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Title: Solution properties, unperturbed dimensions, and chain flexibility of poly(1‐adamantyl acrylate)

Abstract

ABSTRACT Poly(1‐adamantyl acrylate) (PAdA) exhibits much higher glass transition and degradation temperatures than other polyacrylates. However, the quantitative evaluation of the stiffness of this polymer chain has not been reported previously. In this study, the dilute solution properties and conformational characteristics of PAdA were evaluated using viscometry and scattering techniques. The unperturbed dimensions of this polymer were evaluated using the Burchard–Stockmayer–Fixman extrapolation and the touched‐bead wormlike chain model. The PAdA chain has a comparable persistence length, diameter per bead and characteristic ratio to poly(methyl methacrylate) and polystyrene. All these results indicate that PAdA is less flexible than common polyacrylates. In addition, the second virial coefficients ( A 2 ) of PAdA in different solvents obtained by static light scattering were compared. Among the solvents investigated, tetrahydrofuran is a moderate solvent. Radius of gyration of a polymer sample in the various solvents ranged from 16.8 to 30.3 nm. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2017 , 55 , 1526–1531

Authors:
 [1];  [2];  [3];  [4];  [1]; ORCiD logo [4];  [1]
+ Show Author Affiliations
  1. Department of Chemistry University of Tennessee Knoxville Tennessee 37996
  2. Chemical and Engineering Materials Division Neutron Sciences Directorate, Oak Ridge National Laboratory Oak Ridge Tennessee, 37831
  3. Department of Chemistry Aichi University of Education Kariya 448‐8542 Japan
  4. Center for Nanophase Materials Sciences, Oak Ridge National Laboratory Oak Ridge Tennessee 37831
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1374776
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Polymer Science. Part B, Polymer Physics
Additional Journal Information:
Journal Name: Journal of Polymer Science. Part B, Polymer Physics Journal Volume: 55 Journal Issue: 20; Journal ID: ISSN 0887-6266
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
United States
Language:
English

Citation Formats

Lu, Wei, Yin, Panchao, Osa, Masashi, Wang, Weiyu, Kang, Nam‐Goo, Hong, Kunlun, and Mays, Jimmy W. Solution properties, unperturbed dimensions, and chain flexibility of poly(1‐adamantyl acrylate). United States: N. p., 2017. Web. doi:10.1002/polb.24408.
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Lu, Wei, Yin, Panchao, Osa, Masashi, Wang, Weiyu, Kang, Nam‐Goo, Hong, Kunlun, & Mays, Jimmy W. Solution properties, unperturbed dimensions, and chain flexibility of poly(1‐adamantyl acrylate). United States. https://doi.org/10.1002/polb.24408
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Lu, Wei, Yin, Panchao, Osa, Masashi, Wang, Weiyu, Kang, Nam‐Goo, Hong, Kunlun, and Mays, Jimmy W. Fri . "Solution properties, unperturbed dimensions, and chain flexibility of poly(1‐adamantyl acrylate)". United States. https://doi.org/10.1002/polb.24408.
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@article{osti_1374776,
title = {Solution properties, unperturbed dimensions, and chain flexibility of poly(1‐adamantyl acrylate)},
author = {Lu, Wei and Yin, Panchao and Osa, Masashi and Wang, Weiyu and Kang, Nam‐Goo and Hong, Kunlun and Mays, Jimmy W.},
abstractNote = {ABSTRACT Poly(1‐adamantyl acrylate) (PAdA) exhibits much higher glass transition and degradation temperatures than other polyacrylates. However, the quantitative evaluation of the stiffness of this polymer chain has not been reported previously. In this study, the dilute solution properties and conformational characteristics of PAdA were evaluated using viscometry and scattering techniques. The unperturbed dimensions of this polymer were evaluated using the Burchard–Stockmayer–Fixman extrapolation and the touched‐bead wormlike chain model. The PAdA chain has a comparable persistence length, diameter per bead and characteristic ratio to poly(methyl methacrylate) and polystyrene. All these results indicate that PAdA is less flexible than common polyacrylates. In addition, the second virial coefficients ( A 2 ) of PAdA in different solvents obtained by static light scattering were compared. Among the solvents investigated, tetrahydrofuran is a moderate solvent. Radius of gyration of a polymer sample in the various solvents ranged from 16.8 to 30.3 nm. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2017 , 55 , 1526–1531},
doi = {10.1002/polb.24408},
journal = {Journal of Polymer Science. Part B, Polymer Physics},
number = 20,
volume = 55,
place = {United States},
year = {Fri Aug 11 00:00:00 EDT 2017},
month = {Fri Aug 11 00:00:00 EDT 2017}
}
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https://doi.org/10.1002/polb.24408
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