A Zinc–Cerium Cell for Energy Storage Using a Sodium‐Ion Exchange Membrane
Abstract
The redox flow battery with a zinc–cerium (Zn–Ce) chemistry has been developed for about 10 years. Under the traditional battery development principle, a Zn–Ce cell has to be operated with an acidic electrolyte to sustain the redox reactions of Ce compounds (Ce(IV) ↔ Ce(III)) at the positive electrode. However, the use of an acidic electrolyte poses a serious corrosion issue on Zn and limits the electrochemical potential of the Zn electrode. Here, a novel Zn–Ce battery is presented with an alkaline electrolyte at the negative electrode side (anolyte) and an acidic electrolyte at the positive electrode side (catholyte). The two different‐pH liquid electrolytes are separated by a sodium‐ion (Na + ‐ion) solid‐electrolyte separator. The Na + ‐ion, shuttling through the solid electrolyte, is not involved in the redox reactions but rather acts as an ionic mediator to sustain the redox reactions at the negative and positive electrodes. Use of an alkaline anolyte not only eliminates the Zn corrosion problem but also enhances the cell voltage of the Zn–Ce system. In addition, the use of a solid electrolyte prevents the crossover of the liquid electrode materials (Ce(IV) or Ce(III)) and circumvents the concerns of Zn dendrite penetration.
- Authors:
-
- Materials Science and Engineering Program and Texas Materials Institute The University of Texas at Austin Austin TX 78712 USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1378389
- Grant/Contract Number:
- DE‐SC0005397
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Advanced Sustainable Systems
- Additional Journal Information:
- Journal Name: Advanced Sustainable Systems Journal Volume: 1 Journal Issue: 9; Journal ID: ISSN 2366-7486
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Yu, Xingwen, and Manthiram, Arumugam. A Zinc–Cerium Cell for Energy Storage Using a Sodium‐Ion Exchange Membrane. Germany: N. p., 2017.
Web. doi:10.1002/adsu.201700082.
Yu, Xingwen, & Manthiram, Arumugam. A Zinc–Cerium Cell for Energy Storage Using a Sodium‐Ion Exchange Membrane. Germany. https://doi.org/10.1002/adsu.201700082
Yu, Xingwen, and Manthiram, Arumugam. Wed .
"A Zinc–Cerium Cell for Energy Storage Using a Sodium‐Ion Exchange Membrane". Germany. https://doi.org/10.1002/adsu.201700082.
@article{osti_1378389,
title = {A Zinc–Cerium Cell for Energy Storage Using a Sodium‐Ion Exchange Membrane},
author = {Yu, Xingwen and Manthiram, Arumugam},
abstractNote = {The redox flow battery with a zinc–cerium (Zn–Ce) chemistry has been developed for about 10 years. Under the traditional battery development principle, a Zn–Ce cell has to be operated with an acidic electrolyte to sustain the redox reactions of Ce compounds (Ce(IV) ↔ Ce(III)) at the positive electrode. However, the use of an acidic electrolyte poses a serious corrosion issue on Zn and limits the electrochemical potential of the Zn electrode. Here, a novel Zn–Ce battery is presented with an alkaline electrolyte at the negative electrode side (anolyte) and an acidic electrolyte at the positive electrode side (catholyte). The two different‐pH liquid electrolytes are separated by a sodium‐ion (Na + ‐ion) solid‐electrolyte separator. The Na + ‐ion, shuttling through the solid electrolyte, is not involved in the redox reactions but rather acts as an ionic mediator to sustain the redox reactions at the negative and positive electrodes. Use of an alkaline anolyte not only eliminates the Zn corrosion problem but also enhances the cell voltage of the Zn–Ce system. In addition, the use of a solid electrolyte prevents the crossover of the liquid electrode materials (Ce(IV) or Ce(III)) and circumvents the concerns of Zn dendrite penetration.},
doi = {10.1002/adsu.201700082},
journal = {Advanced Sustainable Systems},
number = 9,
volume = 1,
place = {Germany},
year = {Wed Jul 26 00:00:00 EDT 2017},
month = {Wed Jul 26 00:00:00 EDT 2017}
}
https://doi.org/10.1002/adsu.201700082
Web of Science
Works referenced in this record:
Cerium-zinc redox flow battery: Positive half-cell electrolyte studies
journal, June 2011
- Xie, Zhipeng; Zhou, Debi; Xiong, Fengjiao
- Journal of Rare Earths, Vol. 29, Issue 6, p. 567-573
Redox potentials and kinetics of the Ce3+/Ce4+ redox reaction and solubility of cerium sulfates in sulfuric acid solutions
journal, July 2002
- Paulenova, A.; Creager, S. E.; Navratil, J. D.
- Journal of Power Sources, Vol. 109, Issue 2
The use of electrolyte redox potential to monitor the Ce(IV)/Ce(III) couple
journal, September 2008
- Trinidad, P.; de León, C. Ponce; Walsh, F. C.
- Journal of Environmental Management, Vol. 88, Issue 4
Impact of electrolyte composition on the performance of the zinc–cerium redox flow battery system
journal, December 2013
- Nikiforidis, Georgios; Berlouis, Léonard; Hall, David
- Journal of Power Sources, Vol. 243
The role of cerium redox state in the SOD mimetic activity of nanoceria
journal, June 2008
- Heckert, Eric G.; Karakoti, Ajay S.; Seal, Sudipta
- Biomaterials, Vol. 29, Issue 18
Effect of Mixed Acid Media on the Positive Side of the Hybrid Zinc-Cerium Redox Flow Battery
journal, September 2014
- Nikiforidis, Georgios; Daoud, Walid A.
- Electrochimica Acta, Vol. 141
Redox flow batteries for the storage of renewable energy: A review
journal, January 2014
- Alotto, Piergiorgio; Guarnieri, Massimo; Moro, Federico
- Renewable and Sustainable Energy Reviews, Vol. 29
Corrosion of the zinc negative electrode of zinc–cerium hybrid redox flow batteries in methanesulfonic acid
journal, August 2014
- Leung, P. K.; Ponce-de-León, C.; Recio, F. J.
- Journal of Applied Electrochemistry, Vol. 44, Issue 9
Long-Life, High-Voltage Acidic Zn-Air Batteries
journal, December 2015
- Li, Longjun; Manthiram, Arumugam
- Advanced Energy Materials, Vol. 6, Issue 5
Inhibition of zinc corrosion in alkali solutions
journal, March 1995
- Ravindran, Visalakshi; Muralidharan, V. S.
- Anti-Corrosion Methods and Materials, Vol. 42, Issue 3
The Development of Zn-Ce Hybrid Redox Flow Batteries for Energy Storage and Their Continuing Challenges
journal, November 2014
- Walsh, Frank C.; Ponce de Léon, Carlos; Berlouis, Len
- ChemPlusChem, Vol. 80, Issue 2
Process Parameters and Kinetics for the Electrochemical Generation of Cerium(IV) Methanesulphonate from Cerium(III) Methanesulphonate
journal, November 2008
- Raju, Thasan; Basha, C. Ahmed
- Industrial & Engineering Chemistry Research, Vol. 47, Issue 22
Zinc deposition and dissolution in methanesulfonic acid onto a carbon composite electrode as the negative electrode reactions in a hybrid redox flow battery
journal, July 2011
- Leung, P. K.; Ponce-de-León, C.; Low, C. T. J.
- Electrochimica Acta, Vol. 56, Issue 18
High-potential zinc–lead dioxide rechargeable cells
journal, September 2012
- Leung, P. K.; Xu, Q.; Zhao, T. S.
- Electrochimica Acta, Vol. 79
A novel flow battery: A lead acid battery based on an electrolyte with soluble lead(II) Part I. Preliminary studies
journal, January 2004
- Hazza, Ahmed; Pletcher, Derek; Wills, Richard
- Physical Chemistry Chemical Physics, Vol. 6, Issue 8, p. 1773-1778
Characterization of a zinc–cerium flow battery
journal, June 2011
- Leung, P.K.; Ponce-de-León, C.; Low, C.T.J.
- Journal of Power Sources, Vol. 196, Issue 11, p. 5174-5185
Redox flow batteries a review
journal, September 2011
- Weber, Adam Z.; Mench, Matthew M.; Meyers, Jeremy P.
- Journal of Applied Electrochemistry, Vol. 41, Issue 10, p. 1137-1164
Investigation of Factors Affecting Performance of the Iron-Redox Battery
journal, January 1981
- Hruska, L. W.
- Journal of The Electrochemical Society, Vol. 128, Issue 1
Ce(III)/Ce(IV) in methanesulfonic acid as the positive half cell of a redox flow battery
journal, February 2011
- Leung, P. K.; Ponce de León, C.; Low, C. T. J.
- Electrochimica Acta, Vol. 56, Issue 5
Redox Species of Redox Flow Batteries: A Review
journal, November 2015
- Pan, Feng; Wang, Qing
- Molecules, Vol. 20, Issue 11
Mass transport and active area of porous Pt/Ti electrodes for the Zn-Ce redox flow battery determined from limiting current measurements
journal, December 2016
- Arenas, Luis F.; León, Carlos Ponce de; Walsh, Frank C.
- Electrochimica Acta, Vol. 221
An electrochemical study on the positive electrode side of the zinc–cerium hybrid redox flow battery
journal, January 2014
- Nikiforidis, Georgios; Berlouis, Léonard; Hall, David
- Electrochimica Acta, Vol. 115
3D-printed porous electrodes for advanced electrochemical flow reactors: A Ni/stainless steel electrode and its mass transport characteristics
journal, April 2017
- Arenas, L. F.; Ponce de León, C.; Walsh, F. C.
- Electrochemistry Communications, Vol. 77
Study of the Ce 3+ /Ce 4+ Redox Couple in Mixed-Acid Media (CH 3 SO 3 H and H 2 SO 4 ) for Redox Flow Battery Application
journal, May 2011
- Xie, Zhipeng; Xiong, Fengjiao; Zhou, Debi
- Energy & Fuels, Vol. 25, Issue 5
A study of different carbon composite materials for the negative half-cell reaction of the zinc cerium hybrid redox flow cell
journal, December 2013
- Nikiforidis, Georgios; Berlouis, Léonard; Hall, David
- Electrochimica Acta, Vol. 113
A study of the Ce(III)/Ce(IV) redox couple for redox flow battery application
journal, September 2002
- Fang, B.
- Electrochimica Acta, Vol. 47, Issue 24
Advanced Redox-Flow Batteries: A Perspective
journal, September 2015
- Perry, Mike L.; Weber, Adam Z.
- Journal of The Electrochemical Society, Vol. 163, Issue 1
A Quinone-Bromide Flow Battery with 1 W/cm2 Power Density
journal, July 2015
- Chen, Qing; Gerhardt, Michael R.; Hartle, Lauren
- Journal of The Electrochemical Society, Vol. 163, Issue 1, p. A5010-A5013
A biomimetic redox flow battery based on flavin mononucleotide
journal, October 2016
- Orita, Akihiro; Verde, Michael G.; Sakai, Masanori
- Nature Communications, Vol. 7, Issue 1
An undivided zinc–cerium redox flow battery operating at room temperature (295 K)
journal, August 2011
- Leung, P. K.; Ponce de León, C.; Walsh, F. C.
- Electrochemistry Communications, Vol. 13, Issue 8
The influence of operational parameters on the performance of an undivided zinc–cerium flow battery
journal, October 2012
- Leung, P. K.; Ponce de Leon, C.; Walsh, F. C.
- Electrochimica Acta, Vol. 80
The developments and challenges of cerium half-cell in zinc–cerium redox flow battery for energy storage
journal, February 2013
- Xie, Zhipeng; Liu, Qingchao; Chang, Zhiwen
- Electrochimica Acta, Vol. 90
Progress in redox flow batteries, remaining challenges and their applications in energy storage
journal, January 2012
- Leung, Puiki; Li, Xiaohong; Ponce de León, Carlos
- RSC Advances, Vol. 2, Issue 27
Corrosion of Zinc as a Function of pH
journal, January 2012
- Thomas, S.; Birbilis, N.; Venkatraman, M. S.
- CORROSION, Vol. 68, Issue 1
Flow Batteries: Current Status and Trends
journal, September 2015
- Soloveichik, Grigorii L.
- Chemical Reviews, Vol. 115, Issue 20
A comparative UV–vis-diffuse reflectance study on the location and interaction of cerium ions in Al- and Zr-pillared montmorillonite clays
journal, January 2005
- Rao, G. Ranga; Mishra, Braja Gopal
- Materials Chemistry and Physics, Vol. 89, Issue 1
The Importance of Cell Geometry and Electrolyte Properties to the Cell Potential of Zn-Ce Hybrid Flow Batteries
journal, November 2015
- Arenas, L. F.; Walsh, F. C.; de León, C. Ponce
- Journal of The Electrochemical Society, Vol. 163, Issue 1
Redox-Flow Batteries: From Metals to Organic Redox-Active Materials
journal, November 2016
- Winsberg, Jan; Hagemann, Tino; Janoschka, Tobias
- Angewandte Chemie International Edition, Vol. 56, Issue 3
Engineering aspects of the design, construction and performance of modular redox flow batteries for energy storage
journal, June 2017
- Arenas, L. F.; Ponce de León, C.; Walsh, F. C.
- Journal of Energy Storage, Vol. 11
Editors' Choice—Electrodeposition of Platinum on Titanium Felt in a Rectangular Channel Flow Cell
journal, December 2016
- Arenas, Luis F.; de León, Carlos Ponce; Boardman, Richard P.
- Journal of The Electrochemical Society, Vol. 164, Issue 2
Electrochemical redox processes involving soluble cerium species
journal, July 2016
- Arenas, L. F.; Ponce de León, C.; Walsh, F. C.
- Electrochimica Acta, Vol. 205
A study of the Ce3+/Ce4+ redox couple in sulfamic acid for redox battery application
journal, November 2012
- Xiong, Fengjiao; Zhou, Debi; Xie, Zhipeng
- Applied Energy, Vol. 99