Morphology of a Ternary Blend Solar Cell Based on Small Molecule:Conjugated Polymer:Fullerene Fabricated by Blade Coating
Abstract
Abstract Here, conjugated polymer is added as third component to tune the solution viscosity, morphology, and function of small molecule (SM) based bulk‐heterojunction (BHJ) solar cells, which are fabricated using blade coating. Novel information about the effect of blade coating speed on the nanoscale morphology and function of ternary blend solar cells is provided. The crystal sizes increase with an increase of coating speed for both binary and ternary blends, while the addition of the third component tends to favor smaller SM crystal grains and improves the connectivity of SM crystals. Small angle neutron scattering experiments provide the first clear experimental evidence that the addition of the third component would significantly impact the fullerene phase separation, which is crucial for bimolecular recombination and charge transport. It shows that for both binary and ternary blends, the concentration and sizes of [6,6]‐phenyl‐C61‐butyric acid methyl ester (PCBM) aggregates increase with an increase of coating speed, while addition of third component does not affect the volume fraction of PCBM aggregates but impacts the size of PCBM aggregates. It is demonstrated that the judicious selection of blade coating speed and addition of conjugated polymer optimize the morphology of SM‐BHJ, providing guidelines for high performance SM‐BHJsmore »
- Authors:
-
- Institute of Optoelectronic Display National &, Local United Engineering Lab of Flat Panel Display Technology Fuzhou University Fuzhou 350002 China
- Institute of Optoelectronic Display National &, Local United Engineering Lab of Flat Panel Display Technology Fuzhou University Fuzhou 350002 China, College of Information Science and Engineering Fujian University of Technology Fuzhou 350108 China
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1378793
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Advanced Functional Materials
- Additional Journal Information:
- Journal Name: Advanced Functional Materials Journal Volume: 27 Journal Issue: 40; Journal ID: ISSN 1616-301X
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Wu, Xiaomin, Lan, Shuqiong, Zhang, Guocheng, Chen, Qizhen, Chen, Huipeng, and Guo, Tailiang. Morphology of a Ternary Blend Solar Cell Based on Small Molecule:Conjugated Polymer:Fullerene Fabricated by Blade Coating. Germany: N. p., 2017.
Web. doi:10.1002/adfm.201703268.
Wu, Xiaomin, Lan, Shuqiong, Zhang, Guocheng, Chen, Qizhen, Chen, Huipeng, & Guo, Tailiang. Morphology of a Ternary Blend Solar Cell Based on Small Molecule:Conjugated Polymer:Fullerene Fabricated by Blade Coating. Germany. https://doi.org/10.1002/adfm.201703268
Wu, Xiaomin, Lan, Shuqiong, Zhang, Guocheng, Chen, Qizhen, Chen, Huipeng, and Guo, Tailiang. Wed .
"Morphology of a Ternary Blend Solar Cell Based on Small Molecule:Conjugated Polymer:Fullerene Fabricated by Blade Coating". Germany. https://doi.org/10.1002/adfm.201703268.
@article{osti_1378793,
title = {Morphology of a Ternary Blend Solar Cell Based on Small Molecule:Conjugated Polymer:Fullerene Fabricated by Blade Coating},
author = {Wu, Xiaomin and Lan, Shuqiong and Zhang, Guocheng and Chen, Qizhen and Chen, Huipeng and Guo, Tailiang},
abstractNote = {Abstract Here, conjugated polymer is added as third component to tune the solution viscosity, morphology, and function of small molecule (SM) based bulk‐heterojunction (BHJ) solar cells, which are fabricated using blade coating. Novel information about the effect of blade coating speed on the nanoscale morphology and function of ternary blend solar cells is provided. The crystal sizes increase with an increase of coating speed for both binary and ternary blends, while the addition of the third component tends to favor smaller SM crystal grains and improves the connectivity of SM crystals. Small angle neutron scattering experiments provide the first clear experimental evidence that the addition of the third component would significantly impact the fullerene phase separation, which is crucial for bimolecular recombination and charge transport. It shows that for both binary and ternary blends, the concentration and sizes of [6,6]‐phenyl‐C61‐butyric acid methyl ester (PCBM) aggregates increase with an increase of coating speed, while addition of third component does not affect the volume fraction of PCBM aggregates but impacts the size of PCBM aggregates. It is demonstrated that the judicious selection of blade coating speed and addition of conjugated polymer optimize the morphology of SM‐BHJ, providing guidelines for high performance SM‐BHJs from roll‐to‐roll production.},
doi = {10.1002/adfm.201703268},
journal = {Advanced Functional Materials},
number = 40,
volume = 27,
place = {Germany},
year = {Wed Sep 06 00:00:00 EDT 2017},
month = {Wed Sep 06 00:00:00 EDT 2017}
}
https://doi.org/10.1002/adfm.201703268
Web of Science
Works referenced in this record:
Design Rules for Organic Donor–Acceptor Heterojunctions: Pathway for Charge Splitting and Detrapping
journal, May 2015
- Poelking, Carl; Andrienko, Denis
- Journal of the American Chemical Society, Vol. 137, Issue 19
Enhanced Efficiency Parameters of Solution-Processable Small-Molecule Solar Cells Depending on ITO Sheet Resistance
journal, May 2013
- Wang, Dong Hwan; Kyaw, Aung Ko Ko; Gupta, Vinay
- Advanced Energy Materials, Vol. 3, Issue 9
Numerical Flow Simulation of Viscoplastic Slurries and Design Criteria for a Tape Casting Unit
journal, January 1994
- Loest, Hagen; Lipp, Roland; Mitsoulis, Evan
- Journal of the American Ceramic Society, Vol. 77, Issue 1
Ternary blend polymer solar cells with enhanced power conversion efficiency
journal, August 2014
- Lu, Luyao; Xu, Tao; Chen, Wei
- Nature Photonics, Vol. 8, Issue 9
Small Molecule Solution-Processed Bulk Heterojunction Solar Cells †
journal, February 2011
- Walker, Bright; Kim, Chunki; Nguyen, Thuc-Quyen
- Chemistry of Materials, Vol. 23, Issue 3
Hierarchical Nanomorphologies Promote Exciton Dissociation in Polymer/Fullerene Bulk Heterojunction Solar Cells
journal, September 2011
- Chen, Wei; Xu, Tao; He, Feng
- Nano Letters, Vol. 11, Issue 9, p. 3707-3713
Fluorination-enabled optimal morphology leads to over 11% efficiency for inverted small-molecule organic solar cells
journal, December 2016
- Deng, Dan; Zhang, Yajie; Zhang, Jianqi
- Nature Communications, Vol. 7, Issue 1
Improving the Compatibility of Donor Polymers in Efficient Ternary Organic Solar Cells via Post-Additive Soaking Treatment
journal, December 2016
- Yang, Xiaoyu; Zheng, Fei; Xu, Weilong
- ACS Applied Materials & Interfaces, Vol. 9, Issue 1
The Role of Fullerene Mixing Behavior in the Performance of Organic Photovoltaics: PCBM in Low-Bandgap Polymers
journal, September 2013
- Chen, Huipeng; Peet, Jeff; Hu, Sheng
- Advanced Functional Materials, Vol. 24, Issue 1
The Impact of Fullerene Structure on Its Miscibility with P3HT and Its Correlation of Performance in Organic Photovoltaics
journal, June 2014
- Chen, Huipeng; Peet, Jeff; Hsiao, Yu-Che
- Chemistry of Materials, Vol. 26, Issue 13
1,3-Bis(thieno[3,4- b ]thiophen-6-yl)-4 H -thieno[3,4- c ]pyrrole-4,6(5 H )-dione-Based Small-Molecule Donor for Efficient Solution-Processed Solar Cells
journal, February 2017
- Zhang, Zhongbo; Zhou, Zichun; Hu, Qin
- ACS Applied Materials & Interfaces, Vol. 9, Issue 7
Ternary Organic Solar Cells Based on Two Compatible Nonfullerene Acceptors with Power Conversion Efficiency >10%
journal, September 2016
- Liu, Tao; Guo, Yuan; Yi, Yuanping
- Advanced Materials, Vol. 28, Issue 45
Large-area organic solar cells by accelerated blade coating
journal, July 2015
- Tsai, Pei-Ting; Yu, Kai-Chieh; Chang, Chia-Ju
- Organic Electronics, Vol. 22
Nanoparticle concentration profile in polymer-based solar cells
journal, January 2010
- Kiel, Jonathan W.; Kirby, Brian J.; Majkrzak, Charles F.
- Soft Matter, Vol. 6, Issue 3, p. 641-646
Versatile third components for efficient and stable organic solar cells
journal, January 2015
- Cheng, Pei; Zhan, Xiaowei
- Materials Horizons, Vol. 2, Issue 5
Roll-to-roll fabrication of monolithic large-area polymer solar cells free from indium-tin-oxide
journal, September 2009
- Krebs, Frederik C.
- Solar Energy Materials and Solar Cells, Vol. 93, Issue 9
Impact of Fullerene Structure on Nanoscale Morphology and Miscibility and Correlation of Performance on Small Molecules: Fullerene Solar Cell
journal, September 2016
- Lan, Shuqiong; Yang, Huihuang; Zhang, Guocheng
- The Journal of Physical Chemistry C, Vol. 120, Issue 38
Synergistic Impact of Solvent and Polymer Additives on the Film Formation of Small Molecule Blend Films for Bulk Heterojunction Solar Cells
journal, July 2015
- McDowell, Caitlin; Abdelsamie, Maged; Zhao, Kui
- Advanced Energy Materials, Vol. 5, Issue 18
Ternary Blend Composed of Two Organic Donors and One Acceptor for Active Layer of High-Performance Organic Solar Cells
journal, April 2016
- Lee, Jong Won; Choi, Yoon Suk; Ahn, Hyungju
- ACS Applied Materials & Interfaces, Vol. 8, Issue 17
High Performance Organic Solar Cells Processed by Blade Coating in Air from a Benign Food Additive Solution
journal, October 2016
- Ye, Long; Xiong, Yuan; Yao, Huifeng
- Chemistry of Materials, Vol. 28, Issue 20
Über die Kinetik der Kettenpolymerisationen. V.
journal, May 1939
- Schulz, G. V.
- Zeitschrift für Physikalische Chemie, Vol. 43B, Issue 1
Conjugated Polymer–Small Molecule Alloy Leads to High Efficient Ternary Organic Solar Cells
journal, June 2015
- Zhang, Jianqi; Zhang, Yajie; Fang, Jin
- Journal of the American Chemical Society, Vol. 137, Issue 25
Solution-processed small-molecule solar cells with 6.7% efficiency
journal, November 2011
- Sun, Yanming; Welch, Gregory C.; Leong, Wei Lin
- Nature Materials, Vol. 11, Issue 1, p. 44-48
Modeling Flow Coating of Colloidal Dispersions in the Evaporative Regime: Prediction of Deposit Thickness
journal, December 2016
- Doumenc, Frédéric; Salmon, Jean-Baptiste; Guerrier, Béatrice
- Langmuir, Vol. 32, Issue 51
Optimized “Alloy-Parallel” Morphology of Ternary Organic Solar Cells
journal, February 2016
- Wang, Zaiyu; Zhang, Yajie; Zhang, Jianqi
- Advanced Energy Materials, Vol. 6, Issue 9
Nanocarbon for Oxygen Reduction Electrocatalysis: Dopants, Edges, and Defects
journal, January 2017
- Tang, Cheng; Zhang, Qiang
- Advanced Materials, Vol. 29, Issue 13
An Obvious Improvement in the Performance of Ternary Organic Solar Cells with “Guest” Donor Present at the “Host” Donor/Acceptor Interface
journal, August 2016
- Bi, Peng-Qing; Wu, Bo; Zheng, Fei
- ACS Applied Materials & Interfaces, Vol. 8, Issue 35
Solar Cells: Film Morphology of High Efficiency Solution-Processed Small-Molecule Solar Cells (Adv. Funct. Mater. 40/2013)
journal, October 2013
- Love, John A.; Proctor, Christopher M.; Liu, Jianhua
- Advanced Functional Materials, Vol. 23, Issue 40
Distinguishing the Importance of Fullerene Phase Separation from Polymer Ordering in the Performance of Low Band Gap Polymer:Bis-Fullerene Heterojunctions
journal, September 2014
- Chen, Huipeng; Hsiao, Yu-Che; Chen, Jihua
- Advanced Functional Materials, Vol. 24, Issue 46
Precise Structural Development and its Correlation to Function in Conjugated Polymer: Fullerene Thin Films by Controlled Solvent Annealing
journal, October 2012
- Chen, Huipeng; Hu, Sheng; Zang, Huidong
- Advanced Functional Materials, Vol. 23, Issue 13
Effect of Annealing on Exciton Diffusion in a High Performance Small Molecule Organic Photovoltaic Material
journal, April 2017
- Long, Yun; Hedley, Gordon J.; Ruseckas, Arvydas
- ACS Applied Materials & Interfaces, Vol. 9, Issue 17
Non-Basic High-Performance Molecules for Solution-Processed Organic Solar Cells
journal, June 2012
- van der Poll, Thomas S.; Love, John A.; Nguyen, Thuc-Quyen
- Advanced Materials, Vol. 24, Issue 27
Continuous Convective Assembling of Fine Particles into Two-Dimensional Arrays on Solid Surfaces
journal, January 1996
- Dimitrov, Antony S.; Nagayama, Kuniaki
- Langmuir, Vol. 12, Issue 5
High-Molecular-Weight Insulating Polymers Can Improve the Performance of Molecular Solar Cells
journal, April 2014
- Huang, Ye; Wen, Wen; Mukherjee, Subhrangsu
- Advanced Materials, Vol. 26, Issue 24
Upscaling of polymer solar cell fabrication using full roll-to-roll processing
journal, January 2010
- Krebs, Frederik C.; Tromholt, Thomas; Jørgensen, Mikkel
- Nanoscale, Vol. 2, Issue 6
Creating Controlled Thickness Gradients in Polymer Thin Films via Flowcoating
journal, May 2014
- Davis, Raleigh L.; Jayaraman, Sahana; Chaikin, Paul M.
- Langmuir, Vol. 30, Issue 19
Understanding Morphology Compatibility for High-Performance Ternary Organic Solar Cells
journal, August 2016
- Mai, Jiangquan; Lau, Tsz-Ki; Li, Jun
- Chemistry of Materials, Vol. 28, Issue 17
Guided crystallization of P3HT in ternary blend solar cell based on P3HT:PCPDTBT:PCBM
journal, January 2014
- Gu, Yu; Wang, Cheng; Liu, Feng
- Energy Environ. Sci., Vol. 7, Issue 11
Tuning the Morphology and Performance of Low Bandgap Polymer:Fullerene Heterojunctions via Solvent Annealing in Selective Solvents
journal, May 2014
- Chen, Huipeng; Hsiao, Yu-Che; Hu, Bin
- Advanced Functional Materials, Vol. 24, Issue 32