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Title: 3D printing technologies for electrochemical energy storage

Abstract

We present that fabrication and assembly of electrodes and electrolytes play an important role in promoting the performance of electrochemical energy storage (EES) devices such as batteries and supercapacitors. Traditional fabrication techniques have limitations in controlling the geometry and architecture of the electrode and solid-state electrolytes, which would otherwise compromise the performance. 3D printing, a disruptive manufacturing technology, has emerged as an innovative approach to fabricating EES devices from nanoscale to macroscale, providing great opportunities to accurately control device geometry (e.g., dimension, porosity, and morphology) and structure with enhanced specific energy and power densities. Moreover, the “additive” manufacturing nature of 3D printing provides excellent controllability of the electrode thickness with much simplified process in a cost effective manner. Additionally, with the unique spatial and temporal material manipulation capability, 3D printing can integrate multiple nano-materials in the same print, and multi-functional EES devices (including functional gradient devices) can be fabricated. Herein, we review recent advances in 3D printing of EES devices. We focus on two major 3D printing technologies including direct writing and inkjet printing. The direct material deposition characteristics of these two processes enable them to print on a variety of flat substrates, even a conformal one, well suiting themmore » to applications such as wearable devices and on-chip integrations. Other potential 3D printing techniques such as freeze nano-printing, stereolithography, fused deposition modeling, binder jetting, laminated object manufacturing, and metal 3D printing are also introduced. The advantages and limitations of each 3D printing technology are extensively discussed. More importantly, we provide a perspective on how to integrate the emerging 3D printing with existing technologies to create structures over multiple length scale from nano to macro for EES applications.« less

Authors:
 [1];  [2];  [3];  [1];  [3];  [2];  [1]
  1. University at Buffalo, The State University of New York, Buffalo, NY (United States). Department of Industrial Engineering
  2. University at Buffalo, The State University of New York, Buffalo, NY (United States). Department of Chemical and Biological Engineering
  3. Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Publication Date:
Research Org.:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1395280
Alternate Identifier(s):
OSTI ID: 1549760
Report Number(s):
PNNL-SA-126437
Journal ID: ISSN 2211-2855; PII: S221128551730513X
Grant/Contract Number:  
AC05-76RL01830; AC05-76RLO1830
Resource Type:
Accepted Manuscript
Journal Name:
Nano Energy
Additional Journal Information:
Journal Volume: 40; Journal Issue: C; Journal ID: ISSN 2211-2855
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; 42 ENGINEERING; 36 MATERIALS SCIENCE; 3D printing; Electrochemical energy storage; Inkjet printing; Direct ink writing; Nano printing

Citation Formats

Zhang, Feng, Wei, Min, Viswanathan, Vilayanur V., Swart, Benjamin, Shao, Yuyan, Wu, Gang, and Zhou, Chi. 3D printing technologies for electrochemical energy storage. United States: N. p., 2017. Web. https://doi.org/10.1016/J.NANOEN.2017.08.037.
Zhang, Feng, Wei, Min, Viswanathan, Vilayanur V., Swart, Benjamin, Shao, Yuyan, Wu, Gang, & Zhou, Chi. 3D printing technologies for electrochemical energy storage. United States. https://doi.org/10.1016/J.NANOEN.2017.08.037
Zhang, Feng, Wei, Min, Viswanathan, Vilayanur V., Swart, Benjamin, Shao, Yuyan, Wu, Gang, and Zhou, Chi. Thu . "3D printing technologies for electrochemical energy storage". United States. https://doi.org/10.1016/J.NANOEN.2017.08.037. https://www.osti.gov/servlets/purl/1395280.
@article{osti_1395280,
title = {3D printing technologies for electrochemical energy storage},
author = {Zhang, Feng and Wei, Min and Viswanathan, Vilayanur V. and Swart, Benjamin and Shao, Yuyan and Wu, Gang and Zhou, Chi},
abstractNote = {We present that fabrication and assembly of electrodes and electrolytes play an important role in promoting the performance of electrochemical energy storage (EES) devices such as batteries and supercapacitors. Traditional fabrication techniques have limitations in controlling the geometry and architecture of the electrode and solid-state electrolytes, which would otherwise compromise the performance. 3D printing, a disruptive manufacturing technology, has emerged as an innovative approach to fabricating EES devices from nanoscale to macroscale, providing great opportunities to accurately control device geometry (e.g., dimension, porosity, and morphology) and structure with enhanced specific energy and power densities. Moreover, the “additive” manufacturing nature of 3D printing provides excellent controllability of the electrode thickness with much simplified process in a cost effective manner. Additionally, with the unique spatial and temporal material manipulation capability, 3D printing can integrate multiple nano-materials in the same print, and multi-functional EES devices (including functional gradient devices) can be fabricated. Herein, we review recent advances in 3D printing of EES devices. We focus on two major 3D printing technologies including direct writing and inkjet printing. The direct material deposition characteristics of these two processes enable them to print on a variety of flat substrates, even a conformal one, well suiting them to applications such as wearable devices and on-chip integrations. Other potential 3D printing techniques such as freeze nano-printing, stereolithography, fused deposition modeling, binder jetting, laminated object manufacturing, and metal 3D printing are also introduced. The advantages and limitations of each 3D printing technology are extensively discussed. More importantly, we provide a perspective on how to integrate the emerging 3D printing with existing technologies to create structures over multiple length scale from nano to macro for EES applications.},
doi = {10.1016/J.NANOEN.2017.08.037},
journal = {Nano Energy},
number = C,
volume = 40,
place = {United States},
year = {2017},
month = {8}
}

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    • DOI: 10.1002/aenm.201901839

    Nanomaterials in Advanced, High-Performance Aerogel Composites: A Review
    journal, April 2019


    Microfluidics‐Based Biomaterials and Biodevices
    journal, October 2018


    3D printed electrochemical energy storage devices
    journal, January 2019

    • Chang, Peng; Mei, Hui; Zhou, Shixiang
    • Journal of Materials Chemistry A, Vol. 7, Issue 9
    • DOI: 10.1039/c8ta11860d

    A Study of Metal Free Supercapacitors Using 3D Printing
    journal, July 2018

    • Tanwilaisiri, Anan; Xu, Yanmeng; Harrison, David
    • International Journal of Precision Engineering and Manufacturing, Vol. 19, Issue 7
    • DOI: 10.1007/s12541-018-0127-7

    The Road Towards Planar Microbatteries and Micro‐Supercapacitors: From 2D to 3D Device Geometries
    journal, June 2019


    Ink-based 3D printing technologies for graphene-based materials: a review
    journal, January 2019

    • Wang, Jingfeng; Liu, Yuyan; Fan, Zhimin
    • Advanced Composites and Hybrid Materials, Vol. 2, Issue 1
    • DOI: 10.1007/s42114-018-0067-9

    Towards smart free form-factor 3D printable batteries
    journal, January 2018

    • Ragones, Heftsi; Menkin, Svetlana; Kamir, Yosi
    • Sustainable Energy & Fuels, Vol. 2, Issue 7
    • DOI: 10.1039/c8se00122g

    Scalable nanomanufacturing of inkjet-printed wearable energy storage devices
    journal, January 2019

    • Huang, Tao-Tse; Wu, Wenzhuo
    • Journal of Materials Chemistry A, Vol. 7, Issue 41
    • DOI: 10.1039/c9ta05239a

    Review—Electrolytic Metal Atoms Enabled Manufacturing of Nanostructured Sensor Electrodes
    journal, January 2020

    • Jiang, Junhua; Wang, Congjian
    • Journal of The Electrochemical Society, Vol. 167, Issue 3
    • DOI: 10.1149/2.0212003jes

    Architectured Leaf-Inspired Ni 0.33 Co 0.66 S 2 /Graphene Aerogels via 3D Printing for High-Performance Energy Storage
    journal, October 2018

    • Tang, Xingwei; Zhu, Chengling; Cheng, Dongdong
    • Advanced Functional Materials, Vol. 28, Issue 51
    • DOI: 10.1002/adfm.201805057

    Biotemplated Synthesis of Transition Metal Nitride Architectures for Flexible Printed Circuits and Wearable Energy Storages
    journal, October 2018

    • Yi, Yuyang; Yu, Lianghao; Tian, Zhengnan
    • Advanced Functional Materials, Vol. 28, Issue 50
    • DOI: 10.1002/adfm.201805510

    Inkjet Printing of Li‐Rich Cathode Material for Thin‐Film Lithium‐Ion Microbatteries
    journal, November 2019

    • Kolchanov, Denis S.; Mitrofanov, Ilya; Kim, Artem
    • Energy Technology, Vol. 8, Issue 3
    • DOI: 10.1002/ente.201901086

    Graphene-Based Inks for Printing of Planar Micro-Supercapacitors: A Review
    journal, March 2019

    • Sang Tran, Tuan; Dutta, Naba; Roy Choudhury, Namita
    • Materials, Vol. 12, Issue 6
    • DOI: 10.3390/ma12060978

    3D-Printed Graphene Oxide Framework with Thermal Shock Synthesized Nanoparticles for Li-CO 2 Batteries
    journal, October 2018

    • Qiao, Yun; Liu, Yang; Chen, Chaoji
    • Advanced Functional Materials, Vol. 28, Issue 51
    • DOI: 10.1002/adfm.201805899

    Three-Dimensional Printing of a LiFePO4/Graphite Battery Cell via Fused Deposition Modeling
    journal, December 2019