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Title: Using complimentary microscopy methods to examine Ni-Mn-Si-precipitates in highly-irradiated reactor pressure vessel steels

Nano-scale Ni-Mn-Si-rich precipitates formed in a reactor pressure vessel steel under high neutron fluence have been characterized using highly complimentary atom probe tomography (APT) and scanning transmission electron microscopy with energy dispersive spectroscopy (STEM-EDS) combined with STEM-EDS modeling. Using these techniques in a synergistic manner to overcome the well-known trajectory aberrations in APT data, the average upper limit Fe concentration within the precipitates was found to be ~6 at.%. Using this knowledge, accurate compositions of the precipitates was determined and it was found that the spread of precipitate compositions was large, but mostly centered around the Γ2-and G-phases. The use of STEM-EDS also allowed for larger areas to be examined, and segregation of minor solutes was observed to occur on grain boundaries, along with Ni-Mn-Si-rich precipitates that were smaller in size than those in the matrix. Solute segregation at the grain boundaries is proposed to occur through a radiation induced segregation or radiation enhanced diffusion mechanism due to the presence of a denuded zone about the grain boundary. It is also proposed that the reduced precipitate size at the grain boundaries is due to the structure of the grain boundary. The lack of Ni-Mn-Si precipitates observed in larger Mo-rich precipitatesmore » is also discussed, and the absence of the minor solutes required to form the Ni-Mn-Si precipitates results in the lack of nucleation. This is in contrast to cementite phases in which Ni-Mn-Si precipitates have been seen to be formed. It was also determined through this work that the exclusion of all the Fe ions during atom probe analysis is a reasonable approximation.« less
Authors:
 [1] ;  [1] ;  [1]
  1. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Publication Date:
Grant/Contract Number:
AC05-00OR22725
Type:
Accepted Manuscript
Journal Name:
Acta Materialia
Additional Journal Information:
Journal Volume: 134; Journal Issue: C; Journal ID: ISSN 1359-6454
Publisher:
Elsevier
Research Org:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Nuclear Science User Facility (NSUF)
Sponsoring Org:
USDOE Office of Nuclear Energy (NE)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE
OSTI Identifier:
1361349
Alternate Identifier(s):
OSTI ID: 1396597

Edmondson, P. D., Parish, C. M., and Nanstad, R. K.. Using complimentary microscopy methods to examine Ni-Mn-Si-precipitates in highly-irradiated reactor pressure vessel steels. United States: N. p., Web. doi:10.1016/j.actamat.2017.05.043.
Edmondson, P. D., Parish, C. M., & Nanstad, R. K.. Using complimentary microscopy methods to examine Ni-Mn-Si-precipitates in highly-irradiated reactor pressure vessel steels. United States. doi:10.1016/j.actamat.2017.05.043.
Edmondson, P. D., Parish, C. M., and Nanstad, R. K.. 2017. "Using complimentary microscopy methods to examine Ni-Mn-Si-precipitates in highly-irradiated reactor pressure vessel steels". United States. doi:10.1016/j.actamat.2017.05.043. https://www.osti.gov/servlets/purl/1361349.
@article{osti_1361349,
title = {Using complimentary microscopy methods to examine Ni-Mn-Si-precipitates in highly-irradiated reactor pressure vessel steels},
author = {Edmondson, P. D. and Parish, C. M. and Nanstad, R. K.},
abstractNote = {Nano-scale Ni-Mn-Si-rich precipitates formed in a reactor pressure vessel steel under high neutron fluence have been characterized using highly complimentary atom probe tomography (APT) and scanning transmission electron microscopy with energy dispersive spectroscopy (STEM-EDS) combined with STEM-EDS modeling. Using these techniques in a synergistic manner to overcome the well-known trajectory aberrations in APT data, the average upper limit Fe concentration within the precipitates was found to be ~6 at.%. Using this knowledge, accurate compositions of the precipitates was determined and it was found that the spread of precipitate compositions was large, but mostly centered around the Γ2-and G-phases. The use of STEM-EDS also allowed for larger areas to be examined, and segregation of minor solutes was observed to occur on grain boundaries, along with Ni-Mn-Si-rich precipitates that were smaller in size than those in the matrix. Solute segregation at the grain boundaries is proposed to occur through a radiation induced segregation or radiation enhanced diffusion mechanism due to the presence of a denuded zone about the grain boundary. It is also proposed that the reduced precipitate size at the grain boundaries is due to the structure of the grain boundary. The lack of Ni-Mn-Si precipitates observed in larger Mo-rich precipitates is also discussed, and the absence of the minor solutes required to form the Ni-Mn-Si precipitates results in the lack of nucleation. This is in contrast to cementite phases in which Ni-Mn-Si precipitates have been seen to be formed. It was also determined through this work that the exclusion of all the Fe ions during atom probe analysis is a reasonable approximation.},
doi = {10.1016/j.actamat.2017.05.043},
journal = {Acta Materialia},
number = C,
volume = 134,
place = {United States},
year = {2017},
month = {5}
}