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Title: Recent progress in the synthesis of metal–organic frameworks

Authors:
 [1];  [1]
  1. Texas A & M Univ., College Station, TX (United States)
Publication Date:
Research Org.:
Texas A & M Univ., College Station, TX (United States); Energy Frontier Research Centers (EFRC) (United States). Center for Gas Separations Relevant to Clean Energy Technologies (CGS)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1239842
Alternate Identifier(s):
OSTI ID: 1387383
Grant/Contract Number:  
SC0001015
Resource Type:
Accepted Manuscript
Journal Name:
Science and Technology of Advanced Materials
Additional Journal Information:
Journal Volume: 16; Journal Issue: 5; Journal ID: ISSN 1468-6996
Publisher:
IOP Publishing
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; metal–organic frameworks, solvothermal synthesis, microwave-assisted synthesis, electrochemical synthesis, post-synthetic modification, post-synthetic exchange; membrane, carbon capture, materials and chemistry by design, synthesis (novel materials), synthesis (self-assembly), synthesis (scalable processing)

Citation Formats

Sun, Yujia, and Zhou, Hong -Cai. Recent progress in the synthesis of metal–organic frameworks. United States: N. p., 2015. Web. doi:10.1088/1468-6996/16/5/054202.
Sun, Yujia, & Zhou, Hong -Cai. Recent progress in the synthesis of metal–organic frameworks. United States. https://doi.org/10.1088/1468-6996/16/5/054202
Sun, Yujia, and Zhou, Hong -Cai. Fri . "Recent progress in the synthesis of metal–organic frameworks". United States. https://doi.org/10.1088/1468-6996/16/5/054202. https://www.osti.gov/servlets/purl/1239842.
@article{osti_1239842,
title = {Recent progress in the synthesis of metal–organic frameworks},
author = {Sun, Yujia and Zhou, Hong -Cai},
abstractNote = {},
doi = {10.1088/1468-6996/16/5/054202},
journal = {Science and Technology of Advanced Materials},
number = 5,
volume = 16,
place = {United States},
year = {Fri Sep 25 00:00:00 EDT 2015},
month = {Fri Sep 25 00:00:00 EDT 2015}
}

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Cited by: 137 works
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  • Stock, Norbert; Biswas, Shyam
  • Chemical Reviews, Vol. 112, Issue 2
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Facile synthesis of nano-sized metal-organic frameworks, chromium-benzenedicarboxylate, MIL-101
journal, February 2011

  • Khan, Nazmul Abedin; Kang, In Joong; Seok, Hwi Young
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Adsorption and Diffusion of Benzene on Chromium-Based Metal Organic Framework MIL-101 Synthesized by Microwave Irradiation
journal, February 2011

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Carbon dioxide adsorption in microwave-synthesized metal organic framework CPM-5: Equilibrium and kinetics study
journal, July 2013


Microwave-assisted solvothermal synthesis of zirconium oxide based metal–organic frameworks
journal, January 2013

  • Liang, Weibin; D'Alessandro, Deanna M.
  • Chemical Communications, Vol. 49, Issue 35
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Modulated synthesis of zirconium-metal organic framework (Zr-MOF) for hydrogen storage applications
journal, January 2014


Microwave-assisted modulated synthesis of zirconium-based metal–organic framework (Zr-MOF) for hydrogen storage applications
journal, May 2014

  • Ren, Jianwei; Segakweng, Tshiamo; Langmi, Henrietta
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Electrochemical Synthesis of Some Archetypical Zn 2+ , Cu 2+ , and Al 3+ Metal Organic Frameworks
journal, June 2012

  • Martinez Joaristi, Alberto; Juan-Alcañiz, Jana; Serra-Crespo, Pablo
  • Crystal Growth & Design, Vol. 12, Issue 7
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High pressure, high temperature electrochemical synthesis of metal–organic frameworks: films of MIL-100 (Fe) and HKUST-1 in different morphologies
journal, January 2013

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Luminescent terbium-containing metal–organic framework films: new approaches for the electrochemical synthesis and application as detectors for explosives
journal, January 2014

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Electrochemical Film Deposition of the Zirconium Metal–Organic Framework UiO-66 and Application in a Miniaturized Sorbent Trap
journal, February 2015

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  • Chemistry of Materials, Vol. 27, Issue 5
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Reusable Oxidation Catalysis Using Metal-Monocatecholato Species in a Robust Metal–Organic Framework
journal, March 2014

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Postsynthetic Covalent Modification of a Neutral Metal−Organic Framework
journal, October 2007

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Single-Crystalline Molecular Flasks: Chemical Transformation with Bulky Reagents in the Pores of Porous Coordination Networks
journal, October 2008

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Tandem Modification of Metal–Organic Frameworks by a Postsynthetic Approach
journal, June 2008

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Direct Observation of the Labile Imine Formation through Single-Crystal-to-Single-Crystal Reactions in the Pores of a Porous Coordination Network
journal, February 2008

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Framework functionalisation triggers metal complex binding
journal, January 2008

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Post-Synthetic Modification of Tagged Metal-Organic Frameworks
journal, October 2008

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Covalent modification of a metal–organic framework with isocyanates: probing substrate scope and reactivity
journal, January 2008

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“Clickable” Metal−Organic Framework
journal, November 2008

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Covalent surface modification of a metal–organic framework: selective surface engineering via CuI-catalyzed Huisgen cycloaddition
journal, January 2008

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Nucleic Acid–Metal Organic Framework (MOF) Nanoparticle Conjugates
journal, May 2014

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Synthesis and click modification of an azido-functionalized Zr( iv ) metal–organic framework and a catalytic study
journal, January 2015


A Mesoporous Metal−Organic Framework with Permanent Porosity
journal, December 2006

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Generation of a solid Brønsted acid site in a chiral framework
journal, January 2008

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Metal–organic framework tethering PNIPAM for ON–OFF controlled release in solution
journal, January 2015

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Metal–Organic Framework Based upon the Synergy of a Brønsted Acid Framework and Lewis Acid Centers as a Highly Efficient Heterogeneous Catalyst for Fixed-Bed Reactions
journal, March 2015

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Stepwise Synthesis of Robust Metal–Organic Frameworks via Postsynthetic Metathesis and Oxidation of Metal Nodes in a Single-Crystal to Single-Crystal Transformation
journal, May 2014

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Enhancing CO 2 Separation Ability of a Metal-Organic Framework by Post-Synthetic Ligand Exchange with Flexible Aliphatic Carboxylates
journal, December 2013

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Metalation of a Thiocatechol-Functionalized Zr(IV)-Based Metal–Organic Framework for Selective C–H Functionalization
journal, February 2015

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Tetrazine functionalized zirconium MOF as an optical sensor for oxidizing gases
journal, January 2015

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Postsynthetic Ligand and Cation Exchange in Robust Metal–Organic Frameworks
journal, October 2012

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A route to drastic increase of CO2 uptake in Zr metal organic framework UiO-66
journal, January 2013

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  • Chemical Communications, Vol. 49, Issue 35
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Photocatalytic CO 2 reduction by a mixed metal (Zr/Ti), mixed ligand metal–organic framework under visible light irradiation
journal, January 2015

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  • Chemical Communications, Vol. 51, Issue 26
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Unusual and Highly Tunable Missing-Linker Defects in Zirconium Metal–Organic Framework UiO-66 and Their Important Effects on Gas Adsorption
journal, May 2013

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A facile synthesis of UiO-66, UiO-67 and their derivatives
journal, January 2013

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A UiO-66 analogue with uncoordinated carboxylic acids for the broad-spectrum removal of toxic chemicals
journal, January 2015

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Tandem Modification of Metal–Organic Frameworks by a Postsynthetic Approach
journal, June 2008

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A Route to the Synthesis of Trivalent Transition-Metal Porous Carboxylates with Trimeric Secondary Building Units
journal, September 2004

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Single-Crystalline Molecular Flasks: Chemical Transformation with Bulky Reagents in the Pores of Porous Coordination Networks
journal, October 2008

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A Highly Stable Zeotype Mesoporous Zirconium Metal-Organic Framework with Ultralarge Pores
journal, November 2014


Hydrogen Storage in the Giant-Pore Metal–Organic Frameworks MIL-100 and MIL-101
journal, December 2006

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How Hydration Drastically Improves Adsorption Selectivity for CO2 over CH4 in the Flexible Chromium Terephthalate MIL-53
journal, November 2006

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Giant Pores in a Chromium 2,6-Naphthalenedicarboxylate Open-Framework Structure with MIL-101 Topology
journal, May 2009

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Metal–Organic Frameworks as Efficient Materials for Drug Delivery
journal, September 2006

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Postsynthetic Modifications of Iron-Carboxylate Nanoscale Metal−Organic Frameworks for Imaging and Drug Delivery
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Zirconium-Metalloporphyrin PCN-222: Mesoporous Metal-Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts
journal, August 2012

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Metal–Organic Frameworks as Efficient Materials for Drug Delivery
journal, September 2006

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Single-Crystalline Molecular Flasks: Chemical Transformation with Bulky Reagents in the Pores of Porous Coordination Networks
journal, October 2008

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Hydrogen Storage in the Giant-Pore Metal–Organic Frameworks MIL-100 and MIL-101
journal, December 2006

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How Hydration Drastically Improves Adsorption Selectivity for CO2 over CH4 in the Flexible Chromium Terephthalate MIL-53
journal, November 2006

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Tandem Modification of Metal–Organic Frameworks by a Postsynthetic Approach
journal, June 2008

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Post-Synthetic Modification of Tagged Metal-Organic Frameworks
journal, October 2008

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Giant Pores in a Chromium 2,6-Naphthalenedicarboxylate Open-Framework Structure with MIL-101 Topology
journal, May 2009

  • Sonnauer, Andreas; Hoffmann, Frank; Fröba, Michael
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Metal-Organic Frameworks: Opportunities for Catalysis
journal, September 2009

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“Heterogeneity within Order” in Metal-Organic Frameworks
journal, January 2015

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Microwave Synthesis of the CPM-5 Metal Organic Framework
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A Rationale for the Large Breathing of the Porous Aluminum Terephthalate (MIL-53) Upon Hydration
journal, March 2004

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Microwave Synthesis of Hybrid Inorganic–Organic Porous Materials: Phase-Selective and Rapid Crystallization
journal, October 2006

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Water Stable Zr-Benzenedicarboxylate Metal-Organic Frameworks as Photocatalysts for Hydrogen Generation
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Modulated Synthesis of Zr-Based Metal-Organic Frameworks: From Nano to Single Crystals
journal, May 2011

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Enhancing CO 2 Separation Ability of a Metal-Organic Framework by Post-Synthetic Ligand Exchange with Flexible Aliphatic Carboxylates
journal, December 2013

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Coordination polymers for energy transfer: Preparations, properties, sensing applications, and perspectives
journal, February 2015


Facile synthesis of nano-sized metal-organic frameworks, chromium-benzenedicarboxylate, MIL-101
journal, February 2011

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  • Chemical Engineering Journal, Vol. 166, Issue 3
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Modulated synthesis of zirconium-metal organic framework (Zr-MOF) for hydrogen storage applications
journal, January 2014


Evaluation of synthetic methods for microporous metal–organic frameworks exemplified by the competitive formation of [Cu2(btc)3(H2O)3] and [Cu2(btc)(OH)(H2O)]
journal, July 2010


Carbon dioxide adsorption in microwave-synthesized metal organic framework CPM-5: Equilibrium and kinetics study
journal, July 2013


Metal−Organic Frameworks with Functional Pores for Recognition of Small Molecules
journal, August 2010

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Electrochemical Synthesis of Some Archetypical Zn 2+ , Cu 2+ , and Al 3+ Metal Organic Frameworks
journal, June 2012

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Synthesis, Single-Crystal X-ray Microdiffraction, and NMR Characterizations of the Giant Pore Metal-Organic Framework Aluminum Trimesate MIL-100
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Luminescent Functional Metal–Organic Frameworks
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Postsynthetic Methods for the Functionalization of Metal–Organic Frameworks
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Synthesis of Metal-Organic Frameworks (MOFs): Routes to Various MOF Topologies, Morphologies, and Composites
journal, September 2011

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Homochiral Metal–Organic Frameworks for Asymmetric Heterogeneous Catalysis
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Rapid Production of Metal−Organic Frameworks via Microwave-Assisted Solvothermal Synthesis
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A Mesoporous Metal−Organic Framework with Permanent Porosity
journal, December 2006

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Postsynthetic Covalent Modification of a Neutral Metal−Organic Framework
journal, October 2007

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Impact of Preparation and Handling on the Hydrogen Storage Properties of Zn4O(1,4-benzenedicarboxylate)3 (MOF-5)
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Main-Group and Transition-Element IRMOF Homologues
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Growth of Metal−Organic Frameworks on Polymer Surfaces
journal, November 2010

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Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine-Appended Metal–Organic Framework mmen-Mg2(dobpdc)
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Postsynthetic Ligand and Cation Exchange in Robust Metal–Organic Frameworks
journal, October 2012

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Unusual and Highly Tunable Missing-Linker Defects in Zirconium Metal–Organic Framework UiO-66 and Their Important Effects on Gas Adsorption
journal, May 2013

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Construction of Ultrastable Porphyrin Zr Metal–Organic Frameworks through Linker Elimination
journal, October 2013

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Rigidifying Fluorescent Linkers by Metal–Organic Framework Formation for Fluorescence Blue Shift and Quantum Yield Enhancement
journal, May 2014

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Stepwise Synthesis of Robust Metal–Organic Frameworks via Postsynthetic Metathesis and Oxidation of Metal Nodes in a Single-Crystal to Single-Crystal Transformation
journal, May 2014

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Nucleic Acid–Metal Organic Framework (MOF) Nanoparticle Conjugates
journal, May 2014

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A Series of Highly Stable Mesoporous Metalloporphyrin Fe-MOFs
journal, August 2014

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A Highly Stable Porphyrinic Zirconium Metal–Organic Framework with shp-a Topology
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Metalation of a Thiocatechol-Functionalized Zr(IV)-Based Metal–Organic Framework for Selective C–H Functionalization
journal, February 2015

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Direct Observation of the Labile Imine Formation through Single-Crystal-to-Single-Crystal Reactions in the Pores of a Porous Coordination Network
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Postsynthetic Modifications of Iron-Carboxylate Nanoscale Metal−Organic Frameworks for Imaging and Drug Delivery
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Adsorptive Separation of Isobutene and Isobutane on Cu 3 (BTC) 2
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A homochiral metal–organic porous material for enantioselective separation and catalysis
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Efficient and tunable white-light emission of metal–organic frameworks by iridium-complex encapsulation
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Kinetically tuned dimensional augmentation as a versatile synthetic route towards robust metal–organic frameworks
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Stable metal-organic frameworks containing single-molecule traps for enzyme encapsulation
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Porous metal–organic-framework nanoscale carriers as a potential platform for drug delivery and imaging
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Hydrogen adsorption in the nanoporous metal-benzenedicarboxylate M(OH)(O 2 C–C 6 H 4 –CO 2 ) (M = Al 3+ , Cr 3+ ), MIL-53
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