In situ imaging during compression of plastic bonded explosives for damage modeling

Manner, Virginia Warren; Yeager, John David; Patterson, Brian M.; Walters, David J.; Stull, Jamie Ann; Cordes, Nikolaus L.; Luscher, Darby Jon; Henderson, Kevin C.; Schmalzer, Andrew Michael; Tappan, Bryce C.

doi:10.3390/ma10060638

Title: In situ imaging during compression of plastic bonded explosives for damage modeling

Journal Article · Sat Jun 10 00:00:00 EDT 2017 · Materials

DOI: https://doi.org/10.3390/ma10060638 · OSTI ID:1369210

Manner, Virginia Warren ^[1];

^[1];

^[1]; Stull, Jamie Ann ^[1]; Cordes, Nikolaus L. ^[1];

^[1];

^[1]

Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

Here, the microstructure of plastic bonded explosives (PBXs) is known to influence behavior during mechanical deformation, but characterizing the microstructure can be challenging. For example, the explosive crystals and binder in formulations such as PBX 9501 do not have sufficient X-ray contrast to obtain three-dimensional data by in situ, absorption contrast imaging. To address this difficulty, we have formulated a series of PBXs using octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX) crystals and low-density binder systems. The binders were hydroxyl-terminated polybutadiene (HTPB) or glycidyl azide polymer (GAP) cured with a commercial blend of acrylic monomers/oligomers. The binder density is approximately half of the HMX, allowing for excellent contrast using in situ X-ray computed tomography (CT) imaging. The samples were imaged during unaxial compression using micro-scale CT in an interrupted in situ modality. The rigidity of the binder was observed to significantly influence fracture, crystal-binder delamination, and flow. Additionally, 2D slices from the segmented 3D images were meshed for finite element simulation of the mesoscale response. At low stiffness, the binder and crystal do not delaminate and the crystals move with the material flow; at high stiffness, marked delamination is noted between the crystals and the binder, leading to very different mechanical properties. Initial model results exhibit qualitatively similar delamination.

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Research Organization:: Los Alamos National Laboratory (LANL)

Sponsoring Organization:: LDRD; USDOE

Grant/Contract Number:: AC52-06NA25396

OSTI ID:: 1369210

Report Number(s):: LA-UR-17-23838

Journal Information:: Materials, Journal Name: Materials Journal Issue: 6 Vol. 10; ISSN 1996-1944; ISSN MATEG9

Publisher:: MDPICopyright Statement

Country of Publication:: United States

Language:: English

References (61)

Examination of Morphological Changes that Affect Gas Permeation through Thermally Damaged Explosives Parker, Gary?R.; Peterson, Paul?D.; Asay, Blaine?W Propellants, Explosives, Pyrotechnics, Vol. 29, Issue 5 https://doi.org/10.1002/prep.200400057	journal	October 2004
Experimental Study of the Oxidative Degradation of PBX 9501 and its Components Salazar, Michael R.; Kress, Joel D.; Lightfoot, J. Michael Propellants, Explosives, Pyrotechnics, Vol. 33, Issue 3 https://doi.org/10.1002/prep.200700272	journal	June 2008
Elasticity of Crystalline Molecular Explosives Hooks, Daniel E.; Ramos, Kyle J.; Bolme, C. A. Propellants, Explosives, Pyrotechnics, Vol. 40, Issue 3 https://doi.org/10.1002/prep.201400282	journal	April 2015
Computational analysis of temperature rises in microstructures of HMX-Estane PBXs Barua, Ananda; Zhou, Min Computational Mechanics, Vol. 52, Issue 1 https://doi.org/10.1007/s00466-012-0803-x	journal	October 2012
Experimentally-validated mesoscale modeling of the coupled mechanical–thermal response of AP–HTPB energetic material under dynamic loading Hu, Ruize; Prakash, Chandra; Tomar, Vikas International Journal of Fracture, Vol. 203, Issue 1-2 https://doi.org/10.1007/s10704-016-0141-7	journal	July 2016
Measure of morphological and performance properties in polymeric silicone foams by X-ray tomography Patterson, Brian M.; Henderson, Kevin; Smith, Zachary Journal of Materials Science, Vol. 48, Issue 5 https://doi.org/10.1007/s10853-012-6965-2	journal	October 2012
Internal Deformation Measurement of Polymer Bonded Sugar in Compression by Digital Volume Correlation of In-situ Tomography Hu, Z.; Luo, H.; Bardenhagen, S. G. Experimental Mechanics, Vol. 55, Issue 1 https://doi.org/10.1007/s11340-014-9856-4	journal	February 2014
Modeling the measured effect of a nitroplasticizer (BDNPA/F) on cookoff of a plastic bonded explosive (PBX 9501) Hobbs, Michael L.; Kaneshige, Michael J.; Erikson, William W. Combustion and Flame, Vol. 173 https://doi.org/10.1016/j.combustflame.2016.08.014	journal	November 2016
Experimental and numerical analysis of mode II fracture between propellant and insulation Niu, Ran-Ming; Zhou, Qing-Chun; Chen, Xiong International Journal of Adhesion and Adhesives, Vol. 52 https://doi.org/10.1016/j.ijadhadh.2014.03.005	journal	July 2014
The cohesive law for the particle/matrix interfaces in high explosives Tan, H.; Liu, C.; Huang, Y. Journal of the Mechanics and Physics of Solids, Vol. 53, Issue 8 https://doi.org/10.1016/j.jmps.2005.01.009	journal	August 2005
Quantifying the three-dimensional damage and stress redistribution mechanisms of braided SiC/SiC composites by in situ volumetric digital image correlation Croom, Brendan P.; Xu, Peng; Lahoda, Edward J. Scripta Materialia, Vol. 130 https://doi.org/10.1016/j.scriptamat.2016.12.021	journal	March 2017
Energy localization in HMX-Estane polymer-bonded explosives during impact loading Barua, A.; Horie, Y.; Zhou, M. Journal of Applied Physics, Vol. 111, Issue 5 https://doi.org/10.1063/1.3688350	journal	March 2012
Computational analysis of hot-spot formation by quasi-steady deformation waves in porous explosive Gilbert, John; Chakravarthy, Sunada; Gonthier, Keith A. Journal of Applied Physics, Vol. 113, Issue 19 https://doi.org/10.1063/1.4804932	journal	May 2013
Mesoscale evolution of voids and microstructural changes in HMX-based explosives during heating through the β-δ phase transition Willey, Trevor M.; Lauderbach, Lisa; Gagliardi, Franco Journal of Applied Physics, Vol. 118, Issue 5 https://doi.org/10.1063/1.4927614	journal	August 2015
Analysis of microstructure-dependent shock dissipation and hot-spot formation in granular metalized explosive Chakravarthy, Sunada; Gonthier, Keith A. Journal of Applied Physics, Vol. 120, Issue 2 https://doi.org/10.1063/1.4956302	journal	July 2016
Time–Temperature Analysis, Tension and Compression in PBXs Thompson, Darla Graff; Deluca, Racci; Brown, Geoff W. Journal of Energetic Materials, Vol. 30, Issue 4 https://doi.org/10.1080/07370652.2011.569831	journal	October 2012
The Thermal and Microstructural Effect of Plasticizing HMX-Nitrocellulose Composites Yeager, John D.; Watkins, Erik B.; Higginbotham Duque, Amanda L. Journal of Energetic Materials, Vol. 36, Issue 1 https://doi.org/10.1080/07370652.2017.1301597	journal	March 2017
A Lagrangian framework for analyzing microstructural level response of polymer-bonded explosives Barua, Ananda; Zhou, Min Modelling and Simulation in Materials Science and Engineering, Vol. 19, Issue 5 https://doi.org/10.1088/0965-0393/19/5/055001	journal	June 2011
Quasi–static studies of the deformation and failure of β –HMX based polymer bonded explosives Rae, P. J.; Goldrein, H. T.; Palmer, S. J. P. Proceedings of the Royal Society of London. Series A: Mathematical, Physical and Engineering Sciences, Vol. 458, Issue 2019 https://doi.org/10.1098/rspa.2001.0894	journal	March 2002
High strain rate properties of a polymer-bonded sugar: their dependence on applied and internal constraints Siviour, C. R.; Laity, P. R.; Proud, W. G. Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 464, Issue 2093 https://doi.org/10.1098/rspa.2007.0214	journal	January 2008
Examination of Morphological Changes that Affect Gas Permeation through Thermally Damaged Explosives Parker, Gary?R.; Peterson, Paul?D.; Asay, Blaine?W Propellants, Explosives, Pyrotechnics, Vol. 29, Issue 5 https://doi.org/10.1002/prep.200400057	journal	October 2004
Experimental Study of the Oxidative Degradation of PBX 9501 and its Components Salazar, Michael R.; Kress, Joel D.; Lightfoot, J. Michael Propellants, Explosives, Pyrotechnics, Vol. 33, Issue 3 https://doi.org/10.1002/prep.200700272	journal	June 2008
Small-Angle Neutron Scattering and Contrast Variation Measurement of the Interfacial Surface Area in PBX 9501 as a Function of Pressing Intensity Mang, Joseph T.; Hjelm, Rex P. Propellants, Explosives, Pyrotechnics, Vol. 36, Issue 5 https://doi.org/10.1002/prep.201100006	journal	September 2011
Elasticity of Crystalline Molecular Explosives Hooks, Daniel E.; Ramos, Kyle J.; Bolme, C. A. Propellants, Explosives, Pyrotechnics, Vol. 40, Issue 3 https://doi.org/10.1002/prep.201400282	journal	April 2015
Computational analysis of temperature rises in microstructures of HMX-Estane PBXs Barua, Ananda; Zhou, Min Computational Mechanics, Vol. 52, Issue 1 https://doi.org/10.1007/s00466-012-0803-x	journal	October 2012
Experimentally-validated mesoscale modeling of the coupled mechanical–thermal response of AP–HTPB energetic material under dynamic loading Hu, Ruize; Prakash, Chandra; Tomar, Vikas International Journal of Fracture, Vol. 203, Issue 1-2 https://doi.org/10.1007/s10704-016-0141-7	journal	July 2016
Measure of morphological and performance properties in polymeric silicone foams by X-ray tomography Patterson, Brian M.; Henderson, Kevin; Smith, Zachary Journal of Materials Science, Vol. 48, Issue 5 https://doi.org/10.1007/s10853-012-6965-2	journal	October 2012
In situ X-ray synchrotron tomographic imaging during the compression of hyper-elastic polymeric materials Patterson, Brian M.; Cordes, Nikolaus L.; Henderson, Kevin Journal of Materials Science, Vol. 51, Issue 1 https://doi.org/10.1007/s10853-015-9355-8	journal	September 2015
Internal Deformation Measurement of Polymer Bonded Sugar in Compression by Digital Volume Correlation of In-situ Tomography Hu, Z.; Luo, H.; Bardenhagen, S. G. Experimental Mechanics, Vol. 55, Issue 1 https://doi.org/10.1007/s11340-014-9856-4	journal	February 2014
Unveiling 3D Deformations in Polymer Composites by Coupled Micro X-Ray Computed Tomography and Volumetric Digital Image Correlation Croom, B.; Wang, W. -M.; Li, J. Experimental Mechanics, Vol. 56, Issue 6 https://doi.org/10.1007/s11340-016-0140-7	journal	February 2016
Combustion of damaged PBX 9501 explosive Berghout, H. L.; Son, S. F.; Skidmore, C. B. Thermochimica Acta, Vol. 384, Issue 1-2 https://doi.org/10.1016/S0040-6031(01)00802-4	journal	February 2002
Overall behaviour of heterogeneous elastoviscoplastic materials: effect of microstructural modelling van der Sluis, O.; Schreurs, P. J. G.; Brekelmans, W. A. M. Mechanics of Materials, Vol. 32, Issue 8 https://doi.org/10.1016/S0167-6636(00)00019-3	journal	August 2000
Modeling the measured effect of a nitroplasticizer (BDNPA/F) on cookoff of a plastic bonded explosive (PBX 9501) Hobbs, Michael L.; Kaneshige, Michael J.; Erikson, William W. Combustion and Flame, Vol. 173 https://doi.org/10.1016/j.combustflame.2016.08.014	journal	November 2016
Modelling the damage and deformation process in a plastic bonded explosive microstructure under tension using the finite element method Arora, H.; Tarleton, E.; Li-Mayer, J. Computational Materials Science, Vol. 110 https://doi.org/10.1016/j.commatsci.2015.08.004	journal	December 2015
Experimental and numerical analysis of mode II fracture between propellant and insulation Niu, Ran-Ming; Zhou, Qing-Chun; Chen, Xiong International Journal of Adhesion and Adhesives, Vol. 52 https://doi.org/10.1016/j.ijadhadh.2014.03.005	journal	July 2014
The cohesive law for the particle/matrix interfaces in high explosives Tan, H.; Liu, C.; Huang, Y. Journal of the Mechanics and Physics of Solids, Vol. 53, Issue 8 https://doi.org/10.1016/j.jmps.2005.01.009	journal	August 2005
Rotation of hard particles in a soft matrix Yang, Weizhu; Liu, Qingchang; Yue, Zhufeng Journal of the Mechanics and Physics of Solids, Vol. 101 https://doi.org/10.1016/j.jmps.2017.01.008	journal	January 2017
Quantifying the three-dimensional damage and stress redistribution mechanisms of braided SiC/SiC composites by in situ volumetric digital image correlation Croom, Brendan P.; Xu, Peng; Lahoda, Edward J. Scripta Materialia, Vol. 130 https://doi.org/10.1016/j.scriptamat.2016.12.021	journal	March 2017
Combustion of damaged PBX 9501 explosive Berghout, H. L.; Son, S. F.; Skidmore, C. B. Thermochimica Acta, Vol. 384, Issue 1-2 https://doi.org/10.1016/s0040-6031(01)00802-4	journal	February 2002
Overall behaviour of heterogeneous elastoviscoplastic materials: effect of microstructural modelling van der Sluis, O.; Schreurs, P. J. G.; Brekelmans, W. A. M. Mechanics of Materials, Vol. 32, Issue 8 https://doi.org/10.1016/s0167-6636(00)00019-3	journal	August 2000
Morphological and Performance Measures of Polyurethane Foams Using X-Ray CT and Mechanical Testing Patterson, Brian M.; Henderson, Kevin; Gilbertson, Robert D. Microscopy and Microanalysis, Vol. 20, Issue 4 https://doi.org/10.1017/S1431927614000993	journal	May 2014
Morphological and Performance Measures of Polyurethane Foams Using X-Ray CT and Mechanical Testing Patterson, Brian M.; Henderson, Kevin; Gilbertson, Robert D. Microscopy and Microanalysis, Vol. 20, Issue 4 https://doi.org/10.1017/s1431927614000993	journal	May 2014
Energy localization in HMX-Estane polymer-bonded explosives during impact loading Barua, A.; Horie, Y.; Zhou, M. Journal of Applied Physics, Vol. 111, Issue 5 https://doi.org/10.1063/1.3688350	journal	March 2012
Ignition criterion for heterogeneous energetic materials based on hotspot size-temperature threshold Barua, A.; Kim, S.; Horie, Y. Journal of Applied Physics, Vol. 113, Issue 6 https://doi.org/10.1063/1.4792001	journal	February 2013
Computational analysis of hot-spot formation by quasi-steady deformation waves in porous explosive Gilbert, John; Chakravarthy, Sunada; Gonthier, Keith A. Journal of Applied Physics, Vol. 113, Issue 19 https://doi.org/10.1063/1.4804932	journal	May 2013
Mesoscale evolution of voids and microstructural changes in HMX-based explosives during heating through the β-δ phase transition Willey, Trevor M.; Lauderbach, Lisa; Gagliardi, Franco Journal of Applied Physics, Vol. 118, Issue 5 https://doi.org/10.1063/1.4927614	journal	August 2015
Compaction shock dissipation in low density granular explosive Rao, Pratap T.; Gonthier, Keith A.; Chakravarthy, Sunada Journal of Applied Physics, Vol. 119, Issue 22 https://doi.org/10.1063/1.4953650	journal	June 2016
Analysis of microstructure-dependent shock dissipation and hot-spot formation in granular metalized explosive Chakravarthy, Sunada; Gonthier, Keith A. Journal of Applied Physics, Vol. 120, Issue 2 https://doi.org/10.1063/1.4956302	journal	July 2016
Characterization of HMX particles in PBX 9501 Skidmore, C. B.; Phillips, D. S.; Son, S. F. The tenth American Physical Society topical conference on shock compression of condensed matter, AIP Conference Proceedings https://doi.org/10.1063/1.55666	conference	January 1998
Time–Temperature Analysis, Tension and Compression in PBXs Thompson, Darla Graff; Deluca, Racci; Brown, Geoff W. Journal of Energetic Materials, Vol. 30, Issue 4 https://doi.org/10.1080/07370652.2011.569831	journal	October 2012
The Thermal and Microstructural Effect of Plasticizing HMX-Nitrocellulose Composites Yeager, John D.; Watkins, Erik B.; Higginbotham Duque, Amanda L. Journal of Energetic Materials, Vol. 36, Issue 1 https://doi.org/10.1080/07370652.2017.1301597	journal	March 2017
A Lagrangian framework for analyzing microstructural level response of polymer-bonded explosives Barua, Ananda; Zhou, Min Modelling and Simulation in Materials Science and Engineering, Vol. 19, Issue 5 https://doi.org/10.1088/0965-0393/19/5/055001	journal	June 2011
Deformation, Strengths and Strains to Failure of Polymer Bonded Explosives Palmer, S. J. P.; Field, J. E.; Huntley, J. M. Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 440, Issue 1909 https://doi.org/10.1098/rspa.1993.0023	journal	February 1993
Quasi–static studies of the deformation and failure of β –HMX based polymer bonded explosives Rae, P. J.; Goldrein, H. T.; Palmer, S. J. P. Proceedings of the Royal Society of London. Series A: Mathematical, Physical and Engineering Sciences, Vol. 458, Issue 2019 https://doi.org/10.1098/rspa.2001.0894	journal	March 2002
High strain rate properties of a polymer-bonded sugar: their dependence on applied and internal constraints Siviour, C. R.; Laity, P. R.; Proud, W. G. Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 464, Issue 2093 https://doi.org/10.1098/rspa.2007.0214	journal	January 2008
Nanoindentation of explosive polymer composites to simulate deformation and failure Yeager, J. D.; Ramos, K. J.; Singh, S. Materials Science and Technology, Vol. 28, Issue 9-10 https://doi.org/10.1179/1743284712Y.0000000011	journal	October 2012
Nanoindentation of explosive polymer composites to simulate deformation and failure Yeager, J. D.; Ramos, K. J.; Singh, S. Materials Science and Technology, Vol. 28, Issue 9-10 https://doi.org/10.1179/1743284712y.0000000011	journal	October 2012
Essential Features of fine Scale Boundary Conditions for Second Gradient Multiscale Homogenization of Statistical Volume Elements Luscher, Darby; McDowell, David; Bronkhorst, Curt International Journal for Multiscale Computational Engineering, Vol. 10, Issue 5 https://doi.org/10.1615/IntJMultCompEng.2012002929	journal	January 2012
Essential Features of fine Scale Boundary Conditions for Second Gradient Multiscale Homogenization of Statistical Volume Elements Luscher, Darby; McDowell, David; Bronkhorst, Curt International Journal for Multiscale Computational Engineering, Vol. 10, Issue 5 https://doi.org/10.1615/intjmultcompeng.2012002929	journal	January 2012
The Thermal and Microstructural Effect of Plasticizing HMX-Nitrocellulose Composites [Supplemental Data] Yeager, John; Watkins, Erik; Higginbotham Duque, Amanda Figshare-Supplementary information for journal article at DOI: 10.1080/07370652.2017.1301597, 1 avi file; 1 PDF https://doi.org/10.6084/m9.figshare.4797892	dataset	March 2017
The Thermal and Microstructural Effect of Plasticizing HMX-Nitrocellulose Composites [Supplemental Data] Yeager, John; Watkins, Erik; Higginbotham Duque, Amanda figshare-Supplementary information for journal article at DOI: 10.1080/07370652.2017.1301597, 1 AVI file (58.61 MB); 1 PDF file (256.27 kB) https://doi.org/10.6084/m9.figshare.4797892.v1	fileset	March 2017

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Glycidyl Azide Polymer and its Derivatives-Versatile Binders for Explosives and Pyrotechnics: Tutorial Review of Recent Progress Jarosz, Tomasz; Stolarczyk, Agnieszka; Wawrzkiewicz-Jalowiecka, Agata Molecules, Vol. 24, Issue 24 https://doi.org/10.3390/molecules24244475	journal	December 2019
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Importance of microstructural features in mechanical response of cast-cured HMX formulations Yeager, John D.; Manner, Virginia W.; Stull, Jamie A. SHOCK COMPRESSION OF CONDENSED MATTER - 2017: Proceedings of the Conference of the American Physical Society Topical Group on Shock Compression of Condensed Matter, AIP Conference Proceedings https://doi.org/10.1063/1.5044842	conference	January 2018
Glycidyl Azide Polymer and its Derivatives-Versatile Binders for Explosives and Pyrotechnics: Tutorial Review of Recent Progress Jarosz, Tomasz; Stolarczyk, Agnieszka; Wawrzkiewicz-Jalowiecka, Agata Molecules, Vol. 24, Issue 24 https://doi.org/10.3390/molecules24244475	journal	December 2019

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