Title: Fabrication of phosphonic acid films on nitinol nanoparticles by dynamic covalent assembly

Nitinol (NiTi) nanoparticles are a valuable metal alloy due to many unique properties that allow for medical applications. NiTi nanoparticles have the potential to form nanofluids, which can advance the thermal conductivity of fluids by controlling the surface functionalization through chemical attachment of organic acids to the surface to form self-assembled alkylphosphonate films. In this study, phosphonic functional head groups such as 16-phosphonohexadecanoic acid, octadecylphosphonic acid, and 12-aminododecylphosphonic acid were used to form an ordered and strongly chemically bounded film on the NiTi nanopowder. The surface of the NiTi nanoparticles was modified in order to tailor the chemical and physical properties to the desired application. The modified NiTi nanoparticles were characterized using infrared spectroscopy, powder X-ray diffraction, X-ray photoelectron spectroscopy, and 31P solid-state nuclear magnetic resonance. The interfacial bonding was identified by spectroscopic data suggesting the phosphonic head group adsorbs in a mixed bidentate/monodentate binding motif on the NiTi nanoparticles. Dynamic light scattering and scanning electron microscopy-energy dispersive X-ray spectroscopy revealed the particle sizes. Differential scanning calorimetry was used to examine the phase transitions. Zeta potential determination as a function of pH was examined to investigate the surface properties of charged nanoparticles. In conclusion, the influence of environmental stability ofmore » the surface modifications was also assessed.« less
Authors:
 [1] ;  [1] ;  [1] ;  [2] ;  [3] ; ORCiD logo [4] ;  [4]
  1. Marshall Univ., Huntington, WV (United States)
  2. Pennsylvania State Univ., University Park, PA (United States)
  3. Pennsylvania State Univ., University Park, PA (United States); Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
  4. West Virginia Univ., Morgantown, WV (United States)
Publication Date:
Grant/Contract Number:
AC05-76RL01830; NNX15AI01H; CHE 1411687
Type:
Accepted Manuscript
Journal Name:
Thin Solid Films
Additional Journal Information:
Journal Volume: 642; Journal ID: ISSN 0040-6090
Publisher:
Elsevier
Research Org:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Org:
USDOE
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; Self-assembly films; Nitinol; Phosphonic acid; Nanoparticles; Zeta potential; Solid-state nuclear magnetic resonance
OSTI Identifier:
1395355

Quinones, Rosalynn, Garretson, Samantha, Behnke, Grayce, Fagan, Jonathan W., Mueller, Karl T., Agarwal, Sushant, and Gupta, Rakesh K.. Fabrication of phosphonic acid films on nitinol nanoparticles by dynamic covalent assembly. United States: N. p., Web. doi:10.1016/J.TSF.2017.09.048.
Quinones, Rosalynn, Garretson, Samantha, Behnke, Grayce, Fagan, Jonathan W., Mueller, Karl T., Agarwal, Sushant, & Gupta, Rakesh K.. Fabrication of phosphonic acid films on nitinol nanoparticles by dynamic covalent assembly. United States. doi:10.1016/J.TSF.2017.09.048.
Quinones, Rosalynn, Garretson, Samantha, Behnke, Grayce, Fagan, Jonathan W., Mueller, Karl T., Agarwal, Sushant, and Gupta, Rakesh K.. 2017. "Fabrication of phosphonic acid films on nitinol nanoparticles by dynamic covalent assembly". United States. doi:10.1016/J.TSF.2017.09.048. https://www.osti.gov/servlets/purl/1395355.
@article{osti_1395355,
title = {Fabrication of phosphonic acid films on nitinol nanoparticles by dynamic covalent assembly},
author = {Quinones, Rosalynn and Garretson, Samantha and Behnke, Grayce and Fagan, Jonathan W. and Mueller, Karl T. and Agarwal, Sushant and Gupta, Rakesh K.},
abstractNote = {Nitinol (NiTi) nanoparticles are a valuable metal alloy due to many unique properties that allow for medical applications. NiTi nanoparticles have the potential to form nanofluids, which can advance the thermal conductivity of fluids by controlling the surface functionalization through chemical attachment of organic acids to the surface to form self-assembled alkylphosphonate films. In this study, phosphonic functional head groups such as 16-phosphonohexadecanoic acid, octadecylphosphonic acid, and 12-aminododecylphosphonic acid were used to form an ordered and strongly chemically bounded film on the NiTi nanopowder. The surface of the NiTi nanoparticles was modified in order to tailor the chemical and physical properties to the desired application. The modified NiTi nanoparticles were characterized using infrared spectroscopy, powder X-ray diffraction, X-ray photoelectron spectroscopy, and 31P solid-state nuclear magnetic resonance. The interfacial bonding was identified by spectroscopic data suggesting the phosphonic head group adsorbs in a mixed bidentate/monodentate binding motif on the NiTi nanoparticles. Dynamic light scattering and scanning electron microscopy-energy dispersive X-ray spectroscopy revealed the particle sizes. Differential scanning calorimetry was used to examine the phase transitions. Zeta potential determination as a function of pH was examined to investigate the surface properties of charged nanoparticles. In conclusion, the influence of environmental stability of the surface modifications was also assessed.},
doi = {10.1016/J.TSF.2017.09.048},
journal = {Thin Solid Films},
number = ,
volume = 642,
place = {United States},
year = {2017},
month = {9}
}