Synthesis and application of ferroelectric poly(vinylidene fluoride-co-trifluoroethylene) films using electrophoretic deposition

Ryu, Jeongjae; No, Kwangsoo; Kim, Yeontae; Park, Eugene; Hong, Seungbum

doi:10.1038/srep36176

Title: Synthesis and application of ferroelectric poly(vinylidene fluoride-co-trifluoroethylene) films using electrophoretic deposition

Journal Article · Wed Nov 02 00:00:00 UTC 2016 · Scientific Reports

DOI: https://doi.org/10.1038/srep36176 · OSTI ID:1352566

Ryu, Jeongjae ^[1]; No, Kwangsoo ^[1]; Kim, Yeontae ^[1]; Park, Eugene ^[2]; Hong, Seungbum ^[3]

Korea Advanced Institute of Science and Technology, Daejeon (Republic of Korea)
Nelson Mandela African Institute of Science and Technology, Arusha (Tanzania)
Korea Advanced Institute of Science and Technology, Daejeon (Republic of Korea); Argonne National Lab. (ANL), Lemont, IL (United States)

In this paper, we investigated the deposition kinetics of polyvinylidene fluoride copolymerized with trifluoroethylene (P(VDF-TrFE)) particles on stainless steel substrates during the electrophoretic deposition (EPD) process. The effect of applied voltage and deposition time on the structure and ferroelectric property of the P(VDF-TrFE) films was studied in detail. A method of repeated EPD and heat treatment above melting point were employed to fabricate crack-free P(VDF-TrFE) thick films. This method enabled us to fabricate P(VDF-TrFE) films with variable thicknesses. The morphology of the obtained films was investigated by scanning electron microscopy (SEM), and the formation of β-phase was confirmed by X-ray diffraction (XRD) and Fourier transform infrared (FTIR) spectroscopy. P(VDF-TrFE) films prepared with various thicknesses showed remnant polarization (P_r) of around 4 μC/cm². To demonstrate the applicability of our processing recipe to complex structures, we fabricated a spring-type energy harvester by depositing P(VDF-TrFE) films on stainless steel springs using EPD process. Our preliminary results show that an electrophoretic deposition can be applied to produce high-quality P(VDF-TrFE) films on planar as well as three-dimensional (3-D) substrates.

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Research Organization:: Argonne National Laboratory (ANL)

Sponsoring Organization:: National Research Foundation (NRF) of Korea; USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1352566

Journal Information:: Scientific Reports, Journal Name: Scientific Reports Journal Issue: 1 Vol. 6; ISSN 2045-2322

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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