Material/element-dependent fluorescence-yield modes on soft X-ray absorption spectroscopy of cathode materials for Li-ion batteries
Abstract
© 2016 Author(s). We evaluate the utilities of fluorescence-yield (FY) modes in soft X-ray absorption spectroscopy (XAS) of several cathode materials for Li-ion batteries. In the case of total-FY (TFY) XAS for LiNi 0.5 Mn 1.5 O 4 , the line shape of the Mn L 3 -edge XAS was largely distorted by the self-absorption and saturation effects, while the distortions were less pronounced at the Ni L 3 edge. The distortions were suppressed for the inverse-partial-FY (IPFY) spectra. We found that, in the cathode materials, the IPFY XAS is highly effective for the Cr, Mn, and Fe L edges and the TFY and PFY modes are useful enough for the Ni L edge which is far from the O K edge.
- Authors:
-
- National Institute of Advanced Industrial Science and Technology, Ibaraki (Japan)
- National Institute of Advanced Industrial Science and Technology, Ibaraki (Japan); Kyushu Univ., Fukuoka (Japan)
- The Univ. of Tokyo, Tokyo (Japan)
- National Renewable Energy Lab. (NREL), Golden, CO (United States)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of California, Santa Cruz, CA (United States)
- The Univ. of Tokyo, Chiba (Japan); Waseda Univ., Tokyo (Japan)
- Jilin Univ., Changchun (People's Republic of China)
- Univ. of Waterloo, Waterloo, ON (Canada)
- Univ. of Saskatchewan, Saskatoon, SK (Canada)
- The Univ. of Tokyo, Chiba (Japan)
- Publication Date:
- Research Org.:
- National Renewable Energy Laboratory (NREL), Golden, CO (United States); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- NREL Laboratory Directed Research and Development (LDRD); USDOE Office of Energy Efficiency and Renewable Energy (EERE)
- OSTI Identifier:
- 1329991
- Alternate Identifier(s):
- OSTI ID: 1378978
- Report Number(s):
- NREL/JA-5900-67327
Journal ID: ISSN 2158-3226; AAIDBI
- Grant/Contract Number:
- AC36-08GO28308; AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- AIP Advances
- Additional Journal Information:
- Journal Volume: 6; Journal Issue: 3; Journal ID: ISSN 2158-3226
- Publisher:
- American Institute of Physics (AIP)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; x-ray absorption spectroscopy; nickel; cathodes; emission spectra; electronic structure
Citation Formats
Asakura, Daisuke, Hosono, Eiji, Nanba, Yusuke, Zhou, Haoshen, Okabayashi, Jun, Ban, Chunmei, Glans, Per -Anders, Guo, Jinghua, Mizokawa, Takashi, Chen, Gang, Achkar, Andrew J., Hawthron, David G., Regier, Thomas Z., and Wadati, Hiroki. Material/element-dependent fluorescence-yield modes on soft X-ray absorption spectroscopy of cathode materials for Li-ion batteries. United States: N. p., 2016.
Web. doi:10.1063/1.4943673.
Asakura, Daisuke, Hosono, Eiji, Nanba, Yusuke, Zhou, Haoshen, Okabayashi, Jun, Ban, Chunmei, Glans, Per -Anders, Guo, Jinghua, Mizokawa, Takashi, Chen, Gang, Achkar, Andrew J., Hawthron, David G., Regier, Thomas Z., & Wadati, Hiroki. Material/element-dependent fluorescence-yield modes on soft X-ray absorption spectroscopy of cathode materials for Li-ion batteries. United States. https://doi.org/10.1063/1.4943673
Asakura, Daisuke, Hosono, Eiji, Nanba, Yusuke, Zhou, Haoshen, Okabayashi, Jun, Ban, Chunmei, Glans, Per -Anders, Guo, Jinghua, Mizokawa, Takashi, Chen, Gang, Achkar, Andrew J., Hawthron, David G., Regier, Thomas Z., and Wadati, Hiroki. Mon .
"Material/element-dependent fluorescence-yield modes on soft X-ray absorption spectroscopy of cathode materials for Li-ion batteries". United States. https://doi.org/10.1063/1.4943673. https://www.osti.gov/servlets/purl/1329991.
@article{osti_1329991,
title = {Material/element-dependent fluorescence-yield modes on soft X-ray absorption spectroscopy of cathode materials for Li-ion batteries},
author = {Asakura, Daisuke and Hosono, Eiji and Nanba, Yusuke and Zhou, Haoshen and Okabayashi, Jun and Ban, Chunmei and Glans, Per -Anders and Guo, Jinghua and Mizokawa, Takashi and Chen, Gang and Achkar, Andrew J. and Hawthron, David G. and Regier, Thomas Z. and Wadati, Hiroki},
abstractNote = {© 2016 Author(s). We evaluate the utilities of fluorescence-yield (FY) modes in soft X-ray absorption spectroscopy (XAS) of several cathode materials for Li-ion batteries. In the case of total-FY (TFY) XAS for LiNi 0.5 Mn 1.5 O 4 , the line shape of the Mn L 3 -edge XAS was largely distorted by the self-absorption and saturation effects, while the distortions were less pronounced at the Ni L 3 edge. The distortions were suppressed for the inverse-partial-FY (IPFY) spectra. We found that, in the cathode materials, the IPFY XAS is highly effective for the Cr, Mn, and Fe L edges and the TFY and PFY modes are useful enough for the Ni L edge which is far from the O K edge.},
doi = {10.1063/1.4943673},
journal = {AIP Advances},
number = 3,
volume = 6,
place = {United States},
year = {Mon Mar 07 00:00:00 EST 2016},
month = {Mon Mar 07 00:00:00 EST 2016}
}
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