Search Menu
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information
Search Scholarly Publications

Title: Discovery-Synthesis, Design, and Prediction of Chalcogenide Phases

Abstract

The discovery of new materials and their efficient syntheses is a fundamental goal of chemistry. A related objective is to identify foundational and rational approaches to enhance the art of synthesis by combining the exquisite predictability of organic synthesis with the high yields of solid-state chemistry. In contrast to so-called solid-state methods, inorganic syntheses in liquid fluxes permit bond formation, framework assembly, and crystallization at lower temperatures because of facile diffusion and chemical reactions with and within the flux itself. The fluxes are bona fide solvents similar to conventional organic or aqueous solvents. Such reactions can produce a wide range of materials, often metastable, from oxides to intermetallics, but typically the formation mechanisms are poorly understood. This article discusses how one can design, perform, observe, understand, and engineer the formation of compounds from inorganic melts. The focus is also design concepts such as "dimensional reduction", "phase homologies", and "panoramic synthesis", and their broad applicability. When well-defined building blocks are present and stable in the reaction, prospects for increased structural diversity and product control increase substantially. Common structural motifs within these materials systems may be related to structural precursors in the melt that may be controlled by tuning reaction conditions andmore » composition. Stabilization of a particular building block is often accomplished with tuning of the flux composition, which controls the Lewis basicity and redox potential. In such tunable and dynamic fluxes, the synthesis can be directed toward new materials. Using complementary techniques of in situ X-ray diffraction, we can create time-dependent maps of reaction space and probe the mobile species present in melts. Lastly, certain thoughts toward the ultimate goal of targeted materials synthesis by controlling inorganic melt chemistry are discussed.« less

Authors:
ORCiD logo [1]
+ Show Author Affiliations
  1. Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry; Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division
Publication Date:
Research Org.:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Org.:
National Science Foundation (NSF); U.S. Department of Homeland Security; USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1352876
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
Inorganic Chemistry
Additional Journal Information:
Journal Volume: 56; Journal Issue: 6; Journal ID: ISSN 0020-1669
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE

Citation Formats

Kanatzidis, Mercouri G. Discovery-Synthesis, Design, and Prediction of Chalcogenide Phases. United States: N. p., 2017. Web. doi:10.1021/acs.inorgchem.7b00188.
Copy to clipboard
Kanatzidis, Mercouri G. Discovery-Synthesis, Design, and Prediction of Chalcogenide Phases. United States. https://doi.org/10.1021/acs.inorgchem.7b00188
Copy to clipboard
Kanatzidis, Mercouri G. Thu . "Discovery-Synthesis, Design, and Prediction of Chalcogenide Phases". United States. https://doi.org/10.1021/acs.inorgchem.7b00188. https://www.osti.gov/servlets/purl/1352876.
Copy to clipboard
@article{osti_1352876,
title = {Discovery-Synthesis, Design, and Prediction of Chalcogenide Phases},
author = {Kanatzidis, Mercouri G.},
abstractNote = {The discovery of new materials and their efficient syntheses is a fundamental goal of chemistry. A related objective is to identify foundational and rational approaches to enhance the art of synthesis by combining the exquisite predictability of organic synthesis with the high yields of solid-state chemistry. In contrast to so-called solid-state methods, inorganic syntheses in liquid fluxes permit bond formation, framework assembly, and crystallization at lower temperatures because of facile diffusion and chemical reactions with and within the flux itself. The fluxes are bona fide solvents similar to conventional organic or aqueous solvents. Such reactions can produce a wide range of materials, often metastable, from oxides to intermetallics, but typically the formation mechanisms are poorly understood. This article discusses how one can design, perform, observe, understand, and engineer the formation of compounds from inorganic melts. The focus is also design concepts such as "dimensional reduction", "phase homologies", and "panoramic synthesis", and their broad applicability. When well-defined building blocks are present and stable in the reaction, prospects for increased structural diversity and product control increase substantially. Common structural motifs within these materials systems may be related to structural precursors in the melt that may be controlled by tuning reaction conditions and composition. Stabilization of a particular building block is often accomplished with tuning of the flux composition, which controls the Lewis basicity and redox potential. In such tunable and dynamic fluxes, the synthesis can be directed toward new materials. Using complementary techniques of in situ X-ray diffraction, we can create time-dependent maps of reaction space and probe the mobile species present in melts. Lastly, certain thoughts toward the ultimate goal of targeted materials synthesis by controlling inorganic melt chemistry are discussed.},
doi = {10.1021/acs.inorgchem.7b00188},
journal = {Inorganic Chemistry},
number = 6,
volume = 56,
place = {United States},
year = {Thu Mar 09 00:00:00 EST 2017},
month = {Thu Mar 09 00:00:00 EST 2017}
}
Copy to clipboard
Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1021/acs.inorgchem.7b00188
Copyright Statement
Other availability
Search WorldCat Search WorldCat to find libraries that may hold this journal
Citation Metrics:
Cited by: 140 works
Citation information provided by
Web of Science
Save / Share:
Export Metadata
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.

Works referenced in this record:

A new molybdenum(IV) thioanion containing the Mo:St unit. Synthesis and structural characterization of bis(tetraethylammonium) nonathiomolybdate
journal, March 1981

  • Simhon, E. D.; Baenziger, N. C.; Kanatzidis, M.
  • Journal of the American Chemical Society, Vol. 103, Issue 5
  • DOI: 10.1021/ja00395a040

Coordination chemistry of heavy polychalcogenide ligands
journal, February 1994

Synthesis and reactions of binary metal sulfides. Structural characterization of the [(S4)2Zn]2-, [(S4)2Ni]2-, [(S5)Mn(S6)]2-, and [(CS4)2Ni]2- anions
journal, January 1985

  • Coucouvanis, D.; Patil, P. R.; Kanatzidis, M. G.
  • Inorganic Chemistry, Vol. 24, Issue 1
  • DOI: 10.1021/ic00195a007

New directions in synthetic solid state chemistry: chalcophosphate salt fluxes for discovery of new multinary solids
journal, April 1997

Chalcogenidometalates of the heavier Group 14 and 15 elements
journal, September 1998

A coordination chemistry approach towards ternary M/14/16 anions
journal, May 2007

Synthesis and Structure of Li 4 GeS 4 a
journal, January 1998

  • Matsushita, Yoshitaka; Kanatzidis, Mercouri G.
  • Zeitschrift für Naturforschung B, Vol. 53, Issue 1
  • DOI: 10.1515/znb-1998-0107

Helical Polymer 1 / ∞ [P 2 Se 6 2 - ]:  Strong Second Harmonic Generation Response and Phase-Change Properties of Its K and Rb Salts
journal, November 2007

  • Chung, In; Malliakas, Christos D.; Jang, Joon I.
  • Journal of the American Chemical Society, Vol. 129, Issue 48
  • DOI: 10.1021/ja075096c

[P 6 Se 12 ] 4 - : A Phosphorus-Rich Selenophosphate with Low-Valent P Centers
journal, April 2006

  • Chung, In; Karst, Angela L.; Weliky, David P.
  • Inorganic Chemistry, Vol. 45, Issue 7
  • DOI: 10.1021/ic0601135

Low valent phosphorus in the molecular anions [P5Se12]5– and β-[P6Se12]4–: phase change behavior and near infrared second harmonic generation
journal, January 2007

  • Chung, In; Jang, Joon I.; Gave, Matthew A.
  • Chemical Communications, Issue 47
  • DOI: 10.1039/b714301j

APSe 6 (A = K, Rb, and Cs):  Polymeric Selenophosphates with Reversible Phase-Change Properties
journal, May 2004

  • Chung, In; Do, Junghwan; Canlas, Christian G.
  • Inorganic Chemistry, Vol. 43, Issue 9
  • DOI: 10.1021/ic035448q

Phase-Change Behavior and Nonlinear Optical Second and Third Harmonic Generation of the One-Dimensional K (1– x ) Cs x PSe 6 and Metastable β-CsPSe 6
journal, February 2015

Self-Assembling Frameworks: Beyond microporous oxides
journal, January 1996

The puzzle of high temperature superconductivity in layered iron pnictides and chalcogenides
journal, October 2010

New and Old Concepts in Thermoelectric Materials
journal, November 2009

  • Sootsman, Joseph R.; Chung, Duck Young; Kanatzidis, Mercouri G.
  • Angewandte Chemie International Edition, Vol. 48, Issue 46, p. 8616-8639
  • DOI: 10.1002/anie.200900598

Overview of Phase-Change Chalcogenide Nonvolatile Memory Technology
journal, November 2004

Low-field amorphous state resistance and threshold voltage drift in chalcogenide materials
journal, May 2004

  • Pirovano, A.; Lacaita, A. L.; Pellizzer, F.
  • IEEE Transactions on Electron Devices, Vol. 51, Issue 5
  • DOI: 10.1109/TED.2004.825805

Phase Change Memory
journal, December 2010

Intrinsic memristance mechanism of crystalline stoichiometric Ge 2 Sb 2 Te 5
journal, July 2013

  • Li, Y.; Zhong, Y. P.; Zhang, J. J.
  • Applied Physics Letters, Vol. 103, Issue 4
  • DOI: 10.1063/1.4816283

Beyond von-Neumann Computing with Nanoscale Phase-Change Memory Devices
journal, December 2012

  • Wright, C. David; Hosseini, Peiman; Diosdado, Jorge A. Vazquez
  • Advanced Functional Materials, Vol. 23, Issue 18
  • DOI: 10.1002/adfm.201202383

Strong Second Harmonic Generation from the Tantalum Thioarsenates A 3 Ta 2 AsS 11 (A = K and Rb)
journal, December 2008

  • Bera, Tarun K.; Jang, Joon I.; Ketterson, John B.
  • Journal of the American Chemical Society, Vol. 131, Issue 1
  • DOI: 10.1021/ja807928d

Soluble Semiconductors AAsSe 2 (A = Li, Na) with a Direct-Band-Gap and Strong Second Harmonic Generation: A Combined Experimental and Theoretical Study
journal, March 2010

  • Bera, Tarun K.; Jang, Joon I.; Song, Jung-Hwan
  • Journal of the American Chemical Society, Vol. 132, Issue 10
  • DOI: 10.1021/ja9094846

Functionalization Based on the Substitutional Flexibility: Strong Middle IR Nonlinear Optical Selenides AX II 4 X III 5 Se 12
journal, August 2013

  • Lin, Hua; Chen, Ling; Zhou, Liu-Jiang
  • Journal of the American Chemical Society, Vol. 135, Issue 34
  • DOI: 10.1021/ja4074084

Exploration of New Second-Order Nonlinear Optical Compounds Containing Main Group Elements
book, January 2012

Second-Harmonic Generation and Crystal Structure of the Diamond-like Semiconductors Li 2 CdGeS 4 and Li 2 CdSnS 4
journal, July 2009

  • Lekse, Jonathan W.; Moreau, Meghann A.; McNerny, Katie L.
  • Inorganic Chemistry, Vol. 48, Issue 16
  • DOI: 10.1021/ic9010339

Ab initio study of elasticity, piezoelectricity, and nonlinear optical performance in monoclinic NaAsSe2
journal, August 2013

Metal Chalcogenides: A Rich Source of Nonlinear Optical Materials
journal, August 2013

  • Chung, In; Kanatzidis, Mercouri G.
  • Chemistry of Materials, Vol. 26, Issue 1
  • DOI: 10.1021/cm401737s

19·9%-efficient ZnO/CdS/CuInGaSe 2 solar cell with 81·2% fill factor
journal, May 2008

  • Repins, Ingrid; Contreras, Miguel A.; Egaas, Brian
  • Progress in Photovoltaics: Research and Applications, Vol. 16, Issue 3
  • DOI: 10.1002/pip.822

New world record efficiency for Cu(In,Ga)Se2 thin-film solar cells beyond 20%
journal, January 2011

  • Jackson, Philip; Hariskos, Dimitrios; Lotter, Erwin
  • Progress in Photovoltaics: Research and Applications, Vol. 19, Issue 7
  • DOI: 10.1002/pip.1078

Solution-Based Synthesis and Characterization of Cu 2 ZnSnS 4 Nanocrystals
journal, September 2009

  • Riha, Shannon C.; Parkinson, Bruce A.; Prieto, Amy L.
  • Journal of the American Chemical Society, Vol. 131, Issue 34
  • DOI: 10.1021/ja9044168

High-Efficiency Solar Cell with Earth-Abundant Liquid-Processed Absorber
journal, May 2010

  • Todorov, Teodor K.; Reuter, Kathleen B.; Mitzi, David B.
  • Advanced Materials, Vol. 22, Issue 20, p. E156-E159
  • DOI: 10.1002/adma.200904155

Hydrazine-Processed Ge-Substituted CZTSe Solar Cells
journal, November 2012

  • Bag, Santanu; Gunawan, Oki; Gokmen, Tayfun
  • Chemistry of Materials, Vol. 24, Issue 23
  • DOI: 10.1021/cm302881g

High performance bulk thermoelectrics via a panoscopic approach
journal, May 2013

Resonant levels in bulk thermoelectric semiconductors
journal, January 2012

  • Heremans, Joseph P.; Wiendlocha, Bartlomiej; Chamoire, Audrey M.
  • Energy Environ. Sci., Vol. 5, Issue 2
  • DOI: 10.1039/C1EE02612G

Band Engineering of Thermoelectric Materials
journal, October 2012

Photon Counting Energy Dispersive Detector Arrays for X-ray Imaging
journal, June 2009

  • Iwanczyk, Jan S.; Nygard, Einar; Meirav, Oded
  • IEEE Transactions on Nuclear Science, Vol. 56, Issue 3
  • DOI: 10.1109/TNS.2009.2013709

High Energy Resolution Hard X-Ray and Gamma-Ray Imagers Using CdTe Diode Devices
journal, June 2009

  • Watanabe, Shin; Ishikawa, Shin-nosuke; Aono, Hiroyuki
  • IEEE Transactions on Nuclear Science, Vol. 56, Issue 3
  • DOI: 10.1109/TNS.2008.2008806

HgCdTe infrared detector material: history, status and outlook
journal, August 2005

Chalcogenide thin-film transistors using oxygenated n-type and p-type phase change materials
journal, July 2008

  • Song, Ki-Bong; Sohn, Sung-Won; Kim, JunHo
  • Applied Physics Letters, Vol. 93, Issue 4
  • DOI: 10.1063/1.2963401

Single-layer MoS2 transistors
journal, January 2011

  • Radisavljevic, B.; Radenovic, A.; Brivio, J.
  • Nature Nanotechnology, Vol. 6, Issue 3, p. 147-150
  • DOI: 10.1038/nnano.2010.279

Single-Layer MoS2 Phototransistors
journal, December 2011

  • Yin, Zongyou; Li, Hai; Li, Hong
  • ACS Nano, Vol. 6, Issue 1, p. 74-80
  • DOI: 10.1021/nn2024557

How Good Can Monolayer MoS 2 Transistors Be?
journal, September 2011

  • Yoon, Youngki; Ganapathi, Kartik; Salahuddin, Sayeef
  • Nano Letters, Vol. 11, Issue 9
  • DOI: 10.1021/nl2018178

A highly ordered nanostructured carbon–sulphur cathode for lithium–sulphur batteries
journal, May 2009

  • Ji, Xiulei; Lee, Kyu Tae; Nazar, Linda F.
  • Nature Materials, Vol. 8, Issue 6, p. 500-506
  • DOI: 10.1038/nmat2460

Lithium batteries: Status, prospects and future
journal, May 2010

Functional Materials for Rechargeable Batteries
journal, March 2011

  • Cheng, Fangyi; Liang, Jing; Tao, Zhanliang
  • Advanced Materials, Vol. 23, Issue 15
  • DOI: 10.1002/adma.201003587

Sodium and sodium-ion energy storage batteries
journal, August 2012

  • Ellis, Brian L.; Nazar, Linda F.
  • Current Opinion in Solid State and Materials Science, Vol. 16, Issue 4, p. 168-177
  • DOI: 10.1016/j.cossms.2012.04.002

A lithium superionic conductor
journal, July 2011

  • Kamaya, Noriaki; Homma, Kenji; Yamakawa, Yuichiro
  • Nature Materials, Vol. 10, Issue 9, p. 682-686
  • DOI: 10.1038/nmat3066

Lithium Ionic Conductor Thio-LISICON: The Li2S-GeS2-P2S5 System
journal, January 2001

  • Kanno, Ryoji; Murayama, Masahiro
  • Journal of The Electrochemical Society, Vol. 148, Issue 7, p. A742-A746
  • DOI: 10.1149/1.1379028

Recent developments of molybdenum and tungsten sulfides as hydrogen evolution catalysts
journal, January 2011

  • Merki, Daniel; Hu, Xile
  • Energy & Environmental Science, Vol. 4, Issue 10, 3878
  • DOI: 10.1039/c1ee01970h

Hydrodeoxygenation of guaiacol with CoMo catalysts. Part I: Promoting effect of cobalt on HDO selectivity and activity
journal, January 2011

  • Bui, Van Ngoc; Laurenti, Dorothée; Afanasiev, Pavel
  • Applied Catalysis B: Environmental, Vol. 101, Issue 3-4, p. 239-245
  • DOI: 10.1016/j.apcatb.2010.10.025

Synthesis and catalysis of copper sulfide/carbon nanodots for oxygen reduction in direct methanol fuel cells
journal, March 2013

(NH 4 )AgMoS 4 : Synthesis, Structure and Catalytic Activity
journal, September 2012

  • Shafaei-Fallah, Maryam; Malliakas, Christos D.; Kanatzidis, Mercouri G.
  • Zeitschrift für anorganische und allgemeine Chemie, Vol. 638, Issue 15
  • DOI: 10.1002/zaac.201200309

Direct Observation of sp−d Exchange Interactions in Colloidal Mn 2+ - and Co 2+ -Doped CdSe Quantum Dots
journal, April 2007

  • Archer, Paul I.; Santangelo, Steven A.; Gamelin, Daniel R.
  • Nano Letters, Vol. 7, Issue 4
  • DOI: 10.1021/nl0702362

Magnetic Doping and Kondo Effect in Bi 2 Se 3 Nanoribbons
journal, March 2010

  • Cha, Judy J.; Williams, James R.; Kong, Desheng
  • Nano Letters, Vol. 10, Issue 3
  • DOI: 10.1021/nl100146n

Quantum Spin Hall Effect and Topological Phase Transition in HgTe Quantum Wells
journal, December 2006

  • Bernevig, B. A.; Hughes, T. L.; Zhang, S.-C.
  • Science, Vol. 314, Issue 5806, p. 1757-1761
  • DOI: 10.1126/science.1133734

Topological insulators in Bi2Se3, Bi2Te3 and Sb2Te3 with a single Dirac cone on the surface
journal, May 2009

  • Zhang, Haijun; Liu, Chao-Xing; Qi, Xiao-Liang
  • Nature Physics, Vol. 5, Issue 6, p. 438-442
  • DOI: 10.1038/nphys1270

p-type Bi2Se3 for topological insulator and low-temperature thermoelectric applications
journal, May 2009

  • Hor, Y. S.; Richardella, A.; Roushan, P.
  • Physical Review B, Vol. 79, Issue 19, Article No. 195208
  • DOI: 10.1103/PhysRevB.79.195208

Superconductivity in Cu x Bi 2 Se 3 and its Implications for Pairing in the Undoped Topological Insulator
journal, February 2010

Chemists join in
journal, March 2013

Separating the bulk and surface n - to p -type transition in the topological insulator GeBi 4 − x Sb x Te 7
journal, July 2013

Two-Dimensional Nanosheets Produced by Liquid Exfoliation of Layered Materials
journal, February 2011

MoS2 and WS2 Analogues of Graphene
journal, April 2010

  • Ramakrishna Matte, H. S. S.; Gomathi, A.; Manna, Arun K.
  • Angewandte Chemie International Edition, Vol. 49, Issue 24
  • DOI: 10.1002/anie.201000009

Electronics and optoelectronics of two-dimensional transition metal dichalcogenides
journal, November 2012

  • Wang, Qing Hua; Kalantar-Zadeh, Kourosh; Kis, Andras
  • Nature Nanotechnology, Vol. 7, Issue 11, p. 699-712
  • DOI: 10.1038/nnano.2012.193

Iron displacements and magnetoelastic coupling in the antiferromagnetic spin-ladder compound BaFe 2 Se 3
journal, November 2011

Orbital-selective magnetism in the spin-ladder iron selenides Ba 1 − x K x Fe 2 Se 3
journal, May 2012

Magnetic states of the two-leg-ladder alkali metal iron selenides A Fe 2 Se 3
journal, January 2013

Synthesis, Structure, Magnetism, and Optical Properties of Cs 2 Cu 3 DyTe 4
journal, October 2012

  • Babo, Jean-Marie; Choi, Eun Sang; Albrecht-Schmitt, Thomas E.
  • Inorganic Chemistry, Vol. 51, Issue 21
  • DOI: 10.1021/ic301649p

Two new ternary lanthanide antimony chalcogenides: Yb4Sb2S11.25 and Tm4Sb2Se11.68 containing chalcogenide Q2− and dichalcogenide (Q2)2− anions
journal, March 2012

Superconductivity in the iron selenide K x Fe 2 Se 2 ( 0 ≤ x ≤ 1.0 )
journal, November 2010

KFe 2 Se 2 is the Parent Compound of K-Doped Iron Selenide Superconductors
journal, July 2012

Electronic and magnetic phase diagram of β-Fe1.01Se with superconductivity at 36.7 K under pressure
journal, June 2009

  • Medvedev, S.; McQueen, T. M.; Troyan, I. A.
  • Nature Materials, Vol. 8, Issue 8
  • DOI: 10.1038/nmat2491

Synthesis and crystal structure of Cs2U3Se7
journal, April 2013

Thermoelectric Properties of TlGdQ2 (Q = Se, Te) and Tl9GdTe6
journal, December 2011

  • Sankar, Cheriyedath Raj; Bangarigadu-Sanasy, Savitree; Kleinke, Holger
  • Journal of Electronic Materials, Vol. 41, Issue 6
  • DOI: 10.1007/s11664-011-1846-z

Crystal Structures, Electronic Structures, and Physical Properties of Tl 4 MQ 4 (M = Zr or Hf; Q = S or Se)
journal, January 2011

  • Sankar, Cheriyedath Raj; Bangarigadu-Sanasy, Savitree; Assoud, Abdeljalil
  • Inorganic Chemistry, Vol. 50, Issue 1
  • DOI: 10.1021/ic101925a

Thermoelectric Properties of Stoichiometric Compounds in the (SnTe) x (Bi 2 Te 3 ) y System
journal, September 2012

  • Kuropatwa, Bryan A.; Kleinke, Holger
  • Zeitschrift für anorganische und allgemeine Chemie, Vol. 638, Issue 15
  • DOI: 10.1002/zaac.201200284

Crystal Structure and Physical Properties of the New One-Dimensional Metal Ba 2 Cu 7– x Te 6
journal, April 2012

  • Kuropatwa, Bryan A.; Assoud, Abdeljalil; Kleinke, Holger
  • Inorganic Chemistry, Vol. 51, Issue 9
  • DOI: 10.1021/ic300239c

Thermoelectric properties of Tl10−xLnxTe6, with Ln=Ce, Pr, Nd, Sm, Gd, Tb, Dy, Ho and Er, and 0.25⩽x⩽1.32
journal, February 2013

  • Bangarigadu-Sanasy, Savitree; Sankar, Cheriyedath Raj; Schlender, Philipp
  • Journal of Alloys and Compounds, Vol. 549
  • DOI: 10.1016/j.jallcom.2012.09.023

Synthesis and Crystal Structure of Two New Quaternary Thallium(I) Copper(I) Lutetium(III) Selenides: TlCu 3 Lu 2 Se 5 and Tl 2 Cu 5 Lu 3 Se 8
journal, September 2012

  • Babo, Jean-Marie; Schleid, Thomas; Albrecht-Schmitt, Thomas E.
  • Zeitschrift für anorganische und allgemeine Chemie, Vol. 638, Issue 15
  • DOI: 10.1002/zaac.201200310

Synthesis, Structure, and Spectroscopy of Two Ternary Uranium(IV) Thiophosphates: UP 2 S 9 and UP 2 S 7 Containing P 2 S 9 2– and P 2 S 7 2– Ligands
journal, June 2013

  • Babo, Jean-Marie; Jouffret, Laurent; Lin, Jian
  • Inorganic Chemistry, Vol. 52, Issue 13
  • DOI: 10.1021/ic400942r

Ce2AgYb5/3Se6, La2CuErTe5, and Ce2CuTmTe5: Three new quaternary interlanthanide chalcogenides
journal, January 2013

Oxidation State of Uranium in A 6 Cu 12 U 2 S 15 (A = K, Rb, Cs) Compounds
journal, May 2012

  • Malliakas, Christos D.; Yao, Jiyong; Wells, Daniel M.
  • Inorganic Chemistry, Vol. 51, Issue 11
  • DOI: 10.1021/ic300172k

Na 1.515 EuGeS 4 , A Three-Dimensional Crystalline Assembly of Empty Nanotubules Constructed with Europium(II/III) Mixed Valence Ions
journal, October 2012

  • Choudhury, Amitava; Grandjean, Fernande; Long, Gary J.
  • Inorganic Chemistry, Vol. 51, Issue 21
  • DOI: 10.1021/ic301724v

Synchrotron X-ray Powder Diffraction and Electronic Band Structure of α- and β-Cu 2 ZnSiS 4
journal, September 2012

  • Rosmus, Kimberly A.; Brunetta, Carl D.; Srnec, Matthew N.
  • Zeitschrift für anorganische und allgemeine Chemie, Vol. 638, Issue 15
  • DOI: 10.1002/zaac.201200259

Synthesis, structure and physicochemical characterization of a noncentrosymmetric, quaternary thiostannate: EuCu2SnS4
journal, January 2009

  • Aitken, Jennifer A.; Lekse, Jonathan W.; Yao, Jin-Lei
  • Journal of Solid State Chemistry, Vol. 182, Issue 1
  • DOI: 10.1016/j.jssc.2008.09.022

Syntheses and Characterization of Six Quaternary Uranium Chalcogenides A 2 M 4 U 6 Q 17 (A = Rb or Cs; M = Pd or Pt; Q = S or Se)
journal, August 2012

  • Oh, George N.; Choi, Eun Sang; Lu, Jun
  • Inorganic Chemistry, Vol. 51, Issue 16
  • DOI: 10.1021/ic300865y

Synthesis, crystal structure, and optical properties of Ba2Cu2ThS5, and electronic structures of Ba2Cu2ThS5 and Ba2Cu2US5
journal, April 2013

  • Mesbah, Adel; Lebègue, Sébastien; Klingsporn, Jordan M.
  • Journal of Solid State Chemistry, Vol. 200
  • DOI: 10.1016/j.jssc.2013.01.016

Synthesis, single-crystal structure, and optical absorption of Rb2Th7Se15
journal, September 2013

  • Koscielski, Lukasz A.; Pozzi, Eric A.; Van Duyne, Richard P.
  • Journal of Solid State Chemistry, Vol. 205
  • DOI: 10.1016/j.jssc.2013.06.013

Growing Crystalline Chalcogenidoarsenates in Surfactants: From Zero-Dimensional Cluster to Three-Dimensional Framework
journal, January 2013

  • Xiong, Wei-Wei; Athresh, Eashwer Umesh; Ng, Yu Ting
  • Journal of the American Chemical Society, Vol. 135, Issue 4
  • DOI: 10.1021/ja3116179

Synthesis, Crystal Structure, and Optical Properties of a Three-Dimensional Quaternary Hg–In–S–Cl Chalcohalide: Hg 7 InS 6 Cl 5
journal, March 2012

  • Liu, Yi; Wei, Fengxia; Yeo, Sing Ning
  • Inorganic Chemistry, Vol. 51, Issue 8
  • DOI: 10.1021/ic202746y

“Zeoball” [Sn 36 Ge 24 Se 132 ] 24– : A Molecular Anion with Zeolite-Related Composition and Spherical Shape
journal, March 2012

  • Lin, Yumei; Massa, Werner; Dehnen, Stefanie
  • Journal of the American Chemical Society, Vol. 134, Issue 10
  • DOI: 10.1021/ja2115635

Thallium Chalcogenide-Based Wide-Band-Gap Semiconductors: TlGaSe 2 for Radiation Detectors
journal, June 2011

  • Johnsen, Simon; Liu, Zhifu; Peters, John A.
  • Chemistry of Materials, Vol. 23, Issue 12
  • DOI: 10.1021/cm200946y

[Ru 2 Bi 14 Br 4 ](AlCl 4 ) 4 by Mobilization and Reorganization of Complex Clusters in Ionic Liquids
journal, July 2012

  • Groh, Matthias F.; Isaeva, Anna; Ruck , Michael
  • Chemistry - A European Journal, Vol. 18, Issue 35
  • DOI: 10.1002/chem.201201038

Strong Kleinman-Forbidden Second Harmonic Generation in Chiral Sulfide: La 4 InSbS 9
journal, January 2012

  • Zhao, Hua-Jun; Zhang, Yong-Fan; Chen, Ling
  • Journal of the American Chemical Society, Vol. 134, Issue 4
  • DOI: 10.1021/ja2109008

Synthesis, crystal structures, and optical properties of NaCdPnS3 (Pn=As, Sb)
journal, January 2012

LiGaGe 2 Se 6 : A New IR Nonlinear Optical Material with Low Melting Point
journal, December 2011

  • Mei, Dajiang; Yin, Wenlong; Feng, Kai
  • Inorganic Chemistry, Vol. 51, Issue 2
  • DOI: 10.1021/ic202202j

BaGa2GeX6(X=S, Se): New mid-IR nonlinear optical crystals with large band gaps
journal, November 2012

A Mixed Valent Thioantimonate(III,V): [SbS 3 ] 3– and [SbS 4 ] 3– as bidentate ligands: Solvothermal synthesis and crystal structure of {Mn(dien) 2 } 2 [MnSb 2 S 7 ]
journal, July 2012

  • Herzberg, Nicola; Näther, Christian; Bensch, Wolfgang
  • Zeitschrift für Kristallographie - Crystalline Materials, Vol. 227, Issue 8
  • DOI: 10.1524/zkri.2012.1478

Sulfosalts — A new class of compound semiconductors for photovoltaic applications
journal, May 2007

Progress in sulfosalt research
journal, May 2009

  • Dittrich, Herbert; Stadler, Andreas; Topa, Dan
  • physica status solidi (a), Vol. 206, Issue 5
  • DOI: 10.1002/pssa.200881242

Stilbazolium-MPS3 Nanocomposites with Large Second-Order Optical Nonlinearity and Permanent Magnetization
journal, February 1994

Magnetoelectric MnPS 3 as a candidate for ferrotoroidicity
journal, September 2010

Photovoltaic effect of Sn 2 P 2 S 6 ferroelectric crystal and ceramics
journal, November 2001

  • Cho, Y. W.; Choi, S. K.; Vysochanskii, Yu. M.
  • Journal of Materials Research, Vol. 16, Issue 11
  • DOI: 10.1557/JMR.2001.0456

Enhanced photorefractive properties of modified Sn2P2S6
journal, February 2001

Electro-optical properties of Sn2P2S6
journal, January 2003

Fast-light in a photorefractive crystal for gravitational wave detection
journal, January 2008

Piezoelectric and elastic properties of new layered ferroelectric-semiconductor materials of Sn 2 P 2 S 6 family
journal, June 2005

  • Samulionis, V.; Banys, J.; Vysochanskii, Yu.
  • Journal de Physique IV (Proceedings), Vol. 126
  • DOI: 10.1051/jp4:2005126028

Dipolar glass phase in ferrielectrics: CuInP2S6 and Ag0.1Cu0.9InP2S6 crystals
journal, June 2010

  • Dziaugys, Andrius; Banys, Juras; Macutkevic, Jan
  • physica status solidi (a), Vol. 207, Issue 8
  • DOI: 10.1002/pssa.200925346

The Characterization of Two Dimensional Electrostrictive CuInP2S6 Materials for Transducers
journal, May 2006

Vapour growth and piezoelectric effect of indium thiophosphate, InPS4
journal, July 1975

The influence of pressure on the birefringence in semiconductor compounds ZnS, CuGaS2, and InPS4
journal, January 2007

  • Lavrentyev, A. A.; Gabrelian, B. V.; Kulagin, B. B.
  • physica status solidi (b), Vol. 244, Issue 1
  • DOI: 10.1002/pssb.200672512

Noncollinear acousto-optic tunable filter: thallium phosphorus selenide system
journal, August 1994

Optoacoustic properties of thallium phosphorous selenide, Tl 3 PSe 4
journal, February 1974

  • Isaacs, T. J.; Gottlieb, M.; Feichtner, J. D.
  • Applied Physics Letters, Vol. 24, Issue 3
  • DOI: 10.1063/1.1655113

CePS 4 Electronic Structure and Optical Properties
journal, September 1998

  • Gauthier, G.; Jobic, S.; Boucher, F.
  • Chemistry of Materials, Vol. 10, Issue 9
  • DOI: 10.1021/cm980711k

Absence of chromatic effect: crystal relaxation around CeIII in Y1−xCexPS4 (0≤x≤1)
journal, December 2000

Performance of TAS crystal for AOTF imaging
journal, May 2001

Formation of superionic crystals from mechanically milled Li2S–P2S5 glasses
journal, February 2003

Material design of new lithium ionic conductor, thio-LISICON, in the Li2S–P2S5 system
journal, May 2004

New lithium ion conducting glass-ceramics prepared from mechanochemical Li2S–P2S5 glasses
journal, December 2002

New Lithium Chalcogenidotetrelates, LiChT: Synthesis and Characterization of the Li + -Conducting Tetralithium ortho- Sulfidostannate Li 4 SnS 4
journal, May 2012

  • Kaib, Thomas; Haddadpour, Sima; Kapitein, Manuel
  • Chemistry of Materials, Vol. 24, Issue 11
  • DOI: 10.1021/cm3011315

Lithium Chalcogenidotetrelates: LiChT—Synthesis and Characterization of New Li + Ion Conducting Li/Sn/Se Compounds
journal, July 2013

  • Kaib, Thomas; Bron, Philipp; Haddadpour, Sima
  • Chemistry of Materials, Vol. 25, Issue 15
  • DOI: 10.1021/cm400541n

Structure of the thio-LISICON, Li4GeS4
journal, December 2002

Li6PS5X: A Class of Crystalline Li-Rich Solids With an Unusually High Li+ Mobility
journal, January 2008

  • Deiseroth, Hans-Jörg; Kong, Shiao-Tong; Eckert, Hellmut
  • Angewandte Chemie International Edition, Vol. 47, Issue 4
  • DOI: 10.1002/anie.200703900

Structural requirements for fast lithium ion migration in Li10GeP2S12
journal, January 2012

  • Adams, Stefan; Prasada Rao, R.
  • Journal of Materials Chemistry, Vol. 22, Issue 16
  • DOI: 10.1039/c2jm16688g

Single-crystal X-ray structure analysis of the superionic conductor Li10GeP2S12
journal, January 2013

  • Kuhn, Alexander; Köhler, Jürgen; Lotsch, Bettina V.
  • Physical Chemistry Chemical Physics, Vol. 15, Issue 28
  • DOI: 10.1039/c3cp51985f

First Principles Study of the Li10GeP2S12 Lithium Super Ionic Conductor Material
journal, December 2011

  • Mo, Yifei; Ong, Shyue Ping; Ceder, Gerbrand
  • Chemistry of Materials, Vol. 24, Issue 1, p. 15-17
  • DOI: 10.1021/cm203303y

A structural, spectroscopic and electrochemical study of a lithium ion conducting Li10GeP2S12 solid electrolyte
journal, May 2013

Discharge Performance of All-Solid-State Battery Using a Lithium Superionic Conductor Li10GeP2S12
journal, January 2012

New strategies to prepare crystalline chalcogenides
journal, January 2014

  • Xiong, Wei-Wei; Zhang, Guodong; Zhang, Qichun
  • Inorganic Chemistry Frontiers, Vol. 1, Issue 4
  • DOI: 10.1039/c4qi00013g

Structure and bonding in metal-rich compounds: Pnictides, chalcides and halides
journal, January 1978

New ternary and quaternary transition-metal selenides: Syntheses and characterization
journal, March 1985

  • Keszler, Douglas A.; Ibers, James A.; Maoyu, Shang
  • Journal of Solid State Chemistry, Vol. 57, Issue 1, p. 68-81
  • DOI: 10.1016/S0022-4596(85)80061-X

Coordination chemistry and the solid state
journal, November 1987

  • Sunshine, Steven A.; Keszler, Douglas A.; Ibers, James A.
  • Accounts of Chemical Research, Vol. 20, Issue 11
  • DOI: 10.1021/ar00143a002

Darstellung, Kristallstruktur und magnetische Eigenschaften von Alkalithioferraten(III). Mit 4 Abbildungen
journal, July 1968

Materials Discovery by Flux Crystal Growth: Quaternary and Higher Order Oxides
journal, January 2012

  • Bugaris, Daniel E.; zur Loye, Hans-Conrad
  • Angewandte Chemie International Edition, Vol. 51, Issue 16
  • DOI: 10.1002/anie.201102676

Layered Ternary and Quaternary Metal Chalcogenides
journal, January 1997

Understanding Fluxes as Media for Directed Synthesis: In Situ Local Structure of Molten Potassium Polysulfides
journal, May 2012

  • Shoemaker, Daniel P.; Chung, Duck Young; Mitchell, J. F.
  • Journal of the American Chemical Society, Vol. 134, Issue 22
  • DOI: 10.1021/ja303047e

Tellurometalates
journal, November 1993

  • Ansari, Mohammad; McConnachie, Jonathan M.; Ibers, James A.
  • Accounts of Chemical Research, Vol. 26, Issue 11
  • DOI: 10.1021/ar00035a002

Dimorphism of K4Ta2S11: Syntheses, Crystal Structures, and Properties of two Alkali Metal Tantalum Sulfides
journal, June 1999

Crystallization of sulfides from alkali polysulfide fluxes
journal, October 1974

A Comparative Study of Two New Structure Types. Synthesis and Structural and Electronic Characterization of K(RE)P 2 Se 6 (RE = Y, La, Ce, Pr, Gd)
journal, January 1996

  • Chen, John H.; Dorhout, Peter K.; Ostenson, J. E.
  • Inorganic Chemistry, Vol. 35, Issue 19
  • DOI: 10.1021/ic9516121

Hydrothermal synthesis of K2PdSe10. Coexistence of two large interpenetrating three-dimensional frameworks of [Pd(Se4)2]2- and [Pd(Se6)2]2-
journal, June 1992

  • Kim, Kang Woo; Kanatzidis, Mercouri G.
  • Journal of the American Chemical Society, Vol. 114, Issue 12
  • DOI: 10.1021/ja00038a063

Heavy-Metal-Ion Capture, Ion-Exchange, and Exceptional Acid Stability of the Open-Framework Chalcogenide (NH 4 ) 4 In 12 Se 20
journal, November 2006

  • Manos, Manolis J.; Malliakas, Christos D.; Kanatzidis, Mercouri G.
  • Chemistry - A European Journal, Vol. 13, Issue 1
  • DOI: 10.1002/chem.200600892

[Co(en) 3 ]CoSb 4 S 8 :  A Novel Non-Centrosymmetric Lamellar Heterometallic Sulfide with Large-Framework Holes
journal, January 1996

  • Stephan, Hans-Oscar; Kanatzidis, Mercouri G.
  • Journal of the American Chemical Society, Vol. 118, Issue 48
  • DOI: 10.1021/ja9628664

Reactivity of Chalcogenostannate Salts: Unusual Synthesis and Structure of a Compound Containing Ternary Cluster Anions [Co4(μ4-Se)(SnSe4)4]10
journal, November 2002

On the Incorporation of Transition Metal Atoms into Thiostannates: Synthesis, Crystal Structures and Spectroscopic Properties of [Ni(en)3]2Sn2S6, [Ni(dap)3]2Sn2S6 · 2 H2O, [Co(tren)]2Sn2S6, and [Ni(tren)]2Sn2S6
journal, July 2003

  • Behrens, Malte; Scherb, Sandra; Näther, Christian
  • Zeitschrift für anorganische und allgemeine Chemie, Vol. 629, Issue 7-8, p. 1367-1373
  • DOI: 10.1002/zaac.200300084

Solvothermal synthesis of [Ni(C4H13N3)2]2Sb4S8: the first compound with a cyclic [Sb4S8]4− anion
journal, January 2001

  • Bensch, Wolfgang; Näther, Christian; Stähler, Ralph
  • Chemical Communications, Issue 5
  • DOI: 10.1039/b009583o

Review. Synthesis of Inorganic-Organic Hybrid Thiometallate Materials with a Special Focus on Thioantimonates and Thiostannates and in situ X-Ray Scattering Studies of their Formation
journal, August 2010

  • Seidlhofer, Beatrix; Pienack, Nicole; Bensch, Wolfgang
  • Zeitschrift für Naturforschung B, Vol. 65, Issue 8
  • DOI: 10.1515/znb-2010-0803

Surfactant-Thermal Method to Synthesize a Novel Two-Dimensional Oxochalcogenide
journal, October 2013

  • Gao, Junkuo; Tay, Qiuling; Li, Pei-Zhou
  • Chemistry - An Asian Journal, Vol. 9, Issue 1
  • DOI: 10.1002/asia.201301023

A new hydrazine-bridged thioantimonate Mn2Sb4S8(N2H4)2: Synthesis, structure, optical and magnetic properties
journal, June 2011

Surfactants as Promising Media for the Preparation of Crystalline Inorganic Materials
journal, August 2015

  • Xiong, Wei-Wei; Zhang, Qichun
  • Angewandte Chemie International Edition, Vol. 54, Issue 40
  • DOI: 10.1002/anie.201502277

Review. Solvothermal Synthesis and Structure of Chalcogenidoarsenate Anions
journal, August 2010

  • Kromm, Anna; Almsick, Tobias van; Sheldrick, William S.
  • Zeitschrift für Naturforschung B, Vol. 65, Issue 8
  • DOI: 10.1515/znb-2010-0802

Network self-assembly patterns in Main Group metal chalcogenide-based materials
journal, January 2000

  • Sheldrick, William S.
  • Journal of the Chemical Society, Dalton Transactions, Issue 18
  • DOI: 10.1039/b003762l

Darstellung und Kristallstruktur von Rb2Sn3S7 � 2H2O und Rb4Sn2Se6
journal, June 1994

  • Sheldrick, W. S.; Schaaf, B.
  • Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 620, Issue 6
  • DOI: 10.1002/zaac.19946200616

Solventothermal Synthesis of Solid-State Chalcogenidometalates
journal, February 1997

  • Sheldrick, William S.; Wachhold, Michael
  • Angewandte Chemie International Edition in English, Vol. 36, Issue 3
  • DOI: 10.1002/anie.199702061

Hydrothermal synthesis of metal polychalcogenides. Structural characterization of [Mo12Se56]12-. A cluster of clusters
journal, September 1990

  • Liao, Ju Hsiou; Kanatzidis, Mercouri G.
  • Journal of the American Chemical Society, Vol. 112, Issue 20
  • DOI: 10.1021/ja00176a053

Polychalcogenide synthesis in molten salts. Novel one-dimensional compounds in the potassium-copper-sulfur system containing exclusively S42- ligands
journal, May 1989

  • Kanatzidis, Mercouri G.; Park, Younbong
  • Journal of the American Chemical Society, Vol. 111, Issue 10
  • DOI: 10.1021/ja00192a055

Molten alkali-metal polychalcogenides as reagents and solvents for the synthesis of new chalcogenide materials
journal, July 1990

Synthesis and Thermoelectric Properties of the New Ternary Bismuth Sulfides KBi 6.33 S 10 and K 2 Bi 8 S 13
journal, January 1996

  • Kanatzidis, Mercouri G.; McCarthy, Timothy J.; Tanzer, Troy A.
  • Chemistry of Materials, Vol. 8, Issue 7
  • DOI: 10.1021/cm9600182

A new low-temperature route to metal polychalcogenides: solid-state synthesis of potassium titanium sulfide (K4Ti3S14), a novel one-dimensional compound
journal, September 1987

  • Sunshine, Steven A.; Kang, Doris; Ibers, James A.
  • Journal of the American Chemical Society, Vol. 109, Issue 20
  • DOI: 10.1021/ja00254a060

Synthesis and Structure of the One-Dimensional Telluride Cs4Zr3Te16
journal, June 1994

  • Cody, Jason A.; Ibers, James A.
  • Inorganic Chemistry, Vol. 33, Issue 13
  • DOI: 10.1021/ic00091a007

Uranium Tellurides: New One- and Two-Dimensional Compounds CsUTe6, CsTiUTe5, Cs8Hf5UTe30.6, and CsCuUTe3
journal, June 1995

  • Cody, Jason A.; Ibers, James A.
  • Inorganic Chemistry, Vol. 34, Issue 12
  • DOI: 10.1021/ic00116a006

Syntheses, crystal structures, and resistivities of the two new ternary uranium selenides, Er3USe8 and Yb3USe8
journal, January 2016

Synthesis and characterization of the quaternary scandium uranium selenide CsScUSe3(Se2)
journal, March 2015

Incorporation of A 2 Q into HgQ and Dimensional Reduction to A 2 Hg 3 Q 4 and A 2 Hg 6 Q 7 (A = K, Rb, Cs; Q = S, Se). Access of Li Ions in A 2 Hg 6 Q 7 through Topotactic Ion-Exchange
journal, January 1998

  • Axtell, Enos A.; Park, Younbong; Chondroudis, Konstantinos
  • Journal of the American Chemical Society, Vol. 120, Issue 1
  • DOI: 10.1021/ja9713486

Dimensional Reduction: A Design Tool for New Radiation Detection Materials
journal, August 2011

  • Androulakis, John; Peter, Sebastian C.; Li, Hao
  • Advanced Materials, Vol. 23, Issue 36
  • DOI: 10.1002/adma.201102450

Formation of native defects in the γ-ray detector material Cs2Hg6S7
journal, November 2012

  • Im, Jino; Jin, Hosub; Li, Hao
  • Applied Physics Letters, Vol. 101, Issue 20
  • DOI: 10.1063/1.4767368

Transient photocurrent measurements in alkali chalcogenide ternary compound semiconductors
journal, December 2012

Investigation of defect levels in Cs 2 Hg 6 S 7 single crystals by photoconductivity and photoluminescence spectroscopies
journal, September 2012

  • Peters, J. A.; Cho, Nam Ki; Liu, Zhifu
  • Journal of Applied Physics, Vol. 112, Issue 6
  • DOI: 10.1063/1.4750982

Cubic AgPbmSbTe2+m: Bulk Thermoelectric Materials with High Figure of Merit.
journal, April 2004

High Thermoelectric Figure of Merit and Nanostructuring in Bulk p-type Na1−xPbmSbyTem+2
journal, June 2006

  • Poudeu, Pierre F. P.; D'Angelo, Jonathan; Downey, Adam D.
  • Angewandte Chemie International Edition, Vol. 45, Issue 23
  • DOI: 10.1002/anie.200600865

High Figure of Merit in Nanostructured n-Type KPb m SbTe m +2 Thermoelectric Materials †
journal, February 2010

  • Poudeu, Pierre F. P.; Guéguen, Aurélie; Wu, Chun-I
  • Chemistry of Materials, Vol. 22, Issue 3
  • DOI: 10.1021/cm902001c

Lead-Free Thermoelectrics: High Figure of Merit in p-type AgSnmSbTem+2
journal, December 2011

  • Han, Mi-Kyung; Androulakis, John; Kim, Sung-Jin
  • Advanced Energy Materials, Vol. 2, Issue 1
  • DOI: 10.1002/aenm.201100613

Sb and Se Substitution in CsBi 4 Te 6 : The Semiconductors CsM 4 Q 6 (M = Bi, Sb; Q = Te, Se), Cs 2 Bi 10 Q 15 , and CsBi 5 Q 8
journal, May 2012

  • Chung, Duck Young; Uher, Ctirad; Kanatzidis, Mercouri G.
  • Chemistry of Materials, Vol. 24, Issue 10
  • DOI: 10.1021/cm300490v

CsMBi 3 Te 6 and CsM 2 Bi 3 Te 7 (M = Pb, Sn):  New Thermoelectric Compounds with Low-Dimensional Structures
journal, March 2002

  • Hsu, Kuei-Fang; Chung, Duck-Young; Lal, Sangeeta
  • Journal of the American Chemical Society, Vol. 124, Issue 11
  • DOI: 10.1021/ja017602i

Modular Construction of A 1+ x M 4 - 2 x M‘ 7+ x Se 15 (A = K, Rb; M = Pb, Sn; M‘ = Bi, Sb):  A New Class of Solid State Quaternary Thermoelectric Compounds
journal, March 2001

  • Choi, Kyoung-Shin; Chung, Duck-Young; Mrotzek, Antje
  • Chemistry of Materials, Vol. 13, Issue 3
  • DOI: 10.1021/cm0003323

“Design” in Solid-State Chemistry Based on Phase Homologies. The Concept of Structural Evolution and the New Megaseries Am[M1+lSe2+l]2m[M2l+nSe2+3l+n]
journal, January 2003

  • Mrotzek, Antje; Kanatzidis, Mercouri G.
  • Accounts of Chemical Research, Vol. 36, Issue 2
  • DOI: 10.1021/ar020099+

Structural Evolution and Phase Homologies for “Design” and Prediction of Solid-State Compounds
journal, April 2005

  • Kanatzidis, Mercouri G.
  • Accounts of Chemical Research, Vol. 38, Issue 4
  • DOI: 10.1021/ar040176w

Dirac fermions and superconductivity in the homologous structures ( Ag x Pb 1 − x Se ) 5 ( Bi 2 Se 3 ) 3 m ( m = 1 , 2 )
journal, July 2014

Structure inhomogeneities, shallow defects, and charge transport in the series of thermoelectric materials K2Bi8−xSbxSe13
journal, December 2006

  • Kyratsi, Theodora; Hatzikraniotis, Euripides; Paraskevopoulos, Konstantinos M.
  • Journal of Applied Physics, Vol. 100, Issue 12
  • DOI: 10.1063/1.2365718

A 2 Bi 8 Se 13 (A = Rb, Cs), CsBi 3.67 Se 6 , and BaBi 2 Se 4 :  New Ternary Semiconducting Bismuth Selenides
journal, January 2001

  • Iordanidis, Lykourgos; Brazis, Paul W.; Kyratsi, Theodora
  • Chemistry of Materials, Vol. 13, Issue 2
  • DOI: 10.1021/cm000734a

CsPb3Bi3Te8 and CsPb4Bi3Te9: low-dimensional compounds and the homologous series CsPbmBi3Te5 + m
journal, May 2002

  • Hsu, Kuei-Fang; Lal, Sangeeta; Hogan, Tim
  • Chemical Communications, Issue 13
  • DOI: 10.1039/b202043b

Perovskites by Design:  A Toolbox of Solid-State Reactions
journal, April 2002

  • Schaak, Raymond E.; Mallouk, Thomas E.
  • Chemistry of Materials, Vol. 14, Issue 4, p. 1455-1471
  • DOI: 10.1021/cm010689m

Single-Crystalline Films of the Homologous Series InGaO3(ZnO)m Grown by Reactive Solid-Phase Epitaxy
journal, February 2003

Structure and Thermoelectric Transport Properties of Isoelectronically Substituted (ZnO)5In2O3
journal, February 2000

  • Masuda, Yoshitake; Ohta, Mitsuru; Seo, Won-Seon
  • Journal of Solid State Chemistry, Vol. 150, Issue 1
  • DOI: 10.1006/jssc.1999.8589

Reticular synthesis and the design of new materials
journal, June 2003

  • Yaghi, Omar M.; O'Keeffe, Michael; Ockwig, Nathan W.
  • Nature, Vol. 423, Issue 6941, p. 705-714
  • DOI: 10.1038/nature01650

Rational Design, Synthesis, Purification, and Activation of Metal−Organic Framework Materials
journal, August 2010

  • Farha, Omar K.; Hupp, Joseph T.
  • Accounts of Chemical Research, Vol. 43, Issue 8, p. 1166-1175
  • DOI: 10.1021/ar1000617

In situ studies of a platform for metastable inorganic crystal growth and materials discovery
journal, July 2014

  • Shoemaker, D. P.; Hu, Y. -J.; Chung, D. Y.
  • Proceedings of the National Academy of Sciences, Vol. 111, Issue 30
  • DOI: 10.1073/pnas.1406211111

The New Semiconductor Cs 4 Cu 3 Bi 9 S 17
journal, February 2017

    Sort by:
    [ × clear filter / sort ]

    Works referencing / citing this record:

    Ag 7 TaSe 6 : a new noncentrosymmetric selenide with fascinating “three in one” coordination modes and a strong second harmonic generation response
    journal, January 2019

    • Li, Zhuang; Zhang, Shengzi; Yin, Wenlong
    • Journal of Materials Chemistry C, Vol. 7, Issue 25
    • DOI: 10.1039/c9tc01587f

    Flux crystal growth: a versatile technique to reveal the crystal chemistry of complex uranium oxides
    journal, January 2019

    • Juillerat, Christian A.; Klepov, Vladislav V.; Morrison, Gregory
    • Dalton Transactions, Vol. 48, Issue 10
    • DOI: 10.1039/c8dt04675a

    Heteroanionic Materials by Design: Progress Toward Targeted Properties
    journal, March 2019

    • Harada, Jaye K.; Charles, Nenian; Poeppelmeier, Kenneth R.
    • Advanced Materials, Vol. 31, Issue 19
    • DOI: 10.1002/adma.201805295

    Unexplored reactivity of (S n ) 2− oligomers with transition metals in low-temperature solid-state reactions
    journal, January 2019

    • Sasaki, Shunsuke; Lesault, Mélanie; Grange, Elodie
    • Chemical Communications, Vol. 55, Issue 44
    • DOI: 10.1039/c9cc01338e

    Dimensional Control in Polyoxometalate Crystals Hybridized with Amphiphilic Polymerizable Ionic Liquids
    journal, July 2019

    • Misawa, Toshiyuki; Kobayashi, Jun; Kiyota, Yoshiki
    • Materials, Vol. 12, Issue 14
    • DOI: 10.3390/ma12142283

    Ba 8 SrPb 24 O 24 Cl 18 : the first alkali-earth metal lead( ii ) oxyhalide with an intriguing multimember-ring layer
    journal, January 2020

    [Hg 4 Te 8 (Te 2 ) 4 ] 8− : ein Schwermetall-Porphyrinoid in einer lamellaren Struktur
    journal, June 2018

    • Donsbach, Carsten; Reiter, Kevin; Sundholm, Dage
    • Angewandte Chemie, Vol. 130, Issue 28
    • DOI: 10.1002/ange.201803233

    Superconductivity in the 2-Dimensional Homologous Series AM m Bi 3 Q 5+ m ( m =1, 2) (A=Rb, Cs; M=Pb, Sn; Q=Se, Te)
    journal, April 2018

    • Malliakas, Christos D.; Chung, Duck Young; Claus, Helmut
    • Chemistry - A European Journal, Vol. 24, Issue 28
    • DOI: 10.1002/chem.201800883

    [Hg 4 Te 8 (Te 2 ) 4 ] 8− : A Heavy Metal Porphyrinoid Embedded in a Lamellar Structure
    journal, June 2018

    • Donsbach, Carsten; Reiter, Kevin; Sundholm, Dage
    • Angewandte Chemie International Edition, Vol. 57, Issue 28
    • DOI: 10.1002/anie.201803233

    The 2019 materials by design roadmap
    journal, October 2018

    • Alberi, Kirstin; Nardelli, Marco Buongiorno; Zakutayev, Andriy
    • Journal of Physics D: Applied Physics, Vol. 52, Issue 1
    • DOI: 10.1088/1361-6463/aad926

    Electronic Bands and Dielectric Functions of In0.5Tl0.5I Solid State Solution with Structural Defects
    journal, July 2019

    SnGa 2 GeSe 6 , a benign addition to the AMIII2M IV Q 6 family: synthesis, crystal structure and nonlinear optical performance
    journal, January 2019

    • Li, Zhuang; Zhang, Shengzi; Guo, Yangwu
    • Dalton Transactions, Vol. 48, Issue 19
    • DOI: 10.1039/c9dt00184k

    “Soft” Alkali Bromide and Iodide Fluxes for Crystal Growth
    journal, June 2020

    • Klepov, Vladislav V.; Juillerat, Christian A.; Pace, Kristen A.
    • Frontiers in Chemistry, Vol. 8
    • DOI: 10.3389/fchem.2020.00518

    Dimensional Control in Polyoxometalate Crystals Hybridized with Amphiphilic Polymerizable Ionic Liquids
    journal, July 2019

    • Misawa, Toshiyuki; Kobayashi, Jun; Kiyota, Yoshiki
    • Materials, Vol. 12, Issue 14
    • DOI: 10.3390/ma12142283
      Sort by:
      [ × clear filter / sort ]

      Similar Records in DOE PAGES and OSTI.GOV collections: