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Title: Cyanide Ligand Assembly by Carbon Atom Transfer to an Iron Nitride

The new iron(IV) nitride complex PhB( iPr 2Im) 3Fe≡N reacts with two equivalents of bis(diisopropylamino)cyclopropenylidene (BAC) to provide PhB( iPr 2Im) 3Fe(CN)(N 2)(BAC). This unusual example of a four-electron reaction involves carbon atom transfer from BAC to create a cyanide ligand along with the alkyne iPr 2N-C≡C-N iPr 2. The iron complex is in equilibrium with an N 2- free species. Further reaction with CO leads to formation of a CO analogue, which can be independently prepared using NaCN as the cyanide source, while reaction with B(C 6F 5) 3 provides the cyanoborane derivative.
Authors:
 [1] ;  [1] ;  [2] ;  [1] ;  [1] ;  [1] ; ORCiD logo [3] ; ORCiD logo [1]
  1. Indiana Univ., Bloomington, IN (United States). Dept. of Chemistry
  2. Indiana Univ., Bloomington, IN (United States). Dept. of Chemistry; Loyola Univ., Chicago, IL (United States)
  3. Univ. of New Mexico, Albuquerque, NM (United States). Dept. of Chemistry and Chemical Biology; Brandeis Univ., Waltham, MA (United States). Dept. of Chemistry
Publication Date:
Grant/Contract Number:
FG02-08ER15996; CHE-1566258; CHE-0443580
Type:
Accepted Manuscript
Journal Name:
Journal of the American Chemical Society
Additional Journal Information:
Journal Volume: 139; Journal Issue: 40; Journal ID: ISSN 0002-7863
Publisher:
American Chemical Society (ACS)
Research Org:
Indiana Univ., Bloomington, IN (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
OSTI Identifier:
1393565

Martinez, Jorge L., Lin, Hsiu-Jung, Lee, Wei-Tsung, Pink, Maren, Chen, Chun-Hsing, Gao, Xinfeng, Dickie, Diane A., and Smith, Jeremy M.. Cyanide Ligand Assembly by Carbon Atom Transfer to an Iron Nitride. United States: N. p., Web. doi:10.1021/jacs.7b08704.
Martinez, Jorge L., Lin, Hsiu-Jung, Lee, Wei-Tsung, Pink, Maren, Chen, Chun-Hsing, Gao, Xinfeng, Dickie, Diane A., & Smith, Jeremy M.. Cyanide Ligand Assembly by Carbon Atom Transfer to an Iron Nitride. United States. doi:10.1021/jacs.7b08704.
Martinez, Jorge L., Lin, Hsiu-Jung, Lee, Wei-Tsung, Pink, Maren, Chen, Chun-Hsing, Gao, Xinfeng, Dickie, Diane A., and Smith, Jeremy M.. 2017. "Cyanide Ligand Assembly by Carbon Atom Transfer to an Iron Nitride". United States. doi:10.1021/jacs.7b08704. https://www.osti.gov/servlets/purl/1393565.
@article{osti_1393565,
title = {Cyanide Ligand Assembly by Carbon Atom Transfer to an Iron Nitride},
author = {Martinez, Jorge L. and Lin, Hsiu-Jung and Lee, Wei-Tsung and Pink, Maren and Chen, Chun-Hsing and Gao, Xinfeng and Dickie, Diane A. and Smith, Jeremy M.},
abstractNote = {The new iron(IV) nitride complex PhB(iPr2Im)3Fe≡N reacts with two equivalents of bis(diisopropylamino)cyclopropenylidene (BAC) to provide PhB(iPr2Im)3Fe(CN)(N2)(BAC). This unusual example of a four-electron reaction involves carbon atom transfer from BAC to create a cyanide ligand along with the alkyne iPr2N-C≡C-NiPr2. The iron complex is in equilibrium with an N2- free species. Further reaction with CO leads to formation of a CO analogue, which can be independently prepared using NaCN as the cyanide source, while reaction with B(C6F5)3 provides the cyanoborane derivative.},
doi = {10.1021/jacs.7b08704},
journal = {Journal of the American Chemical Society},
number = 40,
volume = 139,
place = {United States},
year = {2017},
month = {9}
}