Estimation of terpene content in loblolly pine biomass using a hybrid fast-GC and pyrolysis-molecular beam mass spectrometry method

Harman-Ware, Anne E.; Davis, Mark F.; Peter, Gary F.; Wang, Yongsheng; Sykes, Robert W.

doi:10.1016/j.jaap.2017.01.011

Title: Estimation of terpene content in loblolly pine biomass using a hybrid fast-GC and pyrolysis-molecular beam mass spectrometry method

Journal Article · Mon Jan 16 04:00:00 UTC 2017 · Journal of Analytical and Applied Pyrolysis

DOI: https://doi.org/10.1016/j.jaap.2017.01.011 · OSTI ID:1351152

Harman-Ware, Anne E. ^[1]; Davis, Mark F. ^[1]; Peter, Gary F. ^[2]; Wang, Yongsheng ^[2]; Sykes, Robert W. ^[1]

National Renewable Energy Lab. (NREL), Golden, CO (United States). National Bioenergy Center
Univ. of Florida, Gainesville, FL (United States). School of Forest Resources and Conservation

Terpenes can be used as renewable fuels and chemicals and quantifying their presence in biomass is becoming increasingly important. A novel method was developed to rapidly quantify total diterpenoid resin acids using pyrolysis-molecular beam mass spectrometry (py-MBMS). Pine sapling monoterpenes and diterpenoids were extracted from wood using a 1:1 (v/v) mixture of hexane and acetone and analyses were performed before and after extraction to determine the extraction efficiency of the solvent system. The resulting extract was analyzed for total diterpenoid content using py-MBMS and was combined with total monoterpene content that was determined using a low thermal mass modular accelerated column heater (LTM MACH) fast-GC/FID to measure the terpene content present in pine saplings. Oleoresin extruded from larger pine trees was used to validate mass balance closure of the terpene content in the extract solvent.

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Research Organization:: National Renewable Energy Laboratory (NREL), Golden, CO (United States)

Sponsoring Organization:: USDOE Advanced Research Projects Agency - Energy (ARPA-E)

Grant/Contract Number:: AC36-08GO28308; AR0000209

OSTI ID:: 1351152

Report Number(s):: NREL/JA--5100-67200

Journal Information:: Journal of Analytical and Applied Pyrolysis, Journal Name: Journal of Analytical and Applied Pyrolysis Journal Issue: C Vol. 124; ISSN 0165-2370

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Lignocellulosic Biomass: Understanding Recalcitrance and Predicting Hydrolysis Zoghlami, Aya; Paës, Gabriel Frontiers in Chemistry, Vol. 7 https://doi.org/10.3389/fchem.2019.00874	journal	December 2019
High Throughput Screening Technologies in Biomass Characterization Decker, Stephen R.; Harman-Ware, Anne E.; Happs, Renee M. Frontiers in Energy Research, Vol. 6 https://doi.org/10.3389/fenrg.2018.00120	journal	November 2018

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Title: Estimation of terpene content in loblolly pine biomass using a hybrid fast-GC and pyrolysis-molecular beam mass spectrometry method

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