Janus structured Pt–FeNC nanoparticles as a catalyst for the oxygen reduction reaction
Abstract
Here, we present a new Janus structured catalyst consisting of Pt nanoparticles on Fe–N–C nanoparticles encapsulated by graphene layers for the ORR. The ORR activity of the catalyst increases under potential cycling as the unique Janus nanostructure is further bonded due to a synergetic effect. The present study describes an important advanced approach for the future design of efficient, stable, and low-cost Pt-based electrocatalytic systems.
- Authors:
-
- Brookhaven National Lab. (BNL), Upton, NY (United States); Columbia Univ., New York, NY (United States)
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Brookhaven National Lab. (BNL), Upton, NY (United States); Korea Institute of Energy Research, Daejeon (South Korea)
- Publication Date:
- Research Org.:
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1377060
- Report Number(s):
- BNL-114210-2017-JA
Journal ID: ISSN 1359-7345; CHCOFS; R&D Project: MA510MAEA; KC0302010
- Grant/Contract Number:
- SC00112704
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ChemComm
- Additional Journal Information:
- Journal Volume: 53; Journal Issue: 10; Journal ID: ISSN 1359-7345
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 30 DIRECT ENERGY CONVERSION
Citation Formats
Kuttiyiel, Kurian A., Sasaki, Kotaro, Park, Gu -Gon, Vukmirovic, Miomir B., Wu, Lijun, Zhu, Yimei, Chen, Jingguang G., and Adzic, Radoslav R. Janus structured Pt–FeNC nanoparticles as a catalyst for the oxygen reduction reaction. United States: N. p., 2017.
Web. doi:10.1039/C6CC08709D.
Kuttiyiel, Kurian A., Sasaki, Kotaro, Park, Gu -Gon, Vukmirovic, Miomir B., Wu, Lijun, Zhu, Yimei, Chen, Jingguang G., & Adzic, Radoslav R. Janus structured Pt–FeNC nanoparticles as a catalyst for the oxygen reduction reaction. United States. https://doi.org/10.1039/C6CC08709D
Kuttiyiel, Kurian A., Sasaki, Kotaro, Park, Gu -Gon, Vukmirovic, Miomir B., Wu, Lijun, Zhu, Yimei, Chen, Jingguang G., and Adzic, Radoslav R. Tue .
"Janus structured Pt–FeNC nanoparticles as a catalyst for the oxygen reduction reaction". United States. https://doi.org/10.1039/C6CC08709D. https://www.osti.gov/servlets/purl/1377060.
@article{osti_1377060,
title = {Janus structured Pt–FeNC nanoparticles as a catalyst for the oxygen reduction reaction},
author = {Kuttiyiel, Kurian A. and Sasaki, Kotaro and Park, Gu -Gon and Vukmirovic, Miomir B. and Wu, Lijun and Zhu, Yimei and Chen, Jingguang G. and Adzic, Radoslav R.},
abstractNote = {Here, we present a new Janus structured catalyst consisting of Pt nanoparticles on Fe–N–C nanoparticles encapsulated by graphene layers for the ORR. The ORR activity of the catalyst increases under potential cycling as the unique Janus nanostructure is further bonded due to a synergetic effect. The present study describes an important advanced approach for the future design of efficient, stable, and low-cost Pt-based electrocatalytic systems.},
doi = {10.1039/C6CC08709D},
journal = {ChemComm},
number = 10,
volume = 53,
place = {United States},
year = {Tue Jan 03 00:00:00 EST 2017},
month = {Tue Jan 03 00:00:00 EST 2017}
}
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Works referenced in this record:
Enhancement of the oxygen reduction on nitride stabilized pt-M (M=Fe, Co, and Ni) core–shell nanoparticle electrocatalysts
journal, April 2015
- Kuttiyiel, Kurian A.; Choi, YongMan; Hwang, Sun-Mi
- Nano Energy, Vol. 13
Structurally ordered intermetallic platinum–cobalt core–shell nanoparticles with enhanced activity and stability as oxygen reduction electrocatalysts
journal, October 2012
- Wang, Deli; Xin, Huolin L.; Hovden, Robert
- Nature Materials, Vol. 12, Issue 1, p. 81-87
Identification of catalytic sites for oxygen reduction in iron- and nitrogen-doped graphene materials
journal, August 2015
- Zitolo, Andrea; Goellner, Vincent; Armel, Vanessa
- Nature Materials, Vol. 14, Issue 9
A review on non-precious metal electrocatalysts for PEM fuel cells
journal, January 2011
- Chen, Zhongwei; Higgins, Drew; Yu, Aiping
- Energy & Environmental Science, Vol. 4, Issue 9
Symmetric and Asymmetric Au–AgCdSe Hybrid Nanorods
journal, September 2012
- Liang, Shan; Liu, Xiao-Li; Yang, Yue-Zhou
- Nano Letters, Vol. 12, Issue 10
Structure of Fe–N x –C Defects in Oxygen Reduction Reaction Catalysts from First-Principles Modeling
journal, June 2014
- Holby, Edward F.; Wu, Gang; Zelenay, Piotr
- The Journal of Physical Chemistry C, Vol. 118, Issue 26
Minimizing Operando Demetallation of Fe-N-C Electrocatalysts in Acidic Medium
journal, April 2016
- Choi, Chang Hyuck; Baldizzone, Claudio; Polymeros, George
- ACS Catalysis, Vol. 6, Issue 5
Hybrid Colloidal Heterostructures of Anisotropic Semiconductor Nanocrystals Decorated with Noble Metals: Synthesis and Function
journal, April 2011
- Vaneski, Aleksandar; Susha, Andrei S.; Rodríguez-Fernández, Jessica
- Advanced Functional Materials, Vol. 21, Issue 9, p. 1547-1556
Highly Crystalline Multimetallic Nanoframes with Three-Dimensional Electrocatalytic Surfaces
journal, February 2014
- Chen, C.; Kang, Y.; Huo, Z.
- Science, Vol. 343, Issue 6177
Effect of Surface Composition on Electronic Structure, Stability, and Electrocatalytic Properties of Pt-Transition Metal Alloys: Pt-Skin versus Pt-Skeleton Surfaces
journal, July 2006
- Stamenkovic, Vojislav R.; Mun, Bongjin Simon; Mayrhofer, Karl J. J.
- Journal of the American Chemical Society, Vol. 128, Issue 27
Increased Metal Utilization in Carbon-Supported Pt Catalysts by Adsorption of Preformed Pt Nanoparticles on Colloidal Silica
journal, August 2007
- Zeng, J.; Lee, J. Y.; Chen, J.
- Fuel Cells, Vol. 7, Issue 4
Enhanced Oxygen Reduction Activity of IrCu Core Platinum Monolayer Shell Nano-electrocatalysts
journal, June 2013
- Choi, YongMan; Kuttiyiel, Kurian A.; Labis, Joselito P.
- Topics in Catalysis, Vol. 56, Issue 12
A density functional theory study of catalytic sites for oxygen reduction in Fe/N/C catalysts used in H2/O2 fuel cells
journal, January 2014
- Szakacs, Csaba E.; Lefèvre, Michel; Kramm, Ulrike I.
- Physical Chemistry Chemical Physics, Vol. 16, Issue 27
Graphene Oxide-Assisted Synthesis of Pt-Co Alloy Nanocrystals with High-Index Facets and Enhanced Electrocatalytic Properties
journal, December 2015
- Qin, Yuchen; Zhang, Xin; Dai, Xiaoping
- Small, Vol. 12, Issue 4
Activity Descriptor Identification for Oxygen Reduction on Nonprecious Electrocatalysts: Linking Surface Science to Coordination Chemistry
journal, October 2013
- Ramaswamy, Nagappan; Tylus, Urszula; Jia, Qingying
- Journal of the American Chemical Society, Vol. 135, Issue 41
Hybrid Semiconductor–Metal Nanoparticles: From Architecture to Function
journal, September 2013
- Banin, Uri; Ben-Shahar, Yuval; Vinokurov, Kathy
- Chemistry of Materials, Vol. 26, Issue 1
Hydrogenated Uniform Pt Clusters Supported on Porous CaMnO 3 as a Bifunctional Electrocatalyst for Enhanced Oxygen Reduction and Evolution
journal, December 2013
- Han, Xiaopeng; Cheng, Fangyi; Zhang, Tianran
- Advanced Materials, Vol. 26, Issue 13
High voltage stability of nanostructured thin film catalysts for PEM fuel cells
journal, October 2006
- Debe, Mark K.; Schmoeckel, Alison K.; Vernstrom, George D.
- Journal of Power Sources, Vol. 161, Issue 2
Enhanced Catalytic Performance of Pt-Free Iron Phthalocyanine by Graphene Support for Efficient Oxygen Reduction Reaction
journal, April 2013
- Jiang, Yuanyuan; Lu, Yizhong; Lv, Xiangyu
- ACS Catalysis, Vol. 3, Issue 6
Determination of the kinetic parameters of the oxygen reduction reaction using the rotating ring-disk electrode
journal, August 1987
- Anastasijević, N. A.; Vesović, V.; Adžić, R. R.
- Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 229, Issue 1-2
PEM fuel cell electrocatalysts based on transition metal macrocyclic compounds
journal, May 2016
- Liu, Yuyu; Yue, Xiuping; Li, Kaixi
- Coordination Chemistry Reviews, Vol. 315
Pt Skin on AuCu Intermetallic Substrate: A Strategy to Maximize Pt Utilization for Fuel Cells
journal, June 2014
- Wang, Gongwei; Huang, Bing; Xiao, Li
- Journal of the American Chemical Society, Vol. 136, Issue 27
Iron-based cathode catalyst with enhanced power density in polymer electrolyte membrane fuel cells
journal, August 2011
- Proietti, Eric; Jaouen, Frédéric; Lefèvre, Michel
- Nature Communications, Vol. 2, Issue 1
Aqueous phase synthesis and characterizations of Pt nanoparticles by a modified citrate reduction method assisted by inorganic salt stabilization for PEMFCs
journal, July 2014
- Hou, Zhaohui; Li, Muwu; Han, Mingjia
- Electrochimica Acta, Vol. 134
Iron-Based Catalysts with Improved Oxygen Reduction Activity in Polymer Electrolyte Fuel Cells
journal, April 2009
- Lefèvre, Michel; Proietti, Eric; Jaouen, Frédéric
- Science, Vol. 324, Issue 5923, p. 71-74
Structural parameters of supported fuel cell catalysts: The effect of particle size, inter-particle distance and metal loading on catalytic activity and fuel cell performance
journal, February 2016
- Antolini, Ermete
- Applied Catalysis B: Environmental, Vol. 181
Works referencing / citing this record:
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journal, October 2018
- Zhang, Lingyu; Li, Shengnan; Chen, Xiangjun
- Advanced Functional Materials, Vol. 28, Issue 51
Penta-coordinated transition metal macrocycles as electrocatalysts for the oxygen reduction reaction
journal, January 2020
- Govan, Joseph; Orellana, Walter; Zagal, José H.
- Journal of Solid State Electrochemistry
Nanoammonium salt: a novel and recyclable organocatalyst for one-pot three-component synthesis of 2-amino-3-cyano-4H-pyran derivatives
journal, May 2017
- Honarmand, Moones; Naeimi, Atena; Zahedifar, Mahboobeh
- Journal of the Iranian Chemical Society, Vol. 14, Issue 9