Understanding Film Formation Morphology and Orientation in High Member 2D Ruddlesden-Popper Perovskites for High-Efficiency Solar Cells
Abstract
Abstract 2D Ruddlesden–Popper (RP) perovskites have recently emerged as promising candidates for hybrid perovskite photovoltaic cells, realizing power‐conversion efficiencies (PCEs) of over 10% with technologically relevant stability. To achieve solar cell performance comparable to the state‐of‐the‐art 3D perovskite cells, it is highly desirable to increase the conductivity and lower the optical bandgap for enhanced near‐IR region absorption by increasing the perovskite slab thickness. Here, the use of the 2D higher member ( n = 5) RP perovskite ( n ‐butyl‐NH 3 ) 2 (MeNH 3 ) 4 Pb 5 I 16 in depositing highly oriented thin films from dimethylformamide/dimethylsulfoxide mixtures using the hot‐casting method is reported. In addition, they exhibit superior environmental stability over thin films of their 3D counterpart. These films are assembled into high‐efficiency solar cells with an open‐circuit voltage of ≈1 V and PCE of up to 10%. This is achieved by fine‐tuning the solvent ratio, crystal growth orientation, and grain size in the thin films. The enhanced performance of the optimized devices is ascribed to the growth of micrometer‐sized grains as opposed to more typically obtained nanometer grain size and highly crystalline, densely packed microstructures with the majority of the inorganic slabs preferentially aligned out ofmore »
- Authors:
-
- Northwestern Univ., Evanston, IL (United States); Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
- Northwestern Univ., Evanston, IL (United States)
- Université Europeénne de Bretagne, INSA, FOTON, Rennes (France)
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC) (United States). Center for Light Energy Activated Redox Processes (LEAP); Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE National Nuclear Security Administration (NNSA)
- OSTI Identifier:
- 1479900
- Alternate Identifier(s):
- OSTI ID: 1378113
- Report Number(s):
- LA-UR-18-30010
Journal ID: ISSN 1614-6832
- Grant/Contract Number:
- AC52-06NA25396; SC0001059
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Energy Materials
- Additional Journal Information:
- Journal Volume: 8; Journal Issue: 1; Journal ID: ISSN 1614-6832
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 14 SOLAR ENERGY; 2D perovskites; microstructure; solar cells; thin films
Citation Formats
Soe, Chan Myae Myae, Nie, Wanyi, Stoumpos, Constantinos C., Tsai, Hsinhan, Blancon, Jean-Christophe, Liu, Fangze, Even, Jacky, Marks, Tobin J., Mohite, Aditya D., and Kanatzidis, Mercouri G. Understanding Film Formation Morphology and Orientation in High Member 2D Ruddlesden-Popper Perovskites for High-Efficiency Solar Cells. United States: N. p., 2017.
Web. doi:10.1002/aenm.201700979.
Soe, Chan Myae Myae, Nie, Wanyi, Stoumpos, Constantinos C., Tsai, Hsinhan, Blancon, Jean-Christophe, Liu, Fangze, Even, Jacky, Marks, Tobin J., Mohite, Aditya D., & Kanatzidis, Mercouri G. Understanding Film Formation Morphology and Orientation in High Member 2D Ruddlesden-Popper Perovskites for High-Efficiency Solar Cells. United States. https://doi.org/10.1002/aenm.201700979
Soe, Chan Myae Myae, Nie, Wanyi, Stoumpos, Constantinos C., Tsai, Hsinhan, Blancon, Jean-Christophe, Liu, Fangze, Even, Jacky, Marks, Tobin J., Mohite, Aditya D., and Kanatzidis, Mercouri G. Fri .
"Understanding Film Formation Morphology and Orientation in High Member 2D Ruddlesden-Popper Perovskites for High-Efficiency Solar Cells". United States. https://doi.org/10.1002/aenm.201700979. https://www.osti.gov/servlets/purl/1479900.
@article{osti_1479900,
title = {Understanding Film Formation Morphology and Orientation in High Member 2D Ruddlesden-Popper Perovskites for High-Efficiency Solar Cells},
author = {Soe, Chan Myae Myae and Nie, Wanyi and Stoumpos, Constantinos C. and Tsai, Hsinhan and Blancon, Jean-Christophe and Liu, Fangze and Even, Jacky and Marks, Tobin J. and Mohite, Aditya D. and Kanatzidis, Mercouri G.},
abstractNote = {Abstract 2D Ruddlesden–Popper (RP) perovskites have recently emerged as promising candidates for hybrid perovskite photovoltaic cells, realizing power‐conversion efficiencies (PCEs) of over 10% with technologically relevant stability. To achieve solar cell performance comparable to the state‐of‐the‐art 3D perovskite cells, it is highly desirable to increase the conductivity and lower the optical bandgap for enhanced near‐IR region absorption by increasing the perovskite slab thickness. Here, the use of the 2D higher member ( n = 5) RP perovskite ( n ‐butyl‐NH 3 ) 2 (MeNH 3 ) 4 Pb 5 I 16 in depositing highly oriented thin films from dimethylformamide/dimethylsulfoxide mixtures using the hot‐casting method is reported. In addition, they exhibit superior environmental stability over thin films of their 3D counterpart. These films are assembled into high‐efficiency solar cells with an open‐circuit voltage of ≈1 V and PCE of up to 10%. This is achieved by fine‐tuning the solvent ratio, crystal growth orientation, and grain size in the thin films. The enhanced performance of the optimized devices is ascribed to the growth of micrometer‐sized grains as opposed to more typically obtained nanometer grain size and highly crystalline, densely packed microstructures with the majority of the inorganic slabs preferentially aligned out of plane to the substrate, as confirmed by X‐ray diffraction and grazing‐incidence wide‐angle X‐ray scattering mapping.},
doi = {10.1002/aenm.201700979},
journal = {Advanced Energy Materials},
number = 1,
volume = 8,
place = {United States},
year = {Fri Sep 01 00:00:00 EDT 2017},
month = {Fri Sep 01 00:00:00 EDT 2017}
}
Web of Science
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- Proceedings of the National Academy of Sciences, Vol. 116, Issue 1
Controllable growth of two-dimensional perovskite microstructures
journal, January 2018
- Fang, Chen; Li, Junze; Wang, Jun
- CrystEngComm, Vol. 20, Issue 41
Tailoring vertical phase distribution of quasi-two-dimensional perovskite films via surface modification of hole-transporting layer
journal, February 2019
- Liu, Tiefeng; Jiang, Youyu; Qin, Minchao
- Nature Communications, Vol. 10, Issue 1
Steric Mixed‐Cation 2D Perovskite as a Methylammonium Locker to Stabilize MAPbI 3
journal, December 2019
- Wang, Xingtao; Wang, Yong; Zhang, Taiyang
- Angewandte Chemie, Vol. 132, Issue 4
Tuning optical/electrical properties of 2D/3D perovskite by the inclusion of aromatic cation
journal, January 2018
- Rodríguez-Romero, Jesús; Clasen Hames, Bruno; Galar, Pavel
- Physical Chemistry Chemical Physics, Vol. 20, Issue 48
Structural and optical properties of 2D Ruddlesden‐Popper perovskite (BA) 2 (FA) n−1 Pb n I 3n+1 compounds for photovoltaic applications
journal, January 2019
- Lan, Chunfeng; Liang, Guangxing; Zhao, Shuai
- Journal of the American Ceramic Society, Vol. 102, Issue 7
Fine Multi‐Phase Alignments in 2D Perovskite Solar Cells with Efficiency over 17% via Slow Post‐Annealing
journal, September 2019
- Wu, Guangbao; Li, Xing; Zhou, Jiyu
- Advanced Materials, Vol. 31, Issue 42
Aligned and Graded Type-II Ruddlesden-Popper Perovskite Films for Efficient Solar Cells
journal, May 2018
- Qing, Jian; Liu, Xiao-Ke; Li, Mingjie
- Advanced Energy Materials, Vol. 8, Issue 21
In Situ 2D Perovskite Formation and the Impact of the 2D/3D Structures on Performance and Stability of Perovskite Solar Cells
journal, May 2019
- de Holanda, Matheus S.; Szostak, Rodrigo; Marchezi, Paulo E.
- Solar RRL, Vol. 3, Issue 9
Unveiling the Importance of Precursor Preparation for Highly Efficient and Stable Phenethylammonium‐Based Perovskite Solar Cells
journal, April 2020
- Lee, Da Seul; Kim, Jincheol; Bing, Jueming
- Solar RRL, Vol. 4, Issue 4
Unveiling the operation mechanism of layered perovskite solar cells
text, January 2019
- M. M., Nahid,; S. J., Stuard,; J., Huang,
- The University of North Carolina at Chapel Hill University Libraries
Attaining High Photovoltaic Efficiency and Stability with Multidimensional Perovskites.
text, January 2018
- Kosasih, Felix; Ducati, Caterina
- Apollo - University of Cambridge Repository
The Second Spacer Cation Assisted Growth of a 2D Perovskite Film with Oriented Large Grain for Highly Efficient and Stable Solar Cells
journal, May 2019
- Lian, Xiaomei; Chen, Jiehuan; Qin, Minchao
- Angewandte Chemie, Vol. 131, Issue 28
Design principles for electronic charge transport in solution-processed vertically stacked 2D perovskite quantum wells
journal, May 2018
- Tsai, Hsinhan; Asadpour, Reza; Blancon, Jean-Christophe
- Nature Communications, Vol. 9, Issue 1
Tailoring vertical phase distribution of quasi-two-dimensional perovskite films via surface modification of hole-transporting layer
journal, February 2019
- Liu, Tiefeng; Jiang, Youyu; Qin, Minchao
- Nature Communications, Vol. 10, Issue 1
Unveiling the operation mechanism of layered perovskite solar cells
journal, March 2019
- Lin, Yun; Fang, Yanjun; Zhao, Jingjing
- Nature Communications, Vol. 10, Issue 1
Templated growth of oriented layered hybrid perovskites on 3D-like perovskites
journal, January 2020
- Wang, Jifei; Luo, Shiqiang; Lin, Yun
- Nature Communications, Vol. 11, Issue 1