Magnetically Recoverable Pd/Fe3O4 Core-Shell Nanowire Clusters with Increased Hydrogenation Activity
Abstract
Abstract Core–shell nanostructures are promising candidates for the next generation of catalysts due to synergistic effects which can arise from having two active species in close contact, leading to increased activity. Likewise, catalysts displaying added functionality, such as a magnetic response, can have increased scientific and industrial potential. Here, Pd/Fe 3 O 4 core–shell nanowire clusters are synthesized and applied as hydrogenation catalysts for an industrially important hydrogenation reaction: the conversion of acetophenone to 1‐phenylethanol. During synthesis, the palladium nanowires self‐assemble into clusters which act as a high‐surface‐area framework for the growth of a magnetic iron oxide shell. This material demonstrates excellent catalytic activity due to the presence of palladium while the strong magnetic properties provided by the iron oxide shell enable facile catalyst recovery.
- Authors:
-
- Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
- Publication Date:
- Research Org.:
- Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
- Sponsoring Org.:
- USDOE National Nuclear Security Administration (NNSA)
- OSTI Identifier:
- 1356218
- Alternate Identifier(s):
- OSTI ID: 1401749
- Report Number(s):
- SAND-2017-2638J
Journal ID: ISSN 2192-6506; 651634
- Grant/Contract Number:
- AC04-94AL85000
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ChemPlusChem
- Additional Journal Information:
- Journal Volume: 82; Journal Issue: 3; Journal ID: ISSN 2192-6506
- Publisher:
- ChemPubSoc Europe
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Watt, John, Kotula, Paul G., and Huber, Dale L. Magnetically Recoverable Pd/Fe3O4 Core-Shell Nanowire Clusters with Increased Hydrogenation Activity. United States: N. p., 2017.
Web. doi:10.1002/cplu.201700009.
Watt, John, Kotula, Paul G., & Huber, Dale L. Magnetically Recoverable Pd/Fe3O4 Core-Shell Nanowire Clusters with Increased Hydrogenation Activity. United States. https://doi.org/10.1002/cplu.201700009
Watt, John, Kotula, Paul G., and Huber, Dale L. Mon .
"Magnetically Recoverable Pd/Fe3O4 Core-Shell Nanowire Clusters with Increased Hydrogenation Activity". United States. https://doi.org/10.1002/cplu.201700009. https://www.osti.gov/servlets/purl/1356218.
@article{osti_1356218,
title = {Magnetically Recoverable Pd/Fe3O4 Core-Shell Nanowire Clusters with Increased Hydrogenation Activity},
author = {Watt, John and Kotula, Paul G. and Huber, Dale L.},
abstractNote = {Abstract Core–shell nanostructures are promising candidates for the next generation of catalysts due to synergistic effects which can arise from having two active species in close contact, leading to increased activity. Likewise, catalysts displaying added functionality, such as a magnetic response, can have increased scientific and industrial potential. Here, Pd/Fe 3 O 4 core–shell nanowire clusters are synthesized and applied as hydrogenation catalysts for an industrially important hydrogenation reaction: the conversion of acetophenone to 1‐phenylethanol. During synthesis, the palladium nanowires self‐assemble into clusters which act as a high‐surface‐area framework for the growth of a magnetic iron oxide shell. This material demonstrates excellent catalytic activity due to the presence of palladium while the strong magnetic properties provided by the iron oxide shell enable facile catalyst recovery.},
doi = {10.1002/cplu.201700009},
journal = {ChemPlusChem},
number = 3,
volume = 82,
place = {United States},
year = {Mon Feb 06 00:00:00 EST 2017},
month = {Mon Feb 06 00:00:00 EST 2017}
}
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