DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Equilibrium and kinetic studies of sorption of 2.4-dichlorophenol onto 2 mixtures: bamboo biochar plus calcium sulphate (BC) and hydroxyapatite plus bamboo biochar plus calcium sulphate (HBC), in a fluidized bed circulation column

Abstract

Sorption studies were carried out to investigate removal of 2.4-dichlorophenol (2.4-DCP) from aqueous solution in a fluidized bed by two types of adsorbent mixtures: BC (Bamboo char plus Calcium sulphate), and HBC (Hydroxyapatite plus Bamboo char plus Calcium sulphate); both manufactured in ball shape. The main material bamboo char was characterized by FTIR, DTA and SEM. The adsorption experiments were conducted in a fluidized bed circulation column. Adsorption, isotherms and kinetic studies were established under 180 min operating process time, at different initial 2.4-DCP solution concentrations ranging from 5–10 mg/L, and at different flow rates ranging from 0.25–0.75 L/min. The data obtained fitted well for both the Langmuir and Freundlich isotherm models; indicating favorable condition of monolayer adsorption. The kinetics of both adsorbents complies with the pseudo second-order kinetic model. BC was proven a new effective composite and low cost adsorbent which can be applied in the field of wastewater treatment, and it can also play an important role in industry water treatment

Authors:
 [1];  [1]
  1. Prince of Songkla Univ. (Thailand)
Publication Date:
Research Org.:
Prince of Songkla Univ. (Thailand)
Sponsoring Org.:
USDOE
OSTI Identifier:
1378556
Resource Type:
Accepted Manuscript
Journal Name:
Polish Journal of Chemical Technology
Additional Journal Information:
Journal Volume: 18; Journal Issue: 2; Journal ID: ISSN 1509-8117
Publisher:
De Gruyter
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Alamin, Ahmed Hassan, and Kaewsichan, Lupong. Equilibrium and kinetic studies of sorption of 2.4-dichlorophenol onto 2 mixtures: bamboo biochar plus calcium sulphate (BC) and hydroxyapatite plus bamboo biochar plus calcium sulphate (HBC), in a fluidized bed circulation column. United States: N. p., 2016. Web. doi:10.1515/pjct-2016-0030.
Alamin, Ahmed Hassan, & Kaewsichan, Lupong. Equilibrium and kinetic studies of sorption of 2.4-dichlorophenol onto 2 mixtures: bamboo biochar plus calcium sulphate (BC) and hydroxyapatite plus bamboo biochar plus calcium sulphate (HBC), in a fluidized bed circulation column. United States. https://doi.org/10.1515/pjct-2016-0030
Alamin, Ahmed Hassan, and Kaewsichan, Lupong. Thu . "Equilibrium and kinetic studies of sorption of 2.4-dichlorophenol onto 2 mixtures: bamboo biochar plus calcium sulphate (BC) and hydroxyapatite plus bamboo biochar plus calcium sulphate (HBC), in a fluidized bed circulation column". United States. https://doi.org/10.1515/pjct-2016-0030. https://www.osti.gov/servlets/purl/1378556.
@article{osti_1378556,
title = {Equilibrium and kinetic studies of sorption of 2.4-dichlorophenol onto 2 mixtures: bamboo biochar plus calcium sulphate (BC) and hydroxyapatite plus bamboo biochar plus calcium sulphate (HBC), in a fluidized bed circulation column},
author = {Alamin, Ahmed Hassan and Kaewsichan, Lupong},
abstractNote = {Sorption studies were carried out to investigate removal of 2.4-dichlorophenol (2.4-DCP) from aqueous solution in a fluidized bed by two types of adsorbent mixtures: BC (Bamboo char plus Calcium sulphate), and HBC (Hydroxyapatite plus Bamboo char plus Calcium sulphate); both manufactured in ball shape. The main material bamboo char was characterized by FTIR, DTA and SEM. The adsorption experiments were conducted in a fluidized bed circulation column. Adsorption, isotherms and kinetic studies were established under 180 min operating process time, at different initial 2.4-DCP solution concentrations ranging from 5–10 mg/L, and at different flow rates ranging from 0.25–0.75 L/min. The data obtained fitted well for both the Langmuir and Freundlich isotherm models; indicating favorable condition of monolayer adsorption. The kinetics of both adsorbents complies with the pseudo second-order kinetic model. BC was proven a new effective composite and low cost adsorbent which can be applied in the field of wastewater treatment, and it can also play an important role in industry water treatment},
doi = {10.1515/pjct-2016-0030},
journal = {Polish Journal of Chemical Technology},
number = 2,
volume = 18,
place = {United States},
year = {Thu Jun 30 00:00:00 EDT 2016},
month = {Thu Jun 30 00:00:00 EDT 2016}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Citation Metrics:
Cited by: 6 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Use of a Calcium Sulfate–Calcium Phosphate Synthetic Bone Graft Composite in the Surgical Management of Primary Bone Tumors
journal, February 2013


Use of fly ash for the removal of phenol and its analogues from contaminated water
journal, January 2006


Adsorption of Phenol from Aqueous Solution by Hydroxyapatite Nanopowders. Part II: Kinetic, Equilibrium and Thermodynamic Studies
conference, May 2008

  • Lin, Kaili; Pan, Jiayong; Chen, Yiwei
  • 2008 2nd International Conference on Bioinformatics and Biomedical Engineering
  • DOI: 10.1109/ICBBE.2008.1109

Batch adsorption of phenol onto physiochemical-activated coconut shell
journal, January 2009


Removal of 3-chlorophenol from water using rice-straw-based carbon
journal, August 2007


Modeling of the Dynamics Adsorption of Phenol from an Aqueous Solution on Activated Carbon Produced from Olive Stones
journal, January 2013


An In Vivo Comparative Analysis of the Intra-Operative Properties of Injectable Calcium Phosphate/Calcium Sulphate Based Bone Cements
journal, February 2007


Enhanced capture of elemental mercury by bamboo-based sorbents
journal, November 2012


Agricultural solid waste for the removal of organics: adsorption of phenol from water and wastewater by palm seed coat activated carbon
journal, August 2002


Adsorption of uranium from aqueous solution using biochar produced by hydrothermal carbonization
journal, August 2012

  • Zhang, Zhi-bin; Cao, Xiao-hong; Liang, Ping
  • Journal of Radioanalytical and Nuclear Chemistry, Vol. 295, Issue 2
  • DOI: 10.1007/s10967-012-2017-2

Removal of phenol by powdered activated carbon adsorption
journal, January 2013

  • Ma, Yan; Gao, Naiyun; Chu, Wenhai
  • Frontiers of Environmental Science & Engineering, Vol. 7, Issue 2
  • DOI: 10.1007/s11783-012-0479-7

Individual and competitive adsorption of phenol and nickel onto multiwalled carbon nanotubes
journal, May 2015

  • Abdel-Ghani, Nour T.; El-Chaghaby, Ghadir A.; Helal, Farag S.
  • Journal of Advanced Research, Vol. 6, Issue 3
  • DOI: 10.1016/j.jare.2014.06.001

Analysis of adsorption characteristics of 2,4-dichlorophenol from aqueous solutions by activated carbon fiber
journal, June 2007


Retention of Cd, Zn and Co on hydroxyapatite filters
journal, August 2006


Study the adsorption of phenol from aqueous solution on hydroxyapatite nanopowders
journal, January 2009


Ultrasonic desorption of p-chlorophenol from granular activated carbon
journal, February 2005


Removal of residual phenols from coke wastewater by adsorption
journal, August 2007


Adsorption of 2,4-dichlorophenol from aqueous solution onto microwave modified activated carbon: Kinetics and equilibrium
journal, December 2009

  • Zou, Xuequan; Wan, Xiankai; Shi, Huixiang
  • Transactions of Tianjin University, Vol. 15, Issue 6
  • DOI: 10.1007/s12209-009-0071-9

Modelling of simultaneous biosorption of phenol and nickel(II) onto dried aerobic activated sludge
journal, November 2000


Kinetic and isothermal studies on liquid-phase adsorption of 2,4-dichlorophenol by palm pith carbon
journal, March 2007


Adsorption and desorption of phenol on activated carbon and a comparison of isotherm models
journal, February 2006


Adsorption isotherms, kinetics, thermodynamics and desorption studies of 2,4,6-trichlorophenol on oil palm empty fruit bunch-based activated carbon
journal, May 2009


Effects of pH and temperature on isotherm parameters of chlorophenols biosorption to anaerobic granular sludge
journal, July 2007


Adsorption of phenols from wastewater
journal, July 2005


Adsorption of phenols by papermill sludges
journal, August 2002


Adsorption of 4-chlorophenol onto activated carbon prepared from rattan sawdust
journal, May 2008


Works referencing / citing this record:

Engineered biochar from wood apple shell waste for high-efficient removal of toxic phenolic compounds in wastewater
journal, January 2021