Undoped and Ni-doped CoOx surface modification of porous BiVO4 photoelectrodes for water oxidation

Liu, Ya; Guo, Youhong; Schelhas, Laura T.; Li, Mingtao; Ager, Joel W.

doi:10.1021/acs.jpcc.6b08654

Title: Undoped and Ni-doped CoO_x surface modification of porous BiVO₄ photoelectrodes for water oxidation

Journal Article · Thu Sep 29 00:00:00 EDT 2016 · Journal of Physical Chemistry. C

DOI: https://doi.org/10.1021/acs.jpcc.6b08654 · OSTI ID:1350543

Liu, Ya ^[1]; Guo, Youhong ^[2]; Schelhas, Laura T. ^[3]; Li, Mingtao ^[4]; Ager, Joel W. ^[5]

Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Xi'an Jiaotong Univ., Shaanxi (China)
Univ. of California, San Diego, La Jolla, CA (United States)
SLAC National Accelerator Lab., Menlo Park, CA (United States)
Xi'an Jiaotong Univ., Shaanxi (China)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Surface modification of photoanodes with oxygen evolution reaction (OER) catalysts is an effective approach to enhance water oxidation kinetics, to reduce external bias, and to improve the energy harvesting efficiency of photoelectrochemical (PEC) water oxidation. Here, the surface of porous BiVO₄ photoanodes was modified by the deposition of undoped and Ni-doped CoO_x via nitrogen flow assisted electrostatic spray pyrolysis. This newly developed atmospheric pressure deposition technique allows for surface coverage throughout the porous structure with thickness and composition control. PEC testing of modified BiVO₄ photoanodes shows that after deposition of an undoped CoO_x surface layer, the onset potential shifts negatively by ca. 420 mV and the photocurrent density reaches 2.01 mA cm^–2 at 1.23 vs V_RHE under AM 1.5G illumination. Modification with Ni-doped CoO_x produces even more effective OER catalysis and yields a photocurrent density of 2.62 mA cm^–2 at 1.23 V_RHE under AM 1.5G illumination. Furthermore, the valence band X-ray photoelectron spectroscopy and synchrotron-based X-ray absorption spectroscopy results show the Ni doping reduces the Fermi level of the CoO_x layer; the increased surface band bending produced by this effect is partially responsible for the superior PEC performance.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC02-76SF00515; SC0004993

OSTI ID:: 1350543

Journal Information:: Journal of Physical Chemistry. C, Journal Name: Journal of Physical Chemistry. C Journal Issue: 41 Vol. 120; ISSN 1932-7447

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (63)

p-Type InP Nanopillar Photocathodes for Efficient Solar-Driven Hydrogen Production Lee, Min Hyung; Takei, Kuniharu; Zhang, Junjun Angewandte Chemie International Edition, Vol. 51, Issue 43 https://doi.org/10.1002/anie.201203174	journal	September 2012
Artificial Photosynthesis for Sustainable Fuel and Chemical Production Kim, Dohyung; Sakimoto, Kelsey K.; Hong, Dachao Angewandte Chemie International Edition, Vol. 54, Issue 11 https://doi.org/10.1002/anie.201409116	journal	January 2015
Efficient Water-Splitting Device Based on a Bismuth Vanadate Photoanode and Thin-Film Silicon Solar Cells Han, Lihao; Abdi, Fatwa F.; van de Krol, Roel ChemSusChem, Vol. 7, Issue 10 https://doi.org/10.1002/cssc.201402456	journal	August 2014
Mo-Doped BiVO ₄ Photoanodes Synthesized by Reactive Sputtering Chen, Le; Toma, Francesca M.; Cooper, Jason K. ChemSusChem, Vol. 8, Issue 6 https://doi.org/10.1002/cssc.201402984	journal	February 2015
From Molecules to Materials: Pathways to Artificial Photosynthesis Rozhkova, Elena A.; Ariga, Katsuhiko https://doi.org/10.1007/978-3-319-13800-8	book	January 2015
Solar to Chemical Energy Conversion Sugiyama, Masakazu; Fujii, Katsushi; Nakamura, Shinichiro Lecture Notes in Energy https://doi.org/10.1007/978-3-319-25400-5	book	January 2016
Splitting water with semiconducting photoelectrodes—Efficiency considerations Weber, M.; Dignam, M. International Journal of Hydrogen Energy, Vol. 11, Issue 4 https://doi.org/10.1016/0360-3199(86)90183-7	journal	January 1986
Enhanced photoelectrochemical performance of plate-like WO 3 induced by surface oxygen vacancies Liu, Yang; Li, Jie; Tang, Hui Electrochemistry Communications, Vol. 68 https://doi.org/10.1016/j.elecom.2016.05.004	journal	July 2016
Electrochemical Doping Induced In Situ Homo-species for Enhanced Photoelectrochemical Performance on WO3 Nanoparticles Film Photoelectrodes Liu, Yang; Li, Jie; Li, Wenzhang Electrochimica Acta, Vol. 210 https://doi.org/10.1016/j.electacta.2016.05.165	journal	August 2016
A brief review of atomic layer deposition: from fundamentals to applications Johnson, Richard W.; Hultqvist, Adam; Bent, Stacey F. Materials Today, Vol. 17, Issue 5 https://doi.org/10.1016/j.mattod.2014.04.026	journal	June 2014
Thin-Film Materials for the Protection of Semiconducting Photoelectrodes in Solar-Fuel Generators Hu, Shu; Lewis, Nathan S.; Ager, Joel W. The Journal of Physical Chemistry C, Vol. 119, Issue 43 https://doi.org/10.1021/acs.jpcc.5b05976	journal	October 2015
Origin of the Different Photoelectrochemical Performance of Mesoporous BiVO ₄ Photoanodes between the BiVO ₄ and the FTO Side Illumination Xiao, Shuang; Chen, Haining; Yang, Zhengshi The Journal of Physical Chemistry C, Vol. 119, Issue 41 https://doi.org/10.1021/acs.jpcc.5b07505	journal	October 2015
Atomic Insight into the W-Doping Effect on Carrier Dynamics and Photoelectrochemical Properties of BiVO ₄ Photoanodes Pattengale, Brian; Ludwig, John; Huang, Jier The Journal of Physical Chemistry C, Vol. 120, Issue 3 https://doi.org/10.1021/acs.jpcc.5b11451	journal	January 2016
Improving Stability and Photoelectrochemical Performance of BiVO ₄ Photoanodes in Basic Media by Adding a ZnFe ₂ O ₄ Layer Kim, Tae Woo; Choi, Kyoung-Shin The Journal of Physical Chemistry Letters, Vol. 7, Issue 3 https://doi.org/10.1021/acs.jpclett.5b02774	journal	January 2016
Electronic Structure of Monoclinic BiVO ₄ Cooper, Jason K.; Gul, Sheraz; Toma, Francesca M. Chemistry of Materials, Vol. 26, Issue 18 https://doi.org/10.1021/cm5025074	journal	September 2014
Solar Water Splitting Cells Walter, Michael G.; Warren, Emily L.; McKone, James R. Chemical Reviews, Vol. 110, Issue 11, p. 6446-6473 https://doi.org/10.1021/cr1002326	journal	November 2010
Band Bending in Semiconductors: Chemical and Physical Consequences at Surfaces and Interfaces Zhang, Zhen; Yates, John T. Chemical Reviews, Vol. 112, Issue 10 https://doi.org/10.1021/cr3000626	journal	June 2012
Atomic Layer Deposition: An Overview George, Steven M. Chemical Reviews, Vol. 110, Issue 1, p. 111-131 https://doi.org/10.1021/cr900056b	journal	January 2010
Structure and Valency of a Cobalt−Phosphate Water Oxidation Catalyst Determined by in Situ X-ray Spectroscopy Kanan, Matthew W.; Yano, Junko; Surendranath, Yogesh Journal of the American Chemical Society, Vol. 132, Issue 39 https://doi.org/10.1021/ja1023767	journal	October 2010
Near-Complete Suppression of Surface Recombination in Solar Photoelectrolysis by “Co-Pi” Catalyst-Modified W:BiVO ₄ Zhong, Diane K.; Choi, Sujung; Gamelin, Daniel R. Journal of the American Chemical Society, Vol. 133, Issue 45 https://doi.org/10.1021/ja207348x	journal	November 2011
Efficient and Stable Photo-Oxidation of Water by a Bismuth Vanadate Photoanode Coupled with an Iron Oxyhydroxide Oxygen Evolution Catalyst Seabold, Jason A.; Choi, Kyoung-Shin Journal of the American Chemical Society, Vol. 134, Issue 4, p. 2186-2192 https://doi.org/10.1021/ja209001d	journal	January 2012
Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction McCrory, Charles C. L.; Jung, Suho; Peters, Jonas C. Journal of the American Chemical Society, Vol. 135, Issue 45 https://doi.org/10.1021/ja407115p	journal	October 2013
Efficient and Sustained Photoelectrochemical Water Oxidation by Cobalt Oxide/Silicon Photoanodes with Nanotextured Interfaces Yang, Jinhui; Walczak, Karl; Anzenberg, Eitan Journal of the American Chemical Society, Vol. 136, Issue 17 https://doi.org/10.1021/ja501513t	journal	April 2014
Benchmarking Hydrogen Evolving Reaction and Oxygen Evolving Reaction Electrocatalysts for Solar Water Splitting Devices McCrory, Charles C. L.; Jung, Suho; Ferrer, Ivonne M. Journal of the American Chemical Society, Vol. 137, Issue 13 https://doi.org/10.1021/ja510442p	journal	March 2015
Surface Modification of CoO _x Loaded BiVO ₄ Photoanodes with Ultrathin p -Type NiO Layers for Improved Solar Water Oxidation Zhong, Miao; Hisatomi, Takashi; Kuang, Yongbo Journal of the American Chemical Society, Vol. 137, Issue 15 https://doi.org/10.1021/jacs.5b00256	journal	April 2015
Enhanced Surface Reaction Kinetics and Charge Separation of p–n Heterojunction Co ₃ O ₄ /BiVO ₄ Photoanodes Chang, Xiaoxia; Wang, Tuo; Zhang, Peng Journal of the American Chemical Society, Vol. 137, Issue 26 https://doi.org/10.1021/jacs.5b04186	journal	June 2015
In Operando Identification of Geometrical-Site-Dependent Water Oxidation Activity of Spinel Co ₃ O ₄ Wang, Hsin-Yi; Hung, Sung-Fu; Chen, Han-Yi Journal of the American Chemical Society, Vol. 138, Issue 1 https://doi.org/10.1021/jacs.5b10525	journal	December 2015
In Situ X-ray Fluorescence Measurements During Atomic Layer Deposition: Nucleation and Growth of TiO ₂ on Planar Substrates and in Nanoporous Films Dendooven, Jolien; Pulinthanathu Sree, Sreeprasanth; De Keyser, Koen The Journal of Physical Chemistry C, Vol. 115, Issue 14 https://doi.org/10.1021/jp111314b	journal	March 2011
The Oxidation of Cobalt Nanoparticles into Kirkendall-Hollowed CoO and Co ₃ O ₄ : The Diffusion Mechanisms and Atomic Structural Transformations Ha, Don-Hyung; Moreau, Liane M.; Honrao, Shreyas The Journal of Physical Chemistry C, Vol. 117, Issue 27 https://doi.org/10.1021/jp402939e	journal	June 2013
Photoelectrochemical Tandem Cells for Solar Water Splitting Prévot, Mathieu S.; Sivula, Kevin The Journal of Physical Chemistry C, Vol. 117, Issue 35 https://doi.org/10.1021/jp405291g	journal	July 2013
Metal Oxide Photoelectrodes for Solar Fuel Production, Surface Traps, and Catalysis Sivula, Kevin The Journal of Physical Chemistry Letters, Vol. 4, Issue 10 https://doi.org/10.1021/jz4002983	journal	April 2013
Enhanced Stability and Activity for Water Oxidation in Alkaline Media with Bismuth Vanadate Photoelectrodes Modified with a Cobalt Oxide Catalytic Layer Produced by Atomic Layer Deposition Lichterman, Michael F.; Shaner, Matthew R.; Handler, Sheila G. The Journal of Physical Chemistry Letters, Vol. 4, Issue 23 https://doi.org/10.1021/jz4022415	journal	November 2013
Semiconducting materials for photoelectrochemical energy conversion Sivula, Kevin; van de Krol, Roel Nature Reviews Materials, Vol. 1, Issue 2 https://doi.org/10.1038/natrevmats.2015.10	journal	January 2016
Efficient solar water splitting by enhanced charge separation in a bismuth vanadate-silicon tandem photoelectrode Abdi, Fatwa F.; Han, Lihao; Smets, Arno H. M. Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3195	journal	July 2013
Covalency-reinforced oxygen evolution reaction catalyst Yagi, Shunsuke; Yamada, Ikuya; Tsukasaki, Hirofumi Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9249	journal	September 2015
Reversible amorphization and the catalytically active state of crystalline Co3O4 during oxygen evolution Bergmann, Arno; Martinez-Moreno, Elias; Teschner, Detre Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9625	journal	October 2015
Simultaneous enhancements in photon absorption and charge transport of bismuth vanadate photoanodes for solar water splitting Kim, Tae Woo; Ping, Yuan; Galli, Giulia A. Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9769	journal	October 2015
Universal energy-level alignment of molecules on metal oxides Greiner, Mark T.; Helander, Michael G.; Tang, Wing-Man Nature Materials, Vol. 11, Issue 1 https://doi.org/10.1038/nmat3159	journal	November 2011
Efficient solar water-splitting using a nanocrystalline CoO photocatalyst Liao, Longb; Zhang, Qiuhui; Su, Zhihua Nature Nanotechnology, Vol. 9, Issue 1 https://doi.org/10.1038/nnano.2013.272	journal	December 2013
Artificial photosynthesis for solar water-splitting Tachibana, Yasuhiro; Vayssieres, Lionel; Durrant, James R. Nature Photonics, Vol. 6, Issue 8 https://doi.org/10.1038/nphoton.2012.175	journal	July 2012
Progress in bismuth vanadate photoanodes for use in solar water oxidation Park, Yiseul; McDonald, Kenneth J.; Choi, Kyoung-Shin Chem. Soc. Rev., Vol. 42, Issue 6, p. 2321-2337 https://doi.org/10.1039/C2CS35260E	journal	January 2013
Sunlight absorption in water – efficiency and design implications for photoelectrochemical devices Döscher, H.; Geisz, J. F.; Deutsch, T. G. Energy Environ. Sci., Vol. 7, Issue 9 https://doi.org/10.1039/C4EE01753F	journal	January 2014
A general framework for the assessment of solar fuel technologies Herron, Jeffrey A.; Kim, Jiyong; Upadhye, Aniruddha A. Energy & Environmental Science, Vol. 8, Issue 1 https://doi.org/10.1039/C4EE01958J	journal	January 2015
A taxonomy for solar fuels generators Nielander, Adam C.; Shaner, Matthew R.; Papadantonakis, Kimberly M. Energy & Environmental Science, Vol. 8, Issue 1 https://doi.org/10.1039/C4EE02251C	journal	January 2015
Experimental demonstrations of spontaneous, solar-driven photoelectrochemical water splitting Ager, Joel W.; Shaner, Matthew R.; Walczak, Karl A. Energy & Environmental Science, Vol. 8, Issue 10 https://doi.org/10.1039/C5EE00457H	journal	January 2015
Photoelectrochemical water splitting Miller, E. L. Energy & Environmental Science, Vol. 8, Issue 10 https://doi.org/10.1039/C5EE90047F	journal	January 2015
Solar hydrogen generation from seawater with a modified BiVO4 photoanode Luo, Wenjun; Yang, Zaisan; Li, Zhaosheng Energy & Environmental Science, Vol. 4, Issue 10 https://doi.org/10.1039/c1ee01812d	journal	January 2011
Cobalt-phosphate (Co-Pi) catalyst modified Mo-doped BiVO4 photoelectrodes for solar water oxidation Pilli, Satyananda Kishore; Furtak, Thomas E.; Brown, Logan D. Energy & Environmental Science, Vol. 4, Issue 12 https://doi.org/10.1039/c1ee02444b	journal	January 2011
A new electrochemical synthesis route for a BiOI electrode and its conversion to a highly efficient porous BiVO₄ photoanode for solar water oxidation McDonald, Kenneth J.; Choi, Kyoung-Shin Energy & Environmental Science, Vol. 5, Issue 9, p. 8553-8557 https://doi.org/10.1039/c2ee22608a	journal	January 2012
Co3O4 quantum dots: reverse micelle synthesis and visible-light-driven photocatalytic overall water splitting Zhang, Ning; Shi, Jinwen; Mao, Samuel S. Chemical Communications, Vol. 50, Issue 16 https://doi.org/10.1039/c3cc48026g	journal	January 2014
Energy and environment policy case for a global project on artificial photosynthesis Faunce, Thomas A.; Lubitz, Wolfgang; Rutherford, A. W. (Bill) Energy & Environmental Science, Vol. 6, Issue 3 https://doi.org/10.1039/c3ee00063j	journal	January 2013
An analysis of the optimal band gaps of light absorbers in integrated tandem photoelectrochemical water-splitting systems Hu, Shu; Xiang, Chengxiang; Haussener, Sophia Energy & Environmental Science, Vol. 6, Issue 10 https://doi.org/10.1039/c3ee40453f	journal	January 2013
TiO ₂ /CdSe core–shell nanofiber film for photoelectrochemical hydrogen generation Liu, Ya; Zhao, Liang; Li, Mingtao Nanoscale, Vol. 6, Issue 13 https://doi.org/10.1039/c4nr00856a	journal	January 2014
Dynamics of photogenerated holes in surface modified -Fe2O3 photoanodes for solar water splitting Barroso, M.; Mesa, C. A.; Pendlebury, S. R. Proceedings of the National Academy of Sciences, Vol. 109, Issue 39 https://doi.org/10.1073/pnas.1118326109	journal	July 2012
Facile fabrication of an efficient BiVO4 thin film electrode for water splitting under visible light irradiation Jia, Q.; Iwashina, K.; Kudo, A. Proceedings of the National Academy of Sciences, Vol. 109, Issue 29 https://doi.org/10.1073/pnas.1204623109	journal	June 2012
Depth-profiling X-ray photoelectron spectroscopy (XPS) analysis of interlayer diffusion in polyelectrolyte multilayers Gilbert, J. B.; Rubner, M. F.; Cohen, R. E. Proceedings of the National Academy of Sciences, Vol. 110, Issue 17 https://doi.org/10.1073/pnas.1222325110	journal	April 2013
Electronic structure and bonding properties of cobalt oxide in the spinel structure Chen, Jia; Wu, Xifan; Selloni, Annabella Physical Review B, Vol. 83, Issue 24 https://doi.org/10.1103/PhysRevB.83.245204	journal	June 2011
Charge Carrier Separation in Solar Cells Wurfel, Uli; Cuevas, Andres; Wurfel, Peter IEEE Journal of Photovoltaics, Vol. 5, Issue 1 https://doi.org/10.1109/JPHOTOV.2014.2363550	journal	January 2015
In Situ Formation of an Oxygen-Evolving Catalyst in Neutral Water Containing Phosphate and Co²⁺ Kanan, M. W.; Nocera, D. G. Science, Vol. 321, Issue 5892, p. 1072-1075 https://doi.org/10.1126/science.1162018	journal	August 2008
A Perovskite Oxide Optimized for Oxygen Evolution Catalysis from Molecular Orbital Principles Suntivich, J.; May, K. J.; Gasteiger, H. A. Science, Vol. 334, Issue 6061 https://doi.org/10.1126/science.1212858	journal	October 2011
Nanoporous BiVO₄ Photoanodes with Dual-Layer Oxygen Evolution Catalysts for Solar Water Splitting Kim, Tae Woo; Choi, Kyoung-Shin Science, Vol. 343, Issue 6174, p. 990-994 https://doi.org/10.1126/science.1246913	journal	February 2014
Amorphous TiO2 coatings stabilize Si, GaAs, and GaP photoanodes for efficient water oxidation Hu, S.; Shaner, M. R.; Beardslee, J. A. Science, Vol. 344, Issue 6187 https://doi.org/10.1126/science.1251428	journal	May 2014
The Photochemistry of the Future Ciamician, G. Science, Vol. 36, Issue 926 https://doi.org/10.1126/science.36.926.385	journal	September 1912

Cited By (11)

New Iron-Cobalt Oxide Catalysts Promoting BiVO ₄ Films for Photoelectrochemical Water Splitting Wang, Songcan; He, Tianwei; Yun, Jung-Ho Advanced Functional Materials, Vol. 28, Issue 34 https://doi.org/10.1002/adfm.201802685	journal	June 2018
Strategies for Semiconductor/Electrocatalyst Coupling toward Solar‐Driven Water Splitting Thalluri, Sitaramanjaneya Mouli; Bai, Lichen; Lv, Cuncai Advanced Science, Vol. 7, Issue 6 https://doi.org/10.1002/advs.201902102	journal	March 2020
Electrodeposition of Cobalt Phosphosulfide Nanosheets on Carbon Fiber Paper as Efficient Electrocatalyst for Oxygen Evolution Liu, Zhenchuan; Zhang, Junfeng; Liu, Yangxing ChemElectroChem, Vol. 5, Issue 13 https://doi.org/10.1002/celc.201800384	journal	May 2018
Understanding the Roles of NiO _x in Enhancing the Photoelectrochemical Performance of BiVO ₄ Photoanodes for Solar Water Splitting Zhang, Mengyuan; Antony, Rajini P.; Chiam, Sing Yang ChemSusChem, Vol. 12, Issue 9 https://doi.org/10.1002/cssc.201801780	journal	October 2018
Photoelectrochemical Performance of BiVO ₄ Photoanodes Integrated with [NiFe]-Layered Double Hydroxide Nanocatalysts: Photoelectrochemical Performance of BiVO ₄ Photoanodes Integrated with [NiFe]-Layered Double Hydroxide Nanocatalysts Sinclair, Timothy S.; Gray, Harry B.; Müller, Astrid M. European Journal of Inorganic Chemistry, Vol. 2018, Issue 9 https://doi.org/10.1002/ejic.201701231	journal	December 2017
Photoelectrochemical Performance of BiVO ₄ Photoanodes Integrated with [NiFe]‐Layered Double Hydroxide Nanocatalysts Sinclair, Timothy S.; Gray, Harry B.; Müller, Astrid M. European Journal of Inorganic Chemistry, Vol. 2018, Issue 9 https://doi.org/10.1002/ejic.201800083	journal	January 2018
Interface engineering of 3D BiVO ₄ /Fe-based layered double hydroxide core/shell nanostructures for boosting photoelectrochemical water oxidation Zhu, Yukun; Ren, Jun; Yang, Xianfeng Journal of Materials Chemistry A, Vol. 5, Issue 20 https://doi.org/10.1039/c7ta02179h	journal	January 2017
Ni-Doped CuS as an efficient electrocatalyst for the oxygen evolution reaction Kundu, Joyjit; Khilari, Santimoy; Bhunia, Kousik Catalysis Science & Technology, Vol. 9, Issue 2 https://doi.org/10.1039/c8cy02181c	journal	January 2019
Ultrathin Fe-NiO nanosheets as catalytic charge reservoirs for a planar Mo-doped BiVO ₄ photoanode Li, Lei; Yang, Xiaogang; Lei, Yan Chemical Science, Vol. 9, Issue 47 https://doi.org/10.1039/c8sc03297a	journal	January 2018
The synergistic effect of cation mixing in mesoporous Bi _x Fe _1−x VO ₄ heterojunction photoanodes for solar water splitting Zhang, Mengyuan; Pham, Huu Khue; Fang, Yanan Journal of Materials Chemistry A, Vol. 7, Issue 24 https://doi.org/10.1039/c9ta01791g	journal	January 2019
Surface- and interface-engineered heterostructures for solar hydrogen generation Chen, Xiangyan; Li, Yanrui; Shen, Shaohua Journal of Physics D: Applied Physics, Vol. 51, Issue 16 https://doi.org/10.1088/1361-6463/aab318	journal	March 2018

Similar Records

BiVO{sub 4} photoanodes for water splitting with high injection efficiency, deposited by reactive magnetron co-sputtering

Journal Article · Fri Apr 15 00:00:00 EDT 2016 · AIP Advances · OSTI ID:22611655

Gong, Haibo; Freudenberg, Norman; Nie, Man; +2 more

Effective Corrosion-Resistant Single-Atom Alloy Catalyst on HfO₂-Passivated BiVO₄ Photoanode for Durable (≈800 h) Solar Water Oxidation

Journal Article · Fri Sep 13 00:00:00 EDT 2024 · Advanced Energy Materials · OSTI ID:2447843

Arunachalam, Maheswari; Lee, Kug‐Seung; Zhu, Kai; +1 more

The significance of the local structure of cobalt-based catalysts on the photoelectrochemical water oxidation activity of BiVO₄

Journal Article · Wed Nov 11 23:00:00 EST 2020 · Electrochimica Acta · OSTI ID:1767446

Barzgar Vishlaghi, Mahsa; Kahraman, Abdullah; Apaydin, Sinem; +7 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Title: Undoped and Ni-doped CoOx surface modification of porous BiVO4 photoelectrodes for water oxidation

Citation Formats

References (63)

Cited By (11)

Similar Records

Related Subjects

Title: Undoped and Ni-doped CoO_x surface modification of porous BiVO₄ photoelectrodes for water oxidation