Mechanistic insights into the oxidation behavior of Ni alloys in high-temperature CO2

Oleksak, Richard P.; Baltrus, John P.; Nakano, Jinichiro; Nakano, Anna; Holcomb, Gordon R.; Dogan, Omer N.

doi:10.1016/j.corsci.2017.06.005

Title: Mechanistic insights into the oxidation behavior of Ni alloys in high-temperature CO₂

Journal Article · 01 June 2017 · Corrosion Science

DOI: https://doi.org/10.1016/j.corsci.2017.06.005 · OSTI ID:1366428

Oleksak, Richard P. ^[1]; Baltrus, John P. ^[2]; Nakano, Jinichiro ^[3]; Nakano, Anna ^[3]; Holcomb, Gordon R. ^[1]; Dogan, Omer N. ^[1]

National Energy Technology Lab. (NETL), Albany, OR (United States)
National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States)
National Energy Technology Lab. (NETL), Albany, OR (United States); AECOM, Albany, OR (United States)

We present results of a Ni superalloy oxidized for short times in high purity CO₂ and similarly in Ar containing ≤ 1 ppb O₂. A detailed analysis of the oxidized surfaces reveals striking similarities for the two exposure environments, suggesting O₂ impurities control the oxidation process in high-temperature CO₂. Selective oxidation results in Cr-rich oxide layers grown by 2 outward diffusion, while Cr vacancies left in the metal contribute to significant void formation at the oxide/metal interface. Unlike for most of the alloy surface, the oxidation behavior of secondary phase metal carbides is considerably different in the two environments.

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Research Organization:: National Energy Technology Lab. (NETL), Pittsburgh, PA, and Morgantown, WV (United States). In-house Research

Sponsoring Organization:: USDOE Office of Fossil Energy (FE)

OSTI ID:: 1366428

Alternate ID(s):: OSTI ID: 1495539

Report Number(s):: NETL-PUB-20826

Journal Information:: Corrosion Science, Vol. 125; ISSN 0010-938X

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Effects of Corrosion in Supercritical CO2 on the Microstructural Evolution in 800H Alloy Adam, Benjamin; Teeter, Lucas; Mahaffey, Jacob Oxidation of Metals, Vol. 90, Issue 3-4 https://doi.org/10.1007/s11085-018-9852-7	journal	May 2018
The role of metal vacancies during high-temperature oxidation of alloys Oleksak, Richard P.; Kapoor, Monica; Perea, Daniel. E. npj Materials Degradation, Vol. 2, Issue 1 https://doi.org/10.1038/s41529-018-0046-1	journal	September 2018
High-Temperature Oxidation of Commercial Alloys in Supercritical CO2 and Related Power Cycle Environments Oleksak, Richard P.; Tylczak, Joseph H.; Carney, Casey S. JOM, Vol. 70, Issue 8 https://doi.org/10.1007/s11837-018-2952-7	journal	June 2018

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