Forty years of temporal analysis of products

Morgan, K.; Maguire, N.; Fushimi, R.; Gleaves, J. T.; Goguet, A.; Harold, M. P.; Kondratenko, E. V.; Menon, U.; Schuurman, Y.; Yablonsky, G. S.

doi:10.1039/C7CY00678K

Title: Forty years of temporal analysis of products

Journal Article · Tue May 16 04:00:00 UTC 2017 · Catalysis Science and Technology

DOI: https://doi.org/10.1039/C7CY00678K · OSTI ID:1363934

; Maguire, N.;

; Gleaves, J. T.; Goguet, A.;

; Kondratenko, E. V.; Menon, U.;

; Yablonsky, G. S.

Detailed understanding of mechanisms and reaction kinetics are required in order to develop and optimize catalysts and catalytic processes. While steady state investigations are known to give a global view of the catalytic system, transient studies are invaluable since they can provide more detailed insight into elementary steps. For almost thirty years temporal analysis of products (TAP) has been successfully utilized for transient studies of gas phase heterogeneous catalysis, and there have been a number of advances in instrumentation and numerical modeling methods in that time. In the current work, the range of available TAP apparatus will be discussed while detailed explanations of the types of TAP experiment, the information that can be determined from these experiments and the analysis methods are also included. TAP is a complex methodology and is often viewed as a niche specialty. Here, part of the intention of this work is to highlight the significant contributions TAP can make to catalytic research, while also discussing the issues which will make TAP more relevant and approachable to a wider segment of the catalytic research community. With this in mind, an outlook is also disclosed for the technique in terms of what is needed to revitalize the field and make it more applicable to the recent advances in catalyst characterization (e.g. operando modes).

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Research Organization:: Idaho National Lab. (INL), Idaho Falls, ID (United States)

Sponsoring Organization:: USDOE Office of Nuclear Energy (NE)

Grant/Contract Number:: AC07-05ID14517

OSTI ID:: 1363934

Report Number(s):: INL/JOU--16-39870

Journal Information:: Catalysis Science and Technology, Journal Name: Catalysis Science and Technology Journal Issue: 12 Vol. 7; ISSN CSTAGD; ISSN 2044-4753

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Methanol-to-hydrocarbons conversion: The alkene methylation pathway Brogaard, Rasmus Y.; Henry, Reynald; Schuurman, Yves Journal of Catalysis, Vol. 314 https://doi.org/10.1016/j.jcat.2014.04.006	journal	May 2014
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Evaluation of an in situ spatial resolution instrument for fixed beds through the assessment of the invasiveness of probes and a comparison with a micro-kinetic model Touitou, Jamal; Aiouache, Farid; Burch, Robbie Journal of Catalysis, Vol. 319 https://doi.org/10.1016/j.jcat.2014.09.006	journal	November 2014
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