Natural Abundance 17O DNP NMR Provides Precise O$-$H Distances and Insights into the Brønsted Acidity of Heterogeneous Catalysts

Perras, Frédéric A.; Wang, Zhuoran; Naik, Pranjali; Slowing, Igor I.; Pruski, Marek

doi:10.1002/ange.201704032

Title: Natural Abundance ¹⁷O DNP NMR Provides Precise O$$-$$H Distances and Insights into the Brønsted Acidity of Heterogeneous Catalysts

Authors:

^[1]; Wang, Zhuoran ^[1]; Naik, Pranjali ^[1];

^[1];

^[1]

U.S. DOE Ames Laboratory, and Department of Chemistry, Iowa State University, Ames IA 50011 USA

Publication Date:: Fri May 12 00:00:00 EDT 2017

Sponsoring Org.:: USDOE

OSTI Identifier:: 1374913

Grant/Contract Number:: AC02-07CH11358; FY2015-MPRU-0812

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Angewandte Chemie

Additional Journal Information:: Journal Name: Angewandte Chemie Journal Volume: 129 Journal Issue: 31; Journal ID: ISSN 0044-8249

Publisher:: German Chemical Society

Country of Publication:: Germany

Language:: English

Citation Formats


                    Perras, Frédéric A., Wang, Zhuoran, Naik, Pranjali, Slowing, Igor I., and Pruski, Marek. Natural Abundance 17O DNP NMR Provides Precise O$-$H Distances and Insights into the Brønsted Acidity of Heterogeneous Catalysts.  Germany: N. p., 2017. 
Web.  doi:10.1002/ange.201704032.

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                    Perras, Frédéric A., Wang, Zhuoran, Naik, Pranjali, Slowing, Igor I., & Pruski, Marek. Natural Abundance 17O DNP NMR Provides Precise O$-$H Distances and Insights into the Brønsted Acidity of Heterogeneous Catalysts.  Germany.  https://doi.org/10.1002/ange.201704032

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                    Perras, Frédéric A., Wang, Zhuoran, Naik, Pranjali, Slowing, Igor I., and Pruski, Marek. Fri .  
"Natural Abundance 17O DNP NMR Provides Precise O$-$H Distances and Insights into the Brønsted Acidity of Heterogeneous Catalysts".  Germany.  https://doi.org/10.1002/ange.201704032.

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@article{osti_1374913,

  title        = {Natural Abundance 17O DNP NMR Provides Precise O$-$H Distances and Insights into the Brønsted Acidity of Heterogeneous Catalysts},

  author       = {Perras, Frédéric A. and Wang, Zhuoran and Naik, Pranjali and Slowing, Igor I. and Pruski, Marek},

  abstractNote = {},

  doi          = {10.1002/ange.201704032},

  journal      = {Angewandte Chemie},

  number       = 31,

  volume       = 129,

  place        = {Germany},

  year         = {Fri May 12 00:00:00 EDT 2017},

  month        = {Fri May 12 00:00:00 EDT 2017}

}

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Title: Natural Abundance ¹⁷O DNP NMR Provides Precise O$$-$$H Distances and Insights into the Brønsted Acidity of Heterogeneous Catalysts

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Measurement of NH Bond Lengths by Fast Magic-Angle Spinning Solid-State NMR Spectroscopy: A New Method for the Quantification of Hydrogen Bonds
journal, November 2001

Measuring Brønsted Acid Site O−H Distances in Zeolites HY and HZSM-5 with Low-Temperature ¹⁷ O− ¹ H Double Resonance MAS NMR Spectroscopy
journal, December 2010

Oxygen-17 dynamic nuclear polarisation enhanced solid-state NMR spectroscopy at 18.8 T
journal, January 2017

Dynamic Nuclear Polarization Surface Enhanced NMR Spectroscopy
journal, March 2013

Natural Abundance ¹⁷ O DNP Two-Dimensional and Surface-Enhanced NMR Spectroscopy
journal, June 2015

A Model for the Surface of γ-Alumina ¹
journal, January 1965

Pyridine- ¹⁵ N A Mobile NMR Sensor for Surface Acidity and Surface Defects of Mesoporous Silica
journal, October 2003

Structure of alumina surfaces
journal, January 1996

¹⁷ O NMR Gives Unprecedented Insights into the Structure of Supported Catalysts and Their Interaction with the Silica Carrier
journal, May 2012

Measurements of motionally averaged heteronuclear dipolar couplings in MAS NMR using R-type recoupling
journal, June 2004

Dynamic Nuclear Polarization of Oxygen-17
journal, July 2012

Heteronuclear polarization transfer by symmetry-based recoupling sequences in solid-state NMR
journal, September 2004

Inorganic Solid Acids and Their Use in Acid-Catalyzed Hydrocarbon Reactions
journal, May 1995

Zero-point-of-charge prediction from crystal chemistry and solvation theory
journal, July 1994

Infrared spectroscopic study of hydroxyl group acid strength of silica, alumina, and magnesia mixed oxides
journal, September 1982

Coking and deactivation of zeolites
journal, September 1989

Ab initio Calculation of the ¹⁷ O and ¹ H NMR Parameters for Various OH Groups: Implications to the Speciation and Dynamics of Dissolved Water in Silicate Glasses
journal, May 2001

Theoretical prediction of single-site surface-protonation equilibrium constants for oxides and silicates in water
journal, October 1996

Magic angle spinning oxygen-17 NMR of aluminum oxides and hydroxides
journal, September 1989

Mutable Lewis and Brønsted Acidity of Aluminated SBA-15 as Revealed by NMR of Adsorbed Pyridine- ¹⁵ N
journal, October 2011

Probing Surface Hydrogen Bonding and Dynamics by Natural Abundance, Multidimensional, ¹⁷ O DNP-NMR Spectroscopy
journal, May 2016

Highly Dispersed SiO _x /Al ₂ O ₃ Catalysts Illuminate the Reactivity of Isolated Silanol Sites
journal, September 2015

Dynamic Nuclear Polarization Solid-State NMR in Heterogeneous Catalysis Research
journal, October 2015

Br⊘nsted Acid Sites in Zeolites Characterized by Multinuclear Solid-State NMR Spectroscopy
journal, November 1997