Low-Cost High-Energy Potassium Cathode

Xue, Leigang; Li, Yutao; Gao, Hongcai; Zhou, Weidong; Lü, Xujie; Kaveevivitchai, Watchareeya; Manthiram, Arumugam; Goodenough, John B.

doi:10.1021/jacs.6b12598

Title: Low-Cost High-Energy Potassium Cathode

Journal Article · Thu Jan 26 04:00:00 UTC 2017 · Journal of the American Chemical Society

DOI: https://doi.org/10.1021/jacs.6b12598 · OSTI ID:1352429

^[1]; Li, Yutao ^[1];

^[1]; Zhou, Weidong ^[1];

^[2]; Kaveevivitchai, Watchareeya ^[1]; Manthiram, Arumugam ^[1];

^[1]

Univ. of Texas, Austin, TX (United States). Texas Materials Inst.
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

Potassium has as rich an abundance as sodium in the earth, but the development of a K-ion battery is lagging behind because of the higher mass and larger ionic size of K⁺ than that of Li⁺ and Na⁺, which makes it difficult to identify a high-voltage and high-capacity intercalation cathode host. Here we propose a cyanoperovskite K_xMnFe(CN)₆ (0 ≤ x ≤ 2) as a potassium cathode: high-spin Mn^III/Mn^II and low-spin Fe^III/Fe^II couples have similar energies and exhibit two close plateaus centered at 3.6 V; two active K⁺ per formula unit enable a theoretical specific capacity of 156 mAh g^-1; Mn and Fe are the two most-desired transition metals for electrodes because they are cheap and environmental friendly. As a powder prepared by an inexpensive precipitation method, the cathode delivers a specific capacity of 142 mAh g^-1. Lastly, the observed voltage, capacity, and its low cost make it competitive in large-scale electricity storage applications.

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Research Organization:: Los Alamos National Laboratory (LANL)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); National Science Foundation (NSF)

Grant/Contract Number:: SC0005397

OSTI ID:: 1352429

Report Number(s):: LA-UR-17-20899

Journal Information:: Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 6 Vol. 139; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (20)

Liquid K-Na Alloy Anode Enables Dendrite-Free Potassium Batteries Xue, Leigang; Gao, Hongcai; Zhou, Weidong Advanced Materials, Vol. 28, Issue 43 https://doi.org/10.1002/adma.201602633	journal	September 2016
High-Capacity Aqueous Potassium-Ion Batteries for Large-Scale Energy Storage Su, Dawei; McDonagh, Andrew; Qiao, Shi-Zhang Advanced Materials, Vol. 29, Issue 1 https://doi.org/10.1002/adma.201604007	journal	October 2016
Hard Carbon Microspheres: Potassium-Ion Anode Versus Sodium-Ion Anode Jian, Zelang; Xing, Zhenyu; Bommier, Clement Advanced Energy Materials, Vol. 6, Issue 3 https://doi.org/10.1002/aenm.201501874	journal	November 2015
A Superior Low-Cost Cathode for a Na-Ion Battery Wang, Long; Lu, Yuhao; Liu, Jue Angewandte Chemie International Edition, Vol. 52, Issue 7 https://doi.org/10.1002/anie.201206854	journal	January 2013
The Emerging Chemistry of Sodium Ion Batteries for Electrochemical Energy Storage Kundu, Dipan; Talaie, Elahe; Duffort, Victor Angewandte Chemie International Edition, Vol. 54, Issue 11 https://doi.org/10.1002/anie.201410376	journal	February 2015
The Solvation of Anions in Propylene Carbonate Peruzzi, Niccolò; Lo Nostro, Pierandrea; Ninham, Barry W. Journal of Solution Chemistry, Vol. 44, Issue 6 https://doi.org/10.1007/s10953-015-0335-z	journal	May 2015
Lattice contractions and expansions accompanying the electrochemical conversions of Prussian blue and the reversible and irreversible insertion of rubidium and thallium ions Dostal, Aleš; Kauschka, Günther; Reddy, S. Jayarama Journal of Electroanalytical Chemistry, Vol. 406, Issue 1-2 https://doi.org/10.1016/0022-0728(95)04427-2	journal	April 1996
Ring-opening polymerization of propylene oxide by double metal cyanide catalysts prepared by reacting CoCl2 with various metal cyanide salts Yu, Seong Jae; Liu, Yinshan; Byeon, Seong Jin Catalysis Today, Vol. 232 https://doi.org/10.1016/j.cattod.2013.09.038	journal	September 2014
Potassium intercalation into graphite to realize high-voltage/high-power potassium-ion batteries and potassium-ion capacitors Komaba, Shinichi; Hasegawa, Tatsuya; Dahbi, Mouad Electrochemistry Communications, Vol. 60 https://doi.org/10.1016/j.elecom.2015.09.002	journal	November 2015
Sodium storage in Na-rich Na x FeFe(CN) 6 nanocubes Liu, Yang; Qiao, Yun; Zhang, Wuxing Nano Energy, Vol. 12 https://doi.org/10.1016/j.nanoen.2015.01.012	journal	March 2015
Highly Crystallized Na ₂ CoFe(CN) ₆ with Suppressed Lattice Defects as Superior Cathode Material for Sodium-Ion Batteries Wu, Xianyong; Wu, Chenghao; Wei, Congxiao ACS Applied Materials & Interfaces, Vol. 8, Issue 8 https://doi.org/10.1021/acsami.5b12620	journal	February 2016
Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries Xu, Kang Chemical Reviews, Vol. 104, Issue 10, p. 4303-4418 https://doi.org/10.1021/cr030203g	journal	October 2004
Electrolytes and Interphases in Li-Ion Batteries and Beyond Xu, Kang Chemical Reviews, Vol. 114, Issue 23 https://doi.org/10.1021/cr500003w	journal	October 2014
Removal of Interstitial H ₂ O in Hexacyanometallates for a Superior Cathode of a Sodium-Ion Battery Song, Jie; Wang, Long; Lu, Yuhao Journal of the American Chemical Society, Vol. 137, Issue 7 https://doi.org/10.1021/ja512383b	journal	February 2015
Carbon Electrodes for K-Ion Batteries Jian, Zelang; Luo, Wei; Ji, Xiulei Journal of the American Chemical Society, Vol. 137, Issue 36 https://doi.org/10.1021/jacs.5b06809	journal	September 2015
Manganese hexacyanomanganate open framework as a high-capacity positive electrode material for sodium-ion batteries Lee, Hyun-Wook; Wang, Richard Y.; Pasta, Mauro Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms6280	journal	October 2014
Nanostructured materials for advanced energy conversion and storage devices Aricò, Antonino Salvatore; Bruce, Peter; Scrosati, Bruno Nature Materials, Vol. 4, Issue 5, p. 366-377 https://doi.org/10.1038/nmat1368	journal	May 2005
Rational surface modification of Mn3O4 nanoparticles to induce multiple photoluminescence and room temperature ferromagnetism Giri, Anupam; Goswami, Nirmal; Pal, Monalisa Journal of Materials Chemistry C, Vol. 1, Issue 9 https://doi.org/10.1039/c3tc00709j	journal	January 2013
Origin of low sodium capacity in graphite and generally weak substrate binding of Na and Mg among alkali and alkaline earth metals Liu, Yuanyue; Merinov, Boris V.; Goddard, William A. Proceedings of the National Academy of Sciences, Vol. 113, Issue 14 https://doi.org/10.1073/pnas.1602473113	journal	March 2016
Electrochemical Insertion of Sodium into Carbon Doeff, Marca M. Journal of The Electrochemical Society, Vol. 140, Issue 12 https://doi.org/10.1149/1.2221153	journal	January 1993

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Enhanced K-ion kinetics in a layered cathode for potassium ion batteries Zhang, Haoyang; Xi, Kaiying; Jiang, Kezhu Chemical Communications, Vol. 55, Issue 55 https://doi.org/10.1039/c9cc03156a	journal	January 2019
Utilizing an autogenously protective atmosphere to synthesize a Prussian white cathode with ultrahigh capacity-retention for potassium-ion batteries Dong, Jiahui; Lei, Yu; Han, Da Chemical Communications, Vol. 55, Issue 83 https://doi.org/10.1039/c9cc06248c	journal	January 2019
Two-dimensional transition metal dichalcogenides as promising anodes for potassium ion batteries from first-principles prediction Zhang, Zixiang; Yang, Mingye; Zhao, Ni Physical Chemistry Chemical Physics, Vol. 21, Issue 42 https://doi.org/10.1039/c9cp03948a	journal	January 2019
Potassium manganese hexacyanoferrate/graphene as a high-performance cathode for potassium-ion batteries Sun, Yunpo; Liu, Chunli; Xie, Jian New Journal of Chemistry, Vol. 43, Issue 29 https://doi.org/10.1039/c9nj02085c	journal	January 2019
A highly-effective nitrogen-doped porous carbon sponge electrode for advanced K–Se batteries Huang, Xianglong; Deng, Jianhua; Qi, Yuruo Inorganic Chemistry Frontiers, Vol. 7, Issue 5 https://doi.org/10.1039/c9qi01506j	journal	January 2020
Unlocking high capacities of graphite anodes for potassium-ion batteries Carboni, Marco; Naylor, Andrew J.; Valvo, Mario RSC Advances, Vol. 9, Issue 36 https://doi.org/10.1039/c9ra01931f	journal	January 2019
Carbonyl-based polyimide and polyquinoneimide for potassium-ion batteries Tian, Bingbing; Zheng, Ji; Zhao, Chenxi Journal of Materials Chemistry A, Vol. 7, Issue 16 https://doi.org/10.1039/c9ta00647h	journal	January 2019
A three-dimensional macroporous antimony@carbon composite as a high-performance anode material for potassium-ion batteries He, Xiao-Dong; Liu, Ze-Hua; Liao, Jia-Ying Journal of Materials Chemistry A, Vol. 7, Issue 16 https://doi.org/10.1039/c9ta01968e	journal	January 2019
A novel highly crystalline Fe ₄ (Fe(CN) ₆ ) ₃ concave cube anode material for Li-ion batteries with high capacity and long life He, Xiaowei; Tian, Lidong; Qiao, Mingtao Journal of Materials Chemistry A, Vol. 7, Issue 18 https://doi.org/10.1039/c9ta02265a	journal	January 2019
Passivation of aluminum current collectors in non-aqueous carbonate solutions containing sodium or potassium hexafluorophosphate salts Konarov, Aishuak; Kim, Hee Jae; Yashiro, Hitoshi Journal of Materials Chemistry A, Vol. 7, Issue 21 https://doi.org/10.1039/c9ta03911b	journal	January 2019
Manipulation of 2D carbon nanoplates with a core–shell structure for high-performance potassium-ion batteries Li, Dongjun; Cheng, Xiaolong; Xu, Rui Journal of Materials Chemistry A, Vol. 7, Issue 34 https://doi.org/10.1039/c9ta04663a	journal	January 2019
A small-molecule organic cathode with fast charge–discharge capability for K-ion batteries Xiong, Ming; Tang, Wu; Cao, Bei Journal of Materials Chemistry A, Vol. 7, Issue 35 https://doi.org/10.1039/c9ta06376e	journal	January 2019
Hexaazatriphenylene-based polymer cathode for fast and stable lithium-, sodium- and potassium-ion batteries Kapaev, Roman R.; Zhidkov, Ivan S.; Kurmaev, Ernst Z. Journal of Materials Chemistry A, Vol. 7, Issue 39 https://doi.org/10.1039/c9ta06430c	journal	January 2019
Constructing a 3D compact sulfur host based on carbon-nanotube threaded defective Prussian blue nanocrystals for high performance lithium–sulfur batteries Shen, Guohong; Liu, Zhixiao; Liu, Piao Journal of Materials Chemistry A, Vol. 8, Issue 3 https://doi.org/10.1039/c9ta11209j	journal	January 2020
Metal-organic frameworks and their derived materials for electrochemical energy storage and conversion: Promises and challenges Wu, Hao Bin; Lou, Xiong Wen (David) Science Advances, Vol. 3, Issue 12 https://doi.org/10.1126/sciadv.aap9252	journal	December 2017
A first-principles study of potassium insertion in crystalline vanadium oxide phases as possible potassium-ion battery cathode materials Koch, Daniel; Kulish, Vadym V.; Manzhos, Sergei MRS Communications, Vol. 7, Issue 4 https://doi.org/10.1557/mrc.2017.107	journal	October 2017
Aluminum Chloride-Graphite Batteries with Flexible Current Collectors Prepared from Earth-Abundant Elements Wang, Shutao; Kravchyk, Kostiantyn V.; Filippin, Alejandro N. ETH Zurich https://doi.org/10.3929/ethz-b-000261505	text	January 2018

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