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Title: InAlAs photovoltaic cell design for high device efficiency

Journal Article · · Progress in Photovoltaics
DOI: https://doi.org/10.1002/pip.2895 · OSTI ID:1374129

This study presents a new design for a single-junction InAlAs solar cell, which reduces parasitic absorption losses from the low band-gap contact layer while maintaining a functional window layer by integrating a selective etch stop. The etch stop is then removed prior to depositing an anti-reflective coating. The final cell had a 17.9% efficiency under 1-sun AM1.5 with an anti-reflective coating. Minority carrier diffusion lengths were extracted from external quantum efficiency data using physics-based device simulation software yielding 170 nm in the n-type emitter and 4.6 um in the p-type base, which is more than four times the diffusion length previously reported for a p-type InAlAs base. In conclusion, this report represents significant progress towards a high-performance InAlAs top cell for a triple-junction design lattice-matched to InP.

Research Organization:
National Renewable Energy Laboratory (NREL), Golden, CO (United States)
Sponsoring Organization:
USDOE Advanced Research Projects Agency - Energy (ARPA-E)
Grant/Contract Number:
AC36-08GO28308
OSTI ID:
1374129
Report Number(s):
NREL/JA--5K00-69002
Journal Information:
Progress in Photovoltaics, Journal Name: Progress in Photovoltaics Journal Issue: 8 Vol. 25; ISSN 1062-7995
Publisher:
WileyCopyright Statement
Country of Publication:
United States
Language:
English

References (20)

Wafer-Scale Strain Engineering of Ultrathin Semiconductor Crystalline Layers journal July 2011
Surface recombination velocity and lifetime in InP journal January 1991
Refractive indices of InAlAs and InGaAs/InP from 250 to 1900 nm determined by spectroscopic ellipsometry journal January 1992
Series resistance effects on solar cell measurements journal April 1963
Observation of phase separation and ordering in the InAlAs epilayer grown on InP at the low temperature journal October 1999
Band parameters for III–V compound semiconductors and their alloys journal June 2001
Wide-band-gap InAlAs solar cell for an alternative multijunction approach journal February 2011
The effect of growth temperature on the electrical properties of AlInAs/InP grown by molecular beam epitaxy and metal‐organic chemical‐vapor deposition journal December 1993
Towards an optimized all lattice-matched InAlAs/InGaAsP/InGaAs multijunction solar cell with efficiency >50% journal January 2013
InAlAs solar cell on a GaAs substrate employing a graded In x Ga 1−x As–InP metamorphic buffer layer journal January 2013
Compositional dependence of band‐gap energy and conduction‐band effective mass of In 1− xy Ga x Al y As lattice matched to InP journal September 1982
Direct energy gap of Al 1− x In x As lattice matched to InP journal February 1984
InGaAs/InAlAs HEMT with a strained InGaP Schottky contact layer journal May 1993
Resonant-cavity InGaAs-InAlAs avalanche photodiodes with gain-bandwidth product of 290 GHz journal September 1999
27.6% Conversion efficiency, a new record for single-junction solar cells under 1 sun illumination conference June 2011
First demonstration of monolithic InP-based InAlAs/InGaAsP/InGaAs triple junction solar cells conference June 2011
InAlAs epitaxial growth for wide band gap solar cells conference June 2011
Evaluation of strained InAlAs as a window layer for wide bandgap materials lattice matched to InP
  • Yakes, Michael K.; Schmieder, Kenneth J.; Lumb, Matthew P.
  • 2015 IEEE 42nd Photovoltaic Specialists Conference (PVSC), 2015 IEEE 42nd Photovoltaic Specialist Conference (PVSC) https://doi.org/10.1109/PVSC.2015.7356068
conference June 2015
Modeling and analysis of multijunction solar cells conference February 2011
Simulation of novel InAlAsSb solar cells conference February 2012

Cited By (2)

Contactless electroreflectance study of the surface potential barrier in n -type and p -type InAlAs van Hoof structures lattice matched to InP journal May 2018
Electron transport in the solar-relevant InAlAs journal May 2019

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