Quantitative Analysis of the Morphology of {101} and {001} Faceted Anatase TiO2 Nanocrystals and Its Implication on Photocatalytic Activity
Abstract
The atomistic structure and morphology (shape and size) of nanomaterials have strong influences on their physical and chemical properties. However, many characterization techniques focus exclusively on one length-scale regime or another when developing quantitative morphology/structural models. In this article, we demonstrate that powder X-ray diffraction and neutron pair distribution function (PDF) can be used to obtain accurate average morphology and atomistic structure of {001} and {101} faceted anatase TiO2 nanocrystals based on differential evolution refinements using Debye scattering equation calculations. It is also demonstrated that the morphology polydispersity of TiO2 nanocrystals can be effectively obtained from the diffraction data via a numerical refinement routine. The morphology refinement results are in good agreement with those from transmission electron microscopy and the modeling of small angle neutron scattering data. This method is successfully used to quantify the facet-specified photocatalytic hydrogen evolution activity of anatase TiO2 nanocrystals with different {001} to {101} ratios. It is found that the sample with an intermediate amount of both {001} and {101} facets shows the best photocatalytic hydrogen evolution reaction (HER) activity. As a result, it is expected that the simultaneous structure and morphology refinement technique can be generally used to study the relationship between morphology andmore »
- Authors:
-
[1];
[1];
[2];
[1];
[1]
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Univ. of Kentucky, Lexington, KY (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1376372
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Chemistry of Materials
- Additional Journal Information:
- Journal Volume: 29; Journal Issue: 13; Journal ID: ISSN 0897-4756
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Liu, Jue, Olds, Daniel, Peng, Rui, Yu, Lei, Foo, Guo Shiou, Qian, Shuo, Keum, Jong, Guiton, Beth S., Wu, Zili, and Page, Katharine. Quantitative Analysis of the Morphology of {101} and {001} Faceted Anatase TiO2 Nanocrystals and Its Implication on Photocatalytic Activity. United States: N. p., 2017.
Web. doi:10.1021/acs.chemmater.7b01172.
Liu, Jue, Olds, Daniel, Peng, Rui, Yu, Lei, Foo, Guo Shiou, Qian, Shuo, Keum, Jong, Guiton, Beth S., Wu, Zili, & Page, Katharine. Quantitative Analysis of the Morphology of {101} and {001} Faceted Anatase TiO2 Nanocrystals and Its Implication on Photocatalytic Activity. United States. https://doi.org/10.1021/acs.chemmater.7b01172
Liu, Jue, Olds, Daniel, Peng, Rui, Yu, Lei, Foo, Guo Shiou, Qian, Shuo, Keum, Jong, Guiton, Beth S., Wu, Zili, and Page, Katharine. Wed .
"Quantitative Analysis of the Morphology of {101} and {001} Faceted Anatase TiO2 Nanocrystals and Its Implication on Photocatalytic Activity". United States. https://doi.org/10.1021/acs.chemmater.7b01172. https://www.osti.gov/servlets/purl/1376372.
@article{osti_1376372,
title = {Quantitative Analysis of the Morphology of {101} and {001} Faceted Anatase TiO2 Nanocrystals and Its Implication on Photocatalytic Activity},
author = {Liu, Jue and Olds, Daniel and Peng, Rui and Yu, Lei and Foo, Guo Shiou and Qian, Shuo and Keum, Jong and Guiton, Beth S. and Wu, Zili and Page, Katharine},
abstractNote = {The atomistic structure and morphology (shape and size) of nanomaterials have strong influences on their physical and chemical properties. However, many characterization techniques focus exclusively on one length-scale regime or another when developing quantitative morphology/structural models. In this article, we demonstrate that powder X-ray diffraction and neutron pair distribution function (PDF) can be used to obtain accurate average morphology and atomistic structure of {001} and {101} faceted anatase TiO2 nanocrystals based on differential evolution refinements using Debye scattering equation calculations. It is also demonstrated that the morphology polydispersity of TiO2 nanocrystals can be effectively obtained from the diffraction data via a numerical refinement routine. The morphology refinement results are in good agreement with those from transmission electron microscopy and the modeling of small angle neutron scattering data. This method is successfully used to quantify the facet-specified photocatalytic hydrogen evolution activity of anatase TiO2 nanocrystals with different {001} to {101} ratios. It is found that the sample with an intermediate amount of both {001} and {101} facets shows the best photocatalytic hydrogen evolution reaction (HER) activity. As a result, it is expected that the simultaneous structure and morphology refinement technique can be generally used to study the relationship between morphology and functionality of nanomaterials.},
doi = {10.1021/acs.chemmater.7b01172},
journal = {Chemistry of Materials},
number = 13,
volume = 29,
place = {United States},
year = {Wed Jun 14 00:00:00 EDT 2017},
month = {Wed Jun 14 00:00:00 EDT 2017}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 58 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Amorphous Molybdenum Phosphide Nanoparticles for Electrocatalytic Hydrogen Evolution
journal, August 2014
- McEnaney, Joshua M.; Crompton, J. Chance; Callejas, Juan F.
- Chemistry of Materials, Vol. 26, Issue 16
Synthesis of Highly Monodisperse Citrate-Stabilized Silver Nanoparticles of up to 200 nm: Kinetic Control and Catalytic Properties
journal, April 2014
- Bastús, Neus G.; Merkoçi, Florind; Piella, Jordi
- Chemistry of Materials, Vol. 26, Issue 9
Graphene-Wrapped Fe3O4 Anode Material with Improved Reversible Capacity and Cyclic Stability for Lithium Ion Batteries
journal, September 2010
- Zhou, Guangmin; Wang, Da-Wei; Li, Feng
- Chemistry of Materials, Vol. 22, Issue 18, p. 5306-5313
Nanomaterials for Rechargeable Lithium Batteries
journal, April 2008
- Bruce, Peter G.; Scrosati, Bruno; Tarascon, Jean-Marie
- Angewandte Chemie International Edition, Vol. 47, Issue 16, p. 2930-2946
Titanium Dioxide Nanomaterials: Synthesis, Properties, Modifications, and Applications
journal, July 2007
- Chen, Xiaobo; Mao, Samuel S.
- Chemical Reviews, Vol. 107, Issue 7
Seed-Mediated Growth of Anatase TiO 2 Nanocrystals with Core–Antenna Structures for Enhanced Photocatalytic Activity
journal, August 2015
- Liu, Yiding; Tang, Aiwei; Zhang, Qiao
- Journal of the American Chemical Society, Vol. 137, Issue 35
Anatase TiO2 single crystals with a large percentage of reactive facets
journal, May 2008
- Yang, Hua Gui; Sun, Cheng Hua; Qiao, Shi Zhang
- Nature, Vol. 453, Issue 7195
Shaped Pd–Ni–Pt Core-Sandwich-Shell Nanoparticles: Influence of Ni Sandwich Layers on Catalytic Electrooxidations
journal, June 2014
- Sneed, Brian T.; Young, Allison P.; Jalalpoor, Daniel
- ACS Nano, Vol. 8, Issue 7
Ligand-Mediated Synthesis of Shape-Controlled Cesium Lead Halide Perovskite Nanocrystals via Reprecipitation Process at Room Temperature
journal, February 2016
- Sun, Shibin; Yuan, Dan; Xu, Yuan
- ACS Nano, Vol. 10, Issue 3
Construction of Evolutionary Tree for Morphological Engineering of Nanoparticles
journal, July 2009
- Sohn, Kwonnam; Kim, Franklin; Pradel, Ken C.
- ACS Nano, Vol. 3, Issue 8
Direct Electrodeposition of Tetrahexahedral Pd Nanocrystals with High-Index Facets and High Catalytic Activity for Ethanol Electrooxidation
journal, June 2010
- Tian, Na; Zhou, Zhi-You; Yu, Neng-Fei
- Journal of the American Chemical Society, Vol. 132, Issue 22, p. 7580-7581
Synthesis of Tetrahexahedral Platinum Nanocrystals with High-Index Facets and High Electro-Oxidation Activity
journal, May 2007
- Tian, N.; Zhou, Z. -Y.; Sun, S. -G.
- Science, Vol. 316, Issue 5825, p. 732-735
Shape Control of Semiconductor and Metal Oxide Nanocrystals through Nonhydrolytic Colloidal Routes
journal, May 2006
- Jun, Young-wook; Choi, Jin-sil; Cheon, Jinwoo
- Angewandte Chemie International Edition, Vol. 45, Issue 21
Colloidal nanocrystal synthesis and the organic–inorganic interface
journal, September 2005
- Yin, Yadong; Alivisatos, A. Paul
- Nature, Vol. 437, Issue 7059, p. 664-670
The Morphology of TiO 2 (B) Nanoparticles
journal, October 2015
- Hua, Xiao; Liu, Zheng; Bruce, Peter G.
- Journal of the American Chemical Society, Vol. 137, Issue 42
The Shape of TiO 2 -B Nanoparticles
journal, April 2014
- Andreev, Yuri G.; Panchmatia, Pooja M.; Liu, Zheng
- Journal of the American Chemical Society, Vol. 136, Issue 17
Particle size distributions from small-angle scattering using global scattering functions
journal, July 2004
- Beaucage, G.; Kammler, H. K.; Pratsinis, S. E.
- Journal of Applied Crystallography, Vol. 37, Issue 4
Experimental evidence for quasimelting in small particles
journal, July 1989
- Ajayan, P. M.; Marks, L. D.
- Physical Review Letters, Vol. 63, Issue 3
GaN:ZnO Solid Solution as a Photocatalyst for Visible-Light-Driven Overall Water Splitting
journal, June 2005
- Maeda, Kazuhiko; Takata, Tsuyoshi; Hara, Michikazu
- Journal of the American Chemical Society, Vol. 127, Issue 23
Ferroelectric order in individual nanometre-scale crystals
journal, July 2012
- Polking, Mark J.; Han, Myung-Geun; Yourdkhani, Amin
- Nature Materials, Vol. 11, Issue 8
A profile refinement method for nuclear and magnetic structures
journal, June 1969
- Rietveld, H. M.
- Journal of Applied Crystallography, Vol. 2, Issue 2, p. 65-71
Rietveld refinement of Debye–Scherrer synchrotron X-ray data from Al 2 O 3
journal, April 1987
- Thompson, P.; Cox, D. E.; Hastings, J. B.
- Journal of Applied Crystallography, Vol. 20, Issue 2
Rietveld refinement with spallation neutron powder diffraction data
journal, December 1982
- Von Dreele, R. B.; Jorgensen, J. D.; Windsor, C. G.
- Journal of Applied Crystallography, Vol. 15, Issue 6
Eine quantitative Prüfung der Theorie für die Interferenzerscheinungen bei Röntgenstrahlen
journal, January 1913
- Laue, M.
- Annalen der Physik, Vol. 346, Issue 10
Bestimmung der inneren Struktur und der Größe von Kolloidteilchen mittels Röntgenstrahlen
book, January 1912
- Scherrer, P.
- Kolloidchemie Ein Lehrbuch
Scherrer after sixty years: A survey and some new results in the determination of crystallite size
journal, April 1978
- Langford, J. I.; Wilson, A. J. C.
- Journal of Applied Crystallography, Vol. 11, Issue 2
The Effect of Cold‐Work Distortion on X‐Ray Patterns
journal, June 1950
- Warren, B. E.; Averbach, B. L.
- Journal of Applied Physics, Vol. 21, Issue 6
Whole powder pattern modelling
journal, February 2002
- Scardi, P.; Leoni, M.
- Acta Crystallographica Section A Foundations of Crystallography, Vol. 58, Issue 2
Debye function analysis of structure in diffraction from nanometer-sized particles
journal, February 2000
- Hall, B. D.
- Journal of Applied Physics, Vol. 87, Issue 4
Zerstreuung von Röntgenstrahlen
journal, January 1915
- Debye, P.
- Annalen der Physik, Vol. 351, Issue 6
Nonaqueous Synthesis of TiO 2 Nanocrystals Using TiF 4 to Engineer Morphology, Oxygen Vacancy Concentration, and Photocatalytic Activity
journal, April 2012
- Gordon, Thomas R.; Cargnello, Matteo; Paik, Taejong
- Journal of the American Chemical Society, Vol. 134, Issue 15
Crystal symmetry breaking and vacancies in colloidal lead chalcogenide quantum dots
journal, June 2016
- Bertolotti, Federica; Dirin, Dmitry N.; Ibáñez, Maria
- Nature Materials, Vol. 15, Issue 9
Unraveling Atomic Positions in an Oxide Spinel with Two Jahn−Teller Ions: Local Structure Investigation of CuMn 2 O 4
journal, August 2009
- Shoemaker, Daniel P.; Li, Jun; Seshadri, Ram
- Journal of the American Chemical Society, Vol. 131, Issue 32
Local Atomic Ordering in BaTaO 2 N Studied by Neutron Pair Distribution Function Analysis and Density Functional Theory
journal, August 2007
- Page, Katharine; Stoltzfus, Matthew W.; Kim, Young-Il
- Chemistry of Materials, Vol. 19, Issue 16
Building and refining complete nanoparticle structures with total scattering data
journal, February 2011
- Page, Katharine; Hood, Taylor C.; Proffen, Thomas
- Journal of Applied Crystallography, Vol. 44, Issue 2
Nanoscale Ni/Mn Ordering in the High Voltage Spinel Cathode LiNi 0.5 Mn 1.5 O 4
journal, September 2016
- Liu, Jue; Huq, Ashfia; Moorhead-Rosenberg, Zachary
- Chemistry of Materials, Vol. 28, Issue 19
Relationship between the atomic pair distribution function and small-angle scattering: implications for modeling of nanoparticles
journal, April 2009
- Farrow, Christopher L.; Billinge, Simon J. L.
- Acta Crystallographica Section A Foundations of Crystallography, Vol. 65, Issue 3, p. 232-239
Influence of neglected small-angle scattering in radial distribution function analysis
journal, August 1971
- Cargill, G. S.
- Journal of Applied Crystallography, Vol. 4, Issue 4
DShaper : an approach for handling missing low- Q data in pair distribution function analysis of nanostructured systems
journal, October 2015
- Olds, Daniel; Wang, Hsiu-Wen; Page, Katharine
- Journal of Applied Crystallography, Vol. 48, Issue 6
Electrochemical Photolysis of Water at a Semiconductor Electrode
journal, July 1972
- Fujishima, Akira; Honda, Kenichi
- Nature, Vol. 238, Issue 5358, p. 37-38
Reactivity of Anatase TiO 2 Nanoparticles: The Role of the Minority (001) Surface
journal, October 2005
- Gong, Xue-Qing; Selloni, Annabella
- The Journal of Physical Chemistry B, Vol. 109, Issue 42
Structure and energetics of stoichiometric anatase surfaces
journal, March 2001
- Lazzeri, Michele; Vittadini, Andrea; Selloni, Annabella
- Physical Review B, Vol. 63, Issue 15
Anatase shows its reactive side
journal, August 2008
- Selloni, Annabella
- Nature Materials, Vol. 7, Issue 8
The surface science of titanium dioxide
journal, January 2003
- Diebold, Ulrike
- Surface Science Reports, Vol. 48, Issue 5-8
Anatase TiO 2 with Dominant High-Energy {001} Facets: Synthesis, Properties, and Applications
journal, September 2011
- Liu, Shengwei; Yu, Jiaguo; Jaroniec, Mietek
- Chemistry of Materials, Vol. 23, Issue 18
Synthesis of Titania Nanosheets with a High Percentage of Exposed (001) Facets and Related Photocatalytic Properties
journal, March 2009
- Han, Xiguang; Kuang, Qin; Jin, Mingshang
- Journal of the American Chemical Society, Vol. 131, Issue 9
Constructing Hierarchical Spheres from Large Ultrathin Anatase TiO 2 Nanosheets with Nearly 100% Exposed (001) Facets for Fast Reversible Lithium Storage
journal, May 2010
- Chen, Jun Song; Tan, Yi Ling; Li, Chang Ming
- Journal of the American Chemical Society, Vol. 132, Issue 17
On the True Photoreactivity Order of {001}, {010}, and {101} Facets of Anatase TiO2 Crystals
journal, January 2011
- Pan, Jian; Liu, Gang; Lu, Gao Qing Max
- Angewandte Chemie International Edition, Vol. 50, Issue 9
Titanium Dioxide Crystals with Tailored Facets
journal, May 2014
- Liu, Gang; Yang, Hua Gui; Pan, Jian
- Chemical Reviews, Vol. 114, Issue 19
Effect of Fluorination on the Surface Properties of Titania P25 Powder: An FTIR Study
journal, October 2009
- Minella, Marco; Faga, Maria Giulia; Maurino, Valter
- Langmuir, Vol. 26, Issue 4
Hydrothermal Stability of {001} Faceted Anatase TiO 2
journal, August 2011
- Yang, Xiao Hua; Li, Zhen; Sun, Chenghua
- Chemistry of Materials, Vol. 23, Issue 15
DISCUS : a program for diffuse scattering and defect-structure simulation
journal, April 1997
- Proffen, Th.; Neder, R. B.
- Journal of Applied Crystallography, Vol. 30, Issue 2
The Nanoscale Ordered MAterials Diffractometer NOMAD at the Spallation Neutron Source SNS
journal, September 2012
- Neuefeind, Jörg; Feygenson, Mikhail; Carruth, John
- Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 287
Fast synthesis and refinement of the atomic pair distribution function
journal, May 2015
- Coelho, A. A.; Chater, P. A.; Kern, A.
- Journal of Applied Crystallography, Vol. 48, Issue 3
The Bio-SANS instrument at the High Flux Isotope Reactor of Oak Ridge National Laboratory
journal, June 2014
- Heller, William T.; Urban, Volker S.; Lynn, Gary W.
- Journal of Applied Crystallography, Vol. 47, Issue 4
Mantid—Data analysis and visualization package for neutron scattering and SR experiments
journal, November 2014
- Arnold, O.; Bilheux, J. C.; Borreguero, J. M.
- Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 764
Irena : tool suite for modeling and analysis of small-angle scattering
journal, February 2009
- Ilavsky, Jan; Jemian, Peter R.
- Journal of Applied Crystallography, Vol. 42, Issue 2
Small-angle scattering. Information content and error analysis
journal, April 1980
- Moore, P. B.
- Journal of Applied Crystallography, Vol. 13, Issue 2
Efficient algorithms for calculating small-angle scattering from large model structures
journal, May 2014
- Olds, Daniel P.; Duxbury, Phillip M.
- Journal of Applied Crystallography, Vol. 47, Issue 3
NIH Image to ImageJ: 25 years of image analysis
journal, June 2012
- Schneider, Caroline A.; Rasband, Wayne S.; Eliceiri, Kevin W.
- Nature Methods, Vol. 9, Issue 7
Prediction of TiO 2 Nanoparticle Phase and Shape Transitions Controlled by Surface Chemistry
journal, July 2005
- Barnard, A. S.; Curtiss, L. A.
- Nano Letters, Vol. 5, Issue 7
X-ray line broadening from filed aluminium and wolfram
journal, January 1953
- Williamson, G. K.; Hall, W. H.
- Acta Metallurgica, Vol. 1, Issue 1
A fundamental parameters approach to X-ray line-profile fitting
journal, April 1992
- Cheary, R. W.; Coelho, A.
- Journal of Applied Crystallography, Vol. 25, Issue 2
Size, Shape, and Internal Atomic Ordering of Nanocrystals by Atomic Pair Distribution Functions: A Comparative Study of γ-Fe 2 O 3 Nanosized Spheres and Tetrapods
journal, October 2009
- Petkov, Valeri; Cozzoli, P. Davide; Buonsanti, Raffaella
- Journal of the American Chemical Society, Vol. 131, Issue 40
Differential Evolution – A Simple and Efficient Heuristic for global Optimization over Continuous Spaces
journal, January 1997
- Storn, Rainer; Price, Kenneth
- Journal of Global Optimization, Vol. 11, Issue 4, p. 341-359
Estimating grain-size distributions in nanocrystalline materials from X-ray diffraction profile analysis
journal, March 1998
- Kril, C. E.; Birringer, R.
- Philosophical Magazine A, Vol. 77, Issue 3
A total scattering Debye function analysis study of faulted Pt nanocrystals embedded in a porous matrix
journal, October 2016
- Bertolotti, Federica; Moscheni, Daniele; Migliori, Andrea
- Acta Crystallographica Section A Foundations and Advances, Vol. 72, Issue 6
Crossing the boundary between face-centred cubic and hexagonal close packed: the structure of nanosized cobalt is unraveled by a model accounting for shape, size distribution and stacking faults, allowing simulation of XRD, XANES and EXAFS
journal, September 2014
- Longo, Alessandro; Sciortino, Luisa; Giannici, Francesco
- Journal of Applied Crystallography, Vol. 47, Issue 5
DEBUSSY 2.0 : the new release of a Debye user system for nanocrystalline and/or disordered materials
journal, November 2015
- Cervellino, Antonio; Frison, Ruggero; Bertolotti, Federica
- Journal of Applied Crystallography, Vol. 48, Issue 6
DEBUSSY : a Debye user system for nanocrystalline materials
journal, November 2010
- Cervellino, Antonio; Giannini, Cinzia; Guagliardi, Antonietta
- Journal of Applied Crystallography, Vol. 43, Issue 6
Magnetite–Maghemite Nanoparticles in the 5–15 nm Range: Correlating the Core–Shell Composition and the Surface Structure to the Magnetic Properties. A Total Scattering Study.
journal, November 2013
- Frison, Ruggero; Cernuto, Giuseppe; Cervellino, Antonio
- Chemistry of Materials, Vol. 25, Issue 23
Structure of Flame-Made Silica Nanoparticles by Ultra-Small-Angle X-ray Scattering
journal, March 2004
- Kammler, Hendrik K.; Beaucage, Gregory; Mueller, Roger
- Langmuir, Vol. 20, Issue 5
The real origin of lognormal size distributions of nanoparticles in vapor growth processes
journal, January 1999
- Kiss, L. B.; Söderlund, J.; Niklasson, G. A.
- Nanostructured Materials, Vol. 12, Issue 1-4
Evidence for Crystal-Face-Dependent TiO 2 Photocatalysis from Single-Molecule Imaging and Kinetic Analysis
journal, May 2011
- Tachikawa, Takashi; Yamashita, Soichiro; Majima, Tetsuro
- Journal of the American Chemical Society, Vol. 133, Issue 18
Enhanced Photocatalytic CO 2 -Reduction Activity of Anatase TiO 2 by Coexposed {001} and {101} Facets
journal, June 2014
- Yu, Jiaguo; Low, Jingxiang; Xiao, Wei
- Journal of the American Chemical Society, Vol. 136, Issue 25
Direct Observation of Charge Separation on Anatase TiO 2 Crystals with Selectively Etched {001} Facets
journal, February 2016
- Liu, Xiaogang; Dong, Guojun; Li, Shaopeng
- Journal of the American Chemical Society, Vol. 138, Issue 9
Engineering Coexposed {001} and {101} Facets in Oxygen-Deficient TiO 2 Nanocrystals for Enhanced CO 2 Photoreduction under Visible Light
journal, January 2016
- Liu, Lianjun; Jiang, Yuqiu; Zhao, Huilei
- ACS Catalysis, Vol. 6, Issue 2
Synthesis, characterization and enhanced photocatalytic CO 2 reduction activity of graphene supported TiO 2 nanocrystals with coexposed {001} and {101} facets
journal, January 2016
- Xiong, Zhuo; Luo, Ying; Zhao, Yongchun
- Physical Chemistry Chemical Physics, Vol. 18, Issue 19
Methods, Mechanism, and Applications of Photodeposition in Photocatalysis: A Review
journal, December 2016
- Wenderich, Kasper; Mul, Guido
- Chemical Reviews, Vol. 116, Issue 23
Modulating the photocatalytic redox preferences between anatase TiO 2 {001} and {101} surfaces
journal, January 2017
- Zhou, Peng; Zhang, Hongna; Ji, Hongwei
- Chemical Communications, Vol. 53, Issue 4
A selectively exposed crystal facet-engineered TiO 2 thin film photoanode for the higher performance of the photoelectrochemical water splitting reaction
journal, January 2015
- Kim, Chang Woo; Yeob, So Jin; Cheng, Hui-Ming
- Energy & Environmental Science, Vol. 8, Issue 12
Works referencing / citing this record:
Interaction mechanism between TiO 2 nanostructures and bovine leukemia virus proteins in photoluminescence-based immunosensors
journal, January 2018
- Tereshchenko, Alla; Smyntyna, Valentyn; Ramanavicius, Arunas
- RSC Advances, Vol. 8, Issue 66
Engineering the Surface/Interface Structures of Titanium Dioxide Micro and Nano Architectures towards Environmental and Electrochemical Applications
journal, November 2017
- Wang, Xiaoliang; Zhao, Yanyan; Mølhave, Kristian
- Nanomaterials, Vol. 7, Issue 11
The Role of Surface Texture on the Photocatalytic H2 Production on TiO2
journal, January 2019
- Pellegrino, Francesco; Sordello, Fabrizio; Minella, Marco
- Catalysts, Vol. 9, Issue 1
Insight into Different Mechanisms for Oxidation of Liquid and Gaseous Pollutants by Bi−NaBiO 3 with or without Visible Light Illumination
journal, March 2019
- Gong, Jianyu; Chen, Ayan; Wang, Yunyang
- ChemCatChem, Vol. 11, Issue 9
TiO 2 nanocrystals with the {001} and {101} facets co-exposed with MIL-100(Fe): an egg-like composite nanomaterial for efficient visible light-driven photocatalysis
journal, January 2019
- Wu, Wan; Zhu, Jie; Deng, Yue Hong
- RSC Advances, Vol. 9, Issue 54
Understanding structure of small $${\hbox {TiO}}_2$$ nanoparticles and adsorption mechanisms of PbS quantum dots for solid-state applications: a combined theoretical and experimental study
journal, June 2019
- Díaz-Rodríguez, T. G.; Pacio, M.; Agustín-Serrano, R.
- Theoretical Chemistry Accounts, Vol. 138, Issue 7
A suite-level review of the neutron powder diffraction instruments at Oak Ridge National Laboratory
journal, September 2018
- Calder, S.; An, K.; Boehler, R.
- Review of Scientific Instruments, Vol. 89, Issue 9
Engineering the Surface/Interface Structures of Titanium Dioxide Micro and Nano Architectures towards Environmental and Electrochemical Applications
journal, November 2017
- Wang, Xiaoliang; Zhao, Yanyan; Mølhave, Kristian
- Nanomaterials, Vol. 7, Issue 11