Enhanced Kinetics of Electrochemical Hydrogen Uptake and Release by Palladium Powders Modified by Electrochemical Atomic Layer Deposition

Benson, David M.; Tsang, Chu F.; Sugar, Joshua Daniel; Jagannathan, Kaushik; Robinson, David B.; El Gabaly, Farid; Cappillino, Patrick J.; Stickney, John L.

doi:10.1021/acsami.7b03005

Title: Enhanced Kinetics of Electrochemical Hydrogen Uptake and Release by Palladium Powders Modified by Electrochemical Atomic Layer Deposition

Abstract

One method for the formation of nanofilms of materials, is Electrochemical atomic layer deposition (E-ALD), one atomic layer at a time. It uses the galvanic exchange of a less noble metal, deposited using underpotential deposition (UPD), to produce an atomic layer of a more noble element by reduction of its ions. This process is referred to as surface limited redox replacement and can be repeated in a cycle to grow thicker deposits. Previously, we performed it on nanoparticles and planar substrates. In the present report, E-ALD is applied for coating a submicron-sized powder substrate, making use of a new flow cell design. E-ALD is used to coat a Pd powder substrate with different thicknesses of Rh by exchanging it for Cu UPD. Furthermore, cyclic voltammetry and X-ray photoelectron spectroscopy indicate an increasing Rh coverage with increasing numbers of deposition cycles performed, in a manner consistent with the atomic layer deposition (ALD) mechanism. Cyclic voltammetry also indicated increased kinetics of H sorption and desorption in and out of the Pd powder with Rh present, relative to unmodified Pd.

Authors:

^[1]; Tsang, Chu F. ^[1]; Sugar, Joshua Daniel ^[2]; Jagannathan, Kaushik ^[1]; Robinson, David B. ^[2]; El Gabaly, Farid ^[2]; Cappillino, Patrick J. ^[3]; Stickney, John L. ^[1]

Univ. of Georgia, Athens, GA (United States). Dept. of Chemistry
Sandia National Lab. (SNL-CA), Livermore, CA (United States)
Sandia National Lab. (SNL-CA), Livermore, CA (United States); Univ. of Massachusetts, North Dartmouth, MA (United States). Dept. of Chemistry and Biochemistry

Publication Date:: Fri Apr 28 00:00:00 EDT 2017

Research Org.:: Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Sponsoring Org.:: USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1360933

Report Number(s):: SAND-2017-5175J
Journal ID: ISSN 1944-8244; 653340; TRN: US1701980

Grant/Contract Number:: AC04-94AL85000; NA0003525; AC02-05CH11231

Resource Type:: Accepted Manuscript

Journal Name:: ACS Applied Materials and Interfaces

Additional Journal Information:: Journal Volume: 9; Journal Issue: 21; Journal ID: ISSN 1944-8244

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; E-ALD; electrodeposition; flow cell; palladium; powder; rhodium; SLRR; UPD

Citation Formats


                    Benson, David M., Tsang, Chu F., Sugar, Joshua Daniel, Jagannathan, Kaushik, Robinson, David B., El Gabaly, Farid, Cappillino, Patrick J., and Stickney, John L. Enhanced Kinetics of Electrochemical Hydrogen Uptake and Release by Palladium Powders Modified by Electrochemical Atomic Layer Deposition.  United States: N. p., 2017. 
Web.  doi:10.1021/acsami.7b03005.

Copy to clipboard


                    Benson, David M., Tsang, Chu F., Sugar, Joshua Daniel, Jagannathan, Kaushik, Robinson, David B., El Gabaly, Farid, Cappillino, Patrick J., & Stickney, John L. Enhanced Kinetics of Electrochemical Hydrogen Uptake and Release by Palladium Powders Modified by Electrochemical Atomic Layer Deposition.  United States.  https://doi.org/10.1021/acsami.7b03005

Copy to clipboard


                    Benson, David M., Tsang, Chu F., Sugar, Joshua Daniel, Jagannathan, Kaushik, Robinson, David B., El Gabaly, Farid, Cappillino, Patrick J., and Stickney, John L. Fri .  
"Enhanced Kinetics of Electrochemical Hydrogen Uptake and Release by Palladium Powders Modified by Electrochemical Atomic Layer Deposition".  United States.  https://doi.org/10.1021/acsami.7b03005.  https://www.osti.gov/servlets/purl/1360933.

Copy to clipboard


                    
@article{osti_1360933,

  title        = {Enhanced Kinetics of Electrochemical Hydrogen Uptake and Release by Palladium Powders Modified by Electrochemical Atomic Layer Deposition},

  author       = {Benson, David M. and Tsang, Chu F. and Sugar, Joshua Daniel and Jagannathan, Kaushik and Robinson, David B. and El Gabaly, Farid and Cappillino, Patrick J. and Stickney, John L.},

  abstractNote = {One method for the formation of nanofilms of materials, is Electrochemical atomic layer deposition (E-ALD), one atomic layer at a time. It uses the galvanic exchange of a less noble metal, deposited using underpotential deposition (UPD), to produce an atomic layer of a more noble element by reduction of its ions. This process is referred to as surface limited redox replacement and can be repeated in a cycle to grow thicker deposits. Previously, we performed it on nanoparticles and planar substrates. In the present report, E-ALD is applied for coating a submicron-sized powder substrate, making use of a new flow cell design. E-ALD is used to coat a Pd powder substrate with different thicknesses of Rh by exchanging it for Cu UPD. Furthermore, cyclic voltammetry and X-ray photoelectron spectroscopy indicate an increasing Rh coverage with increasing numbers of deposition cycles performed, in a manner consistent with the atomic layer deposition (ALD) mechanism. Cyclic voltammetry also indicated increased kinetics of H sorption and desorption in and out of the Pd powder with Rh present, relative to unmodified Pd.},

  doi          = {10.1021/acsami.7b03005},

  journal      = {ACS Applied Materials and Interfaces},

  number       = 21,

  volume       = 9,

  place        = {United States},

  year         = {Fri Apr 28 00:00:00 EDT 2017},

  month        = {Fri Apr 28 00:00:00 EDT 2017}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (DOE)

Publisher's Version of Record

https://doi.org/10.1021/acsami.7b03005

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 5 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Atomic Layer Deposition: An Overview
journal, January 2010

George, Steven M.
Chemical Reviews, Vol. 110, Issue 1, p. 111-131
DOI: 10.1021/cr900056b

Supported Ru−Pt Bimetallic Nanoparticle Catalysts Prepared by Atomic Layer Deposition
journal, August 2010

Christensen, Steven T.; Feng, Hao; Libera, Joseph L.
Nano Letters, Vol. 10, Issue 8
DOI: 10.1021/nl101567m

Toward atomically-precise synthesis of supported bimetallic nanoparticles using atomic layer deposition
journal, February 2014

Lu, Junling; Low, Ke-Bin; Lei, Yu
Nature Communications, Vol. 5, Issue 1
DOI: 10.1038/ncomms4264

Ordered Anion Adlayers on Metal Electrode Surfaces
journal, March 2002

Magnussen, O. M.
Chemical Reviews, Vol. 102, Issue 3
DOI: 10.1021/cr000069p

Thin-layer electrochemical studies of the underpotential deposition of cadmium and tellurium on polycrystalline Au, Pt and Cu electrodes
journal, October 1990

Gregory, Brian W.; Norton, Michael L.; Stickney, John L.
Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 293, Issue 1-2
DOI: 10.1016/0022-0728(90)80054-a

Electrochemical atomic layer epitaxy (ECALE)
journal, February 1991

Gregory, Brian W.; Stickney, John L.
Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 300, Issue 1-2
DOI: 10.1016/0022-0728(91)85415-l

Conditions for the Deposition of CdTe by Electrochemical Atomic Layer Epitaxy
journal, May 1991

Gregory, Brian W.; Suggs, D. Wayne; Stickney, John L.
Journal of The Electrochemical Society, Vol. 138, Issue 5
DOI: 10.1149/1.2085773

Underpotential Deposition at Single Crystal Surfaces of Au, Pt, Ag and Other Materials
journal, July 2001

Herrero, Enrique; Buller, Lisa J.; Abruña, Héctor D.
Chemical Reviews, Vol. 101, Issue 7
DOI: 10.1021/cr9600363

Surface-Enhanced Raman Scattering on Uniform Platinum-Group Overlayers: Preparation by Redox Replacement of Underpotential-Deposited Metals on Gold
journal, December 2001

Mrozek, Melissa F.; Xie, Yong; Weaver, Michael J.
Analytical Chemistry, Vol. 73, Issue 24
DOI: 10.1021/ac0106391

Platinum Nanofilm Formation by EC-ALE via Redox Replacement of UPD Copper: Studies Using in-Situ Scanning Tunneling Microscopy
journal, September 2006

Kim, Youn-Geun; Kim, Jay Y.; Vairavapandian, Deepa
The Journal of Physical Chemistry B, Vol. 110, Issue 36, p. 17998-18006
DOI: 10.1021/jp063766f

Epitaxial Growth by Monolayer-Restricted Galvanic Displacement
journal, January 2005

Vasilic, R.; Dimitrov, N.
Electrochemical and Solid-State Letters, Vol. 8, Issue 11
DOI: 10.1149/1.2063267

Electrochemical Atomic Layer Deposition (E-ALD) of Pt Nanofilms Using SLRR Cycles
journal, January 2012

Jayaraju, Nagarajan; Vairavapandian, Deepa; Kim, Youn Guen
Journal of The Electrochemical Society, Vol. 159, Issue 10
DOI: 10.1149/2.053210jes

Formation of Palladium Nanofilms Using Electrochemical Atomic Layer Deposition (E-ALD) with Chloride Complexation
journal, January 2013

Sheridan, Leah B.; Gebregziabiher, Daniel K.; Stickney, John L.
Langmuir, Vol. 29, Issue 5
DOI: 10.1021/la303816z

Electrodeposition of Ru by atomic layer deposition (ALD)
journal, September 2008

Thambidurai, Chandru; Kim, Youn-Geun; Stickney, John L.
Electrochimica Acta, Vol. 53, Issue 21
DOI: 10.1016/j.electacta.2008.01.003

Hydrogen sorption properties of bare and Rh-modified Pd nanofilms grown via surface limited redox replacement reactions
journal, May 2014

Sheridan, Leah B.; Yates, Veronica M.; Benson, David M.
Electrochimica Acta, Vol. 128
DOI: 10.1016/j.electacta.2013.10.096

Hydrogen Sorption Kinetics on Bare and Platinum-Modified Palladium Nanofilms, Grown by Electrochemical Atomic Layer Deposition (E-ALD)
journal, January 2016

Jagannathan, Kaushik; Benson, David M.; Robinson, David B.
Journal of The Electrochemical Society, Vol. 163, Issue 12
DOI: 10.1149/2.0051612jes

The effect of surface species on the rate of H sorption into nanostructured Pd
journal, January 2004

Bartlett, P. N.; Marwan, J.
Physical Chemistry Chemical Physics, Vol. 6, Issue 11
DOI: 10.1039/b404028g

Surface and Subsurface Hydrogen: Adsorption Properties on Transition Metals and Near-Surface Alloys
journal, March 2005

Greeley, Jeff; Mavrikakis, Manos
The Journal of Physical Chemistry B, Vol. 109, Issue 8
DOI: 10.1021/jp046540q

Effects of surface thermodynamics on hydrogen isotope exchange kinetics in palladium: Particle and flow models
journal, January 2015

Salloum, Maher; James, Scott C.; Robinson, David B.
Chemical Engineering Science, Vol. 122
DOI: 10.1016/j.ces.2014.09.001

Ternary semiconductor compounds CuInS2 (CIS) thin films synthesized by electrochemical atomic layer deposition (EC-ALD)
journal, April 2010

Lin, Shaoxiong; Shi, Xuezhao; Zhang, Xin
Applied Surface Science, Vol. 256, Issue 13
DOI: 10.1016/j.apsusc.2010.02.032

Electrochemical growth of Cu–Zn sulfides
journal, December 2013

Innocenti, M.; Becucci, L.; Bencistà, I.
Journal of Electroanalytical Chemistry, Vol. 710
DOI: 10.1016/j.jelechem.2013.01.024

Electrodeposited Cu2ZnSnS4 thin films
journal, May 2014

Valdes, M.; Modibedi, M.; Mathe, M.
Electrochimica Acta, Vol. 128
DOI: 10.1016/j.electacta.2013.10.206

Nanocrystallized Cu2Se grown on electroless Cu coated p-type Si using electrochemical atomic layer deposition
journal, January 2015

Zhang, Lu; He, Wenya; Chen, Xiang-yu
Surface Science, Vol. 631
DOI: 10.1016/j.susc.2014.08.014

Pt Submonolayers on Ru Nanoparticles: A Novel Low Pt Loading, High CO Tolerance Fuel Cell Electrocatalyst
journal, January 2001

Brankovic, S. R.; Wang, J. X.; Adžić, R. R.
Electrochemical and Solid-State Letters, Vol. 4, Issue 12
DOI: 10.1149/1.1414943

Highly porous palladium bulk: Preparation and properties as active metal material for displacement chromatographic process
journal, February 2009

Li, M.; Yang, W.
International Journal of Hydrogen Energy, Vol. 34, Issue 3
DOI: 10.1016/j.ijhydene.2008.12.014

Palladium in fuel cell catalysis
journal, January 2009

Antolini, Ermete
Energy & Environmental Science, Vol. 2, Issue 9
DOI: 10.1039/b820837a

Palladium particles embedded into silica optical fibers for hydrogen gas detection
conference, May 2014

Leparmentier, Stéphanie; Auguste, Jean-Louis; Humbert, Georges
SPIE Proceedings
DOI: 10.1117/12.2054303

Palladium-based electrocatalysts for hydrogen oxidation and oxygen reduction reactions
journal, March 2011

Shao, Minhua
Journal of Power Sources, Vol. 196, Issue 5
DOI: 10.1016/j.jpowsour.2010.10.093

Surface-modified advanced hydrogen storage alloys for hydrogen separation and purification
journal, September 2011

Lototsky, M. V.; Williams, M.; Yartys, V. A.
Journal of Alloys and Compounds, Vol. 509
DOI: 10.1016/j.jallcom.2010.09.206

Electrochemical study of palladium powder catalysts
journal, September 1976

Mallat, T.
Journal of Catalysis, Vol. 44, Issue 3
DOI: 10.1016/0021-9517(76)90410-3

Model of hydrogen permeation behavior in palladium membranes
journal, February 1999

Ward, Timothy L.; Dao, Tien
Journal of Membrane Science, Vol. 153, Issue 2
DOI: 10.1016/s0376-7388(98)00256-7

Studies of isotopic exchange between gaseous hydrogen and palladium hydride powder
journal, December 1987

Foltz, G.
Journal of Catalysis, Vol. 108, Issue 2
DOI: 10.1016/0021-9517(87)90189-8

Atomic-Layer Electroless Deposition: A Scalable Approach to Surface-Modified Metal Powders
journal, April 2014

Cappillino, Patrick J.; Sugar, Joshua D.; El Gabaly, Farid
Langmuir, Vol. 30, Issue 16, p. 4820-4829
DOI: 10.1021/la500477s

Electrochemical absorption and oxidation of hydrogen on palladium alloys with platinum, gold and rhodium
journal, January 2010

Łukaszewski, Mariusz; Hubkowska, Katarzyna; Czerwiński, Andrzej
Physical Chemistry Chemical Physics, Vol. 12, Issue 43
DOI: 10.1039/c0cp00542h

Electrosorption of hydrogen into palladium–rhodium alloys
journal, April 2006

Żurowski, A.; Łukaszewski, M.; Czerwiński, A.
Electrochimica Acta, Vol. 51, Issue 15
DOI: 10.1016/j.electacta.2005.08.047

Electrochemical Atomic Layer Deposition (E-ALD) of Palladium Nanofilms by Surface Limited Redox Replacement (SLRR), with EDTA Complexation
journal, February 2012

Sheridan, Leah B.; Czerwiniski, Justin; Jayaraju, Nagarajan
Electrocatalysis, Vol. 3, Issue 2
DOI: 10.1007/s12678-012-0080-7

New ambient pressure photoemission endstation at Advanced Light Source beamline 9.3.2
journal, May 2010

Grass, Michael E.; Karlsson, Patrik G.; Aksoy, Funda
Review of Scientific Instruments, Vol. 81, Issue 5
DOI: 10.1063/1.3427218

The quantitative analysis of thin specimens
journal, March 1975

Cliff, G.; Lorimer, G. W.
Journal of Microscopy, Vol. 103, Issue 2
DOI: 10.1111/j.1365-2818.1975.tb03895.x

A study of the dissolution of platinum, palladium, rhodium and gold electrodes in 1 $m$ sulphuric acid by cyclic voltammetry
journal, March 1972

Rand, D. A. J.; Woods, R.
Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 35, Issue 1, p. 209-218
DOI: 10.1016/0368-1874(72)80060-1

Simulation of electron spectra for surface analysis (SESSA): a novel software tool for quantitative Auger-electron spectroscopy and X-ray photoelectron spectroscopy
journal, January 2005

Smekal, Werner; Werner, Wolfgang S. M.; Powell, Cedric J.
Surface and Interface Analysis, Vol. 37, Issue 11
DOI: 10.1002/sia.2097

Atomic Layer Deposition of High-Purity Palladium Films from Pd(hfac) 2 and H 2 and O 2 Plasmas
journal, April 2014

Weber, Matthieu J.; Mackus, Adriaan J. M.; Verheijen, Marcel A.
The Journal of Physical Chemistry C, Vol. 118, Issue 16
DOI: 10.1021/jp5009412

Atomic Layer Electrodeposition
journal, December 2012

Switzer, J. A.
Science, Vol. 338, Issue 6112
DOI: 10.1126/science.1231853

Growth of Pt by surface limited redox replacement of underpotentially deposited hydrogen
journal, December 2013

Nutariya, J.; Fayette, M.; Dimitrov, N.
Electrochimica Acta, Vol. 112
DOI: 10.1016/j.electacta.2013.01.052

Works referencing / citing this record:

Preparation of an ultrathin Pt electrocatalyst via a galvanic replacement reaction of electrodeposited CuCl for the oxidation of methanol in an alkaline medium
journal, January 2018

Chao, Long; Liu, Nian; Xiong, Xiujuan
Chemical Communications, Vol. 54, Issue 30
DOI: 10.1039/c8cc00879e

Similar Records in DOE PAGES and OSTI.GOV collections:

Hydrogen Sorption Kinetics on Bare and Platinum-Modified Palladium Nanofilms, Grown by Electrochemical Atomic Layer Deposition (E-ALD)

Journal Article Jagannathan, Kaushik ; Benson, David M. ; Robinson, David B. ; ... - Journal of the Electrochemical Society

Nanofilms of Pd were grown using an electrochemical form of atomic layer deposition (E-ALD) on 100 nm evaporated Au films on glass. Multiple cycles of surface-limited redox replacement (SLRR) were used to grow deposits. Each SLRR involved the underpotential deposition (UPD) of a Cu atomic layer, followed by open circuit replacement via redox exchange with tetrachloropalladate, forming a Pd atomic layer: one E-ALD deposition cycle. That cycle was repeated in order to grow deposits of a desired thickness. 5 cycles of Pd deposition were performed on the Au on glass substrates, resulting in the formation of 2.5 monolayers of Pd.more »« less
Cited by 2
https://doi.org/10.1149/2.0051612jes

Full Text Available
Adsorption Processes during Electrochemical Atomic Layer Deposition of Gold

Journal Article Wasalathanthri, Ruwani N. ; Gong, Yukun ; Biener, Monika M. ; ... - Journal of the Electrochemical Society

Electrochemical atomic layer deposition (e-ALD) technique offers a simple and effective "wet chemistry" approach enabling high-precision monolayer-by-monolayer deposition of metal films. The process of e-ALD of Au involves lead underpotential deposition (PbUPD) followed by its redox replacement by a Au monolayer. The time evolution of the deposit mass during "one-pot" Au e-ALD is known to exhibit a unique three-stage response that is presently not well understood. In this work, we probe this response using voltammetry, electrochemical quartz crystal microgravimetry (e-QCM), and chronoamperometry to unravel the underlying mechanistic events during Au e-ALD. Furthermore, the presence of adsorbed Au⁺³-ligand complex(es) (Au-L) onmore »« less
https://doi.org/10.1149/1945-7111/ac3310

Full Text Available
Electrochemical and surface studies of the deposition of mercury and selenium at a gold electrode. [Underpotential]

Technical Report Schadewald, L A

The term underpotential deposition (UPD) refers to the electrodeposition of metal ions from solution onto substrates of noble metals at potentials positive to the thermodynamic Nernst potential for bulk deposition of that particular metal. The research described in this dissertation involves the study of the deposition of Hg(II) and Se(IV) at polycrystalline gold electrodes by cyclic voltammetry, flow-through coulometry and various surface spectroscopies. The work described here has been performed over a higher range of concentration than was previously studied. Also, this work includes investigations utilizing Scanning Electron Microscopy (SEM), Auger Electron Spectroscopy (AES), and Electron Spectroscopy for Chemical Analysismore » (ESCA).« less
The effect of specific chloride adsorption on the electrochemicalbehavior of ultrathin Pd films deposited on Pt(111) in acidsolution

Journal Article de, arenz@thch uni-bonn - Surface Science

The electrochemical behavior of thin Pd films supported on a Pt(111) electrode is investigated by cyclic voltammetry (CV) and in-situ Fourier transform infrared (FTIR) spectroscopy. It is demonstrated that in perchloric acid solution underpotential deposition of hydrogen (H{sub upd}) and hydroxyl adsorption (OH{sub ad}) is in strong competition with the adsorption of Cl- anions, the latter being present as a trace impurity in HClO{sub 4}. The interaction of Cl- with Pd is rather strong, controlling the adsorption of H{sub upd} and OH{sub ad} as well as the kinetic rate of CO oxidation. The microscopic insight (the binding sites) of themore »« less
Full Text Available
Energetics of the underpotential deposition of hydrogen on platinum electrodes. 1: Absence of coadsorbed species

Journal Article Zolfaghari, A ; Chayer, M ; Jerkiewicz, G - Journal of the Electrochemical Society

Research on the underpotential deposition of hydrogen (UPD H) on Pt electrodes by cyclic voltammetry in 0.05, 0.10, and 0.50 M aqueous H{sub 2}SO{sub 4} solutions at temperatures from 273 to 343 K shows that the adsorption-desorption profiles shift toward less positive values upon temperature (T) increase. Treatment of the experimental results based on a general electrochemical adsorption isotherm allows determination of {Delta}G{sub ads}{sup o} (H(UPD)) as a function of T and the H(UPD) surface coverage, {theta}{sub H(UPD)}; {Delta}G{sub ads}{sup o} (H(UPD)) varies from {minus}11 to {minus}25 kJ/mol. The relation between {Delta}G{sub ads}{sup o} (H(UPD)) and T for {theta}{sub H(UPD)}more »« less
https://doi.org/10.1149/1.1837955

Similar Records

Title: Enhanced Kinetics of Electrochemical Hydrogen Uptake and Release by Palladium Powders Modified by Electrochemical Atomic Layer Deposition

Abstract

Citation Formats

Atomic Layer Deposition: An Overview journal, January 2010

Supported Ru−Pt Bimetallic Nanoparticle Catalysts Prepared by Atomic Layer Deposition journal, August 2010

Toward atomically-precise synthesis of supported bimetallic nanoparticles using atomic layer deposition journal, February 2014

Ordered Anion Adlayers on Metal Electrode Surfaces journal, March 2002

Thin-layer electrochemical studies of the underpotential deposition of cadmium and tellurium on polycrystalline Au, Pt and Cu electrodes journal, October 1990

Electrochemical atomic layer epitaxy (ECALE) journal, February 1991

Conditions for the Deposition of CdTe by Electrochemical Atomic Layer Epitaxy journal, May 1991

Underpotential Deposition at Single Crystal Surfaces of Au, Pt, Ag and Other Materials journal, July 2001

Surface-Enhanced Raman Scattering on Uniform Platinum-Group Overlayers: Preparation by Redox Replacement of Underpotential-Deposited Metals on Gold journal, December 2001

Platinum Nanofilm Formation by EC-ALE via Redox Replacement of UPD Copper: Studies Using in-Situ Scanning Tunneling Microscopy journal, September 2006

Epitaxial Growth by Monolayer-Restricted Galvanic Displacement journal, January 2005

Electrochemical Atomic Layer Deposition (E-ALD) of Pt Nanofilms Using SLRR Cycles journal, January 2012

Formation of Palladium Nanofilms Using Electrochemical Atomic Layer Deposition (E-ALD) with Chloride Complexation journal, January 2013

Electrodeposition of Ru by atomic layer deposition (ALD) journal, September 2008

Hydrogen sorption properties of bare and Rh-modified Pd nanofilms grown via surface limited redox replacement reactions journal, May 2014

Hydrogen Sorption Kinetics on Bare and Platinum-Modified Palladium Nanofilms, Grown by Electrochemical Atomic Layer Deposition (E-ALD) journal, January 2016

The effect of surface species on the rate of H sorption into nanostructured Pd journal, January 2004

Surface and Subsurface Hydrogen: Adsorption Properties on Transition Metals and Near-Surface Alloys journal, March 2005

Effects of surface thermodynamics on hydrogen isotope exchange kinetics in palladium: Particle and flow models journal, January 2015

Ternary semiconductor compounds CuInS2 (CIS) thin films synthesized by electrochemical atomic layer deposition (EC-ALD) journal, April 2010

Electrochemical growth of Cu–Zn sulfides journal, December 2013

Electrodeposited Cu2ZnSnS4 thin films journal, May 2014

Nanocrystallized Cu2Se grown on electroless Cu coated p-type Si using electrochemical atomic layer deposition journal, January 2015

Pt Submonolayers on Ru Nanoparticles: A Novel Low Pt Loading, High CO Tolerance Fuel Cell Electrocatalyst journal, January 2001

Highly porous palladium bulk: Preparation and properties as active metal material for displacement chromatographic process journal, February 2009

Palladium in fuel cell catalysis journal, January 2009

Palladium particles embedded into silica optical fibers for hydrogen gas detection conference, May 2014

Palladium-based electrocatalysts for hydrogen oxidation and oxygen reduction reactions journal, March 2011

Surface-modified advanced hydrogen storage alloys for hydrogen separation and purification journal, September 2011

Electrochemical study of palladium powder catalysts journal, September 1976

Model of hydrogen permeation behavior in palladium membranes journal, February 1999

Studies of isotopic exchange between gaseous hydrogen and palladium hydride powder journal, December 1987

Atomic-Layer Electroless Deposition: A Scalable Approach to Surface-Modified Metal Powders journal, April 2014

Electrochemical absorption and oxidation of hydrogen on palladium alloys with platinum, gold and rhodium journal, January 2010

Electrosorption of hydrogen into palladium–rhodium alloys journal, April 2006

Electrochemical Atomic Layer Deposition (E-ALD) of Palladium Nanofilms by Surface Limited Redox Replacement (SLRR), with EDTA Complexation journal, February 2012

New ambient pressure photoemission endstation at Advanced Light Source beamline 9.3.2 journal, May 2010

The quantitative analysis of thin specimens journal, March 1975

A study of the dissolution of platinum, palladium, rhodium and gold electrodes in 1 $m$ sulphuric acid by cyclic voltammetry journal, March 1972

Simulation of electron spectra for surface analysis (SESSA): a novel software tool for quantitative Auger-electron spectroscopy and X-ray photoelectron spectroscopy journal, January 2005

Atomic Layer Deposition of High-Purity Palladium Films from Pd(hfac) 2 and H 2 and O 2 Plasmas journal, April 2014

Atomic Layer Electrodeposition journal, December 2012

Growth of Pt by surface limited redox replacement of underpotentially deposited hydrogen journal, December 2013

Preparation of an ultrathin Pt electrocatalyst via a galvanic replacement reaction of electrodeposited CuCl for the oxidation of methanol in an alkaline medium journal, January 2018

Atomic Layer Deposition: An Overview
journal, January 2010

Supported Ru−Pt Bimetallic Nanoparticle Catalysts Prepared by Atomic Layer Deposition
journal, August 2010

Toward atomically-precise synthesis of supported bimetallic nanoparticles using atomic layer deposition
journal, February 2014

Ordered Anion Adlayers on Metal Electrode Surfaces
journal, March 2002

Thin-layer electrochemical studies of the underpotential deposition of cadmium and tellurium on polycrystalline Au, Pt and Cu electrodes
journal, October 1990

Electrochemical atomic layer epitaxy (ECALE)
journal, February 1991

Conditions for the Deposition of CdTe by Electrochemical Atomic Layer Epitaxy
journal, May 1991

Underpotential Deposition at Single Crystal Surfaces of Au, Pt, Ag and Other Materials
journal, July 2001

Surface-Enhanced Raman Scattering on Uniform Platinum-Group Overlayers: Preparation by Redox Replacement of Underpotential-Deposited Metals on Gold
journal, December 2001

Platinum Nanofilm Formation by EC-ALE via Redox Replacement of UPD Copper: Studies Using in-Situ Scanning Tunneling Microscopy
journal, September 2006

Epitaxial Growth by Monolayer-Restricted Galvanic Displacement
journal, January 2005

Electrochemical Atomic Layer Deposition (E-ALD) of Pt Nanofilms Using SLRR Cycles
journal, January 2012

Formation of Palladium Nanofilms Using Electrochemical Atomic Layer Deposition (E-ALD) with Chloride Complexation
journal, January 2013

Electrodeposition of Ru by atomic layer deposition (ALD)
journal, September 2008

Hydrogen sorption properties of bare and Rh-modified Pd nanofilms grown via surface limited redox replacement reactions
journal, May 2014

Hydrogen Sorption Kinetics on Bare and Platinum-Modified Palladium Nanofilms, Grown by Electrochemical Atomic Layer Deposition (E-ALD)
journal, January 2016

The effect of surface species on the rate of H sorption into nanostructured Pd
journal, January 2004

Surface and Subsurface Hydrogen: Adsorption Properties on Transition Metals and Near-Surface Alloys
journal, March 2005

Effects of surface thermodynamics on hydrogen isotope exchange kinetics in palladium: Particle and flow models
journal, January 2015

Ternary semiconductor compounds CuInS2 (CIS) thin films synthesized by electrochemical atomic layer deposition (EC-ALD)
journal, April 2010

Electrochemical growth of Cu–Zn sulfides
journal, December 2013

Electrodeposited Cu2ZnSnS4 thin films
journal, May 2014

Nanocrystallized Cu2Se grown on electroless Cu coated p-type Si using electrochemical atomic layer deposition
journal, January 2015

Pt Submonolayers on Ru Nanoparticles: A Novel Low Pt Loading, High CO Tolerance Fuel Cell Electrocatalyst
journal, January 2001

Highly porous palladium bulk: Preparation and properties as active metal material for displacement chromatographic process
journal, February 2009

Palladium in fuel cell catalysis
journal, January 2009

Palladium particles embedded into silica optical fibers for hydrogen gas detection
conference, May 2014

Palladium-based electrocatalysts for hydrogen oxidation and oxygen reduction reactions
journal, March 2011

Surface-modified advanced hydrogen storage alloys for hydrogen separation and purification
journal, September 2011

Electrochemical study of palladium powder catalysts
journal, September 1976

Model of hydrogen permeation behavior in palladium membranes
journal, February 1999

Studies of isotopic exchange between gaseous hydrogen and palladium hydride powder
journal, December 1987

Atomic-Layer Electroless Deposition: A Scalable Approach to Surface-Modified Metal Powders
journal, April 2014

Electrochemical absorption and oxidation of hydrogen on palladium alloys with platinum, gold and rhodium
journal, January 2010

Electrosorption of hydrogen into palladium–rhodium alloys
journal, April 2006

Electrochemical Atomic Layer Deposition (E-ALD) of Palladium Nanofilms by Surface Limited Redox Replacement (SLRR), with EDTA Complexation
journal, February 2012

New ambient pressure photoemission endstation at Advanced Light Source beamline 9.3.2
journal, May 2010

The quantitative analysis of thin specimens
journal, March 1975

A study of the dissolution of platinum, palladium, rhodium and gold electrodes in 1 $m$ sulphuric acid by cyclic voltammetry
journal, March 1972

Simulation of electron spectra for surface analysis (SESSA): a novel software tool for quantitative Auger-electron spectroscopy and X-ray photoelectron spectroscopy
journal, January 2005

Atomic Layer Deposition of High-Purity Palladium Films from Pd(hfac) 2 and H 2 and O 2 Plasmas
journal, April 2014

Atomic Layer Electrodeposition
journal, December 2012

Growth of Pt by surface limited redox replacement of underpotentially deposited hydrogen
journal, December 2013

Preparation of an ultrathin Pt electrocatalyst via a galvanic replacement reaction of electrodeposited CuCl for the oxidation of methanol in an alkaline medium
journal, January 2018