Electrochemistry and Spectroelectrochemistry of the Pu (III/IV) and (IV/VI) Couples in Nitric Acid Systems

Lines, Amanda M.; Adami, Susan R.; Casella, Amanda J.; Sinkov, Sergey I.; Lumetta, Gregg J.; Bryan, Samual A.

doi:10.1002/elan.201700465

Title: Electrochemistry and Spectroelectrochemistry of the Pu (III/IV) and (IV/VI) Couples in Nitric Acid Systems

Authors:

Lines, Amanda M. ^[1]; Adami, Susan R. ^[1]; Casella, Amanda J. ^[1]; Sinkov, Sergey I. ^[1]; Lumetta, Gregg J. ^[1]; Bryan, Samual A. ^[1]

Nuclear Chemistry and Engineering, Pacific Northwest National Laboratory, Richland WA 99352

Publication Date:: Wed Sep 20 00:00:00 EDT 2017

Sponsoring Org.:: USDOE Office of Nuclear Energy (NE)

OSTI Identifier:: 1393275

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Electroanalysis

Additional Journal Information:: Journal Name: Electroanalysis; Journal ID: ISSN 1040-0397

Publisher:: Wiley Blackwell (John Wiley & Sons)

Country of Publication:: Germany

Language:: English

Citation Formats


                    Lines, Amanda M., Adami, Susan R., Casella, Amanda J., Sinkov, Sergey I., Lumetta, Gregg J., and Bryan, Samual A. Electrochemistry and Spectroelectrochemistry of the Pu (III/IV) and (IV/VI) Couples in Nitric Acid Systems.  Germany: N. p., 2017. 
Web.  doi:10.1002/elan.201700465.

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                    Lines, Amanda M., Adami, Susan R., Casella, Amanda J., Sinkov, Sergey I., Lumetta, Gregg J., & Bryan, Samual A. Electrochemistry and Spectroelectrochemistry of the Pu (III/IV) and (IV/VI) Couples in Nitric Acid Systems.  Germany.  https://doi.org/10.1002/elan.201700465

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                    Lines, Amanda M., Adami, Susan R., Casella, Amanda J., Sinkov, Sergey I., Lumetta, Gregg J., and Bryan, Samual A. Wed .  
"Electrochemistry and Spectroelectrochemistry of the Pu (III/IV) and (IV/VI) Couples in Nitric Acid Systems".  Germany.  https://doi.org/10.1002/elan.201700465.

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@article{osti_1393275,

  title        = {Electrochemistry and Spectroelectrochemistry of the Pu (III/IV) and (IV/VI) Couples in Nitric Acid Systems},

  author       = {Lines, Amanda M. and Adami, Susan R. and Casella, Amanda J. and Sinkov, Sergey I. and Lumetta, Gregg J. and Bryan, Samual A.},

  abstractNote = {},

  doi          = {10.1002/elan.201700465},

  journal      = {Electroanalysis},

  number       = ,

  volume       = ,

  place        = {Germany},

  year         = {Wed Sep 20 00:00:00 EDT 2017},

  month        = {Wed Sep 20 00:00:00 EDT 2017}

}

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Works referenced in this record:

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Chatterjee, Sayandev; Del Negro, Andrew S.; Edwards, Matthew K.
Analytical Chemistry, Vol. 83, Issue 5
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Multivariate Analysis for Quantification of Plutonium(IV) in Nitric Acid Based on Absorption Spectra
journal, August 2017

Lines, Amanda M.; Adami, Susan R.; Sinkov, Sergey I.
Analytical Chemistry, Vol. 89, Issue 17
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Optically Transparent Thin-Film Electrode Chip for Spectroelectrochemical Sensing
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Branch, Shirmir D.; Lines, Amanda M.; Lynch, John
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Similar Records in DOE PAGES and OSTI.GOV collections:

Electrochemistry and Spectroelectrochemistry of the Pu (III/IV) and (IV/VI) Couples in Nitric Acid Systems

Journal Article Lines, Amanda M. ; Adami, Susan R. ; Casella, Amanda J. ; ... - Electroanalysis

The solution chemistry of Pu in nitric acid is explored via electrochemistry and spectroelectrochemistry. By utilizing and comparing these techniques, an improved understanding of Pu behavior and its dependence on nitric acid concentration can be achieved. Here the Pu (III/IV) couple is characterized using cyclic voltammetry, square wave voltammetry, and a spectroelectrochemical Nernst step. Results indicate the formal reduction potential of the couple shifts negative with increasing acid concentration and reversible electrochemistry is no longer attainable above 6 M HNO3. Spectroelectrochemistry is also used to explore the irreversible oxidation of Pu(IV) to Pu(VI) and shine light on the mechanism andmore » acid dependence of the redox reaction.« less
https://doi.org/10.1002/elan.201700465
ABSORPTION SPECTRA OF Pu(III), Pu(IV), Pu(VI), U(IV), AND U(VI) IN NITRIC ACID AND TRI-n-BUTYL PHOSPHATE--n-ALKANE SOLUTIONS AND THEIR USE IN AUTOMATIC PROCESS CONTROL. (in German)

Technical Report Schmieder, H ; Kuhn, E ; Ochsenfeld, W
VERTEILUNGSDATEN FUER PU(IV) UND U(VI) UND DEREN RECHNERISCHE ERMITTLUNG IM SYSTEM METALLNITRAT--SALPETERSAEURE UND TRIBUTYLPHOSPHAT. (Distribution Characteristics of Pu(IV) AND U(VI) and Their Mathematical Determination in Metal Nitrate--Nitric Acid and Tributyl Phosphate Systems). (in German)

Technical Report Ochsenfeld, W ; Schmieder, H ; Baumgaertel, G ; ...
THE INFLUENCE OF ALIPHATIC AND AROMATIC HYDROCARBONS ON TRIBUTYLPHOSPHATE SEPARATION OF U(VI), Pu(IV), Zr(IV) AND Ce(III) FROM NITRIC ACID SOLUTIONS (in Russian)

Journal Article Shevchenko, V B ; Solovkin, A S ; Shilin, I V ; ... - Radiokhimiya (U.S.S.R.) For English translation see Sov. Radiochem. (Engl. Transl.)

The influence of aliphatic and aromatic diluents on the tributyl phosphate extraction of U(VI), Pu(IV), Zr(IV), and Ce(III) from nitric acid solutions was investigated. A definite bond was established between the TBP extraction properties aad the organic phase polarity. Variations of polarity during the extraction process caused variations in salt distribution at high concentrations. (R.V.J.)
THE POTENTIAL OF THE Pu(III)--Pu(IV) COUPLE IN NITRIC ACID SOLUTION AND EQUILIBRIUM CONSTANTS FOR THE NITRATO COMPLEXES OF Pu(IV).

Technical Report Wain, A G

Similar Records

Title: Electrochemistry and Spectroelectrochemistry of the Pu (III/IV) and (IV/VI) Couples in Nitric Acid Systems

Citation Formats

Electrochemical and spectroscopic studies of Pu(IV) and Pu(III) in nitric acid solutions journal, May 2012

Bestimmung von Stabilitätskonstanten einiger Aktinidenkomplexe journal, January 1970

Stability constants of nitrate complexes of trivalent plutonium in aqueous and tributyl phosphate solutions journal, November 1960

The measurement of the diffusion coefficients of Pu(III) in hydrochloric acid by use of an analytical ultracentrifuge journal, May 1985

Spectroscopic monitoring of spent nuclear fuel reprocessing streams: an evaluation of spent fuel solutions via Raman, visible, and near-infrared spectroscopy journal, September 2011

Electrochemistry and Spectroelectrochemistry of Luminescent Europium Complexes journal, May 2016

The absorption spectra of plutonium ions in perchloric acid solutions journal, March 1961

Analytical electrochemistry: methodology and applications of dynamic techniques journal, April 1978

Luminescence-Based Spectroelectrochemical Sensor for [Tc(dmpe) 3 ] 2+/+ (dmpe = 1,2- bis (dimethylphosphino)ethane) within a Charge-Selective Polymer Film journal, March 2011

Multivariate Analysis for Quantification of Plutonium(IV) in Nitric Acid Based on Absorption Spectra journal, August 2017

Optically Transparent Thin-Film Electrode Chip for Spectroelectrochemical Sensing journal, July 2017

Cyclic voltammetry of Pu and Np in nitric acid media journal, November 1971

Chloride, nitrate and sulphate complexes of europium (III) and americium (III) journal, June 1964

Study of the plutonium (IV) electrochemical behavior in nitric acid at a platinum electrode. Application to the cathodic reduction of Pu(IV) in a plate electrolyzer journal, August 2014

An electrochemical experiment using an optically transparent thin layer electrode journal, September 1976

Redox and environmentally relevant aspects of actinide(IV) coordination chemistry journal, May 2014

Electrochemical studies of plutonium ions in perchloric acid solution journal, March 1961

Standard Electrode Potentials and Temperature Coefficients in Water at 298.15 K journal, January 1989

An investigation of the mechanism of the Eu(III)/Eu(II) electrode reaction in the presence of edta journal, November 1972

Mechanism of the Disproportionation of Plutonium (V) journal, May 1949

Electrochemical and spectroscopic studies of Pu(IV) and Pu(III) in nitric acid solutions
journal, May 2012

Bestimmung von Stabilitätskonstanten einiger Aktinidenkomplexe
journal, January 1970

Stability constants of nitrate complexes of trivalent plutonium in aqueous and tributyl phosphate solutions
journal, November 1960

The measurement of the diffusion coefficients of Pu(III) in hydrochloric acid by use of an analytical ultracentrifuge
journal, May 1985

Spectroscopic monitoring of spent nuclear fuel reprocessing streams: an evaluation of spent fuel solutions via Raman, visible, and near-infrared spectroscopy
journal, September 2011

Electrochemistry and Spectroelectrochemistry of Luminescent Europium Complexes
journal, May 2016

The absorption spectra of plutonium ions in perchloric acid solutions
journal, March 1961

Analytical electrochemistry: methodology and applications of dynamic techniques
journal, April 1978

Luminescence-Based Spectroelectrochemical Sensor for [Tc(dmpe) ₃ ] ^2+/+ (dmpe = 1,2- bis (dimethylphosphino)ethane) within a Charge-Selective Polymer Film
journal, March 2011

Multivariate Analysis for Quantification of Plutonium(IV) in Nitric Acid Based on Absorption Spectra
journal, August 2017

Optically Transparent Thin-Film Electrode Chip for Spectroelectrochemical Sensing
journal, July 2017

Cyclic voltammetry of Pu and Np in nitric acid media
journal, November 1971

Chloride, nitrate and sulphate complexes of europium (III) and americium (III)
journal, June 1964

Study of the plutonium (IV) electrochemical behavior in nitric acid at a platinum electrode. Application to the cathodic reduction of Pu(IV) in a plate electrolyzer
journal, August 2014

An electrochemical experiment using an optically transparent thin layer electrode
journal, September 1976

Redox and environmentally relevant aspects of actinide(IV) coordination chemistry
journal, May 2014

Electrochemical studies of plutonium ions in perchloric acid solution
journal, March 1961

Standard Electrode Potentials and Temperature Coefficients in Water at 298.15 K
journal, January 1989

An investigation of the mechanism of the Eu(III)/Eu(II) electrode reaction in the presence of edta
journal, November 1972

Mechanism of the Disproportionation of Plutonium (V)
journal, May 1949