Sustainable Energy-Storage Materials from Lignin-Graphene Nanocomposite-Derived Porous Carbon Film
Abstract
We present a simple, green approach to fabricating porous free-standing carbon films. An alkaline solution of low-cost, renewable lignin and graphene oxide (GO) is cast, followed by simultaneous carbonization and activation. Lignin, which is the least valued product from several biomass processing industries, is an efficient source of carbon when used as an intercalating agent to separate graphene sheets derived from homogeneous GO/lignin nanocomposite films prepared from an aqueous alkaline (KOH) solution. After thermal treatment the GO/lignin films show complete dispersion of reduced GO sheets within amorphous lignin-derived carbon. Furthermore, the presence of KOH in the film produces activated carbon. The resulting activated carbon films display a specific surface area of up to 1744 m2 g 1 and consist of a balance of pore volumes with pore sizes below and above 1 nm. A two-electrode supercapacitor composed of these films in an aqueous electrolyte exhibits near-ideal capacitive behavior at an ultrahigh scan rate of 1 V s 1, while maintaining an excellent specific capacitance of 162 F g 1. Such outstanding performance of renewable carbon as a supercapacitor, in addition to the ease of electrode fabrication from a precursor containing 85 % lignin, offers a novel method for valorization ofmore »
- Authors:
-
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division; Univ. of Tennessee, Knoxville, TN (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science and Neutron Science Directorate
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
- Sponsoring Org.:
- USDOE Office of Science (SC)
- OSTI Identifier:
- 1362202
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Energy Technology
- Additional Journal Information:
- Journal Volume: 5; Journal ID: ISSN 2194-4288
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; 36 MATERIALS SCIENCE
Citation Formats
Tran, Chau D., Ho, Hoi Chun, Keum, Jong K., Chen, Jihua, Gallego, Nidia C., and Naskar, Amit K. Sustainable Energy-Storage Materials from Lignin-Graphene Nanocomposite-Derived Porous Carbon Film. United States: N. p., 2017.
Web. doi:10.1002/ente.201700090.
Tran, Chau D., Ho, Hoi Chun, Keum, Jong K., Chen, Jihua, Gallego, Nidia C., & Naskar, Amit K. Sustainable Energy-Storage Materials from Lignin-Graphene Nanocomposite-Derived Porous Carbon Film. United States. https://doi.org/10.1002/ente.201700090
Tran, Chau D., Ho, Hoi Chun, Keum, Jong K., Chen, Jihua, Gallego, Nidia C., and Naskar, Amit K. Tue .
"Sustainable Energy-Storage Materials from Lignin-Graphene Nanocomposite-Derived Porous Carbon Film". United States. https://doi.org/10.1002/ente.201700090. https://www.osti.gov/servlets/purl/1362202.
@article{osti_1362202,
title = {Sustainable Energy-Storage Materials from Lignin-Graphene Nanocomposite-Derived Porous Carbon Film},
author = {Tran, Chau D. and Ho, Hoi Chun and Keum, Jong K. and Chen, Jihua and Gallego, Nidia C. and Naskar, Amit K.},
abstractNote = {We present a simple, green approach to fabricating porous free-standing carbon films. An alkaline solution of low-cost, renewable lignin and graphene oxide (GO) is cast, followed by simultaneous carbonization and activation. Lignin, which is the least valued product from several biomass processing industries, is an efficient source of carbon when used as an intercalating agent to separate graphene sheets derived from homogeneous GO/lignin nanocomposite films prepared from an aqueous alkaline (KOH) solution. After thermal treatment the GO/lignin films show complete dispersion of reduced GO sheets within amorphous lignin-derived carbon. Furthermore, the presence of KOH in the film produces activated carbon. The resulting activated carbon films display a specific surface area of up to 1744 m2 g 1 and consist of a balance of pore volumes with pore sizes below and above 1 nm. A two-electrode supercapacitor composed of these films in an aqueous electrolyte exhibits near-ideal capacitive behavior at an ultrahigh scan rate of 1 V s 1, while maintaining an excellent specific capacitance of 162 F g 1. Such outstanding performance of renewable carbon as a supercapacitor, in addition to the ease of electrode fabrication from a precursor containing 85 % lignin, offers a novel method for valorization of lignin-rich byproduct streams from biomass processing industries.},
doi = {10.1002/ente.201700090},
journal = {Energy Technology},
number = ,
volume = 5,
place = {United States},
year = {Tue May 30 00:00:00 EDT 2017},
month = {Tue May 30 00:00:00 EDT 2017}
}
Web of Science
Works referenced in this record:
Lignin Valorization: Improving Lignin Processing in the Biorefinery
journal, May 2014
- Ragauskas, A. J.; Beckham, G. T.; Biddy, M. J.
- Science, Vol. 344, Issue 6185, p. 1246843-1246843
Ultrafine microporous and mesoporous activated carbon fibers from alkali lignin
journal, January 2013
- Hu, Sixiao; Hsieh, You-Lo
- Journal of Materials Chemistry A, Vol. 1, Issue 37
Graphene, related two-dimensional crystals, and hybrid systems for energy conversion and storage
journal, January 2015
- Bonaccorso, Francesco; Colombo, Luigi; Yu, Guihua
- Science, Vol. 347, Issue 6217
Graphene-based materials as supercapacitor electrodes
journal, January 2010
- Zhang, Li Li; Zhou, Rui; Zhao, X. S.
- Journal of Materials Chemistry, Vol. 20, Issue 29
Electrochemical properties of graphene nanosheet/carbon black composites as electrodes for supercapacitors
journal, May 2010
- Yan, Jun; Wei, Tong; Shao, Bo
- Carbon, Vol. 48, Issue 6
Graphene Oxide−MnO 2 Nanocomposites for Supercapacitors
journal, March 2010
- Chen, Sheng; Zhu, Junwu; Wu, Xiaodong
- ACS Nano, Vol. 4, Issue 5
Carbon-based materials as supercapacitor electrodes
journal, January 2009
- Zhang, Li Li; Zhao, X. S.
- Chemical Society Reviews, Vol. 38, Issue 9
Nanodiamond particles/reduced graphene oxide composites as efficient supercapacitor electrodes
journal, March 2014
- Wang, Qi; Plylahan, Nareerat; Shelke, Manjusha V.
- Carbon, Vol. 68
Bioinspired Effective Prevention of Restacking in Multilayered Graphene Films: Towards the Next Generation of High-Performance Supercapacitors
journal, May 2011
- Yang, Xiaowei; Zhu, Junwu; Qiu, Ling
- Advanced Materials, Vol. 23, Issue 25
Ultrahigh-power micrometre-sized supercapacitors based on onion-like carbon
journal, August 2010
- Pech, David; Brunet, Magali; Durou, Hugo
- Nature Nanotechnology, Vol. 5, Issue 9, p. 651-654
Electric Field Effect in Atomically Thin Carbon Films
journal, October 2004
- Novoselov, K. S.
- Science, Vol. 306, Issue 5696, p. 666-669
3 D Hierarchical Porous Carbon for Supercapacitors Prepared from Lignin through a Facile Template-Free Method
journal, May 2015
- Zhang, Wenli; Lin, Haibo; Lin, Zheqi
- ChemSusChem, Vol. 8, Issue 12
Nanoporous Structured Submicrometer Carbon Fibers Prepared via Solution Electrospinning of Polymer Blends
journal, October 2006
- Peng, Mao; Li, Dasong; Shen, Lie
- Langmuir, Vol. 22, Issue 22
Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide
journal, June 2007
- Stankovich, Sasha; Dikin, Dmitriy A.; Piner, Richard D.
- Carbon, Vol. 45, Issue 7, p. 1558-1565
Polyaniline-Grafted Reduced Graphene Oxide for Efficient Electrochemical Supercapacitors
journal, January 2012
- Kumar, Nanjundan Ashok; Choi, Hyun-Jung; Shin, Yeon Ran
- ACS Nano, Vol. 6, Issue 2
Achieving high specific charge capacitances in Fe3O4/reduced graphene oxide nanocomposites
journal, January 2011
- Shi, Wenhui; Zhu, Jixin; Sim, Dao Hao
- Journal of Materials Chemistry, Vol. 21, Issue 10
Highly Conductive and Porous Activated Reduced Graphene Oxide Films for High-Power Supercapacitors
journal, January 2012
- Zhang, Li Li; Zhao, Xin; Stoller, Meryl D.
- Nano Letters, Vol. 12, Issue 4
Preventing Graphene Sheets from Restacking for High-Capacitance Performance
journal, October 2011
- Wang, Yan; Wu, Yingpeng; Huang, Yi
- The Journal of Physical Chemistry C, Vol. 115, Issue 46
Flexible free-standing graphene paper with interconnected porous structure for energy storage
journal, January 2015
- Shu, Kewei; Wang, Caiyun; Li, Sha
- Journal of Materials Chemistry A, Vol. 3, Issue 8
Carbon-Based Supercapacitors Produced by Activation of Graphene
journal, May 2011
- Zhu, Y.; Murali, S.; Stoller, M. D.
- Science, Vol. 332, Issue 6037, p. 1537-1541
Carbon materials for the electrochemical storage of energy in capacitors
journal, May 2001
- Frackowiak, Elzbieta; Béguin, François
- Carbon, Vol. 39, Issue 6, p. 937-950
Graphene and Graphene Oxide: Synthesis, Properties, and Applications
journal, June 2010
- Zhu, Yanwu; Murali, Shanthi; Cai, Weiwei
- Advanced Materials, Vol. 22, Issue 35, p. 3906-3924
Activated Graphene-Based Carbons as Supercapacitor Electrodes with Macro- and Mesopores
journal, July 2013
- Kim, TaeYoung; Jung, Gyujin; Yoo, Seonmi
- ACS Nano, Vol. 7, Issue 8
Scalable preparation of three-dimensional porous structures of reduced graphene oxide/cellulose composites and their application in supercapacitors
journal, October 2013
- Ouyang, Wenzhu; Sun, Jinhua; Memon, Jamil
- Carbon, Vol. 62
Crumpled Nitrogen-Doped Graphene Nanosheets with Ultrahigh Pore Volume for High-Performance Supercapacitor
journal, August 2012
- Wen, Zhenhai; Wang, Xinchen; Mao, Shun
- Advanced Materials, Vol. 24, Issue 41
Laser Scribing of High-Performance and Flexible Graphene-Based Electrochemical Capacitors
journal, March 2012
- El-Kady, M. F.; Strong, V.; Dubin, S.
- Science, Vol. 335, Issue 6074
Carbon properties and their role in supercapacitors
journal, June 2006
- Pandolfo, A. G.; Hollenkamp, A. F.
- Journal of Power Sources, Vol. 157, Issue 1, p. 11-27
A New Class of Renewable Thermoplastics with Extraordinary Performance from Nanostructured Lignin-Elastomers
journal, March 2016
- Tran, Chau D.; Chen, Jihua; Keum, Jong K.
- Advanced Functional Materials, Vol. 26, Issue 16, p. 2677-2685
Anchoring Hydrous RuO2 on Graphene Sheets for High-Performance Electrochemical Capacitors
journal, August 2010
- Wu, Zhong-Shuai; Wang, Da-Wei; Ren, Wencai
- Advanced Functional Materials, Vol. 20, Issue 20
Single Sheet Functionalized Graphene by Oxidation and Thermal Expansion of Graphite
journal, September 2007
- McAllister, Michael J.; Li, Je-Luen; Adamson, Douglas H.
- Chemistry of Materials, Vol. 19, Issue 18, p. 4396-4404
Low-Temperature Exfoliated Graphenes: Vacuum-Promoted Exfoliation and Electrochemical Energy Storage
journal, October 2009
- Lv, Wei; Tang, Dai-Ming; He, Yan-Bing
- ACS Nano, Vol. 3, Issue 11
Fabrication of porous carbon nanofibers with adjustable pore sizes as electrodes for supercapacitors
journal, August 2013
- Tran, Chau; Kalra, Vibha
- Journal of Power Sources, Vol. 235
Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984)
journal, January 1985
- Sing, K. S. W.
- Pure and Applied Chemistry, Vol. 57, Issue 4, p. 603-619
Lignin as Renewable Raw Material
journal, September 2010
- Calvo-Flores, Francisco García; Dobado, José A.
- ChemSusChem, Vol. 3, Issue 11
Pyrolyzed graphene oxide/resorcinol-formaldehyde resin composites as high-performance supercapacitor electrodes
journal, January 2011
- Zhang, Kai; Ang, Bao Ting; Zhang, Li Li
- Journal of Materials Chemistry, Vol. 21, Issue 8
Flexible graphene–polyaniline composite paper for high-performance supercapacitor
journal, January 2013
- Cong, Huai-Ping; Ren, Xiao-Chen; Wang, Ping
- Energy & Environmental Science, Vol. 6, Issue 4, p. 1185-1191
Graphene oxide/polypyrrole nanocomposites: one-step electrochemical doping, coating and synergistic effect for energy storage
journal, January 2012
- Zhu, Chengzhou; Zhai, Junfeng; Wen, Dan
- Journal of Materials Chemistry, Vol. 22, Issue 13
Nanoporous carbons from natural lignin: study of structural–textural properties and application to organic-based supercapacitors
journal, January 2014
- Navarro-Suárez, Adriana M.; Carretero-González, Javier; Roddatis, Vladimir
- RSC Adv., Vol. 4, Issue 89
Preparation and characterization of graphene oxide paper
journal, July 2007
- Dikin, Dmitriy A.; Stankovich, Sasha; Zimney, Eric J.
- Nature, Vol. 448, Issue 7152, p. 457-460
Studies on Supercapacitor Electrode Material from Activated Lignin-Derived Mesoporous Carbon
journal, January 2014
- Saha, Dipendu; Li, Yunchao; Bi, Zhonghe
- Langmuir, Vol. 30, Issue 3
Fabrication of High-Concentration and Stable Aqueous Suspensions of Graphene Nanosheets by Noncovalent Functionalization with Lignin and Cellulose Derivatives
journal, February 2010
- Yang, Qiang; Pan, Xuejun; Huang, Fang
- The Journal of Physical Chemistry C, Vol. 114, Issue 9, p. 3811-3816
Large Areal Mass, Flexible and Free-Standing Reduced Graphene Oxide/Manganese Dioxide Paper for Asymmetric Supercapacitor Device
journal, April 2013
- Sumboja, Afriyanti; Foo, Ce Yao; Wang, Xu
- Advanced Materials, Vol. 25, Issue 20
Works referencing / citing this record:
A Solvent-Free Synthesis of Lignin-Derived Renewable Carbon with Tunable Porosity for Supercapacitor Electrodes
journal, July 2018
- Ho, Hoi Chun; Nguyen, Ngoc A.; Meek, Kelly M.
- ChemSusChem, Vol. 11, Issue 17
Lignin-derived heteroatom-doped porous carbons for supercapacitor and CO 2 capture applications
journal, April 2018
- Demir, Muslum; Tessema, Tsemre-Dingel; Farghaly, Ahmed A.
- International Journal of Energy Research, Vol. 42, Issue 8
Amending the Structure of Renewable Carbon from Biorefinery Waste-Streams for Energy Storage Applications
journal, May 2018
- Ho, Hoi Chun; Goswami, Monojoy; Chen, Jihua
- Scientific Reports, Vol. 8, Issue 1
Simple and scalable synthesis of hierarchical porous carbon derived from cornstalk without pith for high capacitance and energy density
journal, January 2020
- Li, Jiaming; Jiang, Qimeng; Wei, Lansheng
- Journal of Materials Chemistry A, Vol. 8, Issue 3
Alternatives for Chemical and Biochemical Lignin Valorization: Hot Topics from a Bibliometric Analysis of the Research Published During the 2000–2016 Period
journal, July 2018
- Abejón, Ricardo; Pérez-Acebo, Heriberto; Clavijo, Leonardo
- Processes, Vol. 6, Issue 8